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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

GPU Lifetimes on Titan Supercomputer: Survival Analysis and Reliability

The Cray XK7 Titan was the top supercomputer system in the world for a long time and remained critically important throughout its nearly seven year life. It was an interesting machine from a reliability viewpoint as most of its power came from 18,688 GPUs whose operation was forced to execute three rework cycles, two on the GPU mechanical assembly and one on the GPU circuitboards. We write about the last rework cycle and a reliability analysis of over 100,000 years of GPU lifetimes during Titan’s 6-year-long productive period. Using time between failures analysis and statistical survival analysis techniques, we find that GPU reliability is dependent on heat dissipation to an extent that strongly correlates with detailed nuances of the cooling architecture and job scheduling. We describe the history, data collection, cleaning, and analysis and give recommendations for future supercomputing systems. We make the data and our analysis codes publicly available.

Ostrouchov, George↗

Thermally Grown Oxide Stress in PS-PVD and EB-PVD Thermal Barrier Coatings Observed at Various Lifetimes Via Synchrotron X-ray Diffraction

The current standard application method for thermal barrier coatings (TBCs) on turbine blades for jet engines is electron-beam physical vapor deposition (EB-PVD) due to its high strain tolerance and low thermal conductivity. An emerging deposition method, plasma-spray physical vapor deposition (PS-PVD), presents an opportunity for a tailorable microstructure, and non-line-of-sight deposition that is faster and less expensive. To compare the lifetime behavior of both PS-PVD and EB-PVD coatings, samples subjected to 300 and 600 thermal cycles were measured during a 1 h thermal cycle to determine the strains, which were converted to stress, in the thermally grown oxide (TGO) layer of the TBCs using synchrotron X-ray diffraction (XRD). Room temperature XRD measurements indicated among samples that PS-PVD coatings experienced greater variation in in-plane room temperature strain in the TGO after cycling than the EB-PVD coatings. In-situ XRD measurements indicated similar high-temperature strain and no spallation after 600 thermal cycles for both coatings. Further, microscopy imaging after cycling showed greater rumpling in PS-PVD coatings that led to different failure modes between the two coatings’ TGO layers. The tailorability of PS-PVD coatings allows for adjustments in the processing parameters to improve their overall performance after aging and bridge the differences between the two deposition methods.

36 MATERIALS SCIENCE↗

Precision measurement of the neutral pion lifetime

The explicit breaking of the axial symmetry by quantum fluctuations gives rise to the so-called axial anomaly. This phenomenon is solely responsible for the decay of the neutral pion π0 into two photons (γγ), leading to its unusually short lifetime. Here, we precisely measured the decay width Γ of the π 0 → γγ process. The differential cross sections for π0 photoproduction at forward angles were measured on two targets, carbon-12 and silicon-28, yielding Γ(π 0 → γγ)=7.798±0.056(stat.)±0.109(syst.) eV, where stat. denotes the statistical uncertainty and syst. the systematic uncertainty. We combined the results of this and an earlier experiment to generate a weighted average of Γ(π 0 → γγ)=7.802±0.052(stat.)±0.105(syst.) eV. Our final result has a total uncertainty of 1.50% and confirms the prediction based on the chiral anomaly in quantum chromodynamics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Triaxiality of neutron-rich ruthenium nuclei studied by lifetime measurements

The breaking of axial symmetry in nuclei enables otherwise precluded behaviours, making it an interesting phenomenon to study. Experimental fingerprints such as very low-lying $2^+_2$ states suggest pronounced triaxial deformation for the neutron-rich ruthenium isotopes. Nevertheless, theoretical calculations differ in the description of the triaxial deformation and its evolution with neutron number, making experimental data crucial to understanding it. We investigated the evolution of the degree of triaxiality and $γ$ rigidity in neutron-rich ruthenium isotopes by measuring lifetimes of excited states in 108-112 Ru with the recoil distance Doppler-shift method. The experiment was carried out at the Grand Accélérateur National d’Ions Lourds using the Advanced Gamma Tracking Array coupled to the Variable Mode Spectrometer. We obtained B(E2) values for 29 transitions in the studied nuclei and compared them with fully microscopic symmetry conserving configuration mixing calculations, and phenomenological generalized triaxial rotor and triaxial particle-rotor models. The models generally reproduce the measured transition strengths, and show an increase in triaxiality with neutron number, reaching near maximum triaxiality in 112 Ru. The results are consistent with a transition from soft to rigid motion as the neutron number increases.

Heines, Johannes Sorby [Univ. of Oslo (Norway); No↗

Braneworld cosmological effect on freeze-in dark matter density and lifetime frontier

In the 5-dimensional braneworld cosmology, the Friedmann equation of our 4-dimensional universe on a brane is modified at high temperatures while the standard Big Bang cosmology is reproduced at low temperatures. Based on two well-known scenarios, the Randall–Sundrum and Gauss–Bonnet braneworld cosmologies, we investigate the braneworld cosmological effect on the relic density of a non-thermal dark matter particle whose interactions with the Standard Model particles are so weak that its relic density is determined by the freeze-in mechanism. For dark matter production processes in the early universe, we assume a simple scenario with a light vector-boson mediator for the dark matter particle to communicate with the Standard Model particles. We find that the braneworld cosmological effect can dramatically alters the resultant dark matter relic density from the one in the standard Big Bang cosmology. As an application, we consider a right-handed neutrino dark matter in the minimal B – L extended Standard Model with a light B – L gauge boson (Z') as a mediator. We find an impact of the braneworld cosmological effect on the search for the long-lived Z' boson at the planned/proposed Lifetime Frontier experiments.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Significant Improvements to Si Calendar Lifetime Using Rapid Electrolyte Screening via Potentiostatic Holds

Silicon-based lithium-ion batteries exhibit severe time-based degradation resulting in poor calendar lives. This has been identified as the major impediment towards commercialization with cycle life considered a solved issue through nanosizing and protective coatings allowing over 1000 cycles of life to be achieved. In this work, rapid screening of sixteen electrolytes for calendar life extension of Si-rich systems (70 wt% Si) is performed using the voltage hold (V-hold) protocol. V-hold significantly shortens the testing duration over the traditional open circuit voltage reference performance test allowing us to screen electrolytes within a span of two months. We find a novel ethylene carbonate (EC) free electrolyte formulation containing lithium hexafluorophosphate (LiPF 6 ) salt, and binary solvent mix of fluoroethylene carbonate (FEC), ethyl methyl carbonate (EMC) that extends calendar life of Si cells as compared to conventional EC based electrolyte. Our coupled experimental-theoretical analysis framework provides a decoupling of the parasitic currents during V-hold, allowing us to extrapolate the capacity loss to predict semiquantitative calendar lifetimes. Subsequently, cycle aging and oxidative stability tests of the EC free system also show enhanced performance over baseline electrolyte.

25 ENERGY STORAGE↗

The Solid Electrolyte Interphase Dispersion Can Predict Cycle and Calendar Lifetimes in Silicon Anodes for Lithium-Ion Batteries

The solid electrolyte interphase (SEI) plays a critical role in lithium-ion battery (LIB) anodes. It is responsible for passivating the reactive surface of lithiated anodes against degradation of the electrolyte which enables long cycle and calendar lifetimes for LIBs. This role is especially important in high energy density anodes like silicon, that undergo massive volumetric changes during electrochemical cycling. The mechanism by which the SEI performs this role, however, is not clear which makes designing an SEI to passivate silicon anodes impossible. Through decades of research, dozens of chemical species have been identified within the SEI ranging from inorganic solids to polymeric coatings all of which simultaneously exist in a 'mosaic' composition at the anode surface. This mosaic creates a highly dispersive environment in which electrostatic screening of the anode surface from the electrolyte is not always complete. Here, we present an electrochemical technique to directly test the dispersion at the anode surface. We use this technique to screen more than 20 different electrolytes against silicon anodes and find correlations between both the cycle life and calendar life. The insights from this study offer a new framework to think about the SEI and a rapid screening method to test novel electrode/electrolyte combinations.

battery↗

GPU Lifetimes on Titan Supercomputer: Survival Analysis and Reliability

George Ostrouchov, Don Maxwell, Rizwan Ashraf, Mallikarjun Shankar, and James Rogers. 2020. GPU Lifetimes on Titan Supercomputer: Survival Analysis and Reliability. In Proceedings of the International Conference for High Performance Computing, Networking, Storage and Analysis (SC '20). Association for Computing Machinery, New York, NY, USA. Data and code for SC20 paper about Titan GPU reliability analysis: https://github.com/olcf/TitanGPULife. Includes R code to generate graphics for paper and additional analyses. See code/README for instructions. Includes original Titan GPU reliability data on over 100,000 collective hours of operation: data/titan.gpu.history.txt - history data, data/titan.service.txt - service nodes for exclusion. Includes output data files produced by code/TitanGPUmodel.Rmd: data/gc_full.csv - cleaned up data (see paper and R code); data/gc_summary_loc.csv - one record per GPU (variables: SN, time, nlife, nloc, last, col, row, cage, slot, node, max_loc_events, time_max_loc, dbe, dbe_loc, otb, otb_loc, out, batch, days, years, dead, dead_otb, dead_dbe) (see paper and R code). Includes .Rmd analysis document as TitanGPUmode.html. Includes Python code to process data/gc_full.csv into graphics from time-between-failure analyses: See code/tbf-analyses/README for instructions.

42 ENGINEERING↗

Efficient general method for numerically modeling laser pulse propagation, overlap, and lifetime effects in amplifiers

An efficient numerical time-dependent general method is developed to address incoherent pulse overlap and lifetime effects in laser amplifiers. The alternating propagation-population laser energetics method (APPLE) has been validated against a semi-discrete coupled rate equation numerical method (SDRE) and analytic formalisms in bounding cases. APPLE is based on decoupled rates applied to a time-dependent framework where both space-time-dependent populations and pulse energetics are consistently updated in each time step. A significant advantage of APPLE lies in its conceptual simplicity, ease of implementation, and relatively small computational cost. SDRE tracks the populations through coupled rates and uses the method of lines to discretize the hyperbolic partial differential transport equations allowing for use of ordinary differential equation solvers. With reasonably sized mesh, we report both energetic and power pulse shape relative differences on the order of one percent between the models over a large range of initial conditions.

47 OTHER INSTRUMENTATION↗

A Project Lifetime Approach to the Management of Induced Seismicity Risk at Geologic Carbon Storage Sites

The geologic storage of carbon dioxide (CO 2 ) is one method that can help reduce atmospheric CO 2 by sequestering it into the subsurface. Large-scale deployment of geologic carbon storage, however, may be accompanied by induced seismicity. We present a project lifetime approach to address the induced seismicity risk at these geologic storage sites. This approach encompasses both technical and nontechnical stakeholder issues related to induced seismicity and spans the time period from the initial consideration phase to postclosure. These recommendations are envisioned to serve as general guidelines, setting expectations for operators, regulators, and the public. They contain a set of seven actionable focus areas, the purpose of which are to deal proactively with induced seismicity issues. Although each geologic carbon storage site will be unique and will require a custom approach, these general best practice recommendations can be used as a starting point to any site-specific plan for how to systematically evaluate, communicate about, and mitigate induced seismicity at a particular reservoir.

58 GEOSCIENCES↗

Quantum efficiency and lifetime study for negative electron affinity GaAs nanopillar array photocathode

Recent studies showed significant improvement in quantum efficiency (QE) by negative electron affinity (NEA) GaAs nanopillar array (NPA) photocathodes over their flat surface peers, particularly at 500 ─ 800 nm waveband. However, the underlying physics is yet to be well understood for further improvement in its performance. In this report, NEA GaAs NPA photocathodes with different dimensions were studied. The diameter of the nanopillars varied from 200 ─ 360 nm, the height varied from 230 ─ 1000 nm and the periodicity varied from 470 ─ 630 nm. The QE and photocathode lifetime were measured. Mie-resonance enhancement was observed at tunable resonance wavelengths. Simulations was also performed to understand the mechanism of photo-absorption and possible ways to further improve the photocathode performance to meet the stringent requirement of the electron sources in large scale electron accelerators. **Acknowledgement** Authored by Jefferson Science Associates, LLC under U.S. DOE contract no. DE-AC05-06OR23177. The U.S. Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce this manuscript for U.S. Government purposes. *mrahm008@odu.edu

Rahman, M.↗

Lifetime extension of legacy CEBAF LLRF hardware

A significant portion of the Low-Level Radio Frequency (LLRF) hardware in Jefferson Lab’s CEBAF is from the original construction of the facility using 1980’s CAMAC technology. Of the fifty-three zones in CEBAF, thirty-six of them are legacy hardware. The age of the legacy system has led to difficulties in maintaining the hardware due to parts going obsolete without suitable drop in replacements. Continued operation of the legacy system is required as the installation of LLRF 3.0 systems is costly and cannot be completed in a short period of time with the available resources. The most pressing failure in the legacy system was a failing buffer card, which is responsible for communication between the EPICs network and individual RF control modules. A new buffer card was designed as a transparent, drop in, replacement so that upgrades are simply a matter of swapping the existing legacy hardware. This buffer card upgrades a single point failure component and promises to extend the operable lifetime of CEBAF’s legacy systems.

Accelerator Physics↗

Transverse Beam Tails and Beam Lifetime in the EIC Electron Storage Ring

For most storage ring design purposes it is sufficient to assume a Gaussian distribution of the electrons in a bunch. However, a more detailed knowledge of the population in the transverse tails beyond a few sigma is necessary to predict the beam lifetime and the synchrotron radiation load in the interaction region due to beam-gas scattering and the beam-beam interaction. This report presents simulations to determine the required vacuum level as well as to serve as input data for detailed synchrotron radiation simulations.

43 PARTICLE ACCELERATORS↗

LLNL FY23 Aging and Lifetimes Exit Criteria: Milestone 8650, GC #4

Silicone rubbers are important materials within the complex and are used in various applications due to wide operating temperatures, favorable aging characteristics, and chemical inertness. However, silicone rubbers are susceptible to degradation in the presence of acid or base. The goal of the project is to design outgassing vessels to probe material degradation byproducts from additively manufactured (AM) silicones compressed against Arrhenius base under dry (sub 100 ppm moisture) environments. The overarching goal of this task is to develop a mechanistic understanding of degradation from experimental data that will be used to inform predictive lifetime and aging models. An outgassing chamber for multi-material compressive aging was designed. The chamber consists of a stainless-steel enclosure, which is hermetically sealed once AM silicone samples are compressed against Arrhenius base pellets in compression rigs (Fig. 1). Outgassing chambers, compression rigs, and accessories were procured, arrived onsite, and received surface treatments. Outgassing of degradation byproducts will be monitored over 12 weeks at 35 °C and 70 °C.

36 MATERIALS SCIENCE↗

High Efficacy, Long Lifetime Flexible White OLED Lighting Panels

In this project, OLEDWorks and partners made significant progress in advancing OLED light extraction technology. Improving light extraction efficiency remains one of the most important research topics for OLEDs. Current state-of-the-art white OLED products extract only about 50% of the photons that are generated within the device. Promising new light extraction concepts, such as those based on sub electrode micro lens arrays (SEMLAs), were explored in this project with the potential to achieve extraction efficiency of 60% or higher. Flexible thin glass substrates with integrated SEMLAs were successfully fabricated and scaled to large area. When combined with optimized high efficiency stacked white OLED structures, we achieved the program goals of 120 LPW efficacy and long lifetime more than 100,000 hours.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Accelerated Lifetime Testing of Main Shaft Seals for Tidal Turbine Rotors

This document will briefly discuss the observations and results from an NREL conducted accelerated lifetime testing of the main shaft seal for the Verdant Power fifth generation Gen5 underwater Tidal Energy Converter (TEC) turbine, which successfully performed at the RITE project in 2020-2021. In order to evaluate a 5-year Service Interval ( SI) for this component, testing at NREL operated the main shaft seal nearly continuously for over 135 (text says 130 days on page 5 and 125 days on page 7 and 137 days on page 11) days at a rotational velocity of 160 rpm while the test stand recorded water pressure, barrier fluid pressure, temperature, and number of cycles., representing ~ 40% of the SI. An additional separate test was conducted to measure the aging behavior of the rubber drive rings. The water pressure reservoir was held constant as 29 psi. Barrier fluid pressure remained relatively constant throughout the duration of the test but was seen to sink to as low as 10.1 psi. No barrier fluid leakage was observed throughout the test. A sudden failure occurred within the seal after the power to test machine was interrupted for a scheduled building maintenance procedure. Upon restarting, the main shaft seal lost all ability to prevent water ingress. The exact cause is not known but is believed to be either a seal assembly issue or a change in the alignment of the seal components during or following the power outage. Following seal disassembly, significant wear was seen on one of the graphite sealing rings. Based on these results it is recommended that a follow-on TEAMER be conducted to rectify protocol and assembly issues to further evaluate SI of this component. The support and participation of Verdant Power Inc, Dovetail Solutions LLC and Garlock Manufacturing Inc were instrumental in understanding the results. NREL thanks them for their significant effort.

13 HYDRO ENERGY↗