Search NASA⌕ Search

SEARCH · Search NASA

Results for “pitting”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Research on the Corrosion Behavior of X70 Pipeline Steel Under Coupling Effect of AC + DC and Stress

The coupling effect of stray AC (alternating current) + DC (direct current) and tensile stress-induced X70 pipeline corrosion is complicated with its mechanism uncovered. In this work, the corrosion behavior of X70 pipeline steel under three different corrosion (including an individual AC corrosion, mixed AC + 150 MPa tensile stress corrosion, coupling effect of AC + a 30 A/m{sup 2} DC interference and 150 MPa tensile stress corrosion) conditions in Dagang soil simulated solution was investigated by COMSOL Multiphysics software simulation, electrochemical tests, scanning electron microscope and other techniques. The results indicated that with the increase in AC density, the open-circuit potential of the X70 steel samples was negatively shifted and corrosion rate increased in three different corrosion conditions. The corrosion rates of X70 steel samples under individual AC interference were almost unchanged when 150.9 MPa tensile stress was applied. When applying 30 A/m{sup 2} DC interference, the corrosion rate of X70 steel increases significantly. Therefore, the factors affecting corrosion performance of X70 pipeline steel were DC > AC > stress. Under individual AC interference, uniform corrosion occurred on the X70 steel at an AC current density of less than 30 A/m{sup 2}, while the pitting corrosion occurred at an AC current density of greater than 100 A/m{sup 2}. The application of tensile stress and DC had a certain inhibitory effect on pitting corrosion.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Li Morphology Evolution during Initial Cycles in a Gel Composite Polymer Electrolyte

Understanding and controlling lithium morphology evolution and lithium dendrite formation and growth during cycling is one of the key challenges for high-energy lithium metal batteries. This challenge applies to liquid electrolyte batteries as well as solid-state and semi-solid-state batteries. Our current knowledge about the evolution of the Li morphology is mostly obtained from liquid electrolyte-based studies in a Li–Li symmetrical cell configuration. The knowledge obtained in such conditions may not readily transfer into solid-state or semi-solid-state batteries. In this work, Li morphology evolution during initial cycling in a full cell configuration with the LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NMC 622) cathode and a semi-solid-state gel composite electrolyte is monitored via post-mortem photographs and scanning electron microscopy at multiple length scales. The gel composite electrolyte contains a cross-linked poly(ethylene oxide)-based polymer electrolyte, ceramic fillers, and a liquid plasticizer. The results show that severe surface pitting occurs as early as the second stripping cycle. Pit formation and continuous dissolution during the stripping process are the main cause of the Li surface roughening and dendrite growth mechanism in the model gel composite electrolyte. Comparing Li dendrite growth mechanisms in liquid, polymer, and ceramic solid electrolytes, the dendrite growth mechanism observed in this model electrolyte resembles that of the liquid electrolyte the most. This study suggests that strategies to control Li morphology and prevent dendrite growth in a gel composite electrolyte should be similar to strategies applicable to liquid electrolytes.

25 ENERGY STORAGE↗
DOE OSTI2018

The Development of the Corrosion Control Limits for Direct Feed Low-Activity Waste Melter-Off Gas Returns to Hanford Tank Farms - 18196

The Savannah River National Laboratory has been developing a corrosion model to facilitate implementation of Hanford's Direct Feed Low Waste (DFLAW) flowsheet. Laboratory testing and statistical analysis have been used to determine the necessary corrosion controls for returning effluent from the Hanford Waste Treatment and Immobilization Plant's Low Activity Waste Vitrification melter off-gas treatment system to the tank farms. The stream compositions are projected to contain components at relative concentrations that are significantly more corrosive toward carbon steel, specifically halide and sulfate anions, than the current waste compositions in the tank farms. Administrative programs are in place to mitigate potential corrosion mechanisms and thereby maintain the structural and leak integrity functions of these waste tanks throughout their intended service life. Waste chemistry and temperature control are the means by which corrosion degradation of the waste tanks is minimized. The current administrative specification for chemical composition and temperature for the underground carbon steel waste tanks is not designed to control the higher halide or sulfate composition. The content of the DFLAW waste streams will be diverse and depend on several factors, such as the melter feed composition and melter idle time. Other factors, such as effluent management of the off gas water collections, will impact the variability of the return streams even more. The work performed by the Savannah River National Laboratory has confirmed that the halide ions are the most aggressive species in the return stream compositions projected using a flowsheet simulation, and nitrite is the most effective inhibitor at pH 10 and 40 deg. C. This test program has employed statistically designed test matrices to determine the dependent variables and the interaction terms between the variables that are significant for the corrosion model and definition of the corrosion control specifications. The first phase of testing focused on identifying aggressive species in off-gas condensate return compositions that present a propensity for localized corrosion attack, namely pitting corrosion. The second phase of testing focused on developing a corrosion model from the interaction terms that will predict the susceptibility of pitting in the double shell tank system based on waste composition and the required amount of corrosion inhibitor. The data collected from this testing program in conjunction with other testing programs, both at the Savannah River Site and the Hanford Site, along with operations knowledge, has determined the chemistry ranges and chemical species requirements for corrosion control in the Hanford double-shell tank system for the effluents generated in the Hanford Waste Treatment and Immobilization Plant's Low Activity Waste facility during the DFLAW phase of operations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Age at Release, Size, and Maturation Status Influence Residualism in Hatchery Steelhead

Abstract Steelhead Oncorhynchus mykiss that fail to emigrate seaward after release from hatcheries, commonly referred to as “residuals,” can have negative impacts on natural populations ranging from competition and predation to interbreeding with returning anadromous adults. We investigated how age at release, size, and maturation status influenced the rate of residual production in hatchery summer-run steelhead released from the Winthrop National Fish Hatchery (Methow River, Washington) between 2010 and 2015. Migration data from 21,598 individuals implanted with PIT tags identified 1,783 residual steelhead expressing two distinct phenotypes: immature male and female parr; and precociously mature males. We found that age at release significantly affected the predominant residual phenotype. Age-1 steelhead residuals (S1 rearing strategy) were dominated by smaller parr of both sexes (fish < 146 mm FL), while age-2 residuals (S2 rearing strategy) were dominated by mature males, although both phenotypes were present in both S1 and S2 residual groups. Collections of residual steelhead in the Methow River indicated that parr phenotype residuals grew as well as natural-origin juvenile O. mykiss, suggesting potential competition for food resources and habitat. Detections of PIT tags within the Methow River basin indicated that precocious male residuals may overlap both spatially and temporally with previously documented spawning anadromous adults, posing a potential genetic management risk. Both residual phenotypes had poor overwinter survival, and only 1 of the 1,783 residual fish eventually returned to the Methow River as an anadromous adult. We conclude that the ecological and genetic consequences of residual steelhead far outweigh their potential contribution to anadromous production, and measures should be taken to reduce their production by changing hatchery rearing practices.

Tatara, Christopher P.↗
DOE OSTI2021

Performance of Subyearling Fall Chinook Salmon Tagged with 8-, 9-, and 12-mm Passive Integrated Transponder Tags in the Snake River

Abstract Inferences based on tagged individuals from a population are limited in part by the minimum size of fish that can be tagged. Smaller tags allow a greater proportion of a population to be represented by tagging and should reduce potential tag effects on fish performance. We evaluated different performance metrics of juvenile fall Chinook Salmon Oncorhynchus tshawytscha tagged with 8-, 9-, and 12-mm PIT tags in the Snake River. We did not find evidence that posttagging mortality of 45–49-mm-FL fish tagged with 8-mm tags was higher than the posttagging mortality of larger fish tagged with 9- and 12-mm tags. The incisions of fish tagged with 8-mm tags using 14-guage needles healed faster than those of fish tagged with larger tags using 12-guage needles. For individuals that received 8-mm tags, growth in length and mass was higher for 45–49-mm fish than for 50–59-mm fish and 60-mm and larger fish. Growth of the larger size-classes (50–59 and ≥60 mm) was also generally higher for those tagged with 8-mm tags compared to those tagged with 9- and 12-mm tags, respectively. There were no strong relationships between tag burden (i.e., tag weight expressed as a percentage of fish weight) at the time of tagging and growth metrics for any tag size or fish size-class. Releases made to compare the detection efficiency of the three tag types in the juvenile fish bypass at Lower Granite Dam, Washington, showed that 99–100% of all fish were detected. Survival of fish from rearing areas to Lower Granite Dam generally increased with fish size and varied by year, but there was no strong evidence of a tag size effect. The 8-mm PIT tag allowed us to represent a larger portion (i.e., 6.2–24.1%) of the subyearling fall Chinook Salmon population in the Snake River without compromising fish performance or detectability at the dam.

Tiffan, Kenneth F.↗
DOE OSTI2016

Performance of a Vertical‐Slot Fish Pass for the Sea Lamprey Petromyzon marinus L. and Habitat Recolonization

Abstract In 2011, a vertical‐slot fish pass was built at the Coimbra Açude‐Ponte dam (Mondego River, Portugal), approximately 45 km upstream from the river mouth. The performance of this infrastructure for sea lamprey passage was evaluated between 2011 and 2015 using several complementary methodologies, namely radio telemetry [conventional and electromyogram (EMG)], passive integrated transponder (PIT) telemetry and electrofishing surveys. During the study period, the electrofishing revealed a 29‐fold increase in the abundance of larval sea lamprey upstream of the fish pass. Of the 20 radio‐tagged individuals released downstream from the dam, 33% managed to find and successfully surpass the obstacle in less than 2 weeks, reaching the spawning areas located in the upstream stretch of the main river and in one important tributary. Fish pass efficiency was assessed with a PIT antenna installed in the last upstream pool and revealed a 31% efficiency, with differences between and within migratory seasons. Time of day and river flow significantly influenced the attraction efficiency of the fish pass, with lampreys negotiating it mainly during the night period and when discharge was below 50 m 3 s −1 . Sea lampreys tagged with EMG transmitters took 3 h to negotiate the fish pass, during which high muscular effort was only registered during passage, or passage attempts, of the vertical slots. The use of complementary methodologies provided a comprehensive passage evaluation for sea lamprey, a species for which there is a considerable paucity of valuable data concerning behavioural, physiological and environmental influences on obstacle negotiation. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd.

Pereira, E.↗
DOE OSTI2019

Design and characterization of Ion sources for CHIP-TRAP

At Central Michigan University, we are developing a high-precision Penning trap mass spectrometer (CHIP-TRAP) for precise mass measurements with stable and long-lived isotopes. Ions will be produced using external ion sources and then transported to the Penning trap at low energy using electrostatic ion optics. Ion sources that will be utilized with CHIP-TRAP include a laser ablation ion source (LAS) that has already been commissioned, and a low current Penning ion trap (PIT) source that is currently being developed. The LAS enables ion production from solid targets via ablation and ionization with a high-powered laser pulse. The PIT source is a novel Penning ionization gauge (PIG) type source, consisting of a 0.55 T NdFeB ring magnet, cylindrical Penning trap, and low current thermal electron emitter that enables ion production via electron impact ionization of gaseous samples. For both ion sources, small bunches of ~100 – 1000 ions can be produced from a minimal sample of source material. Finally, the ion bunches are then transported along the CHIP-TRAP beamline, where time-of-flight mass filtering can be performed before they are captured in the CHIP-TRAP Penning traps.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Variation of the Passive Film on Compositionally Concentrated Dual-Phase Al 0.3 Cr 0.5 Fe 2 Mn 0.25 Mo 0.15 Ni 1.5 Ti 0.3 and Implications for Corrosion

The passive film on a dual-phase Al 0.3 Cr 0.5 Fe 2 Mn 0.25 Mo 0.15 Ni 1.5 Ti 0.3 FCC + Heusler (L2 1 ) compositionally concentrated alloy formed during extended exposure to an applied potential in the passive range in dilute chloride solution was characterized. Each phase, with its own distinct composition of passivating elements, formed unique passive films separated by a heterophase interface. High-resolution, surface sensitive characterization enabled chemical analysis of the passive film formed over individual phases. The film formed over the L2 1 phase had a higher concentration of Al, Ni, and Ti, while the film formed over FCC phase was of similar thickness but contained comparatively higher Cr, Fe, and Mo concentrations, consistent with the differences in bulk microstructure composition. The passive film was continuous across phase boundaries and the distribution of passivating elements (Al, Cr, and Ti) indicated both phases were independently passivated. Spatially resolved analysis of the surface chemistry of the dual-phase CCA revealed that the cation with the highest composition in passive film formed on the FCC phase was Cr (52.4 at. pct) and for the L2 1 phase was Ti (53.1 at. pct) despite the bulk concentration of each element being below 20 at. pct in their respective phases. Al, Cr, and Ti were enriched in both phases within the passive film relative to their respective bulk compositions. In parallel studies, single-phase alloys with compositions representative of the FCC and L2 1 phases were synthesized to evaluate the corrosion behavior of each phase in isolation. The corrosion behavior of the dual-phase alloy showed passivity evidenced by a pitting potential of 0.615 V SCE in 0.01 M NaCl. The pitting potential and other electrochemical parameters suggested a combination of behaviors of both single-phase samples, suggesting that the global corrosion behavior may be represented by a composite theory applied to phases, their area fractions, and interphase length. However, the interphase in the dual-phase CCA was a local corrosion initiation site and may limit localized corrosion protectiveness. The alloy design implications for optimization of second phase structure and morphology are discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2018

A Micro-Mechanism-Based Continuum Corrosion Fatigue Damage Model for Steels

A micro-mechanism-based corrosion fatigue damage model is developed for studying the high-cycle corrosion fatigue of steel from multi-scale viewpoint. The developed physical corrosion fatigue damage model establishes micro-macro relationships between macroscopic continuum damage evolution and collective evolution behavior of microscopic pits and cracks, which can be used to describe the multi-scale corrosion fatigue process of steel. As a case study, the model is used to predict continuum damage evolution and number density of the corrosion pit and short crack of steel component in 5% NaCl water under constant stress amplitude at 20 kHz, and the numerical results are compared with experimental results. It shows that the model is effective and can be used to evaluate the continuum macroscopic corrosion fatigue damage and study microscopic corrosion fatigue mechanisms of steel.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effect of Low-Temperature Sensitization on the Corrosion Behavior of AISI Type 304L SS Weld Metal in Simulated Groundwater

The manuscript presents the investigations carried out on the effect of low-temperature sensitization (LTS) of 304L SS weld metal on its corrosion behavior in simulated groundwater, for its application as a canister material for long-term storage of nuclear vitrified high-level waste in geological repositories. AISI type 304L SS weld pad was fabricated by multipass gas tungsten arc welding process using 308L SS filler wire. The as-welded specimens were subsequently subjected to carbide nucleation and further to LTS at 500 °C for 11 days to simulate a temperature of 300 °C for 100-year life of the canister in geological repositories. Delta ferrite (δ-ferrite) content of the 304L SS weld metal substantially decreased on carbide nucleation treatment and further only a marginal decrease occurred on LTS treatment. The microstructure of the as-welded consisted of δ-ferrite as a minor phase distributed in austenite matrix. The δ-ferrite appeared fragmented in the carbide-nucleated and LTS-treated weld metal. The degree of sensitization measured by double-loop electrochemical potentokinetic reactivation method indicated an increase in carbide nucleation treatment when compared to the as-welded specimens, and further increase occurred on LTS treatment. Potentiodynamic anodic polarization investigations in simulated groundwater indicated a substantial decrease in the localized corrosion resistance of the carbide-nucleated and LTS 304L SS weld metals, when compared to the as-welded specimens. Post-experimental micrographs indicated pitting as the primary mode of attack in the as-welded, while pitting and intergranular corrosion (IGC) occurred in the carbide-nucleated weld metal. LTS-treated weld metal predominantly underwent IGC attack. The decrease in the localized corrosion resistance of the weld metal after LTS treatment was found to have a direct correlation with the degree of sensitization and the weld microstructure. The results are detailed in the manuscript.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Systematic Insight into Chloride Concentration, Applied Potential and Time Effect on the Passive Film of Cu-Zn-Ni Ternary Alloy in Alkaline Solution

The effects of chloride concentration, applied potential and time on the passive film of Cu-Zn-Ni ternary alloy in alkaline solution were systematically investigated using potentiodynamic and potentiostatic polarizations, electrochemical impedance spectroscopy, Mott–Schottky analysis, laser confocal microscopy, atomic force microscopy and x-ray photoelectron spectroscopy. Results showed that the pitting potential decreased as a linear function of log(a{sub Cl{sup −}}), and the size of pits extended faster in the horizontal direction than in the vertical direction. The passive oxide film formed on Cu-Zn-Ni alloy mainly exhibited p-type semiconductor behavior, which was consistent with cuprous and nickel oxide, the main components in the film. The density of cation vacancy (approximately 10{sup 20}-10{sup 21} cm{sup −3}) increased with potentiostatic time but reduced by the increasing potentials. The kinetics of passive film growth followed a parabolic law D = m * t{sup n}, where m is a constant considered as the initial growth rate and n is the time exponent. Subsequent to the formation of a compact and coherent passive film at higher potential, it was hard for an ion to migrate or for an aggressive ion to penetrate, which indicated better corrosion resistance for passive film formed under higher potential.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Corrosion Behavior of Q235 Steel Exposed in Deepwater of South China Sea

For the first time, the corrosion behavior of Q235 steel in 1200, 2000 and 3000 m deepwater of South China Sea for 0.5 year was reported in this study. The corrosion morphology and corrosion products properties were investigated using different techniques, such as 3D optical microscope, scanning electron microscope, x-ray diffraction analyzer and electrochemical impedance spectroscopy. The main environmental factors influencing the corrosion rate of Q235 in deep sea were discussed by applying gray relational analysis. The results indicated that uniform thinning occurred after exposure. A large number of tiny pits were distributed under the corrosion products with a two-layer structure. The corrosion rate and average pitting depth of samples exposed at 2000 m were lower than those exposed at 1200 and 3000 m, and the main environmental factors determining the variation of corrosion rate at different depths were temperature and dissolved oxygen concentration. Hydrostatic pressure had slight effect on the corrosion rate of Q235 steel, but promoted the formation of a more uniform corrosion morphology.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Effect of thermal aging on corrosion behavior of duplex stainless steels

Abstract Despite their exceptional mechanical and corrosion properties, duplex stainless steels (DSS) have not found widespread use in high-temperature applications due to concerns over thermal aging and embrittlement at elevated operational temperatures (> 300 °C). The present study investigated the effect of thermal aging time on the electrochemical properties of lean and standard grade DSS that are exposed to a range of pressurized water reactors containing LiOH and H 3 BO 3 . The results indicated that the electrolyte chemistry plays a significant role in the corrosion behavior of the DSS alloys. Corrosion resistance decreased with thermal aging time for all DSS alloys; however, standard grade DSS (2205 and 2209-w) alloys showed better corrosion resistance than lean grades (2003, 2101, 2101-w). The presence of dissolved oxygen in the electrolytes resulted in a significant increase in corrosion rate for the DSS alloys, but it did not affect the general trend of corrosion rates with aging time. All DSS alloys became vulnerable to pitting corrosion due to chloride addition, but the pitting resistance decreased with increasing thermal aging time. Increased boron B content resulted in degradation of corrosion resistance of the DSS alloys, while minor changes in pH did not show a significant change in corrosion resistance. Mechanical and metallurgical characterization coupled with electrochemical characterization of the DSS alloys gave a comprehensive insight into the effects of thermal aging on the electrochemical response of the DSS. Graphical abstract

Murkute, Pratik (ORCID:0000000278636346)↗
DOE OSTI2020

Nonaxisymmetric Shapes of Biological Membranes from Locally Induced Curvature

In various biological processes such as endocytosis and caveolae formation, the cell membrane is locally deformed into curved morphologies. Previous models to study membrane morphologies resulting from locally induced curvature often only consider the possibility of axisymmetric shapes-an indeed unphysical constraint. Past studies predict that the cell membrane buds at low resting tensions and stalls at a flat pit at high resting tensions. In this work, we lift the restriction to axisymmetry to study all possible membrane morphologies. Only if the resting tension of the membrane is low, we reproduce axisymmetric membrane morphologies. When the resting tension is moderate to high, we show that 1) axisymmetric membrane pits are unstable and 2) nonaxisymmetric ridge-shaped structures are energetically favorable. Furthermore, we find the interplay between intramembrane viscous flow and the rate of induced curvature affects the membrane's ability to transition into nonaxisymmetric ridges and axisymmetric buds. In particular, we show that axisymmetric buds are favored when the induced curvature is rapidly increased, whereas nonaxisymmetric ridges are favored when the curvature is slowly increased. Overall, our results hold relevant implications for biological processes such as endocytosis and physical phenomena like phase separation in lipid bilayers.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Influence of carbon nanotubes on microstructure and corrosion performance of additively manufactured 316L stainless steel

For this study, laser powder bed fusion (LPBF) was performed on feedstock-modified 316L stainless steel powder with 1 and 2 vol% carbon nanotubes (CNT). The corrosion resistance was evaluated following cyclic potentiodynamic polarization tests conducted in 0.6 M NaCl at room temperature, 35 and 50 °C, and immersion tests in 6 % FeCl 3 . The CNT addition has increased the pitting potential and decreased number of pits formed during immersion in FeCl 3 solution, which could be attributed to Mn-Si-O nano inclusions refinement and segregation of chromium around the inclusions. The observed corrosion behavior was correlated with the altered microstructure due to CNT addition.

36 MATERIALS SCIENCE↗
DOE OSTI2020

An anode-free Li metal cell with replenishable Li designed for long cycle life

Pit corrosion of Li during stripping is an important factor responsible for poor Li cycling efficiency, a metric that determines its cycling life. When excess Li is present, it has been observed that Li tends to strip in a non-uniform fashion, forming pits that extend well past the theoretical Li depth that inevitably lead to the formation of electronically isolated “dead” Li particles. In this work, a novel cell with replenishable Li is shown to inherently mitigate the formation of this “dead” Li, as a direct result of a design in which the intrinsically more homogenous stripping behavior of anode-free cells are combined with a replenishable limited Li reservoir. These novel cells (Li|Cu||LiFePO 4 ) exhibit 25% and 34% higher cumulative capacities than the conventional cells (Cu|Li||LiFePO 4 ) in carbonate and ether electrolytes, respectively, enabling a significant increase in cycle life without impacting energy density. This improvement strategy represents a new direction in Li metal battery improvement, in which improved cycling can be achieved regardless of electrolyte chemistry.

Long cycle life↗
DOE OSTI2018

Quantifying dry supercritical CO 2 -induced changes of the Utica Shale

Traditionally, shale formations have been studied as sealing layers that prevent vertical migration of hydrocarbons and CO2 due to their low permeability and fracture porosity. Recent research has focused on storing CO2 in hydrocarbon-bearing shale formations that have already undergone depletion through primary production and using CO2 as a potential fracturing agent for unconventional reservoirs. The injected CO2 will interact with shale components (i.e. clays, organic matter) and affect rock properties through chemical alteration, matrix swelling/shrinkage, and related geomechanical effects. As changes in rock properties will impact both anthropogenic CO2 storage and hydraulic fracturing, it is imperative to increase our understanding of the CO2-shale interactions. In-situ Fourier Transform infrared (FT-IR) spectroscopy coupled with high temperature and pressure capability was used to examine the interaction of dry CO2 on Utica Shale, clay, and kerogen samples at the molecular scale and characterize vibrational changes of sorption bands sensitive to the gas-solid environment. The Utica Shale was also analyzed for micro and macro-scale chemical and physical changes before and after exposure to dry CO2 at subsurface storage conditions using surface relocation techniques via high-resolution field-emission scanning electron microscopy (FE-SEM). Brunauer-Emmett-Teller (BET) surface area/pore size analysis and quantitative adsorption isotherms were applied to understand changes in surface area, pore volumes, and understand the storage potential of CO2 in the Utica Shale sample. FT-IR and feature relocation via FE-SEM indicate carbonate formation and dissolution occurs in shale exposed to dry CO2. Results indicate that etching and pitting occur, with minor calcite precipitation along the surface of the shale sample. Quantitative isotherm results indicate that shales with a higher content of kerogen and illite-smectite clays would be expected to have the highest CO2 storage capacity provided these constituents were accessible for interaction.

04 OIL SHALES AND TAR SANDS↗