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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 307 records · Page 17
All sourcesNASA NTRSDOE OSTI
NASA NTRS1956

A thermal equation for flame quenching

An approximate thermal equation was derived for quenching distance based on a previously proposed diffusional treatment. The quenching distance was expressed in terms of the thermal conductivity, the fuel mole fraction, the heat capacity, the rate of the rate-controlling chemical reaction, a constant that depends on the geometry of the quenching surface, and one empirical constant. The effect of pressure on quenching distance was shown to be inversely proportional to the pressure dependence of the flame reaction, with small correction necessitated by the effect of pressure on flame temperature. The equation was used with the Semenov equation for burning velocity to show that the quenching distance was inversely proportional to burning velocity and pressure at any given initial temperature and equivalence ratio.

Potter, A E , Jr↗
DOE OSTI2024

Materials descriptors for advanced water dissociation catalysts in bipolar membranes

The voltage penalty driving water dissociation (WD) at high current density is a major obstacle in the commercialization of bipolar membrane (BPM) technology for energy devices. Here, in this study, we show that three materials descriptors, that is, electrical conductivity, microscopic surface area and (nominal) surface-hydroxyl coverage, effectively control the kinetics of WD in BPMs. Using these descriptors and optimizing mass loading, we design new earth-abundant WD catalysts based on nanoparticle SnO 2 synthesized at low temperature with high conductivity and hydroxyl coverage. These catalysts exhibit exceptional performance in a BPM electrolyser with low WD overvoltage (η wd ) of 100 ± 20 mV at 1.0 A cm -2 . The new catalyst works equivalently well with hydrocarbon proton-exchange layers as it does with fluorocarbon-based Nafion, thus providing pathways to commercializing advanced BPMs for a broad array of electrolysis, fuel-cell and electrodialys is applications.

Sasmal, Sayantan↗
DOE OSTI2021

Effect of the Addition of a Low Equivalent Stress Mechanism to the Analysis of Geomechanical Behavior of the SPR West Hackberry Site

Sandia National Laboratories has long used the Munson-Dawson (M-D) model to predict the geomechanical behavior of salt caverns used to store oil at the Strategic Petroleum Reserve (SPR). Salt creep causes storage caverns to deform inward, thus losing volume. This loss of volume affects the salt above and around the caverns, puts stresses and strains on borehole casings, and creates surface subsidence which affects surface infrastructure. Therefore, accurate evaluation of salt creep behavior drives decisions about cavern operations. Parameters for the M-D model are typically fit against laboratory creep tests, but nearly all historic creep tests have been performed at equivalent stresses of 8 MPa or higher. Creep rates at lower equivalent stresses are very slow, such that tests take months or years to run, and the tests are sensitive to small temperature perturbations (<0.1°C). A recent collaboration between US and German researchers, recently characterized the creep behavior at low equivalent (deviatoric) stresses (<8 MPa) of salt from the Waste Isolation Pilot Plant. In addition, the M-D model was recently extended to include a low stress creep “mechanism”. This paper details new simulations of SPR caverns that use this extended M-D model, called the M-D Viscoplastic model. The results show that the inclusion of low stress creep significantly alters the prediction of steady-state cavern closure behavior and indicate that low stress creep is the dominant displacement mechanism at the dome scale. The implications for evaluating cavern and well integrity are demonstrated by investigating three phenomena: the extent of stress changes around the cavern; the predicted vertical strains applied to wellbore casings; and the evaluation of oscillating stress changes around the cavern due to oil sale cycles and their potential effect on salt fatigue.

58 GEOSCIENCES↗
NASA NTRS2015

Suomi-NPP VIIRS Solar Diffuser Stability Monitor Performance

When illuminated by the Sun, the onboard solar diffuser (SD) panel provides a known spectral radiance source to calibrate the reflective solar bands of the Visible Infrared Imaging Radiometer Suite on the Suomi-NPP satellite. The SD bidirectional reflectance distribution function (BRDF) degrades over time due to solar exposure, and this degradation is measured using the SD stability monitor (SDSM). The SDSM acts as a ratioing radiometer, comparing solar irradiance measurements off the SD panel to those from a direct Sun view. We discuss the design and operations of the SDSM, the SDSM data analysis, including improvements incorporated since launch, and present the results through 1000 days after launch. After 1000 days, the band-dependent H-factors, a quantity describing the relative degradation of the BRDF of the SD panel since launch, range from 0.716 at 412 nanometers to 0.989 at 926 nanometers. The random uncertainty of these H-factors is about 0.1 percent, which is confirmed by the similar standard deviation values computed from the residuals of quadratic exponential fits to the H-factor time trends. The SDSM detector gains have temperature sensitivity of up to about 0.36 percent per kelvin, but this does not affect the derived H-factors. An initial error in the solar vector caused a seasonal bias to the H-factors of up to 0.5 percent. The total exposure of the SD panel to UV light after 1000 orbits is equivalent to about 100 hours of direct sunlight illumination perpendicular to the SD panel surface.

Fulbright, Jon↗
NASA NTRS1985

Characteristics of Basaltic Lava Flows on Venus

Some ideas relating to the formation of lava flows on Venus are reviewed. The surface morphological features seen in the panoramic images made by the Venera 13 and 14 landers are examined in detail. The major element compositions measured by the Soviet probes indicate that the surface rocks at the Venera 13 site resemble a terrestrial tholeite composite whereas the Venera 14 rocks are similar to terrestrial alkali basalts. Few data exist on the rheological properties of such magma types on Earth; these properties are a strong function of magma volatile content, and there are important gaps in our knowledge of the typical volatiles to be associated with the magmas on Venus. However, the suggestion that Venusian magmas may be water poor together with consideration of the fact that the high Venusian surface temperatures may cause magmas to experience up to 50 K less cooling during their rise to the surface than corresponding terrestrial counterparts, leads to the finding that Venusian magmas may typically have plastic viscosities, E, up to a factor of three greater than terrestrial counterparts on eruption. A similar analysis of yield strength variations with temperature, magma composition and volatile content suggests that temperature will exert the main control and that Venusian magma yield strengths, Y, may be a factor of several times smaller than those of terrestrial equivalents.

Wilson, L.↗
NASA NTRS2000

Space Environmentally Stable Polyimides and Copolyimides

Polyimides with a unique combination of properties including low color in thin films, atomic oxygen (AO), ultra-violet (UV) radiation resistance, solubility in organic solvents in the imide form, high glass transition (T(sub g)) temperatures and high thermal stability have been prepared and characterized. The polymers were prepared by reacting a novel aromatic diamine with aromatic dianhydrides in a polar aprotic solvent. The solubility of the polymers in the imide form as well as the color density of thin films were dependent upon the chemical structure of the dianhydride. Several thin films (25-50 mm thick) prepared by solution casting of amide acid or imide solutions exhibited very low color and high optical transparency (approximately 90%) as determined by UV/visible spectroscopy. The polymers exhibited T(sub g)s >200 C depending upon the structure of the dianhydride and temperatures of 5% weight loss approximately 500C in air as determined by dynamic thermogravimetric analysis. Thin films coated with silver/inconel were exposed to a high fluence of AO and 1000 equivalent solar hours of UV radiation. The effects of these exposures on optical properties were minor. These space environmentally durable polymers are potentially useful in a variety of applications on spacecraft such as thin film membranes on antennas, second-surface mirrors, thermal/optical coatings and multi-layer thermal insulation (MLI) blanket materials. The chemistry, physical and mechanical properties of the polymers as well as their responses to AO and UV exposure will be discussed.

Watson, Kent A.↗
NASA NTRS2017

Validation of Globsnow-2 Snow Water Equivalent Over Eastern Canada

In Qubec, Eastern Canada, snowmelt runoff contributes more than 30% of the annual energy reserve for hydroelectricity production, and uncertainties in annual maximum snow water equivalent (SWE) over the region are one of the main constraints for improved hydrological forecasting. Current satellite-based methods for mapping SWE over Qubec's main hydropower basins do not meet Hydro-Qubec operational requirements for SWE accuracies with less than 15% error. This paper assesses the accuracy of the GlobSnow-2 (GS-2) SWE product, which combines microwave satellite data and in situ measurements, for hydrological applications in Qubec. GS-2 SWE values for a 30-year period (1980 to 2009) were compared with space- and time-matched values from a comprehensive dataset of in situ SWE measurements (a total of 38,990 observations in Eastern Canada). The root mean square error (RMSE) of the GS-2 SWE product is 94.1+/- 20.3 mm, corresponding to an overall relative percentage error (RPE) of 35.9%. The main sources of uncertainty are wet and deep snow conditions (when SWE is higher than 150 mm), and forest cover type. However, compared to a typical stand-alone brightness temperature channel difference algorithm, the assimilation of surface information in the GS-2 algorithm clearly improves SWE accuracy by reducing the RPE by about 30%. Comparison of trends in annual mean and maximum SWE between surface observations and GS-2 over 1980-2009 showed agreement for increasing trends over southern Qubec, but less agreement on the sign and magnitude of trends over northern Qubec. Extended at a continental scale, the GS-2 SWE trends highlight a strong regional variability.

Snow water equivalent↗
DOE OSTI2020

Modeling Nondestructive Defect Detection in Additively Manufactured Metallic Structures for Nuclear Applications

The future of quickly, economically produced metallic nuclear reactor parts with minimal supply-chain dependence lies in Laser Powder Bed Fusion (LPBF) Additive Manufacturing (AM): a 3D printing method involving laser melting and net shaping stainless steel and Inconel metallic powder into a solid structure. However, intrinsic features in LPBF frequently leads to the formation of materials defects, such as pores, within 3D printed structures. As safe long-term use in energy applications requires knowledge of all relevant defects before deployment in a reactor, we must develop methods for nondestructive detection of these defects. We are investigating Pulsed Thermal Tomography (PTT), which is a non-contact nondestructive imaging method scalable to arbitrary structure size. Thermal tomography (TT) is a computational method for 3D spatial reconstruction of material thermal effusivity from flash or pulsed thermography temperature data cube. Thermography data cube consists of 2D surface temperature measurements at different times. The objective of the present work is to investigate limits on defect detection in AM metallic structures with PTT. To this effect, we modeled PTT with COMSOL heat transfer computer simulations. We developed a layered media COMSOL simulation consisting of a Stainless Steel 316 (SS316) plate with an internal layer of un-sintered SS316 powder. Thermophysical properties of the powder layer were modeled with equivalent volume mixing model. To account for partial sintering at the boundary of the defect, the transition between solid and powder layers was modeled as a Gaussian. Using data from COMSOL simulations, we reconstructed depth-dependent thermal effusivity, which allowed defect visibility estimation. A series of parametric studies determined that at 1mm depth, 50µm is the smallest detectable defect. In addition, classification of the defects which can lead to early fatigue of the metallic structure in a reactor is briefly discussed.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS2002

Chandra Discovery of Luminous Supersoft X-Ray Sources in M81

A Chandra ACIS-S imaging observation of the nearby galaxy M81 (NGC 3031) reveals 9 luminous soft X-ray sources. The local environments, X-ray spectral properties, and X-ray light curves of the sources are presented and discussed in the context of prevailing physical models for supersoft sources. It is shown that the sample falls within expectations based on population synthesis models taken from the literature though the high observed luminosities (L approx.2e36 to approx.3e38 ergs in the 0.2--2.0-keV band) and equivalent blackbody temperatures (T approx.40 to 80 eV) place the brightest detected M81 objects at the high luminosity end of the class of supersoft sources defined by previous ROSAT and Einstein studies of nearby galaxies. This is interpreted as a natural consequence of the higher sensitivity of Chandra to hotter and more luminous systems. Most of the sources can be explained as canonical supersoft sources, secreting white dwarfs powered by steady surface nuclear burning, with X-ray spectra well-fit by hot white dwarf local thermodynamic equilibrium atmosphere models. An exceptionally bright source is scrutinized in greater detail as its estimated barometric luminosity, L approx. 1.5e39 ergs, greatly exceeds theoretical estimates for supersoft sources. This source may be beyond the stability limit and undergoing a phase of mass outflow under extreme conditions. Alternatively, a model in which the observed X-ray spectrum arises from an accretion disk around a blacklists of mass approx.1200/sqrt(cosi) solar masses (viewed at an inclination angle 1) cannot be excluded.

Swartz, Douglas A.↗
NASA NTRS2011

The Various Influences due to Aerosol Depositions

Recently the issue on glacier retreats comes up and many factors should be relevant to the issue. The absorbing aerosols such as dust and black carbon (BC) are considered to be one of the factors. After they deposited onto the snow surface, it will reduce snow albedo (called snow darkening effect) and probably contribute to further melting of glacier. The Goddard Earth Observing System version 5 (GEOS-5) has developed at NASA/GSFC. However, the original snowpack model used in the land surface model in the GEOS-5 did not consider the snow darkening effect. Here we developed the new snow albedo scheme which can consider the snow darkening effect. In addition, another scheme on calculating mass concentrations on the absorbing aerosols in snowpack was also developed, in which the direct aerosol depositions from the chemical transport model in the GEOS-5 were used. The scheme has been validated with the observed data obtained at backyard of the Institute of Low Temperature Science, Hokkaido University, by Dr. Teruo Aoki (Meteorological Research Institute) et al. including me. The observed data was obtained when I was Ph.D.caftdidate. The original GEOS-5 during 2007-2009 over the Himalayas and Tibetan Plateau region showed more reductions of snow than that of the new GEOS-5 because the original one used lower albedo settings. On snow cover fraction, the new GEOS-5 simulated more realistic snow-covered area comparing to the MODIS snow cover fraction. The reductions on snow albedo, snow cover fraction, and snow water equivalent were seen with statistically significance if we consider the snow darkening effect comparing to the results without the snow darkening effect. In the real world, debris cover, inside refreezing process, surface flow of glacier, etc. affect glacier mass balance and the simulated results immediately do not affect whole glacier retreating. However, our results indicate that some surface melting over non debris covered parts of the glacier would be explained by the snow darkening effect. Further discussion and observations are necessary to assess the glacier issue.

Yasunari, Teppei↗
DOE OSTI2024

NPFTURBULENCE: Best Estimate Aerosol Size Distribution by airborne measurements

The original data were collected during the field campaign of “Turbulent layers promoting New Particle Formation” experiment (NPFTURBULENCE; https://www.arm.gov/research/campaigns/aaf2024npfturbulence) over the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) Atmospheric Observatory (https://www.arm.gov/capabilities/observatories/sgp ) in north-central Oklahoma. The ARM Aerial Facility ArcticShark uncrewed aerial system (UAS) was based at Blackwell–Tonkawa Municipal Airport (IATA: BWL, ICAO: KBKN, FAA LID: BKN, 36.74475° N, 97.34918° W, 313.9 m MSL), for the field campaign from May 5 through May 29, 2024. The ArcticShark UAS performed 11 flights, including 10 research flights over the Central Facility of the ARM SGP to measure atmospheric state, turbulence, surface IT temperature and imagery, aerosol number concentration and size distribution. The current data set presents Best Estimate Aerosol Size Distribution: a merged aerosol size distribution composed of the data from 2 sensors: miniaturized Scanning Electrical Mobility Sizer (mSEMS) and Portable Optical Particle Spectrometer (POPS). The mSEMS data were interpolated to 1 second from “native” time resolution of about 15 second to match the other probe. The POPS data were converted from equivalent optical size into geometric size using value of aerosol refractive index of 1.477 from the HISCALE field campaign (same geographical area, altitudes, and time of year; http://www.arm.gov/campaigns/aaf2016hiscale ).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2000

Discovery of a 6.4 keV Emission Line in a Burst from SGR 1900+14

We present evidence indicating the presence of a 6.4 keV emission line during a burst from the soft gamma-ray repeater SGR 1900+14. The Rossi X-ray Timing Explorer (RXTE) Monitored this source extensively during its outburst in the summer of 1998. A strong burst observed on August 29, 1998 revealed a number of unique properties. The burst exhibits a precursor and is followed by a long ($\sim 10(+)3$ s) tail modulated at the 5.16 s stellar rotation period. The precursor has a duration of $\sim 0.85$ s and shows both significant spectral evolution as well as an emission feature centered near 6.4 keV during the first 0.3 s of the event, when the X-ray spectrum was hardest. The continuum during the burst is well fit with an optically thin thermal bremsstrahlung (OTTB) spectrum with the temperature ranging from as high as $\sim 40$ to as low as 10 keV. The line is strong, with an equivalent width of $\sim 400$ eV, and the centroid is consistent with Fe K-$\alpha$ fluorescence from relatively cool material. If the rest-frame energy is indeed 6.4 keV, then the lack of an observed redshift indicates that the source of the line is at least $\sim 80$ km above the surface of the neutron star. We briefly discuss the implications of the line detection in the context of models for SGRs.

Strohmayer, Tod↗
NASA NTRS2012

Incorporation of the Mass Concentration and the New Snow Albedo Schemes into the Global Forecasting Model, GEOS-5 and the Impact of the New Schemes over Himalayan Glaciers

Recently the issue on glacier retreats comes up and many factors should be relevant to the issue. The absorbing aerosols such as dust and black carbon (BC) are considered to be one of the factors. After they deposited onto the snow surface, it will reduce snow albedo (called snow darkening effect) and probably contribute to further melting of glacier. The Goddard Earth Observing System version 5 (GEOS-5) has developed at NASA/GSFC. However, the original snowpack model used in the land surface model in the GEOS-5 did not consider the snow darkening effect. Here we developed the new snow albedo scheme which can consider the snow darkening effect. In addition, another scheme on calculating mass concentrations on the absorbing aerosols in snowpack was also developed, in which the direct aerosol depositions from the chemical transport model in the GEOS-5 were used. The scheme has been validated with the observed data obtained at backyard of the Institute of Low Temperature Science, Hokkaido University, by Dr. Teruo Aoki (Meteorological Research Institute) et aL including me. The observed data was obtained when I was Ph.D. candidate. The original GEOS-5during 2007-2009 over the Himalayas and Tibetan Plateau region showed more reductions of snow than that of the new GEOS-5 because the original one used lower albedo settings. On snow cover fraction, the new GEOS-5 simulated more realistic snow-covered area comparing to the MODIS snow cover fraction. The reductions on snow albedo, snow cover fraction, and snow water equivalent were seen with statistically significance if we consider the snow darkening effect comparing to the results without the snow darkening effect. In the real world, debris cover, inside refreezing process, surface flow of glacier, etc. affect glacier mass balance and the simulated results immediately do not affect whole glacier retreating. However, our results indicate that some surface melting over non debris covered parts of the glacier would be explained by the snow darkening effect. Further discussion and observations are necessary to assess the glacier issue.

Yasunari, Teppei↗
NASA NTRS2012

The Studies on Aerosol Transport, Its Deposition, and Its Impact on Climate - the Study on the Surface Material Circulation can Connect from the Past to the Future

Recently the issue on glacier retreats comes up and many factors should be relevant to the issue. The absorbing aerosols such as dust and black carbon (BC) are considered to be one of the factors. After they deposited onto the snow surface, it will reduce snow albedo (called snow darkening effect) and probably contribute to further melting of glacier. The Goddard Earth Observing System version 5 (GEOS-5) has developed at NASAlGSFC. However, the original snowpack model used in the land surface model in the GEOS-5 did not consider the snow darkening effect. Here we developed the new snow albedo scheme which can consider the snow darkening effect. In addition, another scheme on calculating mass concentrations on the absorbing aerosols in snowpack was also developed, in which the direct aerosol depositions from the chemical transport model in the GEOS-5 were used. The scheme has been validated with the observed data obtained at backyard of the Institute of Low Temperature Science, Hokkaido University, by Dr. Teruo Aoki (Meteorological Research Institute) et al. including me. The observed data was obtained when I was Ph.D. candidate. The original GEOS-5 during 2007-2009 over the Himalayas and Tibetan Plateau region showed more reductions of snow than that of the new GEOS-5 because the original one used lower albedo settings. On snow cover fraction, the new GEOS-5 simulated more realistic snow-covered area comparing to the MODIS snow cover fraction. The reductions on snow albedo, snow cover fraction, and snow water equivalent were seen with statistically significance if we consider the snow darkening effect comparing to the results without the snow darkening effect. In the real world, debris-cover, inside refreezing process, surface flow of lacier, etc. affect glacier mass balance and the simu.latedresults immediately do not affect whole glacier retreating. However, our results indicate that some surface melting over non debris-covered parts of the glacier would be explained by the snow darkening effect. Further discussion and observations are necessary to assess the glacier issue.

Yasunari, Teppei↗
DOE OSTI2025

Oxidation and recharge of reactive structural Fe( II ) in titanomagnetite (Fe 3− x Ti x O 4 ) nanoparticles

Mixed-valent iron oxide minerals, such as magnetite (Fe(II)(Fe(III)) 2 O 4 ), are an important source of solid-state ferrous iron (Fe(II)) that can impact the speciation and transport of electron accepting contaminants in the Earth’s subsurface, such as radioactive pertechnetate ( 99 Tc(VII)O 4 − ). However, when oxidizing conditions are encountered, structural Fe(II) at the mineral surface is consumed yielding a maghemite (γ-Fe(III) 2 O 3 )-like layer that limits further electron transfer. This oxidized surface layer can be recharged back to the original Fe(II)/(III) ratio by re-exposure to reducing conditions, i.e., aqueous solutions containing Fe 2+ . However, for substituted magnetite (Fe 3−x M x O 4 , M = transition metal cation), the extent of this redox recyclability is unclear. Here, we examine oxidation and recharge for titanomagnetite (Fe 3−x Ti x O 4 ) nanoparticles, where the Fe(II)/Fe(III) ratio varies by the amount of Fe(II) required to charge balance the titanium (Ti(IV)) substituted into the structure. The nanoparticles were synthesized by aqueous precipitation from a solution containing ferrous, ferric and titanium chloride at room temperature. Transmission electron microscopy combined with electron energy loss spectroscopy revealed that rapid precipitation formed core–shell-like nanoparticles consisting of a hyperstoichiometric magnetite core, with Ti(IV) and charge balancing Fe(II) enriched at the surface. This surface enrichment made Fe(II) more available for electron transfer reactions with redox active solution species. Examination of oxidation by H 2 O 2 followed by recharge with aqueous Fe 2+ indicates recyclability of reducing equivalents in the nanoparticles, yielding a core recrystallized to stoichiometric magnetite and a shell bearing excess Fe(II) to charge balance the substituted Ti(IV). The recharged particles are shown to have restored redox reactivity with 99 Tc(VII)O 4 − resulting in reduction to 99 Tc(IV)O 2 and oxidation of the structural Fe(II) to Fe(III).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Significant impact of forcing uncertainty in a large ensemble of climate model simulations

Forcing due to solar and volcanic variability, on the natural side, and greenhouse gas and aerosol emissions, on the anthropogenic side, are the main inputs to climate models. Reliable climate model simulations of past and future climate change depend crucially upon them. Here we analyze large ensembles of simulations using a comprehensive Earth System Model to quantify uncertainties in global climate change attributable to differences in prescribed forcings. The different forcings considered here are those used in the two most recent phases of the Coupled Model Intercomparison Project (CMIP), namely CMIP5 and CMIP6. We show significant differences in simulated global surface air temperature due to volcanic aerosol forcing in the second half of the 19th century and in the early 21st century. The latter arise from small-to-moderate eruptions incorporated in CMIP6 simulations but not in CMIP5 simulations. We also find significant differences in global surface air temperature and Arctic sea ice area due to anthropogenic aerosol forcing in the second half of the 20th century and early 21st century. These differences are as large as those obtained in different versions of an Earth System Model employing identical forcings. In simulations from 2015 to 2100, we find significant differences in the rates of projected global warming arising from CMIP5 and CMIP6 concentration pathways that differ slightly but are equivalent in terms of their nominal radiative forcing levels in 2100. Our results highlight the influence of assumptions about natural and anthropogenic aerosol loadings on carbon budgets, the likelihood of meeting Paris targets, and the equivalence of future forcing scenarios.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1980

Pollutant emissions from flat-flame burners at high pressures

Maximum flame temperatures and pollutant emission measurements for NOx, CO, and UHC (unburned hydrocarbons) are reported for premixed methane air flat flames at constant total mass flow rate over the pressure range from 1.9 to 30 atm and for equivalence ratios from 0.84 to 1.12. For any given pressure, maxima typically occur in both the temperature and NOx emissions curves slightly to the lean side of stoichiometric conditions. The UHC emissions show minima at roughly the same equivalence ratios. The CO emissions, however, increase continually with increasing equivalence ratio. Flame temperature and NOx emissions decrease with increasing pressure, while the opposite is true for the CO and UHC emissions. The NOx data correlate reasonably well as a function of flame temperature only. Four flameholders, differing only slightly, were used. In general, the temperature and emissions data from these four flameholders are similar, but some differences also exist. These differences appear to be related to minor variations in the condition of the flameholder surfaces.

Maahs, H. G.↗
NASA NTRS1985

Experimental and Theoretical Studies of Wetting and Multilayer Adsorption

The recent work with partially miscible binary liquid mixtures has established that the structure of the liquid-vapor interface can undergo a first-order phase transition from incomplete to complete wetting of the vapor as the temperature is raised. A discontinuity in the change of interfacial tension as a function of temperature at the phase transition has been predicted to occur in many systems and to play an important role in the growth of uniform composites from alloy melts at monotectic points. These measurements are the first to establish the order of the transition. Studies of capillary rise in SF6 in a unique interferometer have led to the first measurements of the thickness of wetting layers (or equivalently, multilayer adsorbed films) on a solid surface near a liquid-vapor critical point. Instabilities in wetting layers were observed. A theory for the instabilities is being developed and will be checked by both static and dynamic optical experiments. The effect of gravity on the apparent thickness of interfaces (as measured by ellipsometry) is under study.

Moldover, M. R.↗