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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS2010

A Study of Cirrus Ice Particle Size Distribution Using TC4 Observations

An analysis of two days of in situ observations of ice particle size spectra, in convectively generated cirrus, obtained during NASA s Tropical Composition, Cloud, and Climate Coupling (TC4) mission is presented. The observed spectra are examined for their fit to the exponential, gamma, and lognormal function distributions. Characteristic particle size and concentration density scales are determined using two (for the exponential) or three (for the gamma and lognormal functions) moments of the spectra. It is shown that transformed exponential, gamma, and lognormal distributions should collapse onto standard curves. An examination of the transformed spectra, and of deviations of the transformed spectra from the standard curves, shows that the lognormal function provides a better fit to the observed spectra.

Tian, Lin↗
DOE OSTI2019

A Multiscale Approach to High-Resolution Ocean Profile Observations within a 4DVAR Analysis System

Most ocean data assimilation systems are tuned to process and assimilate observations to constrain features on the order of the mesoscale and larger. Typically this involves removal of observations or computing averaged observations. This procedure, while necessary, eliminates many observations from the analysis step and can reduce the overall effectiveness of a particular observing platform. Simply including these observations is not an option as doing so can produce an overdetermined, ill-conditioned problem that is more difficult to solve. An approach, presented here, aims to avoid such issues while at the same time increasing the number of observations within the assimilation. A two-step assimilation procedure with the four-dimensional variational data assimilation (4DVAR) system is adopted. The first step attempts to constrain the large-scale features by assimilating a set of super observations with appropriate background error correlation scales and error variances. The second step then attempts to correct smaller-scale features by assimilating the full observation set with shorter background error correlation scales and appropriate error variances; here the background state is taken as the analysis from the first step. Results using a real high-density observation set from underwater gliders in the region southeast of Iceland, collected during the 2017 Nordic Recognized Environmental Picture (NREP) experiment, will be shown using the Navy Coastal Ocean Model 4DVAR (NCOM-4DVAR).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1990

Spatial analysis of IRAS observations of nearby spirals

The unbiased survey of the infrared sky carried out by the Infrared Astronomy Satellite (IRAS) satellite has greatly accelerated advances in understanding the dust component of our own and external galaxies. However, most extragalactic studies to date have been based on the IRAS Point Source Catalog (PSC), which has two serious limitations. First, in sources where a significant fraction of the flux is extended, significant errors may result from using PSC fluxes in comparative studies, and these errors could be systematic if the tendency to be non-pointlike depends on physical properties of the galaxy. Additionally, use of PSC fluxes rules out any direct investigation of the spatial distribution of the IRAS emission from disks in external galaxies. Since work on the Galactic IRAS results has shown that very different physical processes can make varying contributions to the observed flux, it is important to look at a wide sample of galaxies with some spatial resolution to study the relative dominance of these processes under a variety of conditions. Here, researchers report on work they are doing to carry out this program for many nearby spirals, using an analysis package that was developed for this purpose. Researchers carried out analysis for a sample of 121 nearby spirals. The fraction of the flux contained in a point source varies from 0 to 1 across the sample, all of which are well resolved at their nominal optical diameters. There is no evidence that the galaxies of smaller angular size are less likely to be resolved by IRAS at this level. The program gives results which are quite repeatable from scan to scan; the fraction f (point source flux over total flux) at 60 microns has typical errors of 0.03 when different scans are combined. Approximately two-thirds of the sample have more flux in the extended than in the nuclear component. There is a tendency for earlier-type spirals to be less centrally concentrated, but this effect is slight and the degree of variation is large for all types. Barred spirals are also found across the spectrum of f, but are much more likely to have little or no nuclear emission.

Ball, Roger↗
DOE OSTI2022

Nanotomographic observation and statistical analysis of overcharging induced cracks in LiCoO 2 single crystalline particles

Particle fracture represents an important mode of battery electrode degradation. Extensive cracking occurs in the layered oxide cathodes of lithium-ion rechargeable batteries when they are charged beyond safe operational voltages. In this paper, we analyze the morphology and distribution of cracks in over 100 overcharged LiCoO 2 (LCO) single-crystalline particles imaged via X-ray nanotomography. Herein, we observe a strong particle size dependence in both nucleation and growth of cracks, with percentage of cracked particles, crack size, and crack surface area per unit volume all increasing significantly with particle volume. Increasing the cutoff voltage above 4.6V is found to trigger much more pronounced crack growth, which we attribute to the large misfit stress caused by the H1-3 to O1 phase transition. This study offers valuable statistical insights into the fracture behavior of layered oxide cathodes and reveals the importance of particle size control on electromechanical degradation of battery electrodes.

25 ENERGY STORAGE↗
NASA NTRS2003

Analysis of Burst Observations by GLAST's LAT Detector

Analyzing data from GLAST's Large Area Telescope (LAT) will require sophisticated techniques. The PSF and effective area are functions of both photon energy and the position in the field-of-view. During most of the mission the observatory will survey the sky continuously and thus the LAT will detect each count from a source at a different detector orientation; each count requires its own response function! The likelihood as a function of celestial position and photon energy will be the foundation of the standard analysis techniques. However the 20 MeV-300 GeV emission at the time of the approx.100 keV burst emission (timescale of approx.10 s) can be isolated and analyzed because essentially no non-burst counts are expected within a PSF radius of the burst location during the burst. Both binned and unbinned (in energy) spectral fitting will be possible. Longer timescale afterglow emission will require the likelihood analysis that will be used for persistent sources.

Band, David L.↗
NASA NTRS1993

Scattered light in the echelle modes of the Goddard High Resolution Spectrograph aboard the Hubble Space Telescope. II - Analysis of in-flight spectroscopic observations

We report on an analysis of observations made with the GHRS aboard the HST for the purpose of calibrating the effects of scattered light. The data were obtained during the first 2 years of flight operations as part of the Science Verification, Science Assessment Observations, and Guaranteed Time Observations programs. Both the general level of background light near the spectra and the filling-in of the cores of saturated interstellar absorption lines have been determined as functions of grating, order, wavelength, and aperture. The behavior is in accordance with our detailed analysis of prelaunch laboratory data and validates both the observing procedures and the data reduction developed on the basis of that experience. We present and discuss the use of a background (scattered light) removal algorithm designed to produce net spectra properly corrected for the effects of grating scattered light. The coefficients of the scattered light removal algorithm have been determined, and recommended numerical values are presented.

Cardelli, Jason A.↗
NASA NTRS2018

Linking Improvements in Sulfur Dioxide Emissions to Decreasing Sulfate Wet Deposition by Combining Satellite and Surface Observations with Trajectory Analysis

Sulfur dioxide (SO2), a criteria pollutant, and sulfate (SO42) deposition are major environmental concerns in the eastern U.S. and both have been on the decline for two decades. In this study, we use satellite column SO2 data from the Ozone Monitoring Instrument (OMI), and SO42 wet deposition data from the NADP (National Atmospheric Deposition Program) to investigate the temporal and spatial relationship between trends in SO2 emissions and the downward sulfate wet deposition over the eastern U.S. from 2005 to 2015. To establish the relationship between SO2 emission sources and receptor sites, we conducted a Potential Source Contribution Function (PSCF) analysis using HYSPLIT back trajectories for five selected Air Quality System (AQS) sites - (Hackney, OH, Akron, OH, South Fayette, PA, Wilmington, DE, and Beltsville, MD) - in close proximity to NADP sites with large downward SO42 trends since 2005. Back trajectories were run for three summers (JJA) and three winters (DJF) and used to generate seasonal climatology PSCFs for each site. The OMI SO2 and interpolated NADP sulfate deposition trends were normalized and overlapped with the PSCF, to identify the areas that had the highest contribution to the observed drop. The results suggest that emission reductions along the Ohio River Valley have led to decreases in sulfate deposition in eastern OH and western PA (Hackney, Akron and South Fayette). Farther to the east, emission reductions in southeast PA resulted in improvements in sulfate deposition at Wilmington, DE, while for Beltsville, reductions in both the Ohio River Valley and nearby favorably impacted sulfate deposition. For Beltsville, sources closer than 300km from the site contribute roughly 56% observed deposition trends in winter, and 82% in summer, reflecting seasonal changes in transport pattern as well as faster oxidation and washout of sulfur in summer. This suggests that emissions and wet deposition are linked through not only the location of sources relative to the observing sites, but also to photochemistry and the weather patterns characteristic to the region, as evidenced by a west to east shift in the contribution between winter and summer. The method developed here is applicable to other regions with significant trends such as China and India, and can be used to estimate the potential benefits of emission reduction in those areas.

Acid depostion↗
NASA NTRS2018

Linking Improvements in Sulfur Dioxide Emissions to Decreasing Sulfate Wet Deposition By Combining Satellite and Surface Observations With Trajectory Analysis

Sulfur dioxide (SO2), a criteria pollutant, and sulfate (SO42−) deposition are major environmental concerns in the eastern U.S. and both have been on the decline for two decades. In this study, we use satellite column SO2 data from the Ozone Monitoring Instrument (OMI), and SO42− wet deposition data from the NADP (National Atmospheric Deposition Program) to investigate the temporal and spatial relationship between trends in SO2 emissions and the downward sulfate wet deposition over the eastern U.S. from 2005 to 2015. To establish the relationship between SO2 emission sources and receptor sites, we conducted a Potential Source Contribution Function (PSCF) analysis using HYSPLIT back trajectories for five selected Air Quality System (AQS) sites - (Hackney, OH, Akron, OH, South Fayette, PA, Wilmington, DE, and Beltsville, MD) - in close proximity to NADP sites with large downward SO42− trends since 2005. Back trajectories were run for three summers (JJA) and three winters (DJF) and used to generate seasonal climatology PSCFs for each site. The OMI SO2 and interpolated NADP sulfate deposition trends were normalized and overlapped with the PSCF, to identify the areas that had the highest contribution to the observed drop. The results suggest that emission reductions along the Ohio River Valley have led to decreases in sulfate deposition in eastern OH and western PA (Hackney, Akron and South Fayette). Farther to the east, emission reductions in southeast PA resulted in improvements in sulfate deposition at Wilmington, DE, while for Beltsville, reductions in both the Ohio River Valley and nearby favorably impacted sulfate deposition. For Beltsville, sources closer than 300 km from the site contribute roughly 56% observed deposition trends in winter, and 82% in summer, reflecting seasonal changes in transport pattern as well as faster oxidation and washout of sulfur in summer. This suggests that emissions and wet deposition are linked through not only the location of sources relative to the observing sites, but also to photochemistry and the weather patterns characteristic to the region, as evidenced by a west to east shift in the contribution between winter and summer. The method developed here is applicable to other regions with significant trends such as China and India, and can be used to estimate the potential benefits of emission reduction in those areas.

sulfur dioxide emissions↗
DOE OSTI2023

Surface Analysis Insight Note: Observations relating to photoemission peak shapes, oxidation state, and chemistry of titanium oxide films

It is common practice to describe the coordination of metal atoms in a binding configuration with their nearest neighbors in terms of oxidation state, a measure by which the number of electrons redistributed between atoms forming chemical bonds. In XPS terms, change to an oxidation state is commonly inferred by correlating photoemission signal with binding energy. The assumption, when classifying photoemission signals into distinct spectral shapes, is that a distribution of intensities shifted to lower binding energy is evidence of a reduction in oxidation state. In this Insight note, we raise the prospect that changes in photoemission peak shape may occur without obvious changes, determined by XPS in stoichiometry for a material. It is well known that TiO 2 measured by XPS yields reproducible Ti 2p photoemission peaks. However, on exposing TiO 2 to ion beams, Ti 2p photoemission evolves to complex distributions in intensity, which are particularly difficult to analyze by traditional fitting of bell-shaped curves to these data. For these reasons, in this Insight note, a thin film of TiO 2 deposited on a silicon substrate is chosen for analysis by XPS and linear algebraic techniques. Alterations in spectral shapes created from modified TiO 2 , which might be interpreted as the change in oxidation state, are assessed in terms of relative proportions of titanium to oxygen. It is found through detailed analysis of spectra that quantification by XPS, using procedures routinely used in practice, is not in accord with the typical interpretations of photoemission shapes. The data processing methods used and results presented in this work are of particular relevance to elucidating fundamental phenomena governing the surface evolution of materials-enabled energy processes where cyclic/non-steady usage changes the nature of bonding, especially in the presence of contaminants.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Symmetry-mode analysis for intuitive observation of structure-property relationships in the lead-free antiferroelectric (1-x)AgNbO 3 -xLiTaO 3

Functional materials are of critical importance to electronic and smart devices. A deep understanding of the structure–property relationship is essential for designing new materials. In this work, instead of utilizing conventional atomic coordinates, a symmetry-mode approach is successfully used to conduct structure refinement of the neutron powder diffraction data of (1-x)AgNbO3–xLiTaO3 (0 ≤ x ≤ 0.09) ceramics. This provides rich structural information that not only clarifies the controversial symmetry assigned to pure AgNbO3 but also explains well the detailed structural evolution of (1-x)AgNbO3–xLiTaO3 (0 ≤ x ≤ 0.09) ceramics, and builds a comprehensive and straightforward relationship between structural distortion and electrical properties. It is concluded that there are four relatively large-amplitude major modes that dominate the distorted Pmc21 structure of pure AgNbO3, namely a Λ3 antiferroelectric mode, a T4+ a-a-c0 octahedral tilting mode, an H2 a0a0c+/a0a0c- octahedral tilting mode and a Γ4- ferroelectric mode. The H2 and Λ3 modes become progressively inactive with increasing x and their destabilization is the driving force behind the composition-driven phase transition between the Pmc21 and R3c phases. This structural variation is consistent with the trend observed in the measured temperature-dependent dielectric properties and polarization–electric field (P-E) hysteresis loops. The mode crystallography applied in this study provides a strategy for optimizing related properties by tuning the amplitudes of the corresponding modes in these novel AgNbO3-based (anti)ferroelectric materials.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Transient Mass-loss Analysis of Solar Observations Using Stellar Methods

Low-frequency dynamic spectra of radio bursts from nearby stars offer the best chance to directly detect the stellar signature of transient mass loss on low-mass stars. Crosley et al. (2016) proposes a multi-wavelength methodology to determine coronal mass ejection (CME) parameters, such as speed, mass, and kinetic energy. We test the validity and accuracy of the results derived from the methodology by using Geostationary Operational Environmental Satellite X-ray observations and Bruny Island Radio Spectrometer radio observations. These are analogous observations to those that would be found in the stellar studies. Derived results from these observations are compared to direct white light measurements of the Large Angle and Spectrometric Coronagraph. We find that, when a pre-event temperature can be determined, the accuracy of CME speeds are within a few hundred km s{sup −1}, and are reliable when specific criteria has been met. CME mass and kinetic energies are only useful in determining the approximate order of magnitude measurements when considering the large errors associated to them. These results will be directly applicable to the interpretation of any detected stellar events and the derivation of stellar CME properties.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1994

Mission Operations Data Analysis Tools for Mars Observer Guidance and Control

The focus of this paper is on the data analysis tools for the Mars Observer Attitude and Articulation Control Subsystem (AACS). Four different categories of analysis tools are presented, with details offered for specific tools. These same tools, and extensions thereof, have been adopted by the Galileo mission operations, and are being designed into Cassini and other future spacecraft mission operations.

mission↗
DOE OSTI2017

Statistical analysis of MMS observations of energetic electron escape observed at/beyond the dayside magnetopause

Here, observations from the Energetic Particle Detector (EPD) instrument suite aboard the Magnetospheric Multiscale (MMS) spacecraft show that energetic (greater than tens of keV) magnetospheric particle escape into the magnetosheath occurs commonly across the dayside. This includes the surprisingly frequent observation of magnetospheric electrons in the duskside magnetosheath, an unexpected result given assumptions regarding magnetic drift shadowing. The 238 events identified in the 40 keV electron energy channel during the first MMS dayside season that exhibit strongly anisotropic pitch angle distributions indicating monohemispheric field-aligned streaming away from the magnetopause. A review of the extremely rich literature of energetic electron observations beyond the magnetopause is provided to place these new observations into historical context. Despite the extensive history of such research, these new observations provide a more comprehensive data set that includes unprecedented magnetic local time (MLT) coverage of the dayside equatorial magnetopause/magnetosheath. These data clearly highlight the common escape of energetic electrons along magnetic field lines concluded to have been reconnected across the magnetopause. While these streaming escape events agree with prior studies which show strong correlation with geomagnetic activity (suggesting a magnetotail source) and occur most frequently during periods of southward IMF, the high number of duskside events is unexpected and previously unobserved. Although the lowest electron energy channel was the focus of this study, the events reported here exhibit pitch angle anisotropies indicative of streaming up to 200 keV, which could represent the magnetopause loss of >1 MeV electrons from the outer radiation belt.

58 GEOSCIENCES↗
DOE OSTI2016

Edge dislocations in dicalcium silicates: Experimental observations and atomistic analysis

Understanding defects and influence of dislocations on dicalcium silicates (Ca{sub 2}SiO{sub 4}) is a challenge in cement science. We report a high-resolution transmission electron microscopy image of edge dislocations in Ca{sub 2}SiO{sub 4}, followed by developing a deep atomic understanding of the edge dislocation-mediated properties of five Ca{sub 2}SiO{sub 4} polymorphs. By decoding the interplay between core dislocation energies, core structures, and nucleation rate of reactivity, we find that γ-C2S and α-C2S polymorphs are the most favorable polymorphs for dislocations in Ca{sub 2}SiO{sub 4}, mainly due to their large pore channels which take away majority of the distortions imposed by edge dislocations. Furthermore, in the context of edge dislocation, while α-C2S represents the most active polymorph for reactivity and crystal growth, β-C2S represents the most brittle polymorph suitable for grinding. This work is the first report on the atomistic-scale analysis of edge dislocation-mediated properties of Ca{sub 2}SiO{sub 4} and may open up new opportunities for tuning fracture and reactivity processes of Ca{sub 2}SiO{sub 4} and other cement components.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Pressure-driven stochastization of flux surfaces in stellarator equilibria: a review of the experimental observations and their analysis

Stellarator vacuum fields are designed to have a dense set of nested flux surfaces, with only small islands and stochastic regions in the interior of the confinement region. As the plasma pressure is increased, pressure driven currents appear, and they can significantly modify the vacuum field. The question arises whether pressure driven currents can cause significant flux surface breakage. Both the Wendelstein 7-AS and large helical device stellarators had dedicated experimental campaigns to study the β limit in those devices. In this paper, we review the evidence that the flux surfaces in a significant fraction of the plasma volume were stochastized by the pressure-driven currents in the highest β experiments. That phenomenon appears to have been the dominant source of pressure-driven flux surface loss in these experiments.

stellarator equilibrium↗
DOE OSTI2019

Recent Third Pole's rapid warming accompanies cryospheric melt and water cycle intensification and interactions between monsoon and environment: Multidisciplinary approach with observation, modeling and analysis

The Third Pole (TP) is experiencing rapid warming and is currently in its warmest period in the past 2000 years. This paper reviews the latest development in multi-disciplinary TP research associated with this warming. The rapid warming facilitates intense and broad glacier melt over most of TP, although some glaciers in the northwest are advancing. By heating the atmosphere and reducing snow/ice albedo, aerosols also contribute to the glaciers melting. Glacier melt is accompanied by lake expansion and intensification of the water cycle over the TP. Precipitation has increased over the eastern and northwestern TP. Meanwhile, the TP is greening and most regions are experiencing advancing phenological trends although over the southwest there is a spring phenological delay mainly in response to the recent decline in spring precipitation. Atmospheric and terrestrial thermal and dynamical processes over the TP affect the Asian monsoon at different scales. Recent evidence indicates substantial roles that Meso-scale Convective Systems play in TP's precipitation as well as an association between soil moisture anomalies in TP and the Indian monsoon. Moreover, an increase in geo-hazard events has been associated with recent environmental changes, some of which have had catastrophic consequences caused by glacial lake outbursts and landslides. Active debris flows are growing in both frequency of occurrences and spatial scale. Meanwhile, new types of disasters, such as the twin ice avalanches in Ali in 2016, are now appearing in the region. Adaptation and mitigation measures should be taken to help societies' preparation for future environmental challenges. Some key issues for future TP studies are also discussed.

Third Pole's rapid warming, cryospheric melt↗
DOE OSTI2017

An Analysis of Coordinated Observations from NOAA’s Ronald H. Brown Ship and G-IV Aircraft in a Landfalling Atmospheric River over the North Pacific during CalWater-2015

Using a diverse suite of mobile observing platforms deployed on NOAA’s Ronald H. Brown (RHB) research vessel and G-IV research aircraft during the CalWater-2015 field campaign, this study describes the structure and evolution of a long-lived atmospheric river (AR) modulated by six frontal waves over the northeastern Pacific on 20-25 January 2015. Satellite observations and reanalysis diagnostics provided synoptic-scale context, illustrating the warm, moist southwesterly airstream within the quasi-stationary AR situated between an upper-level trough and ridge. The AR remained offshore of the U.S. West Coast but made landfall across British Columbia where heavy precipitation and high melting levels occurred, resulting in flooding. Forty-seven rawinsondes launched from the RHB provided a comprehensive thermodynamic and kinematic depiction of the AR, including an upward intrusion of strong water-vapor transport in the low-level moist southwesterly flow during the passage of frontal waves 2 through 6. A collocated 1290-MHz wind profiler showed an abrupt frontal transition from southwesterly to northerly flow below 1 km MSL coinciding with the tail-end of AR conditions. Shipborne radar and disdrometer observations in the AR uniquely captured key microphysical characteristics of shallow warm rain, convection, and deep mixed-phase precipitation. Continuous and novel observations of sea-surface fluxes documented persistent ocean-surface evaporation into the AR and sensible-heat transfer from the AR into the ocean. The G-IV aircraft coordinated with the RHB and flew directly over the ship. Dropsonde and radar spatial analyses complemented the temporal depictions of the AR from the RHB. The AR characteristics varied, depending on the location of the cross section through the frontal waves.

54 ENVIRONMENTAL SCIENCES↗