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Alkali-metal contaminants in coal may form low-melting sulfate salts during coal gasification or subsequent combustion which can have very deleterious effects on turbine components. The mechanisms for the hot-corrosion phenomena are not completely understood.
Na+Xe collisions in the presence of two distinct laser fields (rhodamine 110 and Nd:glass) are investigated with reference to the response to nonresonant radiation of alkali metals collisionally perturbed by a buffer gas. It is found that the excited Na-asterisk (4s)+Xe state is produced with a measurable cross section due to two-photon absorption with field intensities as low as 10 MW/sq cm.
Alkaline earth and alkali metal superoxides and peroxides, gamma-Fe2O3 and carbon suboxide polymer, are proposed to be constituents of the Martian surface material. These reactive substances explain the water modified reactions and thermal behaviors of the Martian samples demonstrated by all of the Viking Biology Experiments. It is also proposed that the syntheses of these substances result mainly from electrical discharges between wind-mobilized particles at Martian pressures; plasmas are initiated and maintained by these discharges. Active species in the plasma either combine to form or react with inorganic surfaces to create the reactive constituents.
Simple nonaqueous process synthesizes sodium or potassium, dawsonites effective against hydrocarbon fuel fires. Fire-extinguishing alkali metal dawsonites are prepared using a finely-pulverized equimolar mixture of hydrogen carbonate, or carbonates and aluminum hydroxide heated for 1 to 6 hours under carbon dioxide pressure.
Interactions of valinomycin and form of its analogs in several conformations with the central ions Li(+), Na(+), K(+), Rb(+) and Cs(+) are investigated as part of a study of the specific preference of valinomycin for potassium and the mechanisms of carrier-mediated ion transport across membranes. Ion binding energies and conformational potential energies are calculated taking into account polarization energy formulas and repulsive energy between the central ion and the ligand atoms for conformations representing various stages in ion capture and release for each of the two ring chiralities of valinomycin and its analogs. Results allow the prediction of the chirality and conformation most likely to be observed for a given analog, and may be used to synthesize analogs with a desired rigidity or flexibility. The binding energies with the alkali metal cations are found to decrease with increasing ion size, and to be smaller than the corresponding ion hydration energies. It is pointed out that the observed potassium preference may be explainable in terms of differences between binding and hydration energies. Binding energies are also noted to depend on ligand conformation.
Modified cellulose ether films having an increased electrolytic conductivity and a useable flexibility and in certain instances an increased flexibility are presented. Battery separator membranes comprising a cellulose ether and a minor proportion of a compatible water soluble base selected from the group consisting of alkali metal and ammonium hydroxides, aliphatic amines, and aliphatic hydroxyamines are used.
A program was conducted with the objective of developing advanced thermal barrier coating (TBC) systems. Coating application was by plasma spray. Duplex, triplex and graded coatings were tested. Coating systems incorporated both NiCrAly and CoCrAly bond coats. Four ceramic overlays were tested: ZrO2.82O3; CaO.TiO2; 2CaO.SiO2; and MgO.Al2O3. The best overall results were obtained with a CaO.TiO2 coating applied to a NiCrAly bond coat. This coating was less sensitive than the ZrO2.8Y2O3 coating to process variables and part geometry. Testing with fuels contaminated with compounds containing sulfur, phosphorus and alkali metals showed the zirconia coatings were destabilized. The calcium titanate coatings were not affected by these contaminants. However, when fuels were used containing 50 ppm of vanadium and 150 ppm of magnesium, heavy deposits were formed on the test specimens and combustor components that required frequent cleaning of the test rig. During the program Mars engine first-stage turbine blades were coated and installed for an engine cyclic endurance run with the zirconia, calcium titanate, and calcium silicate coatings. Heavy spalling developed with the calcium silicate system. The zirconia and calcium titanate systems survived the full test duration. It was concluded that these two TBC's showed potential for application in gas turbines.
Progress and plans in various areas of the NASA Space Power Program are discussed. Solar cell research is narrowed to GaAs, multibandgap, and thin Si cells for arrays in planar and concentrator configurations, with further work to increase cell efficiency, radiation hardness, develop flexible encapsulants, and reduce cost. Electrochemical research is concentrating on increasing energy and power density, cycle and wet stand life, reliability and cost reduction of batteries. Further development of the Ni-H2 battery and O2-H2 fuel cell to multihundred kW with a 5 year life and 30,000 cycles is noted. Basic research is ongoing for alkali metal anodes for high energy density secondary cells. Nuclear thermoelectric propulsion is being developed for outer planets exploration propulsion systems, using Si-Ge generators, and studies with rare earth chalcogenides and sulfides are mentioned. Power Systems Management seeks to harmonize increasing power supply levels with inner and outer spacecraft environments, circuits, demands, and automatic monitoring. Concomitant development of bipolar transistors, an infrared rectenna, spacecraft charging measurement, and larger heat pipe transport capacity are noted.
Alkali metal and ammonium dawsonites can be prepared by a nonaqueous process according to which equimolar quantities of the corresponding hydrogen carbonate and aluminum hydroxide in finely divided state are heated together to a tempeature within the range of 150 to 250 C, for a period of 1 to 6 hours under a carbon dioxide pressure within the range of 120 to 360 psig. Carbonates may be used instead of hydrogencarbonates.
The considered Space Energy Conversion Program seeks advancement of basic understanding of energy conversion processes and improvement of component technologies, always in the context of the entire power subsystem. Activities in the program are divided among the traditional disciplines of photovoltaics, electrochemistry, thermoelectrics, and power systems management and distribution. In addition, a broad range of cross-disciplinary explorations of potentially revolutionary new concepts are supported under the advanced energetics program area. Solar cell research and technology are discussed, taking into account the enhancement of the efficiency of Si solar cells, GaAs liquid phase epitaxy and vapor phase epitaxy solar cells, the use of GaAs solar cells in concentrator systems, and the efficiency of a three junction cascade solar cell. Attention is also given to blanket and array technology, the alkali metal thermoelectric converter, a fuel cell/electrolysis system, and thermal to electric conversion.
The alkali metal thermoelectric converter (AMTEC) is a device for the direct conversion of heat to electrical energy. The sodium ion conductor beta-double prime-alumina is used to form a high-temperature regenerative concentration cell for elemental sodium. An AMTEC of mature design should have an efficiency of 20 to 40 percent, a power density of 0.5 kilowatt per kilogram or more, no moving parts, low maintenance requirements, high durability, and efficiency independent of size. It should be usable with high-temperature combustion, nuclear, or solar heat sources. Experiments have demonstrated the feasibility of the AMTEC and confirmed the theoretical analysis of the device. A wide range of applications from aerospace power to utility power plants appears possible.
Small modular alkali metal thermoelectric generator with no moving parts directly converts heat to electrical energy with efficiency of 20 to 40 percent. Unit uses closed regenerative electrochemical concentration cell based on sodium-ion conductor beta alumina.
Candidate high-power supply systems for future space missions are discussed. Solar cells, particularly made from GaAs materials, are projected to be amenable large arrays that will have a 10 yr lifetime with a 15 percent efficiency at the end. Concentrator arrays using GaAs cells could furnish over 200 W/sq m with 100 suns irradiance. Different battery systems, other than the present low-power NiCd storage systems, will be required, and could be either fuel cell systems or NiH2 batteries. The flywheel also offers promise, especially if integrated within the attitude control system. Solar thermal systems are also possible, featuring SiGe thermocouples, or boron alloys or rare earth calcogenides in thermoelectric generators or thermionic converters equipped with alkali metal elements. Mechanical systems, notably the Brayton cycle engine, offer multihundredwatt performance and higher, with at least 3.5 yr lifetimes. Experimentation is still needed to characterize the power supply interaction with the spacecraft environment and to design efficient and long-lasting radiators if heat engines are implemented.
Mixtures of alkali metal dawsonite and metal halide show superior performance. In tests of new dry powder fire extinguishants, mixtures of potassium dawsonite with either stannous iodide or potassium iodide found effective for extinguishing jet-fuel fires on hot metal surfaces (up to 900 degrees C). Mixtures performed more effectively than either compound alone.
This paper addresses issues that should receive further examination in the near-term as concept selection for development of a U.S. space reactor power system is approached. The issues include: the economics, practicality and system reliability associated with transfer of nuclear spacecraft from low earth shuttle orbits to operational orbits, via chemical propulsion versus nuclear electric propulsion; possible astronaut supervised reactor and nuclear electric propulsion startup in low altitude Shuttle orbit; potential deployment methods for nuclear powered spacecraft from Shuttle; the general public safety of low altitude startup and nuclear safe and disposal orbits; the question of preferred reactor power level; and the question of frozen versus molten alkali metal coolant during launch and deployment. These issues must be considered now because they impact the SP-100 concept selection, power level selection, weight and size limits, use of deployable radiators, reliability requirements, and economics, as well as the degree of need for and the urgency of developing space reactor power systems.
Tantalum alloys have a variety of properties which make them attractive candidates for application in nuclear power systems required to operate in space at elevated temperatures (1200 to 1600 K) for extended time periods. Most of the technology development on this class of alloys which is pertinent to space system application occurred during the 1960 to 1972 time period under NASA sponsorship. The most extensive data bases resulting from this earlier work were obtained on the alloys T-111 (Ta-8W-2Hf) and ASTAR 811C (Ta-8W-1Re-0.7Hf-0.025C). Emphasis in this paper is directed at the following technical factors: producibility, creep strength, weldability and compatibility. These factors are considered to be the most important elements in the selection of alloys for this application. Review of the available information indicates that alloys of this type are appropriate for application in many systems, particularly those utilizing alkali metals as the working fluid.
Historically, all space power systems that have actually flown in space have relied on static energy conversion technology. Thus, static conversion is being considered for space nuclear power systems as well. There are four potential static conversion technologies which should be considered. These include: the alkali metal thermoelectric converter (AMTEC), the thermionic converter, the thermoelectric converter, and the thermophotovoltaic converter (TPV). These four conversion technologies will be described in brief detail along with their current status and development needs. In addition, the systems implications of using each of these conversion technologies with a space nuclear reactor power system will be evaluated and some comparisons made.
Existing technologies combined to exploit solar power. Report discusses design concepts for alkali metal thermoelectric power converters heated by Sun. Several alternative configurations of equipment presented, with brief analyses of engineering problems and important features of each.