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At least 307 records · Page 17

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NASA NTRS1972

A review of film boiling at cryogenic temperatures.

Film boiling occurs in the quenching of metals, the chilling of biological species, the regenerative cooling of rockets, and the cooling down of a cryogenic fuel tank. Occasionally film boiling is also found in a nuclear reactor or in a cryomagnet. Aspects of film boiling involving an unconstrained liquid mass are considered, giving attention to the evaporation time, the Leidenfrost temperature, solid-liquid contacts, the thermal properties of the solid, effects of coating or scale, wettability, the metastable condition, and the velocity effect on drops. Developments discussed with regard to pool boiling are related to vertical surfaces, film boiling from horizontal surfaces, film boiling from a horizontal cylinder, film boiling from a sphere, and film boiling of helium. Processes of film boiling in a channel are also analyzed.

Hsu, Y. Y.↗

NASA NTRS1972

Quartz and feldspar glasses produced by natural and experimental shock.

Refractive index, density, and infrared absorption studies of naturally and experimentally shocked-produced glasses formed from quartz, plagioclase, and alkali-feldspar confirm the existence of two main groups of amorphous forms of the framework silicates: solid-state and liquid-state glasses. These were apparently formed as metastable release products of high-pressure-phases above and below the glass transition temperatures. Solid-state glasses exhibit a series of structural states with increasing disorder caused by increasing shock pressures and temperatures. They gradually merge into the structural state of fused minerals similar to that of synthetic glasses quenched from a melt. Shock-fused alkali feldspars can, however, be distinguished from their laboratory-fused counterparts by infrared absorption and by higher density.

Stoeffler, D.↗

NASA NTRS1972

Electric dipole moment of diatomic molecules by configuration interaction. IV.

The theory of basis set dependence in configuration interaction calculations is discussed, taking into account a perturbation model which is valid for small changes in the self-consistent field orbitals. It is found that basis set corrections are essentially additive through first order. It is shown that an error found in a previously published dipole moment calculation by Green (1972) for the metastable first excited state of CO was indeed due to an inadequate basis set as claimed.

Green, S.↗

NASA NTRS1973

Design and experimental performance of short curved wall diffusers with axial symmetry utilizing slot suction

The feasibility of designing short curved wall axially symmetrical subsonic diffusers utilizing suction through slots in the diffuser walls to prevent flow separation was investigated. A potential flow analysis was made, and a digital computer program was written for determining the diffuser wall contour for prescribed boundary conditions. The flow field included branch flow so that the suction slot geometry could be a part of the diffuser design. One bell shaped diffuser and three annular diffusers with area ratios of either 2.5:1 or 3:1 were designed, fabricated, and tested. Minimum suction requirements of metastable operation ranged from 6.3 percent to 12 percent when operating with inlet air velocities in the 1000 to 250 ft/sec (30 to 76 m/sec) range. For stable operation suction rates from 10 percent to 22 percent were required. In all cases the diffuser effectiveness was above 95 percent based on the conventional definition, and from 81 percent to 94 percent when the suction loss was accounted for. The exit velocity profiles were virtually flat with no more than + or - 9% variation over 95 percent of the exit area when operated with sufficient suction to prevent flow separation.

Yang, T.↗

NASA NTRS1972

The smoothing dissector.

A technique for adding a form of buffer store to an image dissector is described that increases markedly the photoelectron-detecting ability of the image dissector. The buffer-store function is accomplished in the phosphor screen of an image intensifier tube by the metastable electronic excitation states resulting in the phosphor screen from high-energy photoelectron bombardment. The addition of this image intensifier to an image dissector is shown to cause no nonlinearity in the input/output characteristics of the image dissector.

Eberhardt, E. H.↗

NASA NTRS1973

Shock wave compression of iron-silicate garnet.

Shock wave compression data to over 650 kb are presented for single-crystal almandine garnet. The data indicate the initiation of a phase transformation near 200 kb. Total transition to the high-pressure polymorph occurs at approximately 300 kb. The elastic properties of the high-pressure phase are calculated from the metastable Hugoniot data by using the linear shock velocity-particle velocity relationships. The overall results obtained strongly suggest that upper mantle minerals are likely to occur in the ilmenite structure over a substantial part of the lower mantle.

Graham, E. K.↗

NASA NTRS1973

Daytime ion chemistry of N2+.

Rocket measurements of the emission of the (0, 0) first negative band of N2+ at 3914 A in the day airglow have been made between 120 and 300 km. The solar zenith angle at the time of the flight was 60 deg, and the zenith intensity above 120 km was 1.6 kR averaged over both legs of the flight. The data are compared with a model in which charge exchange of N2 with metastable O+(2D) ions is included as an additional source of N2 ionization. Above 240 km this mechanism is dominant over the photoionization of N2 by solar extreme ultraviolet radiation. The derived N2+ density is consistent with the results of rocket-borne mass spectrometric observations.

Feldman, P. D.↗

NASA NTRS1974

Computer program for calculating water and steam properties

Computer subprogram, WASP, accepts any two of pressure, temperature, and density as input conditions. Pressure and either entropy or enthalpy are also allowable input variables. This flexibility is especially useful in cycle analysis. Metastable calculations can also be made using WASP.

Hendricks, R. C.↗

NASA NTRS1973

WASP: A flexible FORTRAN 4 computer code for calculating water and steam properties

A FORTRAN 4 subprogram, WASP, was developed to calculate the thermodynamic and transport properties of water and steam. The temperature range is from the triple point to 1750 K, and the pressure range is from 0.1 to 100 MN/m2 (1 to 1000 bars) for the thermodynamic properties and to 50 MN/m2 (500 bars) for thermal conductivity and to 80 MN/m2 (800 bars) for viscosity. WASP accepts any two of pressure, temperature, and density as input conditions. In addition, pressure and either entropy or enthalpy are also allowable input variables. This flexibility is especially useful in cycle analysis. The properties available in any combination as output include temperature, density, pressure, entropy, enthalpy, specific heats, sonic velocity, viscosity, thermal conductivity, surface tension, and the Laplace constant. The subroutine structure is modular so that the user can choose only those subroutines necessary to his calculations. Metastable calculations can also be made by using WASP.

Hendricks, R. C.↗

NASA NTRS1971

Stabilities of nitrogen containing heterocyclic radicals and geometrical influences on non-radiative processes in organic molecules

Theoretical and experimental work on generating radicals by removal of a hydrogen atom from pyrrole, imidazole, indole, and carbazole is reported. Photophysical studies on indolizine and related aza-derivatives show that materials having large S2-S1 energy gaps might exhibit upper state fluorescence. Photodecomposition quantum yields of a series of sterically hindered p-aminobenzene diazonium cations in water were found structurally and wavelength dependent and unquenched in aqueous sodium bromide solutions. Photodecomposition of diazonium materials did not produce a metastable species with a longer lifetime than 1 msec.

Evleth, E. M.↗

NASA NTRS1973

Artificial meteor ablation studies

Artificial meteor ablation was performed on natural minerals, composed predominately of magnetite and hematite, using an arc heated plasma stream of air. Analysis of the ablated debris indicated most was composed of two or more minerals. The more volatile elements were depleted and the relative abundance of Fe increased as a result of both volatile depletion and a reduction in its oxidation state. Hematite was converted to magnetite in the ablation zone, and quartz and apatite minerals were converted to an Fe-rich glass consisting of varying amounts of Si, P, Cl, and Ca, depending upon the accessory minerals available at the time of melting. Artificially created ablation products from iron oxides exhibited unique properties depending on the composition of the original material and the environmental conditions of formation. In addition to the accepted elemental criteria, these properties were morphologic characteristics, textural parameters, and the existence of metastable minerals.

Blanchard, M. B.↗

NASA NTRS1973

The extreme ultraviolet spectrum of solar flares

Extreme ultraviolet flare observations are discussed, with particular attention to relative variations of spectral features during flares. An approximately equal enhancement of most chromospheric, transition-zone, and coronal lines indicates that the thermal conduction may be important at temperatures between 100,000 and one million K in the flare plasma. However, enhancements sometimes appear to be somewhat larger for transition-zone lines and for density-sensitive lines arising from metastable levels. EUV lines characteristics of temperatures between 10,000 and 1.5 million K all show a nearly simultaneous rise in impulsive flares, coincident with the hard X-ray burst. Density increases by factors of 5 to 10 in the transition zone are inferred from emission-measure increases and from line ratios for small flares.

Noyes, R. W.↗

NASA NTRS1973

Chondrules - An origin by impacts between dust grains

Modern theories regarding the origin of chondrules may be divided into two broad categories. According to primary theories, chondrules are thought to condense directly from the cooling nebular gas as stable or metastable liquid droplets. According to secondary theories, chondrules are thought to be produced by the flash heating and remelting of the original dust-like condensate. A collisional mechanism of chondrule formation is discussed.

Lange, D. E.↗

NASA NTRS1974

A statistical-chemical and thermodynamic approach to the study of lunar mineralogy

Principal components analysis is used to study the chemical compositions of pyroxenes of five Apollo 12 specimens. Important correlations are recognized in the variation of oxide weight per cent. These correlations indicating substitutional relationships can be interpreted as representative of stable and metastable trends of crystallization by using crystal-chemical and thermodynamic information. The per cent variance of pyroxene groups with characteristic trends in each specimen can be evaluated and interpreted in terms of history of crystallization. Distribution of Fe and Mg in certain pairs of olivine and pyroxene, which are found in contact in the rock and which may have crystallized simultaneously, is useful in recognizing the tendency towards chemical equilibrium in Fe-Mg distribution during a limited interval in the liquidus or subsolidus stages.

Saxena, S. K.↗

NASA NTRS1974

Grossular in the Allende /Type III carbonaceous/ meteorite

Grossular garnet has been observed in several white inclusions in the Allende meteorite. Compositions range from Gro(95)Py(5) to Gro(88)Py(12) in five inclusions. Its mottled appearance indicates that it crystallized from a glass of near-grossular composition and not by a solid-state reaction between wollastonite, anorthite, and melilite. These grossular-bearing inclusions either condensed directly as metastable liquids from the solar nebula or, if initial solid condensates were liquefied, by some subsequent heating process. In either case, a prolonged residence time in a thermal blanket appears necessary to effect crystallization of the grossular.

Fuchs, L. H.↗

NASA NTRS1974

Liquid-metal atomization for hot working preforms

Rapid quenching of a liquid metal by atomization or splat cooling overcomes the major limitation of most solidification processes, namely, the segregation of alloying elements, impurities, and constituent phases. The cooling rates of different atomizing processes are related to the dendrite arm spacings and to the microstructure of the atomized powders. The increased solubility limits and the formation of metastable compounds in splat-cooled alloys are discussed. Consolidation of the powders by hot isostatic compaction, hot extrusion, or hot forging and rolling processes yields billets with properties equivalent to or better than those of the wrought alloys. The application of this powder processing technology to high-performance alloys is reviewed.

Grant, N. J.↗

NASA NTRS1974

Tough cryogenic alloys from the Fe-Mn and Fe-Mn-Cr systems

By adjusting composition, metastable gamma (austenite) and epsilon (hexagonal) martensite may be retained in Fe-Mn and Fe-Mn-Cr alloys and used to impact toughness through the TRIP mechanism. The resulting alloys have excellent toughness at cryogenic temperatures. The best alloys obtained to date are: Fe-20Mn, with sigma (sub y) = 79ksi and K sub IC = 275ksi square root of (in) at 77 K, and Fc-16Mn-8Cr, with sigma sub y = 85ksi and K sub IC = 72ksi square root of (in) at 77 K.

Schanfein, M. J.↗

NASA NTRS1974

The effect of microstructure on the fracture toughness of titanium alloys

The microstructure of the alpha titanium alloy Ti-5Al-2.5Sn and the metastable beta titanium alloy Beta 3 was examined. The material was from normal and extra low interstitial grade plates which were either air-cooled or furnace-cooled from an annealing treatment. Beta 3 was studied in alpha-aged and omega-aged plates which were heat treated to similar strength levels. Tensile and plane strain fracture toughness tests were conducted at room temperature on the alpha-aged material. The microstructure and fracture mechanisms of alloys were studied using optical metallography, electron microscopy, microprobe analyses, and texture pole figures. Future experiments are described.

Vanstone, R. H.↗