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At least 307 records · Page 17

Calibration of the NOAA 11 solar backscatter ultraviolet (SBUV/2) ozone data set from 1989 to 1993 using in-flight calibration data and SSBUV

Total ozone and ozone profiles are currently being measured by solar backscatter ultraviolet (SBUV/2) instruments onboard NOAA polar orbiting spacecraft using the backscattered ultraviolet technique. The NOAA 11 SBUV/2 operational data set, reprocessed from January 1989 to May 1993 (version 6), includes an updated algorithm and revised prelaunch and postlaunch calibrations of the geometrical albedo observations used to derive ozone values. The postlaunch calibration revisions remove time dependent errors in the ozone amounts due to instrument drift, while the revised prelaunch calibration corrects the absolute value of retrieved ozone. The prelaunch corrections are a result of calibration checks from in-orbit comparisons of ultraviolet geometric albedos measured by shuttle SBUV (SSBUV) and the NOAA 11 SBUV/2. Geometric albedo comparison data are further corrected using a radiative transfer code to account for the small difference in observing conditions between the two spacecraft. The postlaunch corrections rely on in-flight calibration and solar irradiance data to account for time dependent changes in instrument gain, thermal response, and instrument diffuser degradation over time. Comparison of data from three SSBUV flights, which occurred about one year apart, with concurrent SBUV/2 data provided an independent check of the time dependent change derived from the in-flight calibration data. Time independent corrections result in an increase of about 1% for total ozone, 5% for ozone at 1 mbar, and near 0% at 15 mbar. The time dependent corrections amount to an increase of 2% for total ozone, 10% for ozone near 1 mbar, and 3% at 15 mbar at the end of the current record in May 1993. Recent laboratory studies indicate that the absolute radiance calibrations may still be in error by a few percent which results in ozone profile values that are too low. The SBUV/2 total and ozone profile data are compared to the Nimbus SBUV data during the period when the data overlapped. Total ozone values agree to about 1%, while ozone profile differences range from -4% to +6%, depending on latitude and altitude, relative to SBUV. These differences are not statistically significant given the uncertainties of the two data sets.

Hilsenrath, E.↗

Comparisons between TOMS, TOVS and DOBSON observations - Satellite and surface views of total column ozone

The reliability of the ozone retrievals by the TIROS-N Operational Vertical Sounder (TOVS) calculated with the newly developed physical algorithm is investigated by comparing the quality of the TOVS total ozone soundings to the corresponding values obtained by the Nimbus-7 TOMS and by the ground-based DOBSON network. The three-way comparison concentrates on observations during the last 4 months of 1987, the period of the great Antarctic 'ozone hole'. It is shown that each instrument has characteristic strengths and weaknesses, and that each of the three systems makes serious errors under some conditions.

Chesters, Dennis↗

Northwest Airlines flight experiments

An experiment was conducted in which real-time Total Ozone Mapping Spectrometer (TOMS) data was compared with Northwest Airlines upper air charts. It was demonstrated that the regions of steep gradient in total ozone corresponded with fronts in the upper troposphere, specifically breaks in the tropopause associated with jet streams. Other small scale structures in the ozone could be related to minor trough and ridge lines. This suggests that the relation between total ozone and tropopause height might apply even on relatively small scales, and an analysis produced high correlation coefficients provided that the air mass origin was considered. In a second test, cabin ozone mixing at 37,000 ft. varied from less than 100 ppb (300 DU total ozone) to greater than 300 ppb in a trough (400 DU total ozone). A third analysis showed that clear air turbulence was located where upper air fronts were in rapid motion as suggested by comparison of the 1200 UT synoptic charts and the ozone map taken about six hours later.

Krueger, Arlin J.↗

Influence of Transport on Two-Dimensional Model Simulation: 2. Stratospheric Aircraft Perturbations: Stratospheric Aircraft Perturbations - 2

We have adopted the transport scenarios used in Part 1 to examine the sensitivity of stratospheric aircraft perturbations to transport changes in our 2-D model. Changes to the strength of the residual circulation in the upper troposphere and stratosphere and changes to the lower stratospheric K(sub zz) had similar effects in that increasing the transport rates decreased the overall stratospheric residence time and reduced the magnitude of the negative perturbation response in total ozone. Increasing the stratospheric K(sub yy) increased the residence time and enhanced the global scale negative total ozone response. However, increasing K(sub yy) along with self-consistent increases in the corresponding planetary wave drive, which leads to a stronger residual circulation, more than compensates for the K(sub yy)-effect, and results in a significantly weaker perturbation response, relative to the base case, throughout the stratosphere. We found a relatively minor model perturbation response sensitivity to the magnitude of K(sub yy) in the tropical stratosphere, and only a very small sensitivity to the magnitude of the horizontal mixing across the tropopause and to the strength of the mesospheric gravity wave drag and diffusion. These transport simulations also revealed a generally strong correlation between passive NO(sub y) accumulation and age of air throughout the stratosphere, such that faster transport rates resulted in a younger mean age and a smaller NO(y) mass accumulation. However, specific variations in K(sub yy) and mesospheric gravity wave strength exhibited very little NO(sub y)-age correlation in the lower stratosphere, similar to 3-D model simulations performed in the recent NASA "Models and Measurements" II analysis. The base model transport, which gives the most favorable overall comparison with inert tracer observations, simulated a global/annual mean total ozone response of -0.59%, with only a slightly larger response in the northern compared to the southern hemisphere. For transport scenarios which gave tracer simulations within some agreement with measurements, the annual/globally averaged total ozone response ranged from -0.45% to -0.70%. Our previous 1995 model exhibited overly fast transport rates, resulting in a global/annually averaged perturbation total ozone response of -0.25%, which is significantly weaker compared to the 1999 model. This illustrates how transport deficiencies can bias model simulations of stratospheric aircraft.

Fleming, Eric L.↗

The observation of atmospheric structure with TOMS and some potential advancements

An overview is given of the Nimbus 7 Total Ozone Mapping Spectrometer (TOMS) which was designed to observe the spatial characteristics of total ozone that were not resolved by the nadir-viewing Nimbus BUV and SBUV instruments. At the wavelengths suitable for total ozone measurements, the radiance is large enough that the entire daytime atmosphere could be surveyed with about 50-km resolution from a polar orbiting satellite. The resulting high spatial resolution TOMS ozone images are found to reflect the internal dynamic structure of the lower atmosphere. Features which can be identified and tracked include: planetary wave scale troughs and ridges, mesoscale cutoff lows and rapidly moving troughs, jet stream confluence and difluence areas, hurricanes, and polar night lows. These features control the ozone above any given location and account for nearly all the variance in the total ozone. The instrument has been used to track the volcanic eruption clouds from El Chichon, Mount St. Helens, Alaid, and smaller eruptions such as Galunggung. It would be feasible to use a similar instrument on a geostationary platform to obtain half-hourly maps. Determination of the vertical ozone distribution in the lower stratosphere using Radon transform principles would be of importance in measuring jet stream folds and the related troposphere-stratosphere exchange.

Krueger, A. J.↗

Record low global ozone in 1992

The 1992 global average total ozone, measured by the Total Ozone Mapping Spectrometer (TOMS) on the Nimbus-7 satellite, was 2 to 3 percent lower than any earlier year observed by TOMS (1979 to 1991). Ozone amounts were low in a wide range of latitudes in both the Northern and Southern Hemispheres, and the largest decreases were in the regions from 10 to 20 deg S and 10 to 60 deg N. Global ozone in 1992 is at least 1.5 percent lower than would be predicted by a statistical model that includes a linear trend and accounts for solar cycle variation and the quasi-biennial oscillation. These results are confirmed by comparisons with data from other ozone monitoring instruments: the SBUV/2 instrument on the NOAA-11 satellite, the TOMS instrument on the Russian Meteor-3 satellite, the World Standard Dobson Instrument 83, and a collection of 22 ground-based Dobson instruments.

Gleason, J. F.↗

The vertical distribution of ozone at Pretoria from July 1990 to June 1991 and its changes

Total ozone and the vertical distribution of ozone were measured at Pretoria between 1965 and 1968. Total ozone measurements recommenced in Pretoria in August 1989, and measurements of the vertical distribution of ozone near Pretoria recommenced in July 1990. Relative to the earlier data, mean monthly total ozone values are significantly higher in all months, with a mean annual relative increase of 12 percent. The recent profiles show a significant increase in the mean monthly concentration of ozone in the lowest 12 km. Concurrent to this increase a relative decrease in ozone concentration is shown between 12 and 42 km. The increased ozone concentration in the lower troposphere may be related to urbanization and the increase in ozone-forming nitrogen oxides over the last two decades. It is suggested that the decreased ozone concentration in the stratosphere and upper troposphere is evidence of the global decrease in the mid-latitudes of the Southern Hemisphere.

Zunckel, Mark↗

Total ozone-solar activity relationship

Approximately six years of global ozone monthly mean data from the Nimbus 4 BUV instrument are compared with monthly values of solar activity using 10.7-cm flux, F(10.7), as a parameter. Several techniques are explored in calculating the correlation between the two data sets, and all are found to yield relatively high correlations, ranging from R = 0.68 for 'raw' monthly means to 0.94 using a six-month running mean for each data set. It is shown, however, that the bulk of the correlation derives from the long-term decreasing trends in both data sets. When the long-term trends are removed, a cross-correlation analysis produces a maximum with no phase shift or with the ozone variations leading the solar variations by one month, thereby reducing the likelihood of a cause and effect relationship on time scales of this order. In view of the current uncertainty in the long-term stability of the BUV instrument and the resulting uncertainty in any long-term trend derived from its data, it is considered unrealistic to draw firm conclusions about a solar cycle influence on total ozone from this satellite data set.

Reber, C. A.↗

Non-seasonal changes in total column ozone from satellite observations, 1970-86

Analyses of nonseasonal changes in total column ozone from satellite observations during the period 1970-86 suggest, when combined with analyses of Dobson network data, that the largest reduction in global ozone since 1959 occurred between 1978 and 1986. The existence of an Arctic region of enhanced ozone depletion with similar but less pronounced characteristics of the Antarctic region is described. Before 1983 large rates of decrease were confined to high latitudes, subsequently regions of large rates of ozone depletion have appeared at midlatitudes.

Heath, Donald F.↗

Comparisons Between Ground Measurements of Broadband UV Irradiance (300-380 nm) and TOMS UV Estimates at Moscow for 1979-2000

We show the comparisons between ground-based measurements of spectrally integrated (300 nm to 380 nm) ultraviolet (UV) irradiance with satellite estimates from the Total Ozone Mapping Spectrometer (TOMS) total ozone and reflectivity data for the whole period of TOMS measurements (1979-2000) over the Meteorological Observatory of Moscow State University (MO MSU), Moscow, Russia. Several aspects of the comparisons are analyzed, including effects of cloudiness, aerosol, and snow cover. Special emphasis is given to the effect of different spatial and temporal averaging of ground-based data when comparing with low-resolution satellite measurements (TOMS footprint area 50-200 sq km). The comparisons in cloudless scenes with different aerosol loading have revealed TOMS irradiance overestimates from +5% to +20%. A-posteriori correction of the TOMS data accounting for boundary layer aerosol absorption (single scattering albedo of 0.92) eliminates the bias for cloud-free conditions. The single scattering albedo was independently verified using CIMEL sun and sky-radiance measurements at MO MSU in September 2001. The mean relative difference between TOMS UV estimates and ground UV measurements mainly lies within 1 10% for both snow-free and snow period with a tendency to TOMS overestimation in snow-free period especially at overcast conditions when the positive bias reaches 15-17%. The analysis of interannual UV variations shows quite similar behavior for both TOMS and ground measurements (correlation coefficient r=0.8). No long-term trend in the annual mean bias was found for both clear-sky and all-sky conditions with snow and without snow. Both TOMS and ground data show positive trend in UV irradiance between 1979 and 2000. The UV trend is attributed to decreases in both cloudiness and aerosol optical thickness during the late 1990's over Moscow region. However, if the analyzed period is extended to include pre-TOMS era (1968-2000 period), no trend in ground UV irradiance is detected.

Yurova, Alla Y.↗

The nature of the data

The locations of total ozone stations and of stratospheric ozone samplings were presented. The samplings are concentrated in three areas: Japan, Europe, and India. Approximately 75% of the total ozone measurements are made with Dobson instruments which offer the best international measurements. When well calibrated their accuracy is on the order of a few percent. It is found that although the total ozone percent is similar in both hemispheres, the northern hemisphere has 3 to 10% more ozone than the southern hemisphere. The close association between total ozone distribution and pressure distribution in the atmosphere is noted.

Source record↗

The breakup of the Southern Hemisphere spring polar ozone and temperature minimums from 1979 to 1987

The purpose of this study is to quantify the observations of the polar vortex breakup. The data used in this study consist of Total Ozone Mapping Spectrometer (TOMS) data, and National Meteorological Center (NMC) analyses. The final warming is diagnosed using the difference between zonal means at 80 degrees and 50 degrees S for temperature, ozone, and layer mean temperature. The polar vortex breakup can also be diagnosed by the onset of weak zonal mean zonal winds (i.e., u, overbar denotes a zonal average) at 60 degrees S. Computations of the polar vortex breakdown date using NMC meteorological data and TOMS total ozone data indicate that the breakdown is occurring later in the spring in the lowest portion of the stratosphere. At altitudes above 100 mb, the large interannual variance of the breakdown date renders any trend determination of the breakdown date difficult. Individual plots of TOMS total ozone indicate that the total ozone minimum remains intact for a longer period of time than is observed in earlier years.

Newman, Paul A.↗

Ozone transport by diabatic and planetary wave circulations on a beta plane

A beta plane model is used to study the transport of ozone and a tracer distributed like ozone. In the first experiment, ozone is transported with a time dependent diabatic circulation in a beta channel. Increase in the ozone column density occurs principally through downward advection from the high altitude source region into the lower stratosphere. Compared with observations, the maximum in the total ozone field occurs too late and is too large. Transient planetary waves produce large temporary increases in total ozone near the pole during sudden warming events, but permanent increases are much smaller. Warmings which penetrate below the chemical transition region (major warmings) are most effective in changing the zonal mean ozone distribution. Combining the sudden warming and diabatic circulations simulates many of the observed features of the seasonal changes in total ozone at high latitudes. The diabatic circulation provides the major enhancement of the ozone column density while the transient planetary waves move ozone to high latitudes. This result suggests sudden warmings can play an important role in our understanding of the fluctuations in total ozone, and the final warming may be the key event which determines the date and magnitude of the spring maximum.

Rood, R. B.↗

Ozone, jet streaks and severe weather

Data from three independent observing platforms are synthesized to study the role of jet streaks in severe weather. The three data types are: conventional radiosondes; 6.7 micron water vapor imagery from the GOES satellite; and total ozone imagery from Nimbus 7. Diagnoses are then made of potential vorticity, mid-tropospheric moisture, and total ozone at and below the level of jet streaks. Potential vorticity and total ozone distributions are both tracers of stratospheric air. Theoretically, both should respond to the transverse, vertical circulations expected in the vicinity of jet streaks. Both should increase due to the sinking above the left front quadrant of the streaks. Moisture, on the other hand, increases in the ascent under the left front quadrant. This study shows striking agreement between the three parameters independently observed from three different observing platforms. Moreover, the three severe weather case studies suggest a unique distribution of ozone, potential vorticity, and mid-tropospheric moisture relative to a jet streak. This, in turn, led to the creation of a new ozone/jet streak model which shows that the total ozone distribution provides a signature in the vicinity of jet streaks and permits identification of areas most likely to experience severe weather at a later time. The value of such observations to operational forecasting is discussed.

Sechrist, Frank S.↗

Sensitivity of the Assimilated Ozone in the UTLS to Model and Data Selection Changes

This presentation will discuss the sensitivity of assimilated ozone fields in the upper troposphere and lower stratosphere (UTLS) to a number of factors, focusing mainly on aspects of data selection and the prediction model. This is important, because assimilation represents an attempt to construct our best estimates of the true ozone field; however, inaccuracies in the UTLS ozone distribution translate into an uncertainty in factors such as the calculated radiative forcing of climate or the inferred stratosphere-troposphere exchange (STE) of ozone. The 3D ozone data assimilation system, from NASA's Global Modeling and Assimilation Office (GMAO), combines observations of total ozone column and stratospheric profiles with predictions from an off-line, parameterized chemistry and transport model (pCTM) to produce six-hourly, global analyses. The first experiments discussed assimilate ozone retrievals from the Earth-Probe Total Ozone Mapping Spectrometer (EPTOMS) and stratospheric profiles from the Solar Backscatter UltraViolet/2 (SBUV/2) instrument. The SBUV/2 ozone data have a coarse vertical resolution, with increased uncertainty below the ozone maximum, and TOMS provides only total ozone columns. Thus, the assimilated ozone profiles in the UTLS region are only weakly constrained by the incoming SBUV and TOMS data. Consequently, the assimilated ozone distribution should be sensitive to changes in inputs to the statistical analysis scheme. Sensitivity studies have been conducted to examine the responses to TOMS and SBUV/2 data selection, modifications of the forecast and observation error covariance models, and the model formulation (turning off chemistry or using different wind analyses in the pCTM). The second set of experiments includes an additional data type: ozone retrieved from infrared limb-emission by MIPAS on Envisat. These data offer not only improved vertical resolution in the stratosphere, but also give measurements in the polar night. Comparisons of the assimilated ozone fields from both sets of experiments with independent observations, primarily ozone sondes, are used to determine the impact of each of these changes. It is shown that many of the changes have a significant impact on the UTLS ozone estimates. Implications for interpretation of STE and radiative forcing of climate are discussed.

Pawson, Steven↗

Tropical intercontinental optical measurement network of aerosol, precipitable water and total column ozone

A new generation of automatic sunphotometers is used to systematically monitor clear sky total column aerosol concentration and optical properties, precipitable water and total column ozone diurnally and annually in West Africa and South America. The instruments are designed to measure direct beam sun, solar aureole and sky radiances in nine narrow spectral bands from the UV to the near infrared on an hourly basis. The instrumentation and the algorithms required to reduce the data for subsequent analysis are described.

Holben, B. N.↗

Use of satellite data to study tropospheric ozone in the tropics

Three independent examples are discussed which suggest that photochemical ozone production in the troposphere can be observed in the tropics from an analysis of total ozone data. The first finding shows that the seasonal cycle of total columnar ozone is dominated by the seasonal cycle of tropospheric ozone, even though tropospheric ozone accounts for only 5-15 percent of the total ozone. Second, a case study is presented which shows that enhanced total ozone observed over the Amazon Basin can be associated with the presence of biomass burning. In situ measurements have confirmed that biomass burning does result in the production of photochemically generated ozone, analogous to the formation of 'smog' near industrialized areas. Third, an analysis of the distribution of carbon monoxide obtained from a Space Shuttle platform is strongly correlated with the concurrent distribution of total ozone between 5 deg S and 10 deg N. Because all of the sources of carbon monoxide are located in the troposphere, this finding likewise suggests that the gradients of total ozone at low latitudes must also reflect processes occurring in the troposphere.

Fishman, Jack↗

The 1988 Antarctic ozone depletion - Comparison with previous year depletions

The 1988 spring Antarctic ozone depletion was observed by TOMS to be substantially smaller than in recent years. The minimum polar total ozone values declined only 15 percent during September 1988, compared to nearly 50 percent during September 1987. At southern midlatitudes, exceptionally high total ozone values were recorded beginning in July 1988. The total integrated southern hemispheric ozone increased rapidly during the Austral spring, approaching 1980 levels during October. The high midlatitude total ozone values were associated with a substantial increase in eddy activity as indicated by the standard deviation in total ozone in the zonal band 30-60 deg S. Mechanisms through which the increased midlatitude eddy activity could disrupt the formation of the Antarctic ozone hole are briefly discussed.

Schoeberl, Mark R.↗