Instrumentation for hydrogen slush storage containers
Hydrogen liquid and slush tank continuous inventory during ground storage
Collier, R. S.↗
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Correlation of hydrogen evolution with surface blistering in proton-irradiated aluminum
Hydrogen outgassing from proton irradiated aluminum samples, determining gas evolution and blister formation during annealing
Daniels, R. D.↗
A neutral-atmosphere composition experiment for the Atmosphere Explorer-C, -D, and -E.
The neutral-atmosphere composition experiment instrumentation is designed to obtain in-situ measurements of neutral thermosphere composition from Atmosphere Explorer-C, -D, and -E. The system is based on previously flown OGO-6 and San Marco-3 composition instruments. The mass-spectrometer sensor includes a gold-plated thermalizing chamber and ion source, a hyperbolic rod quadrupole analyzer, and an off-axis electron multiplier. Automatic ion-source sensitivity control and pulse-counting techniques provide density measurement capability from approximately 125 to 1000 km altitude. The normal operating mode includes measurement at all masses in the range of 1 to 44 amu, with emphasis on hydrogen, helium, oxygen, nitrogen, and argon.
Pelz, D. T.↗
Emissions of nitrogen oxides from an experimental hydrogen-fueled gas turbine combustor
The effect of operating variables of a hydrogen fueled combustor on exhaust concentrations of total oxides of nitrogen was determined at inlet-air temperature levels up to 810 K, pressure of 414,000N/sa m, and reference velocity of 21.3 m/sec. The combustor, which was originally designed for hydrocarbon fuel produced a NO(x) concentration of 380 ppm with hydrogen at 810 K inlet-air temperature. A reduction in NO(x) of about 30 % was obtained by modification to a lean or rich primary zone. The lowest NO(x) levels obtained with hydrogen were equivalent to those of the reference combustor burning hydrocarbon fuels.
Norgren, C. T.↗
Hydrogen technology survey: Thermophysical properties
The thermodynamic functions, transport properties, and physical properties of both liquid and gaseous hydrogen are presented. The low temperature regime is emphasized. The tabulation of the properties of normal hydrogen in both Si and engineering units is given along with the tabulation of parahydrogen.
Mccarty, R. D.↗
Jupiter: Its infrared spectrum from 10 to 40 microns
Spectral measurements of the thermal radiation from Jupiter in the 16-40 micrometer band were analyzed under the assumption that pressure broadened H2 transitions are responsible for the bulk of the infrared opacity over most of this spectral interval. Both the vertical pressure-temperature profile and the hydrogen mixing ratio were determined. The derived value of the molecular hydrogen mixing ratio, 0.89 + or - 0.11, is consistent with the solar value, 0.86.
Houck, J. R.↗
SAS-2 galactic gamma-ray results. 1: Diffuse emission
Continuing analysis of the data from the SAS-2 high energy gamma ray experiment has produced an improved picture of the sky at photon energies above 35 MeV. On a large scale, the diffuse emission from the galactic plane is the dominant feature observed by SAS-2. This galactic plane emission is most intense between galactic longitudes 310 deg and 45 deg, corresponding to a region within 7 kpc of the galactic center. Within the high-intensity region, SAS-2 observes peaks around galactic longitudes 315, 330, 345, 0, and 35 deg. These peaks appear to be correlated with galactic features and components such as molecular hydrogen, atomic hydrogen, magnetic fields, cosmic-ray concentrations, and photon fields.
Thompson, D. J.↗
The X-ray spectrum of 3C 273
An X-ray spectral measurement of the quasar 3C 273 with the HEAO-A2 experiment in June/July 1978 is reported. The best power law fit to the photon flux over the range 2-60 keV gives a slope of 1.41 + or - 0.02. However, structure is observed, indicating a slope of 1.52 between 2 keV and 9 keV and a slight flattening between 9 keV and 30 keV. Observations with the same experiment in December 1977 and OSO-8 in June 1976 allows confirmation of 40% intensity variability on the time scale of months, although within limits provided by the poorer statistical quality of the additional data no spectral change is discerned. Absorption from the source is found to be low, with the 1978 data yielding a 90% confidence upper limit to the hydrogen column density of 4.5 x 10 to the 21st power atoms/sq cm.
Worrall, D. M.↗
Reduced hydrogen permeability at high temperatures
CO and CO2 reduce hydrogen loss through iron, nickel, and cobalt based alloy tubes. Method is based on concept that oxide film on metal surface reduces hydrogen permeability through metal; adding CO or CO2 forms oxide films continuously during operation, and hydrogen containment is improved. Innovation enhances prospects for Stirling engine system utilization.
Stephens, J. R.↗
Implications of the comparison of ozone abundances measured by the Solar Mesosphere Explorer to model calculations
Two years of ozone measurements from the Solar Mesosphere Explorer satellite are compared to the results of a model of lower mesospheric photochemistry. The measured ozone mixing ratios are larger than those predicted by the model by as much as a factor of two at pressures near 0.1 mbar and 1.3 at 1.0 mbar using currently accepted reaction rate coefficients. The model is brought into good agreement with the measurements over a wide range of latitudes and solar zenith angles only if the efficiency of the odd hydrogen catalytic cycle which destroys odd oxygen is decreased by 30-50 percent.
Rusch, D. W.↗
The molecular content of the nearby galaxy from IRAS and HI observations
Because infrared emission is a very good tracer of mass at high latitudes, by combining it with HI observations it provides a convenient though indirect way of observing the spatial distribution of molecular material. Moreover, these observations will premit placing limits on the fraction of total infrared luminosity emitted by dust associated with molecular and atomic hydrogen clouds. A preliminary result from the study of the correlation between HI column density and 100 micron infrared flux density as measured by the IRAS satellite is reported. The ratio F100/W(HI) = R has an average value of roughty 17 KJy/sr/(K km/s) over the whole sky. Bright regions in the FIR such as the Galactic plane and HII regions are excluded from the data. The histogram of the number of pixels vs R has a strong peak near 17 (same units as before) and is asymmetric about this mean value, having a tail at higher values of R. This basic shape is fairly independent of the region of the sky we observe. The peak confirms the general correlation between infrared emission and HI column density reported previously. One way to explain the shape of the distribution is to assume a constant dust to gas mass ratio and a constant interstellar radiation field and associate points in the tail with molecular clouds. In this case the ratio R is higher for points in the tail because it does not account for the column density of molecular hydrogen.
Bazell, D.↗
High-temperature oxidation/corrosion of iron-based superalloys
The oxidation and sulfidation of several novel iron-base superalloys were evaluated in high-temperature cyclic tests. The experimental austenitic alloys examined were modifications of NASAUT-4GA which were developed for Stirling-engine application. The weight gains and resulting surface scales were measured and analyzed. Mixed oxide scales were found to form on all specimens exposed above 871 C. The build-up of these scales led to a depletion of Mn and Cr in a zone adjacent to the oxides. In addition, the initial oxidation of the Fe-rich alloy was inhibited by a thin but tenacious Si layer which formed at the interface between oxides and the parent layer. Sulfidation tests using Na2SO4 coatings resulted in the formation of a protective spinel and alpha-Fe2O3 phases. Preferential attack of the carbide phase by hydrogen was not observed after 350 h at 871 C.
Lemkey, F. D.↗
Energy storage considerations for a robotic Mars surface sampler
The characteristics of various energy storage systems (including Ni-Cd, Ni-H2, Ag-Zn, Li-XS, Na-S, PbSO4, and regenerative fuel cell systems) considered for a robotic Mars surface sampler are reviewed. It is concluded that the bipolar nickel-hydrogen battery and the sodium-sulfur battery are both viable candidates as storage systems for the rover's Radioisotope Thermoelectric Generator. For a photovoltaic storage system, the regenerative fuel cell and the bipolar nickel-hydrogen battery are the primary candidates.
O'Donnell, P. M.↗
Development of an analytical model to assess fuel property effects on combustor performance
A generalized first-order computer model has been developed in order to analytically evaluate the potential effect of alternative fuels' effects on gas turbine combustors. The model assesses the size, configuration, combustion reliability, and durability of the combustors required to meet performance and emission standards while operating on a broad range of fuels. Predictions predicated on combustor flow-field determinations by the model indicate that fuel chemistry, as defined by hydrogen content, exerts a significant influence on flame retardation, liner wall temperature, and smoke emission.
Sutton, R. D.↗
Nuclear Safety [Vol. 34, No. 1, January-March 1993]
Nuclear Safety is a review journal that covers significant developments in the field of nuclear safety. Its scope includes the analysis and control of hazards associated with nuclear energy, operations involving fissionable materials, and the products of nuclear fission and their effects on the environment. Primary emphasis is on safety in reactor design, construction, and operation; however, the safety aspects of the entire fuel cycle, including fuel fabrication, spent-fuel processing, nuclear waste disposal, handling of radioisotopes, and environmental effects of these operations, are also treated. Table of Contents for this issue follows. GENERAL SAFETY CONSIDERATIONS: 1 An Integrated Regional Approach To Risk Management of Industrial Systems, S. Chakraborty and R. Stratton; 9 Annual Technical Meeting of the NRC Cooperative Severe Accident Research Program, E. G. Silver; ACCIDENT ANALYSIS: 13 Deterministic Severe Accident Criteria as Severe Accident Design Criteria and Policy for the New Production Reactor-Heavy Water Reactor, P. T. Rhoads; 20 Proposed Deterministic Severe Accident Criteria for the Heavy Water Reactor-New Production Reactor Containment, K. D. Bergeron, S. E. Slezak, and C. E. Leach; 33 Quasi-Static Core Liquid Level Depression and Long-Term Core Uncovery During a PWR LOCA, Y. Kukita, R. R. Schultz, H. Nakamura, and J. Katayama; 49 LIRA: An Advanced Containment System to Minimize the Accidental Radioactivity Releases, A. Turricchia; 63 Errata to “A Review of Hydrogen Production During Melt/Water Interaction in LWRs,” Vol. 33, No. 4; CONTROL AND INSTRUMENTATION: 64 The Nuplex 80+™ Advanced Control Complex from ABB Combustion Engineering, F. Ridolfo, D. Harmon, and K. Scarola; DESIGN FEATURES: 76 A Scheme for Passive Isolation of the Containment of a Reactor, A. K. Ghosh, V. V. Raj, and K. Kakodkar; 84 Utility Requirements for Safety in the Passive Advanced Light-Water Reactor, T. U. Marston, W. H. Layman, and G. Bockhold, Jr.; WASTE AND SPENT FUEL MANAGEMENT: 91 Activities Related to Waste and Spent Fuel Management, Compiled by M. D. Muhlheim and E. G. Silver; OPERATING EXPERIENCES: 103 Testing Deficiencies in Auxiliary Systems Feedwater Systems, J. D. Kueck; 110 Reactor Shutdown Experience, Compiled by J. W. Cletcher; 113 Selected Safety-Related Events, Compiled by G. A. Murphy; 115 Operating U.S. Power Reactors, Compiled by M. D. Muhlheim and E. G. Silver; RECENT DEVELOPMENTS: 133 General Administrative Activities, Compiled by M. D. Muhlheim and E. G. Silver; 145 Reports, Standards, and Safety Guides, D. S. Queener; 150 Proposed Rule Changes as of Sept. 30, 1992; ANNOUNCEMENTS: 75 Harvard Short Course on Risk: Science, Assessment, and Management; 102 International Conference on Reactor Physics and Reactor Computations; 102 The Fourth International Conference on Nuclear Waste Reprocessing and Waste Management [RECOD ’94]; 132 International Symposium on the Radiological Exposure of the Population of the European Community from Radioactivity in the Mediterranean Sea [MARINA-MED]; 162 International High-Level Radioactive Waste Conference ‘Technology Integration—Above and Below”; 154 The Authors; 158 Indexes to Nuclear Safety, Volume 33.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Nuclear Safety [Vol. 34, No. 1, January-March 1993]
Nuclear Safety is a review journal that covers significant developments in the field of nuclear safety. Its scope includes the analysis and control of hazards associated with nuclear energy, operations involving fissionable materials, and the products of nuclear fission and their effects on the environment. Primary emphasis is on safety in reactor design, construction, and operation; however, the safety aspects of the entire fuel cycle, including fuel fabrication, spent-fuel processing, nuclear waste disposal, handling of radioisotopes, and environmental effects of these operations, are also treated. Table of Contents for this issue follows. GENERAL SAFETY CONSIDERATIONS: 1 An Integrated Regional Approach To Risk Management of Industrial Systems, S. Chakraborty and R. Stratton; 9 Annual Technical Meeting of the NRC Cooperative Severe Accident Research Program, E. G. Silver; ACCIDENT ANALYSIS: 13 Deterministic Severe Accident Criteria as Severe Accident Design Criteria and Policy for the New Production Reactor-Heavy Water Reactor, P. T. Rhoads; 20 Proposed Deterministic Severe Accident Criteria for the Heavy Water Reactor-New Production Reactor Containment, K. D. Bergeron, S. E. Slezak, and C. E. Leach; 33 Quasi-Static Core Liquid Level Depression and Long-Term Core Uncovery During a PWR LOCA, Y. Kukita, R. R. Schultz, H. Nakamura, and J. Katayama; 49 LIRA: An Advanced Containment System to Minimize the Accidental Radioactivity Releases, A. Turricchia; 63 Errata to “A Review of Hydrogen Production During Melt/Water Interaction in LWRs,” Vol. 33, No. 4; CONTROL AND INSTRUMENTATION: 64 The Nuplex 80+™ Advanced Control Complex from ABB Combustion Engineering, F. Ridolfo, D. Harmon, and K. Scarola; DESIGN FEATURES: 76 A Scheme for Passive Isolation of the Containment of a Reactor, A. K. Ghosh, V. V. Raj, and K. Kakodkar; 84 Utility Requirements for Safety in the Passive Advanced Light-Water Reactor, T. U. Marston, W. H. Layman, and G. Bockhold, Jr.; WASTE AND SPENT FUEL MANAGEMENT: 91 Activities Related to Waste and Spent Fuel Management, Compiled by M. D. Muhlheim and E. G. Silver; OPERATING EXPERIENCES: 103 Testing Deficiencies in Auxiliary Systems Feedwater Systems, J. D. Kueck; 110 Reactor Shutdown Experience, Compiled by J. W. Cletcher; 113 Selected Safety-Related Events, Compiled by G. A. Murphy; 115 Operating U.S. Power Reactors, Compiled by M. D. Muhlheim and E. G. Silver; RECENT DEVELOPMENTS: 133 General Administrative Activities, Compiled by M. D. Muhlheim and E. G. Silver; 145 Reports, Standards, and Safety Guides, D. S. Queener; 150 Proposed Rule Changes as of Sept. 30, 1992; ANNOUNCEMENTS: 75 Harvard Short Course on Risk: Science, Assessment, and Management; 102 International Conference on Reactor Physics and Reactor Computations; 102 The Fourth International Conference on Nuclear Waste Reprocessing and Waste Management [RECOD ’94]; 132 International Symposium on the Radiological Exposure of the Population of the European Community from Radioactivity in the Mediterranean Sea [MARINA-MED]; 162 International High-Level Radioactive Waste Conference ‘Technology Integration—Above and Below”; 154 The Authors; 158 Indexes to Nuclear Safety, Volume 33.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
The effect of hydrogen embrittlement on static and dynamic fatigue of hollow notched tensile specimens Semiannual progress report
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Chow, I. D.↗
Comparison of Commercial, State-of-the-Art, Fossil-Based Hydrogen Production Technologies
This report presents an independent assessment of the cost and performance of select hydrogen production plants utilizing fossil fuel resources as the primary feedstocks – specifically, natural gas (NG), steam methane reforming (SMR), NG autothermal reforming (ATR), coal gasification, and coal/biomass co-gasification – using a systematic, transparent technical and economic approach. Study cases were selected to reflect the capabilities of current, commercial technologies within plant configurations, and at scales, representative of next commercial offerings facing no fundamental research and development (R&D) obstacles. Additionally, several areas of R&D are identified as potential pathways for performance improvements and cost reductions.
08 HYDROGEN↗