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Results for “Absorption columns”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

The ratio of solid to gas phase CO in the line of sight to W33A

Spectroscopic observations of the IR source W33A, obtained in the M band (4.6 microns) at resolution 0.057/cm using the Fourier-transform spectrometer at the Cassegrain focus of the Canada-France-Hawaii Telescope on July 12-13, 1987, are reported. The spectrum is shown, and equivalent widths and CO column densities are presented in tables. The absorption lines detected indicate the presence of gas at both 23 and 120 K, attributed to the molecular-cloud core and gas near the source, respectively, but very little solid-phase CO.

Mitchell, George F.↗
NASA NTRS1989

Pressure-confined Lyman-alpha clouds

Results are presented of numerical models of pressure-confined spherical gas clouds which produce absorption resembling the low to intermediate atomic column density lines found in high-redshift QSO spectra. One-dimensional hydrodynamical models including electron conduction are described, and the rate equations are solved to find ionization and excitation states. Results are presented for both static and adiabatically expanding confining media covering a range of initial pressures. It is found that Ly-alpha lines are very similar over a wide range of conditions and that the most promising diagnostic of pressure is to compare the column density in H I to that in He I and He II. No single-pressure model can explain the wide range of observed H I column densities.

Baron, E.↗
NASA NTRS1993

A search for the rotational transitions of H2D+ at 1370 GHz and H3O+ at 985 GHz

A search was made for the 1370 GHz lowest rotational transition of the molecular ion H2D+ in NGC 2264, W3, and the IRc2 region of M42. No emission lines were seen, but an absorption feature was detected toward IRc2. The column density and fractional abundance were calculated using a tentative identification of the line as the transition of para H2D+. The LSR velocity and the measured line width are consistent with the dynamical parameters of the hot core source. Physical parameters deduced from the data differ from those derived from millimeter-wave observations of the hot core condensation. It is suggested that significant amounts of low-density gas are associated with this region and that the material is cold enough for enhanced deuterium fractionation to occur. A search was also made for the 985 GHz transition of ortho H3O+ in W3 and IRc2 with negative results.

Boreiko, R. T.↗
NASA NTRS1994

Measurements of stratospheric composition using a star pointing spectrometer

Measurements of stratospheric composition have been made with a novel star-pointing spectrometer. The instrument consists of a telescope that focuses light from stars, planets, or the moon onto a spectrometer and two dimensional CCD array detector. Atmospheric absorptions can be measured, from which atmospheric columns of several gases can be determined. The instrument was deployed in Abisko, 69 deg N, during the European Arctic Stratospheric Ozone Experiment (EASOE). The instrument has the potential for measuring O3, OClO, NO2, and NO3. In this paper, a method for the retrieval of vertical columns is described, and some examples of ozone measurements given.

Fish, Deb J.↗
NASA NTRS1985

Infrared Measurements of Atmospheric Ethane (C2H6) From Aircraft and Ground-Based Solar Absorption Spectra in the 3000/ cm Region

A number or prominent Q-branches or the upsilon(sub 7) band or C2H6 have been identified near 3000/ cm in aircraft and ground-based infrared solar absorption spectra. The aircraft spectra provide the column amount above 12 km at various altitudes. The column amount is strongly correlated with tropopause height and can be described by a constant mixing ratio of 0.46 ppbv in the upper troposphere and a mixing ratio scale height of 3.9 km above the tropopause. The, ground-based spectra yield a column of 9.0 x 10(exp 15) molecules/sq cm above 2.1 km; combining these results implies a tropospheric mixing ratio of approximately 0.63 ppbv.

Coffey, M. T.↗
NASA NTRS2008

Black Carbon Concentration from Worldwide Aerosol Robotic Network (AERONET)

Worldwide black carbon concentration measurements are needed to assess the efficacy of the carbon emissions inventory and transport model output. This requires long-term measurements in many regions, as model success in one region or season does not apply to all regions and seasons. AERONET is an automated network of more than 180 surface radiometers located throughout the world. The sky radiance measurements obtained by AERONET are inverted to provide column-averaged aerosol refractive indices and size distributions for the AERONET database, which we use to derive column-averaged black carbon concentrations and specific absorptions that are constrained by the measured radiation field. This provides a link between AERONET sky radiance measurements and the elemental carbon concentration of transport models without the need for an optics module in the transport model. Knowledge of both the black carbon concentration and aerosol absorption optical depth (i.e., input and output of the optics module) will enable improvements to the transport model optics module.

Schuster, Greg↗
DOE OSTI2016

MAGiiCAT IV. Kinematics of the circumgalactic medium and evidence for quiescent evolution around red galaxies

The equivalent widths of Mg II absorption in the circumgalactic medium (CGM) trace the global star formation rate up to z < 6, are larger for star-forming galaxies than passively evolving galaxies, and decrease with increasing distance from the galaxy. We delve further into the physics involved by investigating gas kinematics and cloud column density distributions as a function of galaxy color, redshift, and projected distance from the galaxy (normalized by galaxy virial radius, D/R{sub vir}). For 39 isolated galaxies at 0.3 < z{sub gal} < 1.0, we have detected Mg II absorption in high-resolution (Δv ≃ 6.6 km s{sup −1}) spectra of background quasars within a projected distance of 7 < D < 190 kpc. We characterize the absorption velocity spread using pixel-velocity two-point correlation functions. Velocity dispersions and cloud column densities for blue galaxies do not differ with redshift nor with D/R{sub vir}. This suggests that outflows continually replenish the CGM of blue galaxies with high velocity dispersion, large column density gas out to large distances. Conversely, absorption hosted by red galaxies evolves with redshift where the velocity dispersions (column densities) are smaller (larger) at z{sub gal} < 0.656. After taking into account larger possible velocities in more massive galaxies, we find that there is no difference in the velocity dispersions or column densities for absorption hosted by red galaxies with D/R{sub vir}. Thus, a lack of outflows in red galaxies causes the CGM to become more quiescent over time, with lower velocity dispersions and larger column densities toward lower z{sub gal}. The quenching of star formation appears to affect the CGM out to D/R{sub vir} = 0.75.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2018

Measurement of Atmospheric CO2 Column Concentrations to Cloud Tops With a Pulsed Multi-Wavelength Airborne Lidar

We have measured the column-averaged atmospheric CO2 mixing ratio to a variety of cloud tops by using an airborne pulsed multi-wavelength integrated-path differential absorption (IPDA) lidar. Airborne measurements were made at altitudes up to 13 km during the 2011, 2013 and 2014 NASA Active Sensing of CO2 Emissions over Nights, Days, and Seasons (ASCENDS) science campaigns flown in the United States West and Midwest and were compared to those from an in situ sensor. Analysis of the lidar backscatter profiles shows the average cloud top reflectance was approx. 5% for the CO2 measurement at 1572.335 nm except to cirrus clouds, which had lower reflectance. The energies for 1 micro-s wide laser pulses reflected from cloud tops were sufficient to allow clear identification of CO2 absorption line shape and then to allow retrievals of atmospheric column CO2 from the aircraft to cloud tops more than 90% of the time. Retrievals from the CO2 measurements to cloud tops had minimal bias but larger standard deviations when compared to those made to the ground, depending on cloud top roughness and reflectance. The measurements show this new capability helps resolve CO2 horizontal and vertical gradients in the atmosphere. When used with nearby full-column measurements to ground, the CO2 measurements to cloud tops can be used to estimate the partial-column CO2 concentration below clouds, which should lead to better estimates of surface carbon sources and sinks. This additional capability of the range-resolved CO2 IPDA lidar technique provides a new benefit for studying the carbon cycle in future airborne and space-based CO2 missions.

atmospheric↗
DOE OSTI2020

Low-mass Group Environments Have No Substantial Impact on the Circumgalactic Medium Metallicity

We explore how environment affects the metallicity of the circumgalactic medium (CGM) using 13 low-mass galaxy groups (two to five galaxies) at &lang;z{sub abs}&rang;=0.25 identified near background quasars. Using quasar spectra from the Hubble Space Telescope/COS and from Keck/HIRES or the Very Large Telescope/UVES, we measure column densities of or determine limits on CGM absorption lines. We use a Markov Chain Monte Carlo approach with Cloudy to estimate metallicities of cool (T ~ 10{sup 4} K) CGM gas within groups and compare them to CGM metallicities of 47 isolated galaxies. Both group and isolated CGM metallicities span a wide range (-2 < [Si/H] < 0), where the mean group (-0.54 ± 0.22) and isolated (-0.77 ± 0.14) CGM metallicities are similar. Group and isolated environments have similar distributions of H I column densities as a function of impact parameter. However, contrary to isolated galaxies, we do not find an anticorrelation between H I column density and the nearest group galaxy impact parameter. We additionally divided the groups by member luminosity ratios (i.e., galaxy–galaxy and galaxy–dwarf groups). While there was no significant difference in their mean metallicities, a modest increase in sample size should allow one to statistically identify a higher CGM metallicity in galaxy–dwarf groups compared to galaxy–galaxy groups. We conclude that either environmental effects have not played an important role in the metallicity of the CGM at this stage and expect that this may only occur when galaxies are strongly interacting or merging or that some isolated galaxies have higher CGM metallicities due to past interactions. Thus, environment does not seem to be the cause of the CGM metallicity bimodality.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Spatiotemporal evolution of emission and absorption signatures in a laser-produced plasma

Here we report spatiotemporal evolution of emission and absorption signatures of Al species in a nanosecond (ns) laser-produced plasma (LPP). The plasmas were generated from an Inconel target, which contained ~0:4 wt. % Al, using 1064 nm, ≈6 ns full width half maximum pulses from an Nd:YAG laser at an Ar cover gas pressure of ≈34 Torr. The temporal distributions of the Al I (394.4 nm) transition were collected from various spatial points within the plasma employing time-of-flight (TOF) emission and laser absorption spectroscopy, and they provide kinetics of the excited state and ground state population of the selected transition. The emission and absorption signatures showed multiple peaks in their temporal profiles, although they appeared at different spatial locations and times after the plasma onset. The absorption temporal profiles showed an early time signature representing shock wave propagation into the ambient gas. We also used emission and absorption spectral features for measuring various physical properties of the plasma. The absorption spectral profiles are utilized for measuring linewidths, column density, and kinetic temperature, while emission spectra were used to measure excitation temperature. A comparison between excitation and kinetic temperature was made at various spatial points in the plasma. Our results highlight that the TOF measurements provide a resourceful tool for showing the spatiotemporal LPP dynamics with higher spatial and temporal resolution than is possible with spectral measurements but are difficult to interpret without additional information on excitation temperatures and linewidths. The combination of absorption and emission TOF and spectral measurements thus provides a more complete picture of LPP spatiotemporal dynamics than is possible using any one technique alone.

(140.3440) Laser-induced breakdown, (280.4788) Opt↗
NASA NTRS1975

Observations of the interstellar gas with the Copernicus satellite

Results are reviewed for Copernicus far-UV measurements of the absorption lines of H I, D I, H2, and heavier elements in the interstellar gas. Column densities along several lines of sight, as estimated from Ly-alpha absorption-line profiles, confirm that wide differences in the gas density are present in various directions. The measurement of interstellar D I implies an open universe unless alternate sources for this nuclide are found. Analysis of reddened stars for which the line of sight passes through one or more interstellar clouds indicates a depletion of several heavy elements in the gas. It is suggested that the depleted elements may be present in grains rather than molecules and that the intercloud medium may consist primarily of H II with a few small H I clouds.

Morton, D. C.↗
NASA NTRS2012

Critical Reflectance Derived from MODIS: Application for the Retrieval of Aerosol Absorption over Desert Regions

Aerosols are tiny suspended particles in the atmosphere that scatter and absorb sunlight. Smoke particles are aerosols, as are sea salt, particulate pollution and airborne dust. When you look down at the earth from space sometimes you can see vast palls of whitish smoke or brownish dust being transported by winds. The reason that you can see these aerosols is because they are reflecting incoming sunlight back to the view in space. The reason for the difference in color between the different types of aerosol is that the particles arc also absorbing sunlight at different wavelengths. Dust appears brownish or reddish because it absorbs light in the blue wavelengths and scatters more reddish light to space, Knowing how much light is scattered versus how much is absorbed, and knowin~ that as a function of wavelength is essential to being able to quantify the role aerosols play in the energy balance of the earth and in climate change. It is not easy measuring the absorption properties of aerosols when they are suspended in the atmosphere. People have been doing this one substance at a time in the laboratory, but substances mix when they are in the atmosphere and the net absorption effect of all the particles in a column of air is a goal of remote sensing that has not yet been completely successful. In this paper we use a technique based on observing the point at which aerosols change from brightening the surface beneath to darkening it. If aerosols brighten a surface. they must scatter more light to space. If they darken the surface. they must be absorbing more. That cross over point is called the critical reflectance and in this paper we show that critical reflectance is a monotonic function of the intrinsic absorption properties of the particles. This parameter we call the single scattering albedo. We apply the technique to MODIS imagery over the Sahara and Sahel regions to retrieve the single scattering albedo in seven wavelengths, compare these retrievals to ground-based retrievals from AERONET instruments and compute error bars on each retrieval. The results show that we can retrieve single scattering albedo for pure dust to within +/-0.02 and mixtures of dust and smoke to within +/-0.03. No other space based instrument has achieved a retrieval of single scattering albedo that spans the spectrum from 0.47 microns to 2.13 microns and produces regional maps of aerosol absorption showing gradients and changes. Applied in a more operational fashion, such information will narrow uncertainties in estimating aerosol forcing on climate.

Wells, Kelley C.↗
NASA NTRS1992

Hubble Space Telescope Faint Object Spectrograph and ground-based observations of the broad absorption line quasar 0226-1024

Faint Object Spectrograph data from the Hubble Space Telescope of the broad absorption line quasar 0226-1024 have revealed the presence of 8-10 absorbing ions between 680 and 1000 A (restframe): C III, N III, N IV, O III, O IV, O VI, S V, S VI, possibly Ne VIII, and possibly O V* arising from a metastable excited state. We also present ground-based optical observations of the broad line troughs for the following ions: H I, C IV, N V, Si IV, and possibly Fe III, S IV, P V, and C III* (also arising from a metastable excited state). The results of this fit are used to estimate the absorbing ionic column densities. There is evidence that the broad absorption line clouds are optically thick and either do not completely cover the continuum source or narrow unresolved lines are present.

Korista, Kirk T.↗
NASA NTRS1990

Detection of a z=0.0515, 0.0522 absorption system in the QSO S4 0248+430 due to an intervening galaxy

In some of the few cases where the line of sight to a Quasi-Stellar Object (QSO) passes near a galaxy, the galaxy redshift is almost identical to an absorption redshift in the spectrum of the QSO. Although these relatively low redshift QSO-galaxy pairs may not be typical of the majority of the narrow heavy-element QSO absorption systems, they provide a direct measure of column densities in the outer parts of galaxies and some limits on the relative abundances of the gas. Observations are presented here of the QSO S4 0248+430 and a nearby anonymous galaxy (Kuhr 1977). The 14 second separation of the line of sight to the QSO (z sub e = 1.316) and the z=0.052 spiral galaxy, (a projected separation of 20 kpc ((h sub o = 50, q sub o = 0)), makes this a particularly suitable pair for probing the extent and content of gas in the galaxy. Low resolution (6A full width half maximum), long slit charge coupled device (CCD) spectra show strong CA II H and K lines in absorption at the redshift of the galaxy (Junkkarinen 1987). Higher resolution spectra showing both Ca II H and K and Na I D1 and D2 in absorption and direct images are reported here.

Womble, Donna S.↗
DOE OSTI2019

Prevalence of neutral gas in centres of merging galaxies−II: nuclear H i and multiwavelength properties

Abstract Using a sample of 38 radio-loud galaxy mergers at z ≤ 0.2, we confirm the high detection rate (∼84 per cent) of H i 21-cm absorption in mergers, which is significantly higher (∼4 times) than in non-mergers. The distributions of the H i column density [$N(\rm{H\,{\small I}}$)] and velocity shift of the absorption with respect to the systemic redshift of the galaxy hosting the radio source in mergers are significantly different from that in non-mergers. We investigate the connection of the nuclear H i gas with various multiwavelength properties of the mergers. While the inferred $N(\rm{H\,{\small I}}$) and gas kinematics do not show strong (i.e. ≥3σ level) correlation with galaxy properties, we find that the incidence and $N(\rm{H\,{\small I}}$) of absorption tend to be slightly higher at smaller projected separations between the galaxy pairs and among the lower stellar mass-radio galaxies. The incidence, $N(\rm{H\,{\small I}}$) and line width of H i absorption increase from the pre-merger to the post-merger stages. The 100 per cent detection rate in post-mergers indicates that the neutral gas in the circumnuclear regions survives the coalescence period and is not yet quenched by the nuclear radio activity.

Dutta, R.↗
NASA NTRS1987

Methane absorption variations in the spectrum of Pluto

The lightcurve phases of 0.18, 0.35, 0.49, and 0.98 covered by 5600-10,500 A absolute spectrophotometry of Pluto during four nights include minimum (0.98) light and one near-maximum (0.49) light. The spectra are noted to exhibit significant methane band absorption depth variations at 6200, 7200, 7900, 8400, 8600, 8900, and 10,000 A, with the minimum absorption occurring at minimum light and thereby indicating a 30-percent change in the methane column abundance in the course of three days. An attempt is made to model this absorption strength variation with rotational phase terms of an isotropic surface distribution of methane frost and a clear layer of CH4 gas.

Buie, Marc W.↗
NASA NTRS2015

Laser Amplifier Development for the Remote Sensing of CO2 from Space

Accurate global measurements of tropospheric CO2 mixing ratios are needed to study CO2 emissions and CO2 exchange with the land and oceans. NASA Goddard Space Flight Center (GSFC) is developing a pulsed lidar approach for an integrated path differential absorption (IPDA) lidar to allow global measurements of atmospheric CO2 column densities from space. Our group has developed, and successfully flown, an airborne pulsed lidar instrument that uses two tunable pulsed laser transmitters allowing simultaneous measurement of a single CO2 absorption line in the 1570 nm band, absorption of an O2 line pair in the oxygen A-band (765 nm), range, and atmospheric backscatter profiles in the same path. Both lasers are pulsed at 10 kHz, and the two absorption line regions are sampled at typically a 300 Hz rate. A space-based version of this lidar must have a much larger lidar power-area product due to the approximately x40 longer range and faster along track velocity compared to airborne instrument. Initial link budget analysis indicated that for a 400 km orbit, a 1.5 m diameter telescope and a 10 second integration time, a approximately 2 mJ laser energy is required to attain the precision needed for each measurement. To meet this energy requirement, we have pursued parallel power scaling efforts to enable space-based lidar measurement of CO2 concentrations. These included a multiple aperture approach consists of multi-element large mode area fiber amplifiers and a single-aperture approach consists of a multi-pass Er:Yb:Phosphate glass based planar waveguide amplifier (PWA). In this paper we will present our laser amplifier design approaches and preliminary results.

Solid-State Laser Amplifier↗
NASA NTRS2016

High Energy, Narrow Linewidth 1572nm Eryb-Fiber Based MOPA for a Multi-Aperture CO2 Trace-Gas Laser Space Transmitter

Accurate global measurements of tropospheric CO2 mixing ratios are needed to study CO2 emissions and CO2 exchange with the land and oceans. NASA Goddard Space Flight Center (GSFC) is developing a pulsed lidar approach for an integrated path differential absorption (IPDA) lidar to allow global measurements of atmospheric CO2 column densities from space. Our group has developed, and successfully flown, an airborne pulsed lidar instrument that uses two tunable pulsed laser transmitters allowing simultaneous measurement of a single CO2 absorption line in the 1570 nm band, absorption of an O2 line pair in the oxygen A-band (765 nm), range, and atmospheric backscatter profiles in the same path. Both lasers are pulsed at 10 kHz, and the two absorption line regions are sampled at typically a 300 Hz rate. A space-based version of this lidar must have a much larger lidar power-area product due to the x40 longer range and faster along track velocity compared to airborne instrument. Initial link budget analysis indicated that for a 400 km orbit, a 1.5 m diameter telescope and a 10 second integration time, a 2 mJ laser energy is required to attain the precision needed for each measurement. To meet this energy requirement, we have pursued parallel power scaling efforts to enable space-based lidar measurement of CO2 concentrations. These included a multiple aperture approach consists of multi-element large mode area fiber amplifiers and a single-aperture approach consists of a multi-pass Er:Yb:Phosphate glass based planar waveguide amplifier (PWA). In this paper we will present our laser amplifier design approaches and preliminary results.

micropulse lidar↗