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At least 325 records · Page 18

SABRE Ir-IMes Catalysis for the Masses

The Signal Amplification By Reversible Exchange (SABRE) technique provides enhancement of Nuclear Magnetic Resonance (NMR) signals up to several orders of magnitude using chemical exchange of a substrate and parahydrogen on an iridium complex. Therefore, the availability of such a catalytic complex to a broader community is an absolutely vital step for dissemination of the groundbreaking SABRE methodology. The most common SABRE catalyst, which is activated in situ, is based on Ir-IMes system (IMes = 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene). Earlier approaches for the synthesis of this catalyst often relied on specialized equipment and were limited to a comparatively small scale. This, in turn, increased the barrier of entry for new scientists to the area of SABRE hyperpolarization. Here, we present a robust, inexpensive, and easy to reproduce synthetic procedure for the preparation of this SABRE catalyst, which does not require specialized inert atmosphere equipment like a glove box or Schlenk line. The synthesis was validated on the scale of several grams vs. tens of milligrams scale in the reported approaches. The resulting SABRE catalyst, [Ir(IMes)(COD)Cl], was activated in situ and further evaluated in hyperpolarization experiments resulting in signal enhancements comparable to (or higher than) those for the catalyst prepared using Schlenk line equipment.

Biochemistry & Molecular Biology↗

AEPF: Attention-Enabled Point Fusion for 3D Object Detection

Current state-of-the-art (SOTA) LiDAR-only detectors perform well for 3D object detection tasks, but point cloud data are typically sparse and lacks semantic information. Detailed semantic information obtained from camera images can be added with existing LiDAR-based detectors to create a robust 3D detection pipeline. With two different data types, a major challenge in developing multi-modal sensor fusion networks is to achieve effective data fusion while managing computational resources. With separate 2D and 3D feature extraction backbones, feature fusion can become more challenging as these modes generate different gradients, leading to gradient conflicts and suboptimal convergence during network optimization. To this end, we propose a 3D object detection method, Attention-Enabled Point Fusion (AEPF). AEPF uses images and voxelized point cloud data as inputs and estimates the 3D bounding boxes of object locations as outputs. An attention mechanism is introduced to an existing feature fusion strategy to improve 3D detection accuracy and two variants are proposed. These two variants, AEPF-Small and AEPF-Large, address different needs. AEPF-Small, with a lightweight attention module and fewer parameters, offers fast inference. AEPF-Large, with a more complex attention module and increased parameters, provides higher accuracy than baseline models. Experimental results on the KITTI validation set show that AEPF-Small maintains SOTA 3D detection accuracy while inferencing at higher speeds. AEPF-Large achieves mean average precision scores of 91.13, 79.06, and 76.15 for the car class’s easy, medium, and hard targets, respectively, in the KITTI validation set. Results from ablation experiments are also presented to support the choice of model architecture.

Chemistry↗

Remote Americium Detection Using an Optical Sensor: A D-Optimal Strategy for Efficient PLS-Based Modeling

A fiber-optic visible–near-infrared absorption spectroscopy system in a glove box was demonstrated for remote quantification of Am(III) (0–500 µM) and HNO 3 (0.1–9 M) using partial least squares regression (PLSR) models. The sensor platform, featuring a simple plug-and-play spectrophotometer, can enable noninvasive, real-time monitoring of actinide process solutions. To establish a flexible PLSR model calibration strategy, a D-optimal design developed using Nd(III) in previous studies was successfully extended to an actinide system with Am(III) to effectively minimize sample set size while maintaining robust prediction performance. The results suggest strong spectral similarities between Nd(III) and Am(III) and validate Nd(III) as an effective optical surrogate for trivalent actinide species. This work also supports the generalizability of a D-optimal training set selection approach for two-factor systems. The PLS1 models for Am(III) and HNO 3 outperformed a PLS2 model and maintained reasonable performance in the presence of interfering U(VI). The resulting sensor system and multivariate approach provides a flexible and scalable solution for process monitoring, control, and safety in diverse nuclear applications.

actinide↗

The Evolution of Inclined Binary Black Holes in the Disks of Active Galactic Nuclei

The accretion disks that fuel active galactic nuclei (AGNs) may house numerous stars and compact objects, formed in situ or captured from nearby star clusters. Embedded neutron stars and black holes may form binaries and eventually merge, emitting gravitational waves detectable by LIGO/VIRGO. AGN disks are a particularly promising environment for the production of high-mass gravitational-wave events involving black holes in the pair-instability mass gap, and may facilitate electromagnetic counterparts to black hole binary mergers. However, many orders of magnitude separate the typical length scales of binary formation and those on which gravitational waves can drive binary inspirals, making binary mergers inside the disk uncertain. Previous hydrodynamical simulations of binaries have either been restricted to two dimensions entirely, or focused on binaries aligned with the midplane of the disk. Herein we present the first three-dimensional, high-resolution, local-shearing-box, inviscid hydrodynamical simulations of disk-embedded binaries over a range of orbital inclinations. We find that retrograde binaries can shrink up to 4 times as quickly as prograde binaries, and that all binaries not perfectly aligned (or anti-aligned) with the AGN disk are driven into alignment. An important consequence of this is that initially retrograde binaries will traverse the inclinations where von Zeipel–Lidov–Kozai oscillations can drive binary eccentricities to large values, potentially facilitating mergers. We also find that interactions with the AGN disk may excite eccentricities in retrograde binaries and cause the orbits of embedded binaries to precess.

79 ASTRONOMY AND ASTROPHYSICS↗

Runaway Eccentricity Growth: A Pathway for Binary Black Hole Mergers in AGN Disks

Binary black holes (BBHs) embedded within the accretion disks that fuel active galactic nuclei (AGN) are promising progenitors for the source of gravitational wave (GW) events detected by LIGO/VIRGO. Several recent studies have shown that when these binaries form, they are likely to be highly eccentric and retrograde. However, many uncertainties remain concerning the orbital evolution of these binaries as they either inspiral toward merger or disassociate. Previous hydrodynamical simulations exploring their orbital evolution have been predominantly two-dimensional or have been restricted to binaries on nearly circular orbits. We present the first high-resolution, three-dimensional local shearing-box simulations of both prograde and retrograde eccentric BBHs embedded in AGN disks. We find that retrograde binaries shrink several times faster than their prograde counterparts and exhibit significant orbital eccentricity growth, the rate of which monotonically increases with binary eccentricity. Our results suggest that retrograde binaries may experience runaway orbital eccentricity growth, which may bring them close enough together at pericenter for GW emission to drive them to coalescence. Although their eccentricity is damped, prograde binaries shrink much faster than their orbital eccentricity decays, suggesting they should remain modestly eccentric as they contract toward merger. Finally, binary precession driven by the AGN disk may dominate over precession induced by the supermassive black hole depending on the binary accretion rate and its location in the AGN disk, which can subdue the evection resonance and von Ziepel–Lidov–Kozai cycles.

79 ASTRONOMY AND ASTROPHYSICS↗

Evolution of Magnetohydrodynamic Turbulence in the Expanding Solar Wind: Residual Energy and Intermittency

We conduct 3D magnetohydrodynamic simulations of decaying turbulence in the context of the solar wind. To account for the spherical expansion of the solar wind, we implement the expanding box model. The initial turbulence comprises uncorrelated counterpropagating Alfvén waves and exhibits an isotropic power spectrum. Our findings reveal the consistent generation of negative residual energy whenever nonlinear interactions are present, independent of the normalized cross helicity σc and compressibility. The spherical expansion facilitates this process. The resulting residual energy is primarily distributed in the perpendicular direction, with S 2 (b) − S 2 (u) ∝ l ⊥ or equivalently –E r ∝ k$^{–2}_{⟂}$. Here S 2 (b) and S 2 (u) are second-order structure functions of magnetic field and velocity respectively. In most runs, S 2 (b) develops a scaling relation S 2 (b) ∝ $l$$^{1/2}_{⊥}$ (E b ∝ k$^{–3/2}_{⟂}$). In contrast, S 2 (u) is consistently shallower than S 2 (b), which aligns with in situ observations of the solar wind. We observe that the higher-order statistics of the turbulence, which act as a proxy for intermittency, depend on the initial σc and are strongly affected by the expansion effect. Generally, the intermittency is more pronounced when the expansion effect is present. Finally, we find that in our simulations, although the negative residual energy and intermittency grow simultaneously as the turbulence evolves, the causal relation between them seems to be weak, possibly because they are generated on different scales.

Interplanetary turbulence↗

Introducing the DREAMS Project: DaRk mattEr and Astrophysics with Machine Learning and Simulations

We introduce the DaRk mattEr and Astrophysics with Machine learning and Simulations (DREAMS) project, an innovative approach to understanding the astrophysical implications of alternative dark matter (DM) models and their effects on galaxy formation and evolution. The DREAMS project will ultimately comprise thousands of cosmological hydrodynamic simulations that simultaneously vary over DM physics, astrophysics, and cosmology in modeling a range of systems—from galaxy clusters to ultra-faint satellites. Such extensive simulation suites can provide adequate training sets for machine-learning-based analyses. This paper introduces two new cosmological hydrodynamical suites of warm dark matter (WDM), each comprising 1024 simulations generated using the arepo code. One suite consists of uniform-box simulations covering a ${(25\,{h}^{-1}\,{\rm{Mpc}})}^{3}$ volume, while the other consists of Milky Way zoom-ins with sufficient resolution to capture the properties of classical satellites. For each simulation, the WDM particle mass is varied along with the initial density field and several parameters controlling the strength of baryonic feedback within the IllustrisTNG model. We provide two examples, separately utilizing emulators and convolutional neural networks, to demonstrate how such simulation suites can be used to disentangle the effects of DM and baryonic physics on galactic properties. The DREAMS project can be extended further to include different DM models, galaxy formation physics, and astrophysical targets. In this way, it will provide an unparalleled opportunity to characterize uncertainties on predictions for small-scale observables, leading to robust predictions for testing the particle physics nature of DM on these scales.

cosmological parameters↗

SAGAbg. III. Environmental Stellar Mass Functions, Self-quenching, and the Stellar-to-halo Mass Relation in the Dwarf Galaxy Regime

Recent efforts have extended our view of the number and properties of satellite galaxies beyond the Local Group firmly down to M ⋆ ∼ 10 6 M ⊙ . A similarly complete view of the field dwarf population has lagged behind. Using the background galaxy sample from the Satellites Around Galactic Analogs (SAGA) survey at z < 0.05, we take inventory of the dwarf population down to M ⋆ ∼ 5 × 10 6 M ⊙ using three metrics: the stellar mass function (SMF) as a function of environment, the stellar-to-halo mass relation (SHMR) of dwarf galaxies inferred via abundance matching, and the quenched fraction of highly isolated dwarfs. We find that the low-mass SMF shape shows minimal environmental dependence, with the field dwarf SMF described by a low-mass power-law index of α 1 = −1.44 ± 0.09 down to M ⋆ ∼ 5 × 10 6 M ⊙ , and that the quenched fraction of isolated dwarfs drops monotonically to f q ∼ 10 −3 at M ⋆ ∼ 10 8.5 M ⊙ . Though slightly steeper than estimates from H I kinematic measures, our inferred SHMR agrees with literature measurements of satellite systems, consistent with minimal environmental dependence of the SHMR in the probed mass range. Finally, although most contemporary cosmological simulations against which we compare accurately predict the SAGAbg-SMF SHMR, we find that big-box cosmological simulations largely overpredict isolated galaxy quenched fractions via a turnaround in f q (M ⋆ ) at 10 8 ≲ M ⋆ /M ⊙ ≲ 10 9 , underscoring the complexities in disentangling the drivers of galaxy formation and the need for systematic multidimensional observations of the dwarf population across environments.

Kado-Fong, Erin [Yale Univ., New Haven, CT (United↗

MESA Isochrones and Stellar Tracks (MIST). III. The White Dwarf Cooling Sequence

We present a substantial update to the MESA Isochrones and Stellar Tracks (MIST) library, extending the MIST model grids and isochrones down the white dwarf (WD) cooling sequence with realistic physics for WD cooling timescales. This work provides a large grid of MESA models for carbon–oxygen core WDs with hydrogen atmospheres (spectral type DA/DC), descended from full prior stellar evolution calculations. The model tracks, isochrones, and WD cooling timescale contours are available on the MIST project website and at doi:10.5281/zenodo.15242047. Our WD models provide a very large, publicly available grid with detailed physics for WD cooling timescales: realistic interior and envelope compositions, with element diffusion and heavy-element sedimentation, nuclear burning at the base of the WD hydrogen envelope, core crystallization, and C/O phase separation. As a large grid of open-source stellar evolution models, these WD models provide both out-of-the-box model tracks for comparison with observations and a framework for building further WD models to investigate variations in WD physics.

Astronomy and AstroPhysics↗

Equation-Free Coarse Control of Distributed Parameter Systems via Local Neural Operators

The control of high-dimensional distributed parameter systems (DPS) remains a challenge when explicit coarse-grained equations are unavailable. Classical equation-free (EF) approaches rely on fine-scale simulators treated as black-box timesteppers. However, repeated simulations for steady-state computation, linearization, and control design are often computationally prohibitive, or the microscopic timestepper may not even be available, leaving us with data as the only resource. We propose a data-driven alternative that uses local neural operators, trained on spatiotemporal microscopic/mesoscopic data, to obtain efficient short-time solution operators. These surrogates are employed within Krylov subspace methods to compute coarse steady and unsteady-states, while also providing Jacobian information in a matrix-free manner. Krylov-Arnoldi iterations then approximate the dominant eigenspectrum, yielding reduced models that capture the open-loop slow dynamics without explicit Jacobian assembly. Both discrete-time Linear Quadratic Regulator (dLQR) and pole-placement (PP) controllers are based on this reduced system and lifted back to the full nonlinear dynamics, thereby closing the feedback loop.

93B52, 93C20, 47N70, 65J15, 65M32, 68T07, 68T20, 6↗

Application of PRIM for understanding patterns in carbon dioxide model-observation differences

Reducing uncertainties in regional carbon balances requires a better understanding of CO 2 transport in synoptic weather systems. Here, we apply the Patient Rule Induction Method (PRIM), a data-mining method to identify high-density regions for a target-class within an input parameter space, to airborne observations of potential temperature, wind speed, water vapor mixing ratio, and CO 2 dry mol fraction gathered during the Atmospheric Carbon and Transport (ACT)-America Summer 2016 and Winter 2017 campaigns. ACT observations were targeted at expert-designated cases of fair weather and near-frontal warm and cold sector air at atmospheric boundary-layer, lower-, and higher free tropospheric levels (ABL, LFT, and HFT, respectively). We investigate atmospheric characteristics of these pre-defined cases and associated CO 2 model-observation-differences in the mesoscale WRF-Chem model. PRIM results separate winter- and summertime observations as well as observations from ABL, LFT, and HFT with enrichment factors of 4.0–20.5 inside the PRIM box compared to the entire dataset but cannot distinguish between near-frontal warm and cold sector observations in the higher free troposphere. Analyzing of the parameter space constrained by PRIM, we find that large magnitude model observation differences preferentially associated with times when atmospheric conditions are less typical. This association suggests that PRIM could provide a useful tool for isolating atmospheric conditions with large-magnitude and non-Gaussian CO 2 -residuals for targeted transport model evaluation and to potentially improve inversion results during synoptically active periods.

Gerken, Tobias [James Madison Univ., Harrisonburg,↗

The sources and diurnal variations of submicron aerosols in a coastal–rural environment near Houston, US

Aerosol properties were characterized at a rural site southwest of Houston from May to September 2022 during the intensive operation periods (IOPs) of the Tracking Aerosol Convection Interactions ExpeRiment (TRACER). Backward trajectory analysis reveals three major air mass types: marine air mass from the Gulf, urban air mass influenced by urban emissions, and regional air mass. Marine aerosols typically show a bimodal size distribution and have the lowest particle number and mass concentrations of PM 1 (particulate matter with an aerodynamic diameter of less than 1 µm), while aerosols from air masses strongly influenced by urban emissions exhibit the highest concentrations. Organic aerosol (OA) accounts for more than 50 % of PM 1 for urban and regional air masses, whereas sulfate is comparable to OA in marine air masses. Positive matrix factorization (PMF) analysis of aerosol mass spectra identifies 6 OA factors: hydrocarbon-like OA (HOA), OA from the oxidation of monoterpenes (MT-SOA), OA from the reactive uptake of isoprene epoxydiols by acidic sulfate particles (isoprene-SOA), oxygenated OA arising from shipping emissions (shipping-OOA), and two oxygenated OA factors with high O : C ratios (OOA1 and OOA2). OOA2 has the highest O : C ratio and exhibits elevated mass concentration in the afternoon. Similar diurnal variation of highly oxidized OA factors was commonly observed in the Houston area during previous studies and attributed to the SOA formation by photochemistry and mixing from aloft. Here, using air mass backward trajectories and a 1-D box model, we show the diurnal trend of OOA2 mass concentration is instead driven by changes in air mass arriving at the rural site. The air mass changes are likely caused by the shift between land breezes and sea/bay breezes. Within the same air mass type (e.g., either urban or marine air mass), OOA2 mass concentration is largely independent of wind direction and shows essentially no diurnal variation, suggesting OOA2 is related to aged OA with minimal influence by local emissions. This study helps identify the major sources of OA in the Houston region and highlights the impacts of both atmospheric chemistry and meteorology on aerosol properties in the coastal–rural environment.

54 ENVIRONMENTAL SCIENCES↗

Cloud processing of dimethyl sulfide (DMS) oxidation products limits sulfur dioxide (SO 2 ) and carbonyl sulfide (OCS) production in the eastern North Atlantic marine boundary layer

Dimethyl sulfide (DMS) is the major sulfur species emitted from the ocean. The gas-phase oxidation of DMS by hydroxyl radicals proceeds through the stable, soluble intermediate hydroperoxymethyl thioformate (HPMTF), eventually forming carbonyl sulfide (OCS) and sulfur dioxide (SO 2 ). Recent work has shown that HPMTF is efficiently lost to marine boundary layer (MBL) clouds, thus arresting OCS and SO 2 production and their contributions to new-particle formation and growth events. To date, no long-term field studies exist to assess the extent to which frequent cloud processing impacts the fate of HPMTF. Here, we present 6 weeks of measurements of the cloud fraction and the marine sulfur species methanethiol, DMS, and HPMTF made at the Atmospheric Radiation Measurement (ARM) research facility on Graciosa Island, Azores, Portugal. Using an observationally constrained chemical box model, we determine that cloud loss is the dominant sink of HPMTF in this region of the MBL during the study, accounting for 79 %–91 % of HPMTF loss on average. When accounting for HPMTF uptake to clouds, we calculate campaign average reductions in DMS-derived MBL SO 2 and OCS of 52 %–60 % and 80 %–92 % for the study period. Using yearly measurements of the site- and satellite-measured 3D cloud fraction and DMS climatology, we infer that HPMTF cloud loss is the dominant sink of HPMTF in the eastern North Atlantic during all seasons and occurs on timescales faster than what is prescribed in global chemical transport models. Accurately resolving this rapid loss of HPMTF to clouds has important implications for constraining drivers of MBL new-particle formation.

54 ENVIRONMENTAL SCIENCES↗

Laboratory and field assessment of mid-infrared absorption (MIRA) instrument performance for methane and ethane dry mole fractions

Concurrent measurements of methane (CH 4 ) and ethane (C 2 H 6 ) can be used to identify and separate methane sources, as ethane is present in thermogenic sources (e.g., oil and natural gas) but not in biogenic sources (e.g., agriculture). In this study, we evaluated the performance of multiple Aeris MIRA Ultra instruments (Versions 1 and 2) through controlled laboratory tests and tower-based deployments under field conditions. The systems were modified with an external pump, flow control, a Nafion dryer, and a custom-built auxiliary box to automate the system and transmit near real-time data. We determined the best calibration approach for our application, given practical limitations, to be a full calibration cycle (with ambient and high calibration cylinders) about once per day and an ambient calibration cylinder sampled hourly. Measurement uncertainty was assessed, including the uncertainty due to instrument noise as a function of calibration frequency, uncertainty in the water vapor correction, and cylinder assignment uncertainty. Instrument noise was the dominant source of uncertainty for C 2 H 6 , while the water vapor correction dominated the CH 4 uncertainty. For Version 2 systems with hourly calibrations and a Nafion dryer with counterflow, the mean total uncertainty, including both systematic errors and noise, of hourly averages was 0.8–3.0 ppb CH 4 and 0.35–0.37 ppb C 2 H 6 . Laboratory intercomparisons showed network compatibility within 1.2 ppb CH 4 and 0.23 ppb C 2 H6, and a collocated deployment with a NOAA Picarro system agreed within 1.8 ppb CH 4 . Instrument noise varied substantially amongst the instruments, with errors reaching up to 11 ppb CH 4 and 2 ppb C 2 H 6 for hourly means, with similar variability indicated in a 50 h cylinder test. With appropriate engineering and calibration, the Aeris MIRA Ultra has the potential to distinguish regional methane emission sources in many field settings.

03 NATURAL GAS↗

Moving beyond post hoc explainable artificial intelligence: a perspective paper on lessons learned from dynamical climate modeling

AI models are criticized as being black boxes, potentially subjecting climate science to greater uncertainty. Explainable artificial intelligence (XAI) has been proposed to probe AI models and increase trust. In this review and perspective paper, we suggest that, in addition to using XAI methods, AI researchers in climate science can learn from past successes in the development of physics-based dynamical climate models. Dynamical models are complex but have gained trust because their successes and failures can sometimes be attributed to specific components or sub-models, such as when model bias is explained by pointing to a particular parameterization. We propose three types of understanding as a basis to evaluate trust in dynamical and AI models alike: (1) instrumental understanding, which is obtained when a model has passed a functional test; (2) statistical understanding, obtained when researchers can make sense of the modeling results using statistical techniques to identify input–output relationships; and (3) component-level understanding, which refers to modelers' ability to point to specific model components or parts in the model architecture as the culprit for erratic model behaviors or as the crucial reason why the model functions well. We demonstrate how component-level understanding has been sought and achieved via climate model intercomparison projects over the past several decades. Such component-level understanding routinely leads to model improvements and may also serve as a template for thinking about AI-driven climate science. Currently, XAI methods can help explain the behaviors of AI models by focusing on the mapping between input and output, thereby increasing the statistical understanding of AI models. Yet, to further increase our understanding of AI models, we will have to build AI models that have interpretable components amenable to component-level understanding. We give recent examples from the AI climate science literature to highlight some recent, albeit limited, successes in achieving component-level understanding and thereby explaining model behavior. The merit of such interpretable AI models is that they serve as a stronger basis for trust in climate modeling and, by extension, downstream uses of climate model data.

54 ENVIRONMENTAL SCIENCES↗

ADEPT: A Pedagogical Framework for Integrating Agentic AI with Deterministic Scientific Workflows

The integration of Large Language Models (LLMs) into scientific research promises to accelerate discovery, yet a significant gap remains between the dynamic reasoning of Artificial Intelligence (AI) agents and the static, deterministic nature of canonical scientific workflows. This paper introduces ADEPT (Agentic Discovery and Exploration Platform for Tools), a reference architecture and pedagogical framework explicitly designed to bridge this gap. ADEPT's primary mission is to provide a transparent, "glass-box" environment where researchers and engineers can learn to effectively wrap established scientific software (e.g., BLAST, Nextflow pipelines) and compose it into reliable, agent-driven workflows. We describe its modular, multi-server architecture, which leverages the Model Context Protocol (MCP) for tool serving, LangGraph for robust agentic orchestration, and a secure nsjail-based sandbox for safe code execution. By prioritizing architectural clarity, safety, and modularity, ADEPT serves as an extensible blueprint for building trustworthy AI-augmented systems and fosters the collaborative development necessary to responsibly employ agentic AI for science. We provide practical examples of how to adapt and extend this framework, highlighting its utility in workforce development and AI-readiness capabilities across research and development projects.

97 MATHEMATICS AND COMPUTING↗

Edge ML for CAN bus intrusion detection in AVs

Autonomous Vehicles (AVs) are revolutionizing transportation, but their reliance on interconnected cyber-physical systems exposes them to unprecedented cybersecurity risks. This study addresses the critical challenge of detecting real-time cyber intrusions in self-driving vehicles by leveraging a dataset from the Udacity self-driving car project. We simulate four high-impact attack vectors, Denial of Service (DoS), spoofing, replay, and fuzzy attacks, by injecting noise into spatial features (e.g., bounding box coordinates) to replicate adversarial scenarios. We develop and evaluate two lightweight neural network architectures (NN-1 and NN-2) alongside a logistic regression baseline (LG-1) for intrusion detection. The models achieve exceptional performance, with NN-2 attaining an AUC score of 93.15% and 93.15% accuracy, demonstrating their suitability for edge deployment in AV environments. Through explainable AI techniques, we uncover unique forensic fingerprints of each attack type, such as spatial corruption in fuzzy attacks and temporal anomalies in replay attacks, offering actionable insights for feature engineering and proactive defense. Visual analytics, including confusion matrices, ROC curves, and feature importance plots, validate the models' robustness and interpretability. This research sets a new benchmark for AV cybersecurity, delivering a scalable, field-ready toolkit for Original Equipment Manufacturers (OEMs) and policymakers. By aligning intrusion fingerprints with SAE J3061 automotive security standards, we provide a pathway for integrating machine learning into safety-critical AV systems. Our findings underscore the urgent need for security-by-design AI, ensuring that AVs not only drive autonomously but also defend autonomously. This work bridges the gap between theoretical cybersecurity and life-preserving engineering, offering a leap toward safer, more secure autonomous transportation.

97 MATHEMATICS AND COMPUTING↗

Warm boundary-layer cloud properties and cloud susceptibilities product at the ARM ENA observatory

Cloud liquid water path, albedo, and cloud fraction susceptibilities for marine warm boundary-layer clouds are quantified using the Meteosat retrieved cloud microphysical properties at the ARM Eastern North Atlantic (ENA) observatory in the Azores. The Meteosat cloud retrievals are based on the methods applied by the Clouds and the Earth’s Radiant Energy System (CERES) project, which are specifically tailored to support the ARM user facility over the ARM ground-based observation sites (enavisstpx2dm11minnisX1.c1). Cloud susceptibility is quantified as the slope between cloud properties and Nd within a 1-degree-by-1-degree grid box at each satellite time step using a least-square regression. To reduce uncertainties associated with the adiabatic assumption in the Nd retrieval, for each cloud object, we exclude cloudy pixels at the cloud edge, defined as those adjacent to cloud-free pixels. To minimize influence of cloud heterogeneity and co-variability on the retrieved cloud susceptibility, cloud properties are averaged to 0.25-degree resolution using the 3-km pixel-level retrieval, and the 1-degree cloud susceptibilities are estimated using the smoothed data. Cloud type classification is applied to distinct cloud object, labeling all contiguous cloudy pixels. Marine warm boundary-layer clouds are defined as clouds with 90% of cloud tops below 3km, and Meteosat retrieved cloud phase as liquid.

54 ENVIRONMENTAL SCIENCES↗