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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17

Catalytic Ignition and Upstream Reaction Propagation in Monolith Reactors

Using numerical simulations, this work demonstrates a concept called back-end ignition for lighting-off and pre-heating a catalytic monolith in a power generation system. In this concept, a downstream heat source (e.g. a flame) or resistive heating in the downstream portion of the monolith initiates a localized catalytic reaction which subsequently propagates upstream and heats the entire monolith. The simulations used a transient numerical model of a single catalytic channel which characterizes the behavior of the entire monolith. The model treats both the gas and solid phases and includes detailed homogeneous and heterogeneous reactions. An important parameter in the model for back-end ignition is upstream heat conduction along the solid. The simulations used both dry and wet CO chemistry as a model fuel for the proof-of-concept calculations; the presence of water vapor can trigger homogenous reactions, provided that gas-phase temperatures are adequately high and there is sufficient fuel remaining after surface reactions. With sufficiently high inlet equivalence ratio, back-end ignition occurs using the thermophysical properties of both a ceramic and metal monolith (coated with platinum in both cases), with the heat-up times significantly faster for the metal monolith. For lower equivalence ratios, back-end ignition occurs without upstream propagation. Once light-off and propagation occur, the inlet equivalence ratio could be reduced significantly while still maintaining an ignited monolith as demonstrated by calculations using complete monolith heating.

Struk, Peter M.↗

Radiation sensitive area detection device and method

A radiation sensitive area detection device for use in conjunction with an X ray, ultraviolet or other radiation source is provided which comprises a phosphor containing film which releases a stored diffraction pattern image in response to incoming light or other electromagnetic wave. A light source such as a helium-neon laser, an optical fiber capable of directing light from the laser source onto the phosphor film and also capable of channelling the fluoresced light from the phosphor film to an integrating sphere which directs the light to a signal processing means including a light receiving means such as a photomultiplier tube. The signal processing means allows translation of the fluoresced light in order to detect the original pattern caused by the diffraction of the radiation by the original sample. The optical fiber is retained directly in front of the phosphor screen by a thin metal holder which moves up and down across the phosphor screen and which features a replaceable pinhole which allows easy adjustment of the resolution of the light projected onto the phosphor film. The device produces near real time images with high spatial resolution and without the distortion that accompanies prior art devices employing photomultiplier tubes. A method is also provided for carrying out radiation area detection using the device of the invention.

Carter, Daniel C.↗

Optical devices and methods employing nanoparticles, microcavities, and semicontinuous metal films

An optical sensing enhancing material (and corresponding method of making) comprising: a medium, the medium comprising a plurality of aggregated nanoparticles comprising fractals; and a microcavity, wherein the medium is located in a vicinity of the microcavity. Also an optical sensor and sensing method comprising: providing a doped medium, the medium comprising a plurality of aggregated nanoparticles comprising fractals, with the material; locating the doped medium in the vicinity of a microcavity; exciting the doped medium with a light source; and detecting light reflected from the doped medium. Also an optical sensing enhancing material comprising a medium, the medium comprising a semicontinuous metal film of randomly distributed metal particles and their clusters at approximately their percolation threshold. The medium preferably additionally comprises a microcavity/microresonator. Also devices and methods employing such material.

Armstrong, Robert L.↗

CN anomalies in extremely metal-deficient red giants

New photometric and UV spectroscopic data for the metal-deficient red giants CD -38 deg 245 and BD -18 deg 5550 are presented and discussed in light of recently noted photometric anomalies. From the IUE spectra it is aparent that the UV excess found in BD -18 deg 5550 is not the result of a hot companion. The IUE spectra, in conjunction with other observations, point to anomalous nitrogen abundances as the source of the discrepancies between the photometric and spectroscopic abundances for these stars. CD -38 deg 245 appears to be exceptionally nitrogen-rich while BD -18 deg 5550 is anomalously nitrogen-poor with respect to stars of comparable metallicities. While BD -18 deg 5550 appears to be an exception to the rule for its metallicity, the confirmation of a similar photometric pattern for CS 22885-96 may be an indication that the nitrogen overabundance in CD -38 deg 245 is typical for giants of extreme metal-deficiency.

Anthony-Twarog, Barbara J.↗

Fabrication and Characterization of Thin Film Ion Implanted Composite Materials for Integrated Nonlinear Optical Devices

Ion implantation has been shown to produce a high density of metal colloids within the layer regions of glasses and crystalline materials. The high-precipitate volume fraction and small size of metal nanoclusters formed leads to values for the third-order susceptibility much greater than those for metal doped solids. This has stimulated interest in use of ion implantation to make nonlinear optical materials. On the other side, LiNbO3 has proved to be a good material for optical waveguides produced by MeV ion implantation. Light confinement in these waveguides is produced by refractive index step difference between the implanted region and the bulk material. Implantation of LiNbO3 with MeV metal ions can therefore result into nonlinear optical waveguide structures with great potential in a variety of device applications. We describe linear and nonlinear optical properties of a waveguide structure in LiNbO3-based composite material produced by silver ion implantation in connection with mechanisms of its formation.

Sarkisov, S.↗

Cryogenic glass-filament-wound tank evaluation

High-pressure glass-filament-wound fluid storage vessels with thin aluminum liners were designed, fabricated, and tested at ambient and cryogenic temperatures which demonstrated the feasibility of producing such vessels as well as high performance and light weight. Significant developments and advancements were made in solving problems associated with the thin metal liners in the tanks, including liner bonding to the overwrap and high strain magnification at the vessel polar bosses. The vessels had very high burst strengths, and failed in cyclic fatigue tests by local liner fracture and leakage without structural failure of the composite tank wall. The weight of the tanks was only 40 to 55% of comparable 2219-T87 aluminum and Inconel 718 tanks.

Morris, E. E.↗

Orienting Arc Lamps for Longest Life

Temperature distribution strongly affects performance. Tests on floodlights for Space Shuttle payload bay show useful life of metal halide dc arc lamp prolonged by mounting "anode down" and wiring for maximum heat conduction away from electrodes. Anode-down configuration, anode and cathode temperatures stabilize at 333 degrees and 313 degrees C, respectively, after 1 hour of operation. Temperatures both below limit for quartz-to-metal seals, and lamps able to withstand a 2,000-hour life test with satisfactory light output at end.

Kiss, J.↗

Measurement of temperature and emissivity of specularly reflecting glowing bodies

A new method of measuring the thermodynamic temperature of an object as well as the surface emissivity based on laser reflectivity has been developed. By using rotator analyzer ellipsometry, the light reflected from the sample at a specific angle of incidence can be analyzed for its ellipticity. The normal incidence reflectivity and emissivity are then extracted using standard relations. The thermodynamic temperature of the body is obtained simultaneously by measuring the intensity of emitted light at the same angle of incidence. Room temperature measurements are carried out on selected metals to test the system. Elevated temperature measurements on platinum foils show that this technique is reliable and accurate for monitoring and measuring the temperature and emissivity of specularly reflecting, glowing bodies.

Hansen, G. P.↗

Electrochemical and galvanic corrosion effects in thin-film photovoltaic modules

The electrochemical and galvanic corrosion properties of thin-film photovoltaic (TF-PV) modules and module subcomponents are determined and interpreted in the light of established corrosion science. Results of a detailed study of thin-film aluminum metallization corrosion are presented. Bar-graph corrosion, observed in fielded modules, has been induced experimentally and found to be electrochemical in nature. Corrosion rates and passivation techniques for TF-PV modules are discussed.

Mon, G.↗

A Dual-Band Dual-Polarized Array for Spaceborne SAR

Future synthetic aperture radar antennas will be significantly more sophisticated than their earlier counterparts, requiring enhanced electrical capabilities such as operation at multiple frequencies with multiple polarization ability, as well as desirable non-electrical features such as light weight, easy and reliable deployability, and low cost. The present paper describes the results of a prototype SAR array developed with these considerations in mind. This paper will describe the development of a dual-frequency array operating at L and C bands, with dual linear polarization capability at both bands. Unlike most earlier dual-band arrays, this array shares the same radiating aperture for both bands and both polarizations, resulting the smallest possible aperture area for a given gain specification. A critical constraint in this project was a requirement for an extremely light weight package, leading to the use of foam substrates with thin dielectric membranes for metalizations of the radiating elements and feed networks.

Pozar, David M.↗

ISRU at a Lunar Outpost: Implementation and Opportunities for Partnerships and Commercial Development

The NASA Lunar Architecture Team (LAT), which was commissioned to help answer the question "how" will humans return to the Moon, and the Synthesis Team and the recently released Global Exploration Strategy, which was commissioned to help answer the question "why" will humans return to the Moon and go on to Mars have identified the ability to extract and use in-situ resources as important to extending human frontiers, reduce dependence on Earth, and further economic and commercial expansion into space. The extraction and processing of space resources into useful products, known as In-Situ Resource Utilization (ISRU), can have a substantial impact on mission and architecture concepts. In particular, the ability to make propellants, life support consumables, and fuel cell reagents can significantly reduce the cost, mass, and risk of sustained human activities beyond Earth. Potential lunar resources include solar wind implanted volatiles, vast quantities of metal and mineral oxides, possible water/ice at the poles, abundant solar energy, regions of permanent light and darkness, the vacuum of space itself, and even scavenging leftover descent propellants and/or trash and waste from human crew activities. Suitable processing can transform these raw resources into useful materials and products. The establishment of a human lunar Outpost, as proposed by NASA at the 2nd Space Exploration Conference in Houston in December 2006, opens up the possibility for the first time of breaking our reliance on Earth supplied consumables and learn to "live off the land". The ISRU phasing and capability incorporation strategy developed during LAT Phase I & II is based on the premise that while ISRU is a critical capability and key to successful implementation of the US Vision for Space Exploration, it is also an unproven capability for human lunar exploration and can not be put in the critical path of architecture success until it has been proven. Therefore, ISRU needs to take incremental steps toward the desired end state. However, at the same time, the lunar architecture needs to be open enough to take advantage of ISRU when proven available.

Sanders, Gerald B.↗

The Halite-Bearing Zag and Monahans (1998) Meteorite Breccias: Shock Metamorphism, Thermal Metamorphism and Aqueous Alteration on the H-Chondrite Parent Body

Zag and Monahans (1998) are H-chondrite regolith breccias comprised mainly of lightcolored metamorphosed clasts, dark clasts that exhibit extensive silicate darkening, and a halite-bearing clastic matrix. These meteorites reflect a complex set of modification processes that occurred on the H-chondrite parent body. The light-colored clasts are thermally metamorphosed H5 and H6 rocks that were fragmented and deposited in the regolith. The dark clasts formed from light-colored clasts during shock events that melted and mobilized a significant fraction of their metallic Fe-Ni and troilite grains. The clastic matrices of these meteorites are rich in solar-wind gases. Parent-body water was required to cause leaching of chondri tic minerals and chondrule glass; the fluids became enriched in Na, K, CI, Br, AI, Ca, Mg and Fe. Evaporation of the fluids caused them to become brines as halides and alkalies became supersaturated; grains of halite (and, in the case of Monahans (1998), halite with sylvite inclusions) precipitated at low temperatures (less than or equal to 100 C) in the porous regolith. In both meteorites fluid inclusions were trapped inside the halite crystals. Primary fluid inclusions were trapped in the growing crystals; secondary inclusions formed subsequently from fluid trapped within healed fractures.

Rubin, Alan E.↗

C III] Emission in Star-Forming Galaxies Near and Far

We measure C III Lambda Lambda 1907, 1909 Angstrom emission lines in eleven gravitationally-lensed star-forming galaxies at zeta at approximately 1.6-3, finding much lower equivalent widths than previously reported for fainter lensed galaxies (Stark et al. 2014). While it is not yet clear what causes some galaxies to be strong C III] emitters, C III] emission is not a universal property of distant star-forming galaxies. We also examine C III] emission in 46 star-forming galaxies in the local universe, using archival spectra from GHRS, FOS, and STIS on HST, and IUE. Twenty percent of these local galaxies show strong C III] emission, with equivalent widths less than −5 Angstrom. Three nearby galaxies show C III] emission equivalent widths as large as the most extreme emitters yet observed in the distant universe; all three are Wolf-Rayet galaxies. At all redshifts, strong C III] emission may pick out low-metallicity galaxies experiencing intense bursts of star formation. Such local C III] emitters may shed light on the conditions of star formation in certain extreme high-redshift galaxies.

STAR-FORMING↗

Spectroscopy of dwarf elliptical galaxies in the Fornax cluster

We present the results of spectroscopic observations of 10 nucleated dwarf elliptical galaxies (dE's) in the Fornax cluster. The blue spectra of Fornax dE galaxies indicate a wide range of metallicities at a given luminosity, similar to those of intermediate to metal-rich globular clusters. Metal abundances derived in this paper are well correlated with optical colors and agree with previous spectroscopic results. A discrepancy with metallicities inferred from infrared colors is evident; possible causes include an intermediate age population and dilution of spectral features by a blue light excess. Dwarf ellipticals exhibit a wide variation of hydrogen line strength which points to a complex star formation history. Prominent Balmer absorption lines are the signature of a young stellar population in the nuclei of some (but not all) dE's, while moderately strong Balmer lines in relatively metal-rich dE's are more consistent with an extended main sequence. In a few metal-poor dE galaxies, the hydrogen lines are consisent with, or perhaps weaker than, those found in Galactic globulars of similar metallicity. In the limited magnitude range of this sample, there is no apparent correlation of metallicity either with effective and central surface brightness, or with total and nuclear magnitudes. The velocity distribution of the Fornax dwarfs is flatter than that of brighter galaxies at the 75% confidence level, possibly indicating a difference in the kinematics of the two samples.

Held, Enrico V.↗

BUNDLE: A Novel Furnace for Performing Controlled Directional Solidification Experiments in a Microgravity Environment

NASA Marshall Space Flight Center has developed a novel directional solidification furnace prototype for processing metals and alloys experiments in a microgravity environment. The BUNDLE (Bridgman Unidirectional Dendrite in Liquid Experiment) furnace is intended to accommodate the science requirements of Flight Definition Principle Investigators studying cellular/dendritic growth in aluminum and lead alloys at processing temperatures up to 1200 C. The furnace implements a number of innovative features to achieve high thermal gradients and quench rates in a low-power, light-weight design. These include a pyrolytic boron nitride/graphite composite heating element surrounded by layers of self-supporting refractory metal shielding, and a graphite fiber enhanced cold zone allowing high levels of heat extraction from the sample crucible. Novel to the BUNDLE design is an in-situ helium gas quench capability that ensures rapid freezing of the solidifying region (mushy zone) of the metal sample within the furnace without sample disturbance prior to quenching; this is a stringent requirement for subsequent analysis and understanding of microstructural development. The experiment hardware concept features multiple furnaces that may be "bundled" together so many samples, currently up to eight, can be processed at one time. The design of BUNDLE is flexible enough to be implemented on the Shuttle and Space Station in a number of locations (SpaceHab, Express Rack, MPESS, ISPR, etc). BUNDLE prototype furnaces have directionally solidified and quenched 1cm diameter lead - 5.8 weight percent antimony and aluminum - 4 weight percent copper alloys. Quenching of the mushy zone, as recorded by in-situ thermocouples, occurred on the order of 0.5 seconds or less, a rate within the PI's requirements. Subsequent metallographic examination revealed the solidified microstructure to be, as expected, unidirectional. Both the dendrite tips and the eutectic reaction were planar in nature indicating uniform axial heat flow. Delineation between the growing dendrites and eutectic structure with the "quenched-in" liquid was sharp, attesting to the efficacy of the helium quench. BUNDLE's conception, development, capability, and adaptability are presented (in view of Flight PI's needs and science requirements) through viewgraphs depicting actual hardware, generated thermal analysis, and micrographs prepared from BUNDLE processed, flight-like samples.

Carrasquillo, Edgar J.↗

BUNDLE - A Novel Furnace for Performing Controlled Directional Solidification Experiments in a Microgravity Environment

NASA Marshall Space Flight Center has developed a novel directional solidification furnace prototype for processing metals and alloys experiments in a microgravity environment. The BUNDLE (Bridgman Unidirectional Dendrite in Liquid Experiment) furnace is intended to accommodate the science requirements of Flight Definition Principle Investigators studying cellular/dendritic growth in aluminum and lead alloys at processing temperatures up to 1200 C. The furnace implements a number of innovative features to achieve high thermal gradients and quench rates in a low-power, light-weight design. These include a pyrolytic boron nitride/graphite composite heating element surrounded by layers of self-supporting refractory metal shielding, and a graphite fiber enhanced cold zone allowing high levels of heat extraction from the sample crucible. Novel to the BUNDLE design is an in-situ helium gas quench capability that ensures rapid freezing of the solidifying region (mushy zone) of the metal sample within the furnace without sample disturbance prior to quenching; this is a stringent requirement for subsequent analysis and understanding of microstructural development. The experiment hardware concept features multiple furnaces that may be "bundled" together so many samples, currently up to eight, can be processed at one time. The design of BUNDLE is flexible enough to be implemented on the Shuttle and Space Station in a number of locations (SpaceHab, Express Rack, MPESS, ISPR, etc). BUNDLE prototype furnaces have directionally solidified and quenched 1cm diameter lead - 5.8 weight percent antimony and aluminum - 4 weight percent copper alloys. Quenching of the mushy zone, as recorded by in-situ thermocouples, occurred on the order of 0.5 seconds or less, a rate within the PI's requirements. Subsequent metallographic examination revealed the solidified microstructure to be, as expected, unidirectional. Both the dendrite tips and the eutectic reaction were planar in nature indicating uniform axial heat flow. Delineation between the growing dendrites and eutectic structure with the "quenched-in" liquid was sharp, attesting to the efficacy of the helium quench. BUNDLE's conception, development, capability, and adaptability are presented (in view of Flight PI's needs and science requirements) through viewgraphs depicting actual hardware, generated thermal analysis, and micrographs prepared from BUNDLE processed, flight-like samples.

Carrasquillo, Edgar J.↗

Evaluation of polyimide/glass fiber composites for construction of light weight pressure vessels for cryogenic propellants

The application of polyimide resin as a matrix for glass filament-wound thin metal-lined pressure vessels was studied over a temperature range of (minus) 320 to 600 F. Keramid 601 polyimide was found to perform quite well over the entire range of temperature. Hoop stress values of 425 ksi were determined at 75 F which is equivalent to epoxy resin in similar structures. At -320 and 600 F, 125 and 80% of this strength was retained. Thermal ageing at 500 F for up to 50 hours was studied with severe reduction in strength, but there is evidence that this reduction could be improved. Another polyimide resin studied was P10PA which was found to have processing characteristics inappropriate for filament-winding. NOL ring tensile and shear data was determined from both resins with S-glass. Pressure vessel design, fabrication and test procedures are described in detail.

Petker, I.↗

Electronic Dimmable Ballasts for High-Intensity Discharge Sodium Vapor and Metal Halide Lamps

Two types of high-intensity discharge lamps were tested using dimmable ballasts. The main purpose for evaluating this lighting system was to determine its efficacy for saving power. Whereas previous variable level lighting systems for HID lamps in Advanced Life Support applications were adjustable in two or three steps using capacitive switching, this system allows for continuously adjustable lamp output. This type of lighting system when used as part of an Advanced Life Support biomass production system would provide only the amount of light energy a crop needed at any particular point in its growth cycle. Since most of the equivalent system mass in an ALS system is from the light energy required to grow the crops, controlling that light energy dynamically over a continuous range of operation would dramatically reduce the power consumption and reduce system mass.

Boulanger, Richard↗