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At least 325 records · Page 18

The Dawn of Geostationary Air Quality Monitoring: Case Studies from Seoul and Los Angeles

With the near-future launch of geostationary pollution monitoring satellite instruments over North America, East Asia, and Europe, the air quality community is preparing for an integrated global atmospheric composition observing system at unprecedented spatial and temporal resolutions. One of the ways that NASA has supported this community preparation is through demonstration of future space-borne capabilities using the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument. This paper integrates repeated high-resolution maps from GeoTASO, ground-based Pandora spectrometers, and low Earth orbit measurements from the Ozone Mapping and Profiler Suite (OMPS), for case studies over two metropolitan areas: Seoul, South Korea on June 9, 2016 and Los Angeles, California on June 27, 2017. This dataset provides a unique opportunity to illustrate how geostationary air quality monitoring platforms and ground-based remote sensing networks will close the current spatiotemporal observation gap. GeoTASO observes large differences in diurnal behavior between these urban areas, with NO2 accumulating within the Seoul Metropolitan Area through the day but NO2 peaking in the morning and decreasing throughout the afternoon in the Los Angeles Basin. In both areas, the earliest morning maps exhibit spatial patterns similar to emission source areas (e.g., urbanized valleys, roadways, major airports). These spatial patterns change later in the day due to boundary layer dynamics, horizontal transport, and chemistry. The nominal resolution of GeoTASO is finer than will be obtained from geostationary platforms, but when NO2 data over Los Angeles are up-scaled to the expected resolution of TEMPO, spatial features discussed are conserved. Pandora instruments installed in both metropolitan areas capture the diurnal patterns observed by GeoTASO, continuously and over longer time periods, and will play a critical role in validation of the next generation of satellite measurement. These case studies demonstrate that different regions can have diverse diurnal patterns and that day-to-day variability due to meteorology or anthropogenic patterns such as weekday/weekend variations in emissions is large. Low Earth orbit measurements, despite their inability to capture the diurnal patterns at fine spatial resolution, will be essential for intercalibrating the geostationary radiances and cross-validating the geostationary retrievals in an integrated global observing system.

Geostationary↗

Effects of Vegetation on Fluxes of Nitric Oxide, Nitrogen Dioxide, and Nitrous Oxide in a Mixed Deciduous Forest Clearing

Atmosphere-terrestrial exchange of nitrogen oxides, such as nitric oxide (NO), nitrogen dioxide (NO2) and nitrous oxide (N2O), plays an important role in controlling atmospheric composition and the radiative forcing of Earth’s atmosphere. In this study, the impact of vegetation ground cover on NOx (NOx = NO + NO2) and N2O fluxes in a deciduous forest clearing was studied using dynamic flow chambers located on three experimental plots with differing vegetation ground cover. Microbial emissions of NO and N2O were observed throughout the measurement period, while NO2 was exclusively deposited. Vegetation had no observable impact on NO2 deposition. Under dry conditions, total measured nitrogen emissions were numerically similar across all plots, although the N2O:NO ratio was higher for plots containing plants. Vegetation elevates soil water content through enhanced water retention, a condition that favors denitrification and more N2O production, relative to NO. Two rain events induced pulses of NO and N2O that were higher for bare soil compared to the vegetated plots. Lower NO and N2O emissions in plant-containing chambers stemmed from enhanced root uptake of N following rewetting, which diminished the amount of N substrate available for microbial NO and N2O production. The sensitivity of soil N emissions to vegetation ground cover highlights the need for more studies that investigate this effect over a wide range of ecosystems and to include vegetation effects in future parameterizations of soil NOx and N2O used in atmospheric models. This dataset includes processed data collected from 4 dynamic flux chambers and 17 sensors. Data includes ambient gas measurements made 1 m from the surface and soil flux measurements of NO, NO2, N2O, ozone (O3) and carbon dioxide (CO2). Also included is a suite of meteorological (air temperature, humidity, pressure) and soil parameters (water filled pore space, soil temperature). Refer to the readme for more information about each of the data sets.

54 ENVIRONMENTAL SCIENCES↗

Significant accomplishments in science, 1968

Goddard Space Flight Center is the leading center for science within NASA. It is in fact one of the leading centers of scientific research in the United States and the world. Today members of the Space Sciences Directorate of Goddard are pleased to present to you a review of their accomplishments of t968. Presentations include investigation of earth atmospheric composition, geomagnetism, extraterrestrial radiation, solar activity, and planetary atmospheres by satellite experiment and astronomical observations and much more.

Source record↗

Xe and Kr analyses of silicate inclusions from iron meteorites.

Measurements have been conducted of the amounts and isotopic composition of Xe and Kr in silicate inclusions of several iron meteorites. It is shown that the Xe and Kr contents are comparable to chondritic values. The isotopic compositions show trapped gas of both chondritic and atmospheric composition. Large spallation effects occur in some of the meteorites; the spallation spectra in some instances differ from those reported for stone meteorites. In several meteorites, very large neutron capture effects on Br and I occur. All samples have pronounced Xe129 excesses which apparently indicate differences in the formation times from chondrites of less than about 100 million years; however, the presence of trapped Xe132 in silicates which were enclosed in molten Fe-Ni and cooled slowly proves that they were not entirely outgassed, so that some of the Xe129 excess may also be trapped.

Bogard, D. D.↗

The infrared spectrum of Jupiter

The principal characteristics of Jupiter's infrared spectrum are reviewed with emphasis on their significance for our understanding of the composition and temperature structure of the Jovian upper atmosphere. The spectral region from 1 to 40 microns divides naturally into three regimes: the reflecting region, thermal emission from below the cloud deck (5-micron hot spots), and thermal emission from above the clouds. Opaque parts of the Jovian atmosphere further subdivide these regions into windows, and each is discussed in the context of its past or potential contributions to our knowledge of the planet. Recent results are incorporated into a table of atmospheric composition and abundance which includes positively identified constituents as well as several which require verification. The limited available information about spatial variations of the infrared spectrum is presented

Ridgway, S. T.↗

Mars: Past, Present, and Future. Results from the MSATT Program, part 1

This volume contains papers that were accepted for presentation at the workshop on Mars: Past, Present, and Future -- Results from the MSATT Program. Topics include, but are not limited to: Martian impact craters; thermal emission measurements of Hawaiian palagonitic soils with implications for Mars; thermal studies of the Martian surface; Martian atmospheric composition studies; temporal and spatial mapping of Mars' atmospheric dust opacity and surface albedo; studies of atmospheric dust from Viking IR thermal mapper data; the distribution of Martian ground ice at other epochs; numerical simulation of thermally induced near-surface flows over Martian terrain; the pH of Mars; the mineralogic evolution of the Martian surface through time; geologic controls of erosion and sedimentation on Mars; and dielectric properties of Mars' surface: proposed measurement on a Mars Lander.

Haberle, R. M.↗

Characterizing Uranus with an Ice giant Planetary Origins Probe (Ice-POP)

We now know from studies of planetary transits and microlensing that Neptune-mass planets are ubitquitous and may be the most common class of planets in the Galaxy. As such it is crucial that we understand the formation and evolution of the ice giant planets in our own solar system so that we can better understand planet formation throughout the galaxy. An entry probe mission to Uranus would help accomplish this goal. In fact the Planetary Decadal Survey recommended a Uranus orbiter with entry probe but did not explore in detail the specifications for the entry probe. NASA Ames is currently studying thermal protection system requirements for such a mission and this has led to questions regarding the minimum interesting science payload of such an entry probe. The single most important in-situ measurement for an ice giant entry probe is a measurement of atmospheric composition. For Uranus this would specifically include the methane and noble gas abundances. An in situ measurement of the methane abundance, from below the methane cloud, would constrain the atmospheric carbon abundance, which is believed to be roughly 30 to 50 times solar. There are hints from the transiting planets that extrasolar ice giants show comparable or even greater enhancements of heavy elements compared to their primary stars. However the origin of this carbon enhancement is controversial. Is Uranus a "failed core" of a larger gas giant or was the atmosphere enhanced by accretion of icy planetesimals' Constraining atmospheric abundances of C and perhaps S or even N from below 5 bars would provide badly needed data to address such issues. A measurement of the N abundance would provide clues on the origin of the planetesimals that formed Uranus. Low N-abundance indicates planetesimals from 'warmer' regions where N was mainly in form of NH3, whereas a strong enrichment could indicate planetesimals / cometary material from the colder outer regions of the nebula. Furthermore CO and HCN have been detected in Neptune but not in Uranus. A measurement of the abundance of either would constrain the source mechanisms for these molecules (exogenic or internal). A major surprise from the Galileo Entry Probe was that the heavier noble gases Ar, Kr, and Xe are enhanced in Jupiter's atmosphere at a level comparable to what was seen for the chemically active volatiles N, C, and S. It had been generally expected that Ar, Kr, and Xe would be present in solar abundances, as all were expected to accrete with hydrogen during the gravitational capture of nebular gases. Enhanced abundances of Ar, Kr, and Xe is equivalent to saying that these noble gases have been separated from hydrogen. There are several mechanisms that could accomplish this but these hypotheses require further testing. Measurement of noble gas abundances in an ice giant would constrain the planetary formation and nebular mechanisms responsible for this enhancement. Standard three-layer models of Uranus find that the outer, predominantly H/He layer of Uranus does not reach pressures high enough (approximately 1 Mbar) for H2 to transition to liquid metallic hydrogen. However, valid models can also be constructed with a smaller intermediate water-rich layer, with hydrogen then reaching the metallic hydrogen phase. If this occurs, He should phase separate from the hydrogen and ``rain out," taking along a substantial abundance of Ne, as suggested for Jupiter (and likely also for Saturn). Hence He and Ne depletions could be probes of the planet's structure in the much deeper interior. A determination of Uranus' atmospheric abundances, particularly of the noble gasses, is thus critical to understanding the formation of Uranus, and giant planets in general. These measurements can only be performed with an entry probe. The second key measurement would be a temperature-pressure sounding to provide ground truth for remote measurements of atmospheric temperature and composition and to constrain the internal heat flow. This would also establish that the methane abundance measurements have indeed been made below any possible methane cloud. Finally an ultra stable oscillator would measure wind speeds and constrain atmospheric dynamics. In our presentation we will discuss the importance of all of these measurements and argue that an entry probe is a crucial component of any ice giant mission.

Marley, Mark S.↗

Z-rich solar particle event characteristics 1972-1976

It is found in the reported investigation that Z-rich solar particle events usually have large and prolonged anisotropies in addition to an extremely variable charge composition that varies not only from event to event but also throughout the event. These observations suggest that one can no longer regard the event-averaged composition of solar particle events at low energies as providing an unbiased global sample of the solar atmospheric composition. The variability from event to event and among classes of events is just too great. However, the tendency for the Z-rich events to be associated with both the low-speed solar wind at or just before the onset of solar wind streams and with active regions located in the western hemisphere, indicates that charge composition studies of solar particle events can yield a better knowledge of the flare acceleration process as well as the inhomogeneous nature of magnetic field structure and particle composition in the solar atmosphere.

Zwickl, R. D.↗

The atmosphere of Mars

Effects of Mariner IV ionospheric data on Mars atmosphere composition predictions

MARS ATMOSPHERE↗

Comparisons of measured and theoretical thermospheric daily composition variations

A comparison of the diurnal component of the daily variation in the neutral composition data from the San Marco 3 Nace (Neutral Atmospheric Composition Experiment) mass spectrometer at 220, 250, and 280 km, the OGO-6 model data at 450 km, rocket measurements of nitrogen between 140 and 300 km, and the two-constituent theoretical model of Mayr and Volland (1973) gives good agreement for molecular nitrogen and atomic oxygen. The Nace and rocket measurements overlap in altitude, and there is good agreement in the amplitude and phase of the diurnal and semidiurnal components for molecular nitrogen. The helium diurnal amplitude and phase of the theoretical model are in fair agreement with the Nace results, while the amplitude from the OGO-6 model at 450 km is much larger than the model predicts, a result suggesting that the OGO-6 model diurnal amplitude may be overestimated as the result of an incomplete separation of local-time and seasonal effects.

Kasprzak, W. T.↗

Venus upper atmosphere structure

Atmospheric densities of Venus were measured from the orbital decay of the Pioneer Venus from Dec. 9, 1978 to Aug. 7, 1979 near the 16 deg latitude between 140 and 190 km during the entire day. Comparative atmospheric densities on earth at 150 km are higher by a factor of 3.5 with only a 1% diurnal variation; an atmospheric composition, temperature, and density model based on the orbiter atmospheric drag (OAD) vertical structure is presented. The model shows that atomic oxygen is the major component in the Venus atmosphere above 145 km at night and above 160 km during the day with mixing ratios over 0.1 near 140 km; drag measurements indicate O concentrations from 1 x 10 to the 9th/cu cm in daytime to 3 x 10 to the 7th/cu cm at night. It is concluded that the neutral upper atmosphere of Venus is surprisingly insensitive to solar extreme UV variations and changes in the solar wind.

Keating, G. M.↗

Sulfur trioxide in the lower atmosphere of Venus

Inconsistencies and ambiguities are noted by the present consideration of Pioneer Venus and Venera atmospheric composition measurement of Venus in the context of lower atmosphere thermodynamic equilibrium. Among the scenarios projected on the basis of assumed correctness for selected data subsets, the O2 and SO2 concentrations reported by the Pioneer Venus chromatograph and the H2O concentrations reported by Venera 11 suggest that large concentrations of SO3 are present in the lower atmosphere of Venus. Such SO3 concentrations lead, however, to difficulties in explaining the atmosphere at and above the cloud tops, and in addition require specific assumptions concerning chemical reaction rates at and near the surface.

Craig, R. A.↗

Neutral composition variation above 400 kilometers during a magnetic storm.

Examination of data from the neutral atmospheric composition experiment launched aboard Ogo 6, June 5, 1969, for the period from Sept. 27 through Oct. 3, 1969. Several magnetic storms occurred during this time, and the response of the neutral atmosphere to the energy deposition causing these storms was studied. The data indicate that the major portion of the energy is deposited at high latitudes, causing enhancements in N2 densities corresponding to Jacchia (1970) temperature increases on the order of 400 to 500 K. The time difference between atmospheric response and magnetic activity appears to be very short at high latitudes. The O/N2 ratio variations suggest dynamic processes that cause a circulation in the atmosphere that is upward at the pole with subsidence at the equator.

Taeusch, D. R.↗

Correction Technique for Raman Water Vapor Lidar Signal-Dependent Bias and Suitability for Water Wapor Trend Monitoring in the Upper Troposphere

The MOHAVE-2009 campaign brought together diverse instrumentation for measuring atmospheric water vapor. We report on the participation of the ALVICE (Atmospheric Laboratory for Validation, Interagency Collaboration and Education) mobile laboratory in the MOHAVE-2009 campaign. In appendices we also report on the performance of the corrected Vaisala RS92 radiosonde measurements during the campaign, on a new radiosonde based calibration algorithm that reduces the influence of atmospheric variability on the derived calibration constant, and on other results of the ALVICE deployment. The MOHAVE-2009 campaign permitted the Raman lidar systems participating to discover and address measurement biases in the upper troposphere and lower stratosphere. The ALVICE lidar system was found to possess a wet bias which was attributed to fluorescence of insect material that was deposited on the telescope early in the mission. Other sources of wet biases are discussed and data from other Raman lidar systems are investigated, revealing that wet biases in upper tropospheric (UT) and lower stratospheric (LS) water vapor measurements appear to be quite common in Raman lidar systems. Lower stratospheric climatology of water vapor is investigated both as a means to check for the existence of these wet biases in Raman lidar data and as a source of correction for the bias. A correction technique is derived and applied to the ALVICE lidar water vapor profiles. Good agreement is found between corrected ALVICE lidar measurments and those of RS92, frost point hygrometer and total column water. The correction is offered as a general method to both quality control Raman water vapor lidar data and to correct those data that have signal-dependent bias. The influence of the correction is shown to be small at regions in the upper troposphere where recent work indicates detection of trends in atmospheric water vapor may be most robust. The correction shown here holds promise for permitting useful upper tropospheric water vapor profiles to be consistently measured by Raman lidar within NDACC (Network for the Detection of Atmospheric Composition Change) and elsewhere, despite the prevalence of instrumental and atmospheric effects that can contaminate the very low signal to noise measurements in the UT.

MOHAVE-2009↗

Galileo Space Probe News Conference

This NASA Kennedy Space Center (KSC) video release presents Part 1 of a press conference regarding the successful entry of the Galileo Space Probe into Jupiter's atmosphere. The press conference panel is comprised of twelve principal investigators and project scientists that oversee the Galileo mission. Among these panelists, William J. O'Neil (Jet Propulsion Lab.) begins the video praising all of the scientists that worked on the orbiter mission. He then presents a visual overview of Galileo's overall mission trajectory and schedule. Marcie Smith (NASA Ames Research Center) then describes the Galileo Probe mission and the overall engineering and data acquisition aspects of the Probe's Jupiter atmospheric entry. Dr. Richard Young (NASA Ames Research Center) follows with a brief scientific overview, describing the measurements of the atmospheric composition as well as the instruments that were used to gather the data. Atmospheric pressure, temperature, density, and radiation levels of Jupiter were among the most important parameters measured. It is explained that these measurements would be helpful in determining among other things, the overall dynamic meteorology of Jupiter. A question and answer period follows the individual presentations. Atmospheric thermal structure, water abundances, wind profiles, radiation, cloud structure, chemical composition, and electricity are among the topics discussed. Parts 2 and 3 of the press conference can be found in document numbers NONP-NASA-VT-2000001074, and NONP-NASA-VT-2000001075.

Source record↗

Atmospheric Escape From TOI-700 d: Venus versus Earth Analogs

The recent discovery of an Earth-sized planet (TOI-700 d) in the habitable zone of an early-type M-dwarf by the Transiting Exoplanet Survey Satellite constitutes an important advance. In this Letter, we assess the feasibility of this planet to retain an atmosphere – one of the chief ingredients for surface habitability – over long timescales by employing state-of-the-art magnetohydrodynamic models to simulate the stellar wind and the associated rates of atmospheric escape. We take two major factors into consideration, namely, the planetary atmospheric composition and magnetic field. In all cases, we determine that the atmospheric ion escape rates are potentially a few orders of magnitude higher than the inner Solar system planets, but TOI-700 d is nevertheless capable of retaining a 1 bar atmosphere over gigayear timescales for certain regions of the parameter space. The simulations show that the unmagnetized TOI-700 d with a 1 bar Earth-like atmosphere could be stripped away rather quickly (< 1 gigayear), while the unmagnetized TOI-700 d with a 1 bar CO 2 -dominated atmosphere could persist for many billions of years; we find that the magnetized Earth-like case falls in between these two scenarios. We also discuss the prospects for detecting radio emission of the planet (thereby constraining its magnetic field) and discerning the presence of an atmosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

A Study of the Electrostatic Interaction Between Insulators and Martian/Lunar Soil Simulants

Using our previous experience with the Mars Environmental Compatibility Assessment (MECA) electrometer, we have designed a new type of aerodynamic electrometer. The goal of the research was to measure the buildup of electrostatic surface charge on a stationary cylindrical insulator after windborne granular particles have collided with the insulator surface in a simulated dust storm. The experiments are performed inside a vacuum chamber. This allows the atmospheric composition and pressure to be controlled in order to simulate the atmospheric conditions near the equator on the Martian surface. An impeller fan was used to propel the dust particles at a cylindrically shaped insulator under low vacuum conditions. We tested the new electrometer in a 10 mbar CO2 atmosphere by exposing two types of cylindrical insulators, Teflon (1.9 cm diameter) and Fiberglass (2.5 cm diameter), to a variety of windborne granular particulate materials. The granular materials tested were JSC Mars-1 simulant, which is a mixture of coarse and fine (<5microns diameter) particle sizes, and some of the major mineral constituents of the Martian soil. The minerals included Ottawa sand (SiO2), iron oxide (Fe2O3), aluminum oxide (Al2O3) and magnesium oxide (MgO). We also constructed a MECA-like electrometer that contained an insulator capped planar electrode for measuring the amount of electrostatic charge produced by rubbing an insulator surface over Martian and lunar soil simulants. The results of this study indicate that it is possible to detect triboelectric charging of insulator surfaces by windborne Martian soil simulant, and by individual mineral constituents of the soil simulant. We have also found that Teflon and Fiberglass insulator surfaces respond in different ways by developing opposite polarity surface charge, which decays at different rates after the particle impacts cease.

Mantovani, James G.↗

Linkages Between Ozone-depleting Substances, Tropospheric Oxidation and Aerosols

Coupling between the stratosphere and the troposphere allows changes in stratospheric ozone abundances to affect tropospheric chemistry. Large-scale effects from such changes on chemically produced tropospheric aerosols have not been systematically examined in past studies. We use a composition-climate model to investigate potential past and future impacts of changes in stratospheric ozone depleting substances (ODS) on tropospheric oxidants and sulfate aerosols. In most experiments, we find significant responses in tropospheric photolysis and oxidants, with small but significant effects on methane radiative forcing. The response of sulfate aerosols is sizeable when examining the effect of increasing future nitrous oxide (N2O) emissions. We also find that without the regulation of chlorofluorocarbons (CFCs) through the Montreal Protocol, sulfate aerosols could have increased by 2050 by a comparable amount to the decreases predicted due to relatively stringent sulfur emissions controls. The individual historical radiative forcings of CFCs and N2O through their indirect effects on methane (−22.6mW/sq. m for CFCs and −6.7mW/sq. m for N2O) and sulfate aerosols (−3.0mW/sq. m for CFCs and +6.5mW/sq. m for N2O when considering the direct aerosol effect) discussed here are non-negligible when compared to known historical ODS forcing. Our results stress the importance of accounting for stratosphere-troposphere, gas-aerosol and composition-climate interactions when investigating the effects of changing emissions on atmospheric composition and climate.

troposphere↗