Search NASA⌕ Search

SEARCH · Search NASA

Results for “hazardous materials”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17

A Survey of the Rapidly Emerging Field of Nanotechnology: Potential Applications for Scientific Instruments and Technologies for Atmospheric Entry Probes

The field of Nanotechnology is well funded worldwide and innovations applicable to Solar System Exploration are emerging much more rapidly than thought possible just a few years ago. This presentation will survey recent innovations from nanotechnololgy with a focus on novel applications to atmospheric entry science and probe technology, in a fashion similar to that presented by Arnold and Venkatapathy at the previous workshop forum at Lisbon Portugal, October 6-9, 2003. Nanotechnology is a rapidly emerging field that builds systems, devices and materials from the bottom up, atom by atom, and in so doing provides them with novel and remarkable macro-scale performance. This technology has the potential to revolutionize space exploration by reducing mass and simultaneously increasing capability. Thermal, Radiation, Impact Protective Shields: Atmospheric probes and humans on long duration deep space missions involved in Solar System Exploration must safely endure 3 significant hazards: (i) atmospheric entry; (ii) radiation; and (iii) micrometeorite or debris impact. Nanostructured materials could be developed to address all three hazards with a single protective shield, which would involve much less mass than a traditional approach. The concept can be ready in time for incorporation into NASA s Crew Exploration Vehicle, and possible entry probes to fly on the Jupiter Icy Moons

Meyyappan, M.↗

Neutrons in Space: Shield Models and Design Issues

The normal working and living areas of the astronaut are designed to provide an acceptable level of protection against the hazards of ionizing space radiation. Attempts to reduce the exposures require intervening shield materials to reduce the transmitted radiation. An unwelcome side effect of the shielding is the production of neutrons, which are themselves dangerous particles that can be (but are not always) more hazardous than the particles that produced them. This is especially true depending on the choice of shield materials. Although neutrons are not a normal part of the space environment, this paper focuses on them as principle component of astronaut exposure in the massive spacecraft's required for human space travel and habitation near planetary surfaces or other large bodies of material in space.

Wilson, J. W.↗

Integration of Advanced Structures and Materials Technologies for a Robust Lunar Habitat

NASA’s Artemis program plans to have a sustainable lunar base deployed on the Moon by 2028. The base calls for a foundation surface habitat that can support a crew of four members for a minimum mission duration of 28-days. The lack of a magnetic field and significant lunar atmosphere extends the lifetime of secondary radiation emitted from metallic structures, which is a health hazard for exposed astronauts. Integration of non-metallic structural materials into surface habitat design may alleviate some of these concerns. Additionally, it is favorable for the structure to be collapsible for transportation to optimize payload volume, mass efficiency, and monetary constraints. As a result, inflatable structures are being investigated due to their improved packing efficiency at launch, optimal mass-to-volume ratio, and large surface area that can efficiently disperse structural loads and heat. Currently, only two inflatable airlocks have been deployed in space. Thus, there is a significant need to advance technologies associated with inflatable structures to provide greater options for future missions, i.e., Artemis and beyond. This study focused on the inflatable lunar habitat applications of emerging NASA Langley Research Center (LaRC) technologies and their required development steps to become space qualified. The Bowling Habitat architecture was generated from 13 of these NASA LaRC technologies, five of which were deemed critical, five determined as enhancing technologies, and three were classified as transformational technologies for the Artemis program. To address the payload constraints, the study also considered a tentative timeline that aligned with the current Artemis schedule for transporting the Bowling Habitat to the Moon. Ultimately, the Bowling Habitat mainly addressed the structural needs of an inflatable lunar habitat, meaning that major areas pertaining to the life-style aspects of the habitat must be improved. Areas include, but are not limited to, hard connection points, the monitoring of human health, and extra radiation protection for solar proton events.

Inflatable Habitat↗

ICME for NASA Aerospace Applications: Batteries for Electric Aviation

NASA’s approach to computational materials modeling is detailed in the NASA Vision 2040 Roadmap for Multiscale Modeling and Simulation of Materials and Systems. This report is in the spirit of national initiatives such as the Material Genome Initiative (MGI), Integrated Computational Materials Engineering (ICME), and others. We utilize a combination of fundamental modeling, computational high-throughput screening, and data science methods, e.g., machine learning, are used to find innovative solutions to NASA or national technology challenges. Applications of interest are wide ranging from advanced alloys to batteries to coatings, among others. In this talk, we present three examples for recent work related to NASA applications. First, doping advanced sulfur battery cathodes with selenium boosts electrical conductivity important for electric aircraft applications. First principles calculations will be discussed that result in compositional design maps for these materials. Second, development of icephobic coatings is important to mitigate safety hazards associated with icing for aircraft. Molecular dynamics simulations are reported for ice-surface interfaces to understand adhesion mechanisms and help screen optimal ice-phobic coatings. Third, shape memory alloys have numerous applications as actuators, superelastic materials, etc. for aerospace. We report machine learning models that predict martensitic transition temperatures across a broad swath of compositional space.

John Lawson↗

Mars Sample Handling and Requirements Panel (MSHARP)

In anticipation of the return of samples from Mars toward the end of the first decade of the next century, NASA's Office of Space Sciences chartered a panel to examine how Mars samples should be handled. The panel was to make recommendations in three areas: (1) sample collection and transport back to Earth; (2) certification of the samples as nonhazardous; and (3) sample receiving, curation, and distribution. This report summarizes the findings of that panel. The samples should be treated as hazardous until proven otherwise. They are to be sealed within a canister on Mars, and the canister is not to be opened until within a Biosafety Hazard Level 4 (BSL-4) containment facility here on Earth. This facility must also meet or exceed the cleanliness requirements of the Johnson Space Center (JSC) facility for curation of extraterrestrial materials. A containment facility meeting both these requirements does not yet exist. Hazard assessment and life detection experiments are to be done at the containment facility, while geochemical characterization is being performed on a sterilized subset of the samples released to the science community. When and if the samples are proven harmless, they are to be transferred to a curation facility, such as that at JSC.

Carr, Michael H.↗

Guide for Oxygen Compatibility Assessments on Oxygen Components and Systems

Understanding and preventing fire hazards is necessary when designing, maintaining, and operating oxygen systems. Ignition risks can be minimized by controlling heat sources and using materials that will not ignite or will not support burning in the end-use environment. Because certain materials are more susceptible to ignition in oxygen-enriched environments, a compatibility assessment should be performed before the component is introduced into an oxygen system. This document provides an overview of oxygen fire hazards and procedures that are consistent with the latest versions of American Society for Testing and Materials (ASTM) Standards G63 (1999) and G94 (2005) to address fire hazards associated with oxygen systems. This document supersedes the previous edition, NASA Technical Memorandum 104823, Guide for Oxygen Hazards Analyses on Components and Systems (1996). The step-by-step oxygen compatibility assessment method described herein (see Section 4) enables oxygen-system designers, system engineers, and facility managers to determine areas of concern with respect to oxygen compatibility and, ultimately, prevent damage to a system or injury to personnel.

Rosales, Keisa R.↗

Mars Sample Handling Protocol Workshop Series: Workshop 2

Numerous NASA reports and studies have identified Planetary Protection (PP) as an important part of any Mars sample return mission. The mission architecture, hardware, on-board experiments, and related activities must be designed in ways that prevent both forward- and back-contamination and also ensure maximal return of scientific information. A key element of any PP effort for sample return missions is the development of guidelines for containment and analysis of returned sample(s). As part of that effort, NASA and the Space Studies Board (SSB) of the National Research Council (NRC) have each assembled experts from a wide range of scientific fields to identify and discuss issues pertinent to sample return. In 1997, the SSB released its report on recommendations for handling and testing of returned Mars samples. In particular, the NRC recommended that: a) samples returned from Mars by spacecraft should be contained and treated as potentially hazardous until proven otherwise, and b) rigorous physical, chemical, and biological analyses [should] confirm that there is no indication of the presence of any exogenous biological entity. Also in 1997, a Mars Sample Quarantine Protocol workshop was convened at NASA Ames Research Center to deal with three specific aspects of the initial handling of a returned Mars sample: 1) biocontainment, to prevent 'uncontrolled release' of sample material into the terrestrial environment; 2) life detection, to examine the sample for evidence of organisms; and 3) biohazard testing, to determine if the sample poses any threat to terrestrial life forms and the Earth's biosphere. In 1999, a study by NASA's Mars Sample Handling and Requirements Panel (MSHARP) addressed three other specific areas in anticipation of returning samples from Mars: 1) sample collection and transport back to Earth; 2) certification of the samples as non-hazardous; and 3) sample receiving, curation, and distribution. To further refine the requirements for sample hazard testing and the criteria for subsequent release of sample materials from quarantine, the NASA Planetary Protection Officer convened an additional series of workshops beginning in March 2000. The overall objective of these workshops was to develop comprehensive protocols to assess whether the returned materials contain any biological hazards, and to safeguard the purity of the samples from possible terrestrial contamination. This document is the report of the second Workshop in the Series. The information herein will ultimately be integrated into a final document reporting the proceedings of the entire Workshop Series along with additional information and recommendations.

Rummel, John D.↗

Environmentally-driven Materials Obsolescence: Material Replacements and Lessons Learned from NASA's Space Shuttle Program

The Space Shuttle Program was terminated in 2011 with the last flight of the Shuttle Endeavour. During the 30 years of its operating history, the number of domestic and international environmental regulations increased rapidly and resulted in materials obsolescence risks to the program. Initial replacement efforts focused on ozone depleting substances. As pressure from environmental regulations increased, Shuttle worked on the replacement of heavy metals. volatile organic compounds and hazardous air pollutants. Near the end of the program. Shuttle identified potential material obsolescence driven by international regulations and the potential for suppliers to reformulate materials. During the Shuttle Program a team focused on environmentally-driven materials obsolescence worked to identify and mitigate these risks. Lessons learned from the Shuttle experience can be applied to new NASA Programs as well as other high reliability applications.

Meinhold, Anne↗

Hypergolic Propellant Safety Course

Under the sponsorship of the NASA Safety Training Center at the Johnson Space Center, a hypergolic propellant safety course has been developed. This is a 2-day course on guidelines for hypergolic propellant system design, materials selection, operations, storage, and transportation. Recognizing that numerous fuels and oxidizers can be hypergolic, this course is specific to the hydrazine family of fuels and nitrogen tetroxide and its variants. The objectives of the course are to enable the student to identify and evaluate the hazards of hypergolic propellants, and to understand the methods for controlling those hazards and responding to emergencies. The course covers properties and hazards of the hydrazines and oxidizers; design and operations in hypergolic facilities; materials selection for use in hypergol systems; storage vessels, piping, and component considerations; hypergol detection; fire fighting practices; operating and transportation principles and procedures; and emergency practices and considerations. A hazards analysis methodology is presented. Numerous references are provided and the applicability of certain regulatory documents is discussed. A brief overview of other propellants, including hydrogen peroxide, is given at the end of the course.

Rathgeber, Kurt A.↗

Metallized coatings for corrosion control of Naval ship structures and components

In attempting to improve corrosion control, the U.S. Navy has undertaken a program of coating corrosion-susceptible shipboard components with thermally sprayed aluminum. In this report the program is reviewed in depth, including examination of processes, process controls, the nature and properties of the coatings, nondestructive examination, and possible hazards to personnel. The performance of alternative metallic coating materials is also discussed. It is concluded that thermally sprayed aluminum can provide effective long-term protection against corrosion, thereby obviating the need for chipping of rust and repainting by ship personnel. Such coatings are providing excellent protection to below-deck components such as steam valves, but improvements are needed to realize the full potential of coatings for above-deck service. Several recommendations are made regarding processes, materials, and research and development aimed at upgrading further the performance of these coatings.

Source record↗

Light-Flash Wind-Direction Indicator

Proposed wind-direction indicator read easily by distant observers. Indicator emits bright flashes of light separated by interval of time proportional to angle between true north and direction from which wind blowing. Timing of flashes indicates direction of wind. Flashes, from high-intensity stroboscopic lights seen by viewers at distances up to 5 miles or more. Also seen more easily through rain and fog. Indicator self-contained, requiring no connections to other equipment. Power demand satisfied by battery or solar power or both. Set up quickly to provide local surface-wind data for aircraft pilots during landing or hovering, for safety officers establishing hazard zones and safety corridors during handling of toxic materials, for foresters and firefighters conducting controlled burns, and for real-time wind observations during any of variety of wind-sensitive operations.

Zysko, Jan A.↗

A very low shock alternative to conventional, pyrotechnically operated release devices

NiTiNOL is best known for its ability to remember a preset shape, even after being 'plastically' deformed. This is accomplished by heating the material to an elevated temperature up to 120 degrees C. However, NiTiNOL has other material and mechanical properties that provide a novel method of structural release. This combination of properties allows NiTiNOL to be used as a mechanical fuse between structural components. When electrical power is applied to the NiTiNOL fuse(s), the material is annealed reducing the mechanical strength to a small fraction of the as-wrought material. The preload then fractures the weakened NiTiNOL fuse(s) and releases the structure. This paper describes the mechanical characteristics of the NiTiNOL allow used in this invention, structural separation design concepts using the NiTiNOL material, and initial test data. Elimination of the safety hazard, high shock levels, and non-reusability inherent with pyrotechnic separation devices allows NiTiNOL actuated release devices to become a viable alternative for aerospace components and systems.

Robinson, Steven P.↗

Light, plants, and power for life support on Mars

Regardless of how well other growing conditions are optimized, crop yields will be limited by the available light up to saturation irradiances. Considering the various factors of clouds on Earth, dust storms on Mars, thickness of atmosphere, and relative orbits, there is roughly 2/3 as much light averaged annually on Mars as on Earth. On Mars, however, crops must be grown under controlled conditions (greenhouse or growth rooms). Because there presently exists no material that can safely be pressurized, insulated, and resist hazards of puncture and deterioration to create life support systems on Mars while allowing for sufficient natural light penetration as well, artificial light will have to be supplied. If high irradiance is provided for long daily photoperiods, the growing area can be reduced by a factor of 3-4 relative to the most efficient irradiance for cereal crops such as wheat and rice, and perhaps for some other crops. Only a small penalty in required energy will be incurred by such optimization. To obtain maximum yields, crops must be chosen that can utilize high irradiances. Factors that increase ability to convert high light into increased productivity include canopy architecture, high-yield index (harvest index), and long-day or day-neutral flowering and tuberization responses. Prototype life support systems such as Bios-3 in Siberia or the Mars on Earth Project need to be undertaken to test and further refine systems and parameters.

Non-NASA Center↗

Sealing and External Sterilization of a Sample Container

A method of (1) sealing a sample of material acquired in a possibly b iologically contaminated ("dirty") environment into a hermetic conta iner, (2) sterilizing the outer surface of the container, then (3) d elivering the sealed container to a clean environment has been propos ed. The method now proposed was originally intended to be used to ret urn samples from Mars to Earth, but could also be used on Earth to t ransport material samples acquired in environments that contain biol ogical hazards and/or, in some cases, chemical hazards.

Bar-Cohen, Yoseph↗

Overview of the Life Science Glovebox (LSG) Facility and the Research Performed in the LSG

The Life Science Glovebox (LSG) is a rack facility currently under development with a projected availability for International Space Station (ISS) utilization in the FY2018 timeframe. Development of the LSG is being managed by the Marshal Space Flight Center (MSFC) with support from Ames Research Center (ARC) and Johnson Space Center (JSC). The MSFC will continue management of LSG operations, payload integration, and sustaining following delivery to the ISS. The LSG will accommodate life science and technology investigations in a "workbench" type environment. The facility has a.Ii enclosed working volume that is held at a negative pressure with respect to the crew living area. This allows the facility to provide two levels of containment for handling Biohazard Level II and lower biological materials. This containment approach protects the crew from possible hazardous operations that take place inside the LSG work volume. Research investigations operating inside the LSG are provided approximately 15 cubic feet of enclosed work space, 350 watts of28Vdc and l IOVac power (combined), video and data recording, and real time downlink. These capabilities will make the LSG a highly utilized facility on ISS. The LSG will be used for biological studies including rodent research and cell biology. The LSG facility is operated by the Payloads Operations Integration Center at MSFC. Payloads may also operate remotely from different telescience centers located in the United States and different countries. The Investigative Payload Integration Manager (IPIM) is the focal to assist organizations that have payloads operating in the LSG facility. NASA provides an LSG qualification unit for payload developers to verify that their hardware is operating properly before actual operation on the ISS. This poster will provide an overview of the LSG facility and a synopsis of the research that will be accomplished in the LSG. The authors would like to acknowledge Ames Research Center, Johnson Space Center, Teledyne Brown Engineering, MOOG-Bradford Engineering and the entire LSG Team for their inputs into this abstract.

Cole, J. Michael↗

Auto-ignition of hydrazine by engineering materials

Hydrazine, being a monopropellant, can explode and/or detonate in contact with some materials. This has been generally recognized and minimized by testing the compatibility of engineering materials with hydrazine at ambient temperature. Very limited tests have been done at elevated temperatures. To assess the potential hazard of hydrazine leakage into a propulsion compartment (boattail), autoignition characteristics of hydrazine were tested on 18 engineering materials and coatings at temperatures of 120 C to over 330 C. Furthermore, since hydrazine can decompose violently in nitrogen or helium, common purging cannot assure safety. Therefore tests were also made in nitrogen. Detonations occurred on contact with five materials in air. Similar tests in nitrogen did not lead to ignition.

Perkins, J. H.↗

Materials Degradation in the Jovian Radiation Environment

The radiation environment of Jupiter represents a significant hazard for Europa Lander deorbit stage components, and presents a significant potential mission risk. The radiolytic degradation of ammonium perchlorate (AP) oxidizer in solid propellants may affect its properties and performance. The Monte Carlo code MONSOL was used for modeling of laboratory experiments on the electron irradiation of propellant samples. An approach for flattening dose profiles along the depth of irradiated samples is proposed. Depth-dose distributions produced by Jovian electrons in multi-layer slabs of materials are calculated. It is found that the absorbed dose in a particular slab is significantly affected by backscattered electrons and photons from neighboring slabs. The dose and radiolytic decomposition of AP crystals are investigated and radiation-induced chemical yields and weight percent of radical products are reported.

Miloshevsky, Gennady↗