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At least 307 records · Page 17

Evaluating the effects of heatwave events on hydrological processes in the contiguous United States (2003–2022)

Extreme heat and drought conditions are affecting water availability in many regions worldwide, leading to negative impacts on human societies, agriculture, and ecosystems. However, current research lacks comprehensive spatiotemporal analysis examining the interplay between multiple hydrological factors and heatwave events, especially in the context of climate change. This research broadly pertains to understanding the dynamics of hydrological factors and their potential responses to heatwave during warm seasons across the contiguous United States for the period from 2003 to 2022. Utilizing data from the Global Land Data Assimilation System (GLDAS), we analyzed surface runoff, evapotranspiration (ET), precipitation, Groundwater Storage (GWS), Root Zone Soil Moisture (RZSM), and Total Water Storage (TWS) to discern annual patterns and the impacts of heatwave. Further, the spatial patterns of heatwave highlighted a higher occurrence in the western, central, and northeastern U.S., with longer average durations in the western and south-central regions. These events are predominantly dry, characterized by low Relative Humidity (RH), except in the southeastern U.S., where heatwave coincide with high RH levels. Post-heatwave analysis indicated a reduction in GWS, TWS, RZSM, and ET, alongside an increase in surface runoff, RH, and precipitation. An in-depth examination of rainfall and temperature dynamics during heatwave revealed weak correlations between rainfall and temperature, as well as between rainfall and heatwave duration, highlighting the complex nature of these interactions. The study also found an enhanced probability of rainfall following heatwave, particularly in the eastern regions, drawing attention to the potential for increased flood risks post-heatwave. Our findings contribute to the growing body of knowledge on the impacts of heatwave on hydrological factors, providing valuable insights for climate change adaptation and water resource management strategies.

54 ENVIRONMENTAL SCIENCES↗

Warming of alpine tundra enhances belowground production and shifts community towards resource acquisition traits

Abstract Climate warming is expected to stimulate plant growth in high‐elevation and high‐latitude ecosystems, significantly increasing aboveground net primary production (ANPP). However, the effects of simultaneous changes in temperature, snowmelt timing, and summer water availability on total net primary production (NPP)—and elucidation of both above‐ and belowground responses—remain an important area in need of further study. In particular, measures of belowground net primary productivity (BNPP) are required to understand whether ANPP changes reflect changes in allocation or are indicative of a whole plant NPP response. Further, plant functional traits provide a key way to scale from the individual plant to the community level and provide insight into drivers of NPP responses to environmental change. We used infrared heaters to warm an alpine plant community at Niwot Ridge, Colorado, and applied supplemental water to compensate for soil water loss induced by warming. We measured ANPP, BNPP, and leaf and root functional traits across treatments after 5 yr of continuous warming. Community‐level ANPP and total NPP (ANPP + BNPP) did not respond to heating or watering, but BNPP increased in response to heating. Heating decreased community‐level leaf dry matter content and increased total root length, indicating a shift in strategy from resource conservation to acquisition in response to warming. Water use efficiency (WUE) decreased with heating, suggesting alleviation of moisture constraints that may have enabled the plant community to increase productivity. Heating may have decreased WUE by melting snow earlier and creating more days early in the growing season with adequate soil moisture, but stimulated dry mass investment in roots as soils dried down later in the growing season. Overall, this study highlights how ANPP and BNPP responses to climate change can diverge, and encourages a closer examination of belowground processes, especially in alpine systems, where the majority of NPP occurs belowground.

54 ENVIRONMENTAL SCIENCES↗

Mechanisms dominating thixotropy in limestone calcined clay cement (LC3)

Limestone calcined clay cement (LC3) is a green binder with great practical importance for the cement industry. Growing application has increased the need to understand the mechanisms governing its thixotropy for better control of workability. While formation of C-S-H bridges is understood to dominate the thixotropy of ordinary Portland cement, LC3 paste displayed unique thixotropy properties. In this study, focused beam reflectance measurement, zeta potential, 1H nuclear magnetic resonance relaxometry and micro X-ray computed tomography were used to track the colloidal interaction and hydration extent within LC3 paste. Results showed that flocculation due to the negative surface charge and water affinity of calcined clay appears to be the dominating factor. This leads to a reduction of water available to contribute to fluidity of the paste and, in turn, governing the development of thixotropy over time. In addition, the dilution effect due to high clinker substitution diminishes thixotropy growth with time.

36 MATERIALS SCIENCE↗

Climate Sensitivity of Peatland Methane Emissions Mediated by Seasonal Hydrologic Dynamics

Peatlands are among the largest natural sources of atmospheric methane (CH 4 ) worldwide. Peatland emissions are projected to increase under climate change, as rising temperatures and shifting precipitation accelerate microbial metabolic pathways favorable for CH 4 production. However, how these changing environmental factors will impact peatland emissions over the long term remains unknown. Here, we investigate a novel data set spanning an exceptionally long 11 years to analyze the influence of soil temperature and water table elevation on peatland CH 4 emissions. We show that higher water tables dampen the springtime increases in CH 4 emissions as well as their subsequent decreases during late summer to fall. These results imply that any hydroclimatological changes in northern peatlands that shift seasonal water availability from winter to summer will increase annual CH 4 emissions, even if temperature remains unchanged. Furthermore, advancing hydrological understanding in peatland watersheds will be crucial for improving predictions of CH 4 emissions.

54 ENVIRONMENTAL SCIENCES↗

Analysis of the time-of-flight neutron scattering cross-section data for light water measured at the SEQUOIA spectrometer, Spallation Neutron Source (SNS)

Thermal neutron scattering cross-section data for light water available in the major nuclear data libraries observes significant differences especially at reactor operating temperatures. During the past few years there has been a renewed interest in reviewing the existing thermal scattering models and generating more accurate and reliable thermal scattering cross sections using existing experimental data and in some cases based on Molecular Dynamics (MD) simulations. There is a need for performing new time-of-flight experiments at high temperatures and pressures, to have a better understanding of the physics involved in the scattering process that could help improve the existing TSL data.Lack of experimental thermal scattering data for light water at high temperatures led to a new measurement campaign within the INSIDER project at the Institut de radioprotection et de sûreté nucléaire (IRSN). Double differential scattering cross section for light water have been measured at the SEQUOIA spectrometer based at the Spallation Neutron Source (SNS), Oak Ridge National Laboratory, United States. Several measurements have been carried out at different temperatures and pressures corresponding to liquid light water. Measurements at five different incident neutron energies Ei (8, 60, 160, 280 and 800 meV) have been carried out to help exploring different regions of the frequency spectrum. This paper presents the analysis of the dynamic structure factor and the derived frequency spectrum of light water. The analysis of the experimental data would provide one with better confidence, the behavior of thermal scattering cross sections for light water at high temperatures, knowledge of which is very important for the design of novel reactors as well as existing pressurized water reactors.

Jaiswal, V↗

Evaluation of Global Climate Models for Use in Energy Analysis

The interplay between energy, climate, and weather is becoming more complex due to increasing contributions of renewable energy generation, energy storage, electrified end uses, and the increasing frequency of extreme weather events. Energy system analyses commonly rely on meteorological inputs to estimate renewable energy generation and energy demand; however, these inputs rarely represent the estimated impacts of future climate change. Climate models and publicly available climate change datasets can be used for this purpose, but the selection of inputs from the myriad of available models and datasets is a nuanced and subjective process. In this work, we assess datasets from various global climate models (GCMs) from the Coupled Model Intercomparison Project Phase 6 (CMIP6). We present evaluations of their skills with respect to the historical climate and comparisons of their future projections of climate change for two climate change scenarios. We present the results for different climatic and energy system regions and include interactive figures in the accompanying software repository. Previous work has presented similar GCM evaluations, but none have presented variables and metrics specifically intended for comprehensive energy systems analysis including impacts on energy demand, thermal cooling, hydropower, water availability, solar energy generation, and wind energy generation. We focus on GCM output meteorological variables that directly affect these energy system components including the representation of extreme values that can drive grid resilience events. The objective of this work is not to recommend the best climate model and dataset for a given analysis, but instead to provide a reference to facilitate the selection of climate models and scenarios in subsequent work.

14 SOLAR ENERGY↗

Improving a Multilevel Turbulence Closure Model for a Shallow Lake in Comparison With Other 1-D Models

Lakes differ from lands in water availability, heat capacity, albedo, and roughness, which affect local surface-atmospheric interactions. This study modified a multilevel upper ocean model (UOM) for lake applications and evaluated its performance in Lake Taihu (China) with comprehensive measurements against three popular one-dimensional (1-D) lake models. These models were based on different concepts, including the self-similarity (FLake), the wind-driven eddy diffusion (LISSS), the k-ε turbulence closure (SIMSTRAT), and a simplified turbulence closure (UOM). The surface flux scheme in these models was unified to exclude the discrepancies in representing air-lake exchanges. All models in their default formulations presented obvious cold water temperature biases and largely underestimated the lake surface temperature (LST) diurnal range. For each model, these deficiencies were significantly reduced by incorporating new physics schemes or calibrated tunable parameters based on systematic sensitivity tests. The primary modifications for UOM included (1) a new scheme of decreased surface roughness lengths to better characterize the shallow lake, (2) a solar radiation penetration scheme with increased light extinction coefficient and surface absorption fraction to account for the high water turbidity, and (3) turbulent Prandtl number increased by a factor of 20 to reduce the turbulent vertical mixing. All other models were improved in these three aspects (roughness, extinction, and mixing) within their original formulations. Given these improvements, UOM showed superior performance to other models in capturing LST diurnal cycle and daily to seasonal variations, as well as summer-autumn vertical stratification changes. The new UOM is well suited for application in shallow lakes.

54 ENVIRONMENTAL SCIENCES↗

Soil Water Retention and Hydraulic Conductivity Data and Model at Trail Creek in Taylor River Watershed, Colorado 2024-2025

This data package includes soil water retention and hydraulic conductivity data and model fitting results from measurements of ex-situ soil samples and in-situ soil sensors near Trail Creek. Soil water retention curves (SWRC) characterize soil water content as a function of soil water potential. SWRC depends on soil texture and pore structure and can be used to describe the constraints on biogeochemical processes in terms of soil water availability. In this data package, the sample identification follows the format TR-X-Y, where TR refers to Trail Creek, X is the treatment block identifier, and Y is the location identifier. Specifically, TR-ASCC1 is the control treatment block under the Adaptive Silviculture for Climate Change (ASCC) project, and TR-ASCC2 is the clear-cut treatment block. TR-ASCC-EHSn is associated with ecohydrology sites under the East-Taylor Watershed Community Observatory Sites directory, and TR-ASCC-ERTn (upslope n=1) are ecohydrology sites along the electrical resistivity tomography transects. The sample and location information can be found in metadata.csv, and the data from the soil sensors will be included in a future data version when the observation period becomes sufficiently long for data analysis. Sampling and Measurements Each sample falls into one of the two sampling methods – (1) intact cores or (2) soil sensors – and one of the two measurement methods – (a) laboratory or (b) in-situ. The intact cores were measured using the laboratory methods, which include measurements of soil water potential (HYPROP & WP4C, METER), saturated (KSAT, METER) and unsaturated hydraulic conductivity (HYPROP). The in-situ method uses a pair of co-located soil sensors to measure volumetric water content (TEROS12, METER) and soil water potential (TEROS21, METER), and the hydraulic conductivity was not measured. In comparison, the laboratory methods progress from full saturation to dry conditions, and the in-situ method includes both dry-to-wet and wet-to-dry cycles. The sampling and measurement methods for each sample can be found in metadata.csv, and more information about the measurements is detailed in the Methods section below. Models Retention and hydraulic conductivity data were fitted with four van-Genuchten-type models (specified by “model_name” column in the files): (1) traditional constrained van Genuchten model (“vG_constrained”), (2) traditional unconstrained van Genuchten model (“vG_unconstrained”), (3) PDI-variant of the constrained van Genuchten model (“vG_constrained_PDI”), and (4) PDI-variant of the unconstrained van Genuchten model (“vG_unconstrained_PDI”). The difference between the constrained (1: n) and the unconstrained (2: n, m) van Genuchten models is the number of pore-size distribution parameters in the model equations, giving the unconstrained model more degrees of freedom when fitting the data. Between the traditional and the PDI-variant models, model fitting differs the most at the dry end of the measurements. The traditional models allow infinite suction at the residual water content (water content does not drop below residual water content), and the PDI-variant models enforce a soil water potential value of pF=6.8 (~ -630 MPa) at oven-dryness (water content reaches 0). The inclusion of the van-Genuchten-type models is due to their common application. If other retention models are required, users can access the data in data.csv for further data fitting. More information about the models can be found in the Methods section below. Fitting Tasks The model fitting can be categorized into three levels of tasks (specified by “fitting_task” column in the files). Level 1 (“fit_retention”) only includes retention data fitting (the only level available for the in-situ method). Level 2 (“fit_retention_conductivity”) includes both retention and hydraulic conductivity data fitting, and the saturated hydraulic conductivity (Ks, a parameter of the hydraulic conductivity functions) is fixed by the measurements from KSAT. Level 3 (“fit_retention_conductivity_Ks”) also includes both retention and hydraulic conductivity data fitting, but Ks is a fitted parameter without the constraints from KSAT measurements. Among the same retention models (e.g. vG_constrained models of the same sample), level 1 should produce the best retention data fitting. Level 2 should have the highest misfit of the retention and hydraulic conductivity data, because the retention and hydraulic conductivity functions share common model parameters, and the unsaturated hydraulic conductivity (HYPROP) data fitting is subject to Ks measured independently by KSAT. Level 3 should have mid-level misfits of the retention and hydraulic conductivity data. While level 3 fits the hydraulic conductivity data better than level 2, the fitted Ks value might be unreasonable due to the lack of constraints at the wet end of the measurements. General recommendation when using this data package: (1) Choice of sampling methods: Intact cores might suffer from sample gaps that would lead to overestimation of Ks (sample gaps can be inferred from the “soil_sample_volume” column in metadata.csv when the value is < 249). In-situ method has higher uncertainty in characterizing the wet end of the SWRC because of sensor limitations and the difficulty in reaching full saturation under natural conditions. (2) Choice of fitting tasks: When only retention data is needed, level 1 (“fit_retention”) should be prioritized. When both retention and hydraulic conductivity data are needed, level 2 (“fit_retention_conductivity”) could be prioritized. (3) Choice of models: This could depend on what the downstream models call for. If no specific model is required, model misfit could be used as a ranking criterion. Model misfit values in terms of RMSE can be found in model_parameters.csv. The following files are included in this data package: (1) metadata.csv – This file includes the general information of each sample, including location (description, geocoordinates, elevation), sampling and measurements details (method, depth, time or period, volume, instruments), and soil physical properties (bulk density, saturated hydraulic conductivity, only applicable to physical soil samples). (2) data.csv – This file includes soil water potential, volumetric water content, and unsaturated hydraulic conductivity data of each sample. Column “instrument” specifies the instrument (HYPROP, WP4C, or TEROS) used to perform the measurements. (3) model_fit.csv – This file includes soil water potential, volumetric water content, and unsaturated hydraulic conductivity fitted from the four models and three fitting tasks. Column “model_name” specifies the retention model used, and “fitting_task” specifies the level of data fitting. Missing values indicate that the variable does not apply to that fitting task. (4) model_parameters.csv – This file includes the fitted model parameters, model misfits, and conventional water content thresholds (field capacity and wilting point) from the four models and three fitting tasks. Column “model_name” specifies the retention model used, and “fitting_task” specifies the level of data fitting. Missing values indicate that the parameter does not apply to that model and/or that fitting task. (5) data_Ks.csv – This file includes the saturated hydraulic conductivity measurements from KSAT. (6) /figure/*.png – This folder includes three quick visualizations of the data, retention model fitting results and misfits, and hydraulic conductivity model fitting results, misfits, and parameters. The model fitting results are separated by samples and fitting tasks and colored by models. Zoom-in required. (7) /hyprop/*.bdhx – This folder includes proprietary hyprop files that require the free Labros SoilView-Analysis (METER) to open. Users can explore data fitting using other retention models (i.e. Brooks-Corey, Fredlund-Xing, Kosugi, bimodal models). Be aware that Ks value is pre-entered under “Fitting tab, Conductivity functions parameters” for level 2 fitting. If the value is lost, please refer to metadata.csv under “Ks” column. (8) Six file-level metadata that summarize file, header, column, and variable information of all files. This work was supported by the Watershed Function Science Focus Area at Lawrence Berkeley National Laboratory funded by the US Department of Energy, Office of Science, Biological and Environmental Research under Contract No. DE-AC02-05CH11231.

EARTH SCIENCE > LAND SURFACE > SOILS↗

Approaches to vegetation mapping and ecophysiological hypothesis testing using combined information from TIMS, AVIRIS, and AIRSAR

The Tropical Rainforest Ecology Experiment (TREE) had two primary objectives: (1) to design a method for mapping vegetation in tropical regions using remote sensing and determine whether the result improves on available vegetation maps; and (2) to test a specific hypothesis on plant/water relations. Both objectives were thought achievable with the combined information from the Thermal Infrared Multispectral Scanner (TIMS), Airborne Visible/Infrared Imaging Spectrometer (AVIRIS), and Airborne Synthetic Aperture Radar (AIRSAR). Implicitly, two additional objectives were: (1) to ascertain that the range within each variable potentially measurable with the three instruments is large enough in the site, relative to the sensitivity of the instruments, so that differences between ecological groups may be detectable; and (2) to determine the ability of the three systems to quantify different variables and sensitivities. We found that the ranges in values of foliar nitrogen concentration, water availability, stand structure and species composition, and plant/water relations were large, even within the upland broadleaf vegetation type. The range was larger when other vegetation types were considered. Unfortunately, cloud cover and navigation errors compromised the utility of the TIMS and AVIRIS data. Nevertheless, the AIRSAR data alone appear to have improved on the available vegetation map for the study area. An example from an area converted to a farm is given to demonstrate how the combined information from AIRSAR, TIMS, and AVIRIS can uniquely identify distinct classes of land use. The example alludes to the potential utility of the three instruments for identifying vegetation at an ecological scale finer than vegetation types.

Oren, R.↗

Dryness controls temperature-optimized gross primary productivity across vegetation types

Temperature response of gross primary productivity (GPP) is a well-known property of ecosystem, but GPP at the optimum temperature (GPP_T opt ) has not been fully discussed. Our understanding of how GPP_T opt responds to warming and water availability is highly limited. Here, in this study, we analyzed data at 326 globally distributed eddy covariance sites (79°N-37°S), to identify controlling factors of GPP_T opt . Although GPP_T opt was significantly influenced by soil moisture, global solar radiation, mean annual temperature, and vapor pressure deficit in a non-linear pattern (R 2 = 0.47), the direction and magnitude of these climate variables’ effects on GPP_T opt depend on the dryness index (DI), a ratio of potential evapotranspiration to precipitation. The spatial pattern showed that soil moisture did not affect GPP_T opt across energy-limited sites with DI < 1 while dominated GPP_T opt across water-limited sites with DI >1. The temporal pattern showed that GPP_T opt was lowered by warming or low precipitation in water-limited sites while energy-limited sites tended to maintain a stable GPP_T opt regardless of changes in air temperature. Vegetation types in humid climates tended to have higher GPP_T opt and were more likely to benefit from a warmer climate since it was not restricted by water conditions. This study highlights that the response of GPP_T opt to global warming depends on the dryness conditions, which explains the nonlinear control of water and temperature over GPP_T opt . Our finding is essential to realistic prediction of terrestrial carbon uptake under future climate and vegetation conditions.

54 ENVIRONMENTAL SCIENCES↗

Cerium oxide impact on fresh and hardened properties of cementitious materials

Cements used in global nuclear waste treatment, storage, and disposal require thorough testing of fresh and cured properties to demonstrate regulatory compliance. Using actual radioactive wastes is often cost-prohibitive during early scoping tests necessitating the use of non-radiological surrogates. Cerium (Ce) is often used as a surrogate for actinides uranium (U) and plutonium (Pu) in spent nuclear fuel, yet few studies have explored how Ce impacts the properties used to qualify a cement for use. Here, this work compares the fresh and cured properties of three classes of cements – ordinary portland cements, ultra-high performance cement composites, and magnesium phosphate cements – each with and without ceria (CeO 2 ). Due to CeO 2 sorption of water (54 vol%) that effectively decreases the water available to hydrate and form binding cement phases, variations in key cement properties were detected that suggest surrogate CeO 2 –cementitious matrices may not be representative of matrix behaviors when using U and Pu sources.

36 MATERIALS SCIENCE↗

The Rate of Canopy Development Modulates the Link Between the Timing of Spring Leaf Emergence and Summer Moisture

Shifts in phenological timing have important implications for ecosystem processes, with spring leaf emergence as a dominant control of carbon, water, and energy cycling. Phenological events are predominantly determined by weather and climate, therefore dynamic in time and sensitive to climate feedbacks. Improving our understanding of how ecosystems respond to changes in phenological timing will enhance our ability to assess summer soil water availability, since the timing of spring leaf emergence may lead to soil moisture deficits later in the growing season. We leveraged data from five AmeriFlux towers in central and eastern United States to investigate the extent spring leaf emergence (i.e., start of spring, SoS ) influences rates at which forest canopies develop and how this impacts summer soil moisture ( θ JJA ) variability. Our results indicate that ecosystem processes, specifically gross primary production ( GPP ) and evapotranspiration ( ET ), exhibit compensatory responses to varying leaf emergence; with delayed spring-onset, the canopy developed more quickly, resulting in rapid GPP and ET increases, consistent across sites. Nonetheless, early SoS is a relatively good indicator for potential summer soil water deficits, particularly when it occurs together with meteorological conditions (i.e., lower-than-average precipitation, hot summer temperatures) that contribute to soil water deficits. When these meteorological conditions coincide with early SoS , θ JJA deficits are exacerbated. To the extent that these extreme conditions occur more frequently under future climate scenarios, the dynamics of spring phenology and hydroclimate may play an increasingly important role in portending the likelihood of summer water deficits, which are projected to become more severe.

54 ENVIRONMENTAL SCIENCES↗

Apollo-Era Life Rafts Save Hundreds of Sailors

The space shuttle is unique among spacecraft in that it glides back to Earth and lands like an airplane, usually touching ground near where it launched at Kennedy Space Center, but sometimes, in poor weather, gliding into the back-up landing site at Dryden Flight Research Center and then catching a ride back to the Cape on the back of a modified Boeing 747. Before NASA began flying the shuttle, though, astronauts had a longer, more involved trip back to base after a mission. Their capsule, called the command module, would plunge through the atmosphere before releasing a series of parachutes that would slow the craft enough for it to land on the water without too significant of an impact. Called a splashdown, this type of landing put the astronauts out in the ocean, where a specially designated U.S. Navy ship would then deploy a helicopter to retrieve the space travelers. Waiting for the rescue, the astronauts would release a highly visible marker dye into the water, then leave the command module and climb aboard a life raft. These early space pioneers had traveled thousands of miles and then landed safely back on Earth. The journey s end was in sight, but they had one more obstacle. The rotor downdraft from the helicopter coming to retrieve them, reaching sometimes as much as 100 knots per hour, was enough to flip a typical flat-bottomed life raft. Not willing to be thwarted after coming so far, NASA engineers began devising a solution. They knew they needed a highly stable inflatable raft capable of riding out the rough winds, and the solution was to make use of the most abundant resource available: water. Engineers at NASA s Johnson Space Center went to work designing and patenting a hydrodynamically stabilized ballast system that would prevent a life raft from tipping in choppy seas and fierce winds.

Source record↗

Hydropower flexibility valuation tool for flow requirement evaluation

Timing of generation is becoming more and more valuable. This creates greater potential tension between environmental and power system objectives since both systems require their own flow patterns. Identifying win–win outcomes in this context requires being able to discuss the value of flexibility across stakeholder groups. This research proposes a two-stage optimization method to understand hydropower flexibility to meet both environmental and power system requirements. The tool simulates the two-settlement market process in the U.S. by maximizing revenues from both the day-ahead and real-time markets, subject to plant operational limits, regulatory flow and ramping requirements, and uncertainties associated with water availability and market prices. The model is formulated as linear programming problems and solved using IBM ILOG CPLEX optimizer. By examining a range of flow requirements, ramping constraints, and storage capacities, the proposed tool shows how to make more informed decisions to weigh the cost of specific flow requirements in the context of the overall license requirements. Results from the case study show that revenue is more sensitive to the ramping constraints than the minimum flow constraints. We also demonstrate that removing flow constraints in a dry month increases monthly revenue by up to 118%, as opposed to only 1% in a wet month. In addition, our results suggest that using a learning-based water flow forecast results in an increase of monthly revenue up to 6.4% compared with persistence forecast.

13 HYDRO ENERGY↗

Deep desert aquifers as an archive for Mid- to Late Pleistocene hydroclimate: An example from the southeastern Mediterranean

Many efforts have been made to illuminate the nature of past hydroclimates in semi-arid and arid regions, where current and future shifts in water availability have enormous consequences on human subsistence. Deep desert aquifers, where groundwater is stored for prolonged periods, might serve as a direct record of major paleo-recharge events. To date, groundwater-based paleoclimate reconstructions have mainly focused on a relatively narrow timescale (up to ∼40 kyr), limited by the relatively short half-life of the widely used radiocarbon (5.73 kyr). Here we demonstrate the usage of deep regional aquifers in the arid southeastern Mediterranean as a hydroclimate archive for earlier Mid-to-Late Pleistocene epochs. State-of-the-art dating tools, primarily the 81 Kr radioisotope (t 1/2 = 229 kyr), were combined with other atmosphere-derived tracers to illuminate the impact of four distinguishable wetter episodes over the past 400 kyr, with differences in climatic conditions and paleo-recharge locations. Variations in stable water isotope composition suggest moisture transport from more proximal (Mediterranean) and distal (Atlantic) sources to different parts of the region at distinct times. Large variability in the computed noble gas-based recharge temperature (NGT), ranging ~15–30 °C, cannot be explained by climate variations solely, and points to different recharge pathways, including geothermal heating in the deep unsaturated zone and recharge from high-elevation (colder) regions. The obtained groundwater record complements and enhances the interpretation of other terrestrial archives in the arid region, including a contribution of valuable information regarding the moisture source origin as reflected in the deuterium-excess values, which is unattainable from the common practice analysis of calcitic cave deposits. We conclude that similar applications in other deep (hundred-m-order) regional groundwater systems (e.g., the Sahara desert aquifers) can significantly advance our understanding of long-term (up to 1 Myr) paleo-hydroclimate in arid regions, including places where no terrestrial remnants, such as cave, lake, and spring sediments, are available.

Atom Trap Trace Analysis↗

Development of the International Space Station (ISS) Fine Water Mist (FWM) Portable Fire Extinguisher

NASA is developing a Fine Water Mist Portable Fire Extinguisher for use on the International Space Station. The International Space Station presently uses two different types of fire extinguishers: a water foam extinguisher in the Russian Segment, and a carbon dioxide extinguisher in the US Segment and Columbus and Kibo pressurized elements. Changes in emergency breathing equipment make Fine Water Mist operationally preferable. Supplied oxygen breathing systems allow for safe discharge of a carbon dioxide fire extinguisher, without concerns of the crew inhaling unsafe levels of carbon dioxide. But the Portable Breathing Apparatus (PBA) offers no more than 15 minutes of capability, and continued use of hose based supplied oxygen system increases the oxygen content in a fire situation. NASA has developed a filtering respirator cartridge for use in a fire environment. It is qualified to provide up to 90 minutes of capability, and because it is a filtering respirator it does not add oxygen to the environment. The fire response respirator cartridge does not filter carbon dioxide (CO2), so a crew member discharging a CO2 fire extinguisher while wearing this filtering respirator would be at risk of inhaling unsafe levels of CO2. Fine Water Mist extinguishes a fire without creating a large volume of air with reduced oxygen and elevated CO2. From a flight hardware design perspective, the fine water mist fire extinguisher has two major elements: (1) the nozzle and crew interface, and (2) the tank. The nozzle and crew interface has been under development for several years. It has gone through several design iterations, and has been part of more than 400 fire challenge and spray characterizations. The crew and vehicle interface aspects of the design will use the heritage of the CO2 based Portable Fire Extinguisher, to minimize the disruption to the crew and integration impacts to the ISS. The microgravity use environment of the system poses a set of unique design requirements specifically for the tank. The nozzle requirements drive a tank pressure that is 2-5 times higher than any commercially available water mist systems. Microgravity requires deliberate separation of gas and water, facilitated by a bladder, a diaphragm, a piston, or separate tanks. This paper will describe the design details of the tank and the nozzle, and discuss the trade studies that informed the decisions to select the tank and nozzle configuration.

Clements, Anna L.↗

Development of the International Space Station (ISS) Fine Water Mist (FWM) Portable Fire Extinguisher ICES Abstract

NASA is developing a Fine Water Mist (FWM) Portable Fire Extinguisher (PFE) for use on the International Space Station. The International Space Station presently uses two different types of fire extinguishers: a water foam extinguisher in the Russian Segment, and a carbon dioxide extinguisher in the US Segment and Columbus and Kibo pressurized elements. Changes in emergency breathing equipment make Fine Water Mist operationally preferable. Supplied oxygen breathing systems allow for safe discharge of a carbon dioxide fire extinguisher, without concerns of the crew inhaling unsafe levels of carbon dioxide. But the Portable Breathing Apparatus (PBA) offers no more than 15 minutes of capability, and continued use of hose based supplied oxygen system increases the oxygen content in a fire situation. NASA has developed a filtering respirator cartridge for use in a fire environment. It is qualified to provide up to 90 minutes of capability, and because it is a filtering respirator it does not add oxygen to the environment. The fire response respirator cartridge does not filter carbon dioxide (CO2), so a crew member discharging a CO2 fire extinguisher while wearing this filtering respirator would be at risk of inhaling unsafe levels of CO2. FWM extinguishes a fire without creating a large volume of air with reduced oxygen and elevated CO2. The following paper will discuss the unique functional and performance requirements that have been levied on the FWM PFE. In addition, the NASA ISS specific fire standards will be described which were developed to establish acceptable extinguisher performance. The paper will also discuss the flight hardware design. The fin e water mist fire extinguisher has two major elements: (1) the nozzle and crew interface, and (2) the tank. The nozzle and crew interface have been under development for several years. They have gone through several design iterations, and have been part of more than 400 fire challenge and spray characterizations. The crew and vehicle interface aspects of the design will use the heritage of the CO2 based Portable Fire Extinguisher, to minimize the disruption to the crew and integration impacts to the ISS. The microgravity use environment of the system poses a set of unique design requirements specifically for the tank. The nozzle requirements drive a tank pressure that is 2-5 times higher than any commercially available water mist systems. Microgravity requires deliberate separation of gas and water, facilitated by a bladder, a diaphragm, a piston, or separate tanks. This paper will describe status of the project to date, the design details of the tank and the nozzle, and discuss the trade studies that informed the decisions to select the tank and nozzle configuration.

Clements, Anna L.↗

Next-Generation Intensity-Duration-Frequency Curves for Diverse Land across the Continental United States

The current methods for designing hydrological infrastructure rely on precipitation-based intensity-duration-frequency curves. However, they cannot accurately predict flooding caused by snowmelt or rain-on-snow events, potentially leading to underdesigned infrastructure and property damage. To address these issues, next-generation intensity-duration-frequency (NG-IDF) curves have been developed for the open condition, characterizing water available for runoff from rainfall, snowmelt, and rain-on-snow. However, they lack consideration of land use land cover (LULC) factors, which can significantly affect runoff processes. We address this limitation by expanding open area NG-IDF dataset to include eight vegetated LULCs over the continental United States, including forest (deciduous, evergreen, mixed), shrub, grass, pasture, crop, and wetland. This NG-IDF 2.0 dataset offers a comprehensive analysis of hydrological extreme events and their associated drivers under different LULCs at a continental scale. It will serve as a useful resource for improving standard design practices and aiding in the assessment of infrastructure design risks. Additionally, it provides useful insights into how changes in LULC impact flooding magnitude, mechanisms, timing, and snow water supply.

54 ENVIRONMENTAL SCIENCES↗