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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Valence and patterning of aromatic residues determine the phase behavior of prion-like domains
Abstract not provided
Evolving a New Electron Transfer Pathway for Nitrogen Fixation Uncovers an Electron Bifurcating-Like Enzyme Involved in Anaerobic Aromatic Compound Degradation
There is increasing evidence that protein electron carriers like Fd evolved to form specific partnerships with select electron donors and acceptors to keep native electron transfer pathways insulated from one another. This makes it challenging to integrate a Fd-dependent pathway such as biological nitrogen fixation into non-nitrogen-fixing organisms and provide the high-energy reducing power needed to fix nitrogen.
Isomer-specific spectroscopy of aromatics and their resonance-stabilized radical intermediates
There are many circumstances in which complex gas-phase reaction mixtures must be interrogated and understood, including combustion, plasmas, atmospheres, and molecular clouds. Spectroscopic tools are essential to selective detection and characterization of the widening array of precursors and the reactive intermediates they generate. This research program has focused on the development and implementation of sensitive spectroscopic detection schemes that are isomer-specific and even conformation-specific. In particular, we used an array of laser-based and broadband microwave methods to carry out isomer-specific and conformation-specific spectroscopy on large flexible molecules and reactive intermediates formed by photolysis, pyrolysis, combustion, or electron-driven chemistry.
Radical-radical chain reactions: Low-pressure gas-phase aromatic growth.
Abstract not provided.
Polymer Products from Lignin through De-aromatization and COOH Functionalization
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Energetics and Kinetics of Syntrophic Aromatic Degradation (Final Technical Report)
This DOE Basic Energy Physical Biosciences project spanned a 28-year period and two project investigators. Numerous significant research discoveries have occurred over this time frame. Much of this work has been reported in peer-reviewed literature, with the publication of results from the last four years forthcoming. The overarching project themes have focused on probing the metabolism of syntrophic bacteria and their environments. Research supported by this project has been central to ten doctoral dissertations and one master’s thesis at the University of Oklahoma. The project has also supported numerous undergraduate research projects throughout the years. Additionally, several microbial genomes were sequenced and annotated in association with this work 12-16. Key findings and publications from this work are highlighted. More detailed results are provided for unpublished and embargoed work. A complete list of publications and research products associated with this project is at the report's end.
Amines, Aromatics, and Atmospheric Oxidation: Exploring Nitrogen Chemistry with Photoionization Mass Spectrometry and Computational Chemistry
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Effect of aromaticity on soot formation: A reactive molecular dynamics study
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Effect of aromaticity on soot formation: A reactive molecular dynamics study
This study investigates the formation of soot from n-dodecane and its blend with m-xylene under pyrolytic and low-oxygen conditions with reactive molecular dynamics (MD) simulations.
Evolution and engineering of pathways for aromatic O-demethylation in Pseudomonas putida KT2440 - ALEDB dataset Project: Putida Vanillate
ALE dataset for Pseudomonas putida from https://www.osti.gov/biblio/2404295
Process for enhanced production of desired hydrocarbons from biologically-derived compounds and bio-oils containing cyclic compounds by opening of aromatics and naphthenic ring-containing compounds
A system and process for processing biologically-derived compounds or a complex bio-oil by converting cyclic compounds in a complex bio-oil or biologically-derived compounds to desired materials such as high molecular weight paraffins with minimal carbon loss by using a ring-contraction catalyst to selectively produce C5 ring containing compounds; and then reacting the C5 ring containing compounds with a C5 ring opening catalyst in a second reactor to minimize carbon loss via cracking reactions.
Production of itaconic acid and related molecules from aromatic compounds
This disclosure provides a genetically-modified bacterium from the genus Pseudomonas that produces itaconate or trans-aconitate. The disclosure further provides methods for producing itaconate or trans-aconitate using a genetically-modified bacterium from the genus Pseudomonas.
Renewable aromatics from lignocellulosic lignin
The present invention provides novel and improved processes for treating a lignocellulosic biomass or technical lignin using ionic liquids to obtain lignin breakdown products and polysaccharide biomass components. Recycling of ionic liquids can be included in the methods of the invention.
Numerical Optimization of Microwave Reactor Parameters for Direct Methane Aromatization
AIChE: 3rd Natural Gas Utilization Workshop, Virtual, April 24-25, 2021
Microwave-Enhanced Conversion of Methane into Aromatics Over Mo/ZSM-5 Catalysts
56th Annual Microwave Power Symposium (IMPI 56), Savannah, GA, June 14-16, 2022
Deactivation Study of Mo-HZSM-5 Catalyst for Microwave-Assisted Methane Aromatization: Effect of Reaction Parameters
2022 AIChE Annual Meeting, Phoenix, AZ, November 15-19, 2022
Microwave-assisted Conversion of Natural Gas into Aromatics
For presentation at the Fall 2023 Tri-State Catalysis Club Symposium, Morgantown, WV, September 1, 2023.