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Miniature instrumentation for laser light scattering experiments

Traditional optical systems for photon correlation spectroscopy and laser anemometry have relied upon physically large and fairly expensive lasers, bulk-optics such as lenses of a few inches diameter, large mechanical mounts and carefully selected, fragile and bulky photon counting photomultiplier detectors. In some cases, experimental fluid dynamics at a desired position in a flow, perhaps deep inside complex machinery, is physically impossible or very difficult. Similar problems exist with photon correlation spectroscopy, e.g., remote and heterodyne experiments. Various optical and electro optical components were investigated and characterized with the aim of replacing existing photon correlation laser spectroscopy and anemometry techniques in miniaturized form, and with significant cost reduction. Very recently, a range of miniature, modular light scattering systems were constructed from little solid state optical and electro optical components, and experimentally verified measurement performance comparable to standard lab photon correlation spectroscopy and laser anemometry equipment.

Brown, Robert G. W.↗

Voyager observations of the interstellar medium in the 500- to 1700-A spectral region

Observations of the interstellar medium have been obtained in the 500-1700-A spectral region by the ultraviolet spectrometers installed on the Voyager spacecraft. A preliminary analysis of the least complex of the spectra obtained to date indicates measurable emission in spectral lines at 584, 1026, and 1216 A. These emissions are identified with resonance scattering of solar radiation in transitions of helium and atomic hydrogen. The observations in the direction alpha 324 deg, delta-23 deg contain no measurable direct emission or scattering of stellar radiation by the interstellar medium to an upper limit of 0.0005 R/A at 975 A. Spectra obtained in other directions indicate measurable sources of apparent continua having relatively broad spatial extent.

Shemansky, D. E.↗

Stardust: Studies in microgravity of condensation and agglomeration of cosmic dust analogue

A short description of the program Stardust whose goal is to study the formation and properties of high temperature particles and gases, including silicate and carbonaceous materials, that are of interest in astrophysics and planetary science, is given. The international program was carried out in microgravity conditions in parabolic flight. A description of the laboratory equipment, conceived to perform experimental tests in reduced gravity conditions, and which is based on the gas evaporation technique, is given. The gas evaporation technique utilizes one or more heated crucible to vaporize solids materials (SiO, Mg) in a low pressure of inert or reactive gas inside of a vacuum bell jar. The vapor pressures of the materials are controlled by the temperature of the crucibles. The temperature and pressure of inert gas are also controlled. By varying the vapor pressure relative to the gas temperature and pressure, the conditions for substantial grain condensation can be controlled and grain formation measured using light scattering techniques. Thus the partial pressure for grain condensation, can be measured as a function of temperature. The gas evaporation technique has the advantage that complex chemical systems can be studied by using multiple crucibles each containing solid source material. Experimental results and future trends are addressed.

Ferguson, F.↗

Review of Skin Friction Measurements Including Recent High-Reynolds Number Results from NASA Langley NTF

This paper reviews flat plate skin friction data from early correlations of drag on plates in water to measurements in the cryogenic environment of The NASA Langley National Transonic Facility (NTF) in late 1996. The flat plate (zero pressure gradient with negligible surface curvature) incompressible skin friction at high Reynolds numbers is emphasized in this paper, due to its importance in assessing the accuracy of measurements, and as being important to the aerodynamics of large scale vehicles. A correlation of zero pressure gradient skin friction data minimizing extraneous effects between tests is often used as the first step in the calculation of skin friction in complex flows. Early data compiled by Schoenherr for a range of momentum thickness Reynolds numbers, R(sub Theta) from 860 to 370,000 contained large scatter, but has proved surprisingly accurate in its correlated form. Subsequent measurements in wind tunnels under more carefully controlled conditions have provided inputs to this database, usually to a maximum R(sub Theta) of about 40,000. Data on a large axisymmetric model in the NASA Langley National Transonic Facility extends the upper limit in incompressible R(sub Theta) to 619,800 using the van Driest transformation. Previous data, test techniques, and error sources ar discussed, and the NTF data will be discussed in detail. The NTF Preston tube and Clauser inferred data accuracy is estimated to be within -2 percent of a power-law curve fit, and falls above the Spalding theory by 1 percent at R(sub Theta) of about 600,000.

Watson, Ralph D.↗

Computer Code for Nanostructure Simulation

Due to their small size, nanostructures can have stress and thermal gradients that are larger than any macroscopic analogue. These gradients can lead to specific regions that are susceptible to failure via processes such as plastic deformation by dislocation emission, chemical debonding, and interfacial alloying. A program has been developed that rigorously simulates and predicts optoelectronic properties of nanostructures of virtually any geometrical complexity and material composition. It can be used in simulations of energy level structure, wave functions, density of states of spatially configured phonon-coupled electrons, excitons in quantum dots, quantum rings, quantum ring complexes, and more. The code can be used to calculate stress distributions and thermal transport properties for a variety of nanostructures and interfaces, transport and scattering at nanoscale interfaces and surfaces under various stress states, and alloy compositional gradients. The code allows users to perform modeling of charge transport processes through quantum-dot (QD) arrays as functions of inter-dot distance, array order versus disorder, QD orientation, shape, size, and chemical composition for applications in photovoltaics and physical properties of QD-based biochemical sensors. The code can be used to study the hot exciton formation/relation dynamics in arrays of QDs of different shapes and sizes at different temperatures. It also can be used to understand the relation among the deposition parameters and inherent stresses, strain deformation, heat flow, and failure of nanostructures.

Filikhin, Igor↗

The effect of dissipative inhomogeneous medium on the statistics of the wave intensity

One of the main theoretical points in the theory of wave propagation in random medium is the derivation of closed form equations to describe the statistics of the propagating waves. In particular, in one dimensional problems, the closed form representation of the multiple scattering effects is important since it contributes in understanding such problems like wave localization, backscattering enhancement, and intensity fluctuations. In this the propagation of plane waves in a layer of one-dimensional dissipative random medium is considered. The medium is modeled by a complex permittivity whose real part is a constant representing the absorption. The one dimensional problem is mathematically equivalent to the analysis of a transmission line with randomly perturbed distributed parameters and a single mode lossy waveguide and the results can be used to study the propagation of radio waves through atmosphere and the remote sensing of geophysical media. It is assumed the scattering medium consists of an ensemble of one-dimensional point scatterers randomly positioned in a layer of thickness L with diffuse boundaries. A Poisson impulse process with density lambda is used to model the position of scatterers in the medium. By employing the Markov properties of this process an exact closed form equation of Kolmogorov-Feller type was obtained for the probability density of the reflection coefficient. This equation was solved by combining two limiting cases: (1) when the density of scatterers is small; and (2) when the medium is weakly dissipative. A two variable perturbation method for small lambda was used to obtain solutions valid for thick layers. These solutions are then asymptotically evaluated for small dissipation. To show the effect of dissipation, the mean and fluctuations of the reflected power are obtained. The results were compared with a lossy homogeneous medium and with a lossless inhomogeneous medium and the regions where the effect of absorption is not essential were discussed.

Saatchi, Sasan S.↗

Complex refractive index of Martian dust - Mariner 9 ultraviolet observations

Mariner 9 ultraviolet spectrometer observations of the 1971 dust clouds obscuring the surface of Mars have been analyzed by matching the observed dust phase function with Mie scattering calculations for size distributions of homogeneous and isotropic material. Preliminary results indicate an effective particle radius of not less than 0.2. The real component of the index of refraction is not less than 1.8 at both 268 and 305 nm; corresponding values for the imagery component are 0.02 and 0.01. These values are consistent with those found by Mead (1970) for the visible and near-visible wavelengths. The refractive index and the absorption coefficient increase rapidly with decreasing wavelength in going from the visible to the ultraviolet, indicating the presence of an ultraviolet absorption band which may shield organisms from ultraviolet irradiation.

Pang, K.↗

Complex refractive index of Martian dust - Wavelength dependence and composition

The size distribution and complex refractive index of Martian dust-cloud particles observed in 1971 with the Mariner 9 UV spectrometer are determined by matching the observed single-scattering albedo and phase function with Mie-scattering calculations for size distributions of spheres. Values of phase function times single-scattering albedo are presented for 12 wavelength intervals in the range from 190 to 350 nm, and best-fit values are obtained for the absorption index. It is found that the absorption index of the dust particles increases with decreasing wavelength from 350 to about 210 nm and then drops off shortward of 210 nm, with a structural shoulder occurring in the absorption spectrum between 240 and 250 nm. A search for a candidate material that can explain the strong UV absorption yields TiO2, whose anatase polymorph has an absorption spectrum matching that of the Martian dust. The TiO2 content of the dust particles is estimated to be a few percent or less.

Pang, K.↗

Bidirectional Spectral Reflectance of Earth Resources: Influence of Scene Complexity and Atmospheric Effects on Remote Sensing

Practical methods for remote sensing when scene complexity and atmospheric effects modify intrinsic reflective properties are developed. The radiation history from ground to space of light reflected from individual leaves is initially multiply scattered within the crop canopy, whose geometry provides a controlling influence, then scattered and attenuated as a result of transmission through the Earth's atmosphere. The experimental and theoretical tools for studying these effects quantitatively are under development. A new radiative transfer code which uses Fourier transforms to solve the 3-D equation of transfer was developed. The initial version permits inhomogeneous non-Lambertian surfaces but assumes horizontal uniformity for the atmosphere. The computational results are in excellent agreement with Monte Carlo calculations. Laboratory apparatus to study the variation of spectral reflectance of individual leaves as a function of illumination incidence angle and reflection angle was used. These data can then be used in models to determine canopy scattering effects. Stress tests by observing leaf reflectance at 0.9 microns as a function of time following clipping from the stem was performed. A reflectance increase due to loss of water has been observed.

Diner, D. J.↗

Microscopic optical potential analyses of carbon-carbon elastic scattering

Utilizing eikonal phase shifts determined from a microscopic double-folding optical potential, marked improvement in the agreement between theory and experiment, for elastic carbon-carbon scattering between 200 and 300 MeV, is obtained when only those values for the nucleon-nucleon slope parameter, appropriate for diffractive scattering, are used. The appropriateness of the perturbative eikonal expansion is discussed by comparison with recent results, obtained for the same potentials, using a more exact complex Wentzell-Kramers-Brillouin (WKB) formalism.

Bidasaria, H. B.↗

Dust Optical Properties derived from Sun/Sky Measurements and Satellite Data

We derive the optical properties of dust originating from the Sahara and nearby regions using a combination of ground based and satellite measurements. The AErosol ROBotic NETwork (AERONET) sun/sky radiances from Cap Verde and Sede Boker are used together with Landsat TM data over Senegal and the Atlantic Ocean. The data introduce a cascade of increasing complexity of dust optical properties: The sky aureole radiance is sensitive mainly to the dust size distribution; the TM data over the ocean at 150 deg scattering angle are also sensitive to the spectral refractive index from 470 to 2,210 nm. The TM data over the land measure the balance between the dust scattering and absorption of light reflected by the bright surface, thus very sensitive to dust spectral absorption. Sky radiance at scattering angle of 120 deg, add sensitivity to the dust nonsphericity. Preliminary results, indicative of the ambient dust in the entire atmospheric column, show that dust is less absorbing and with smaller nonspherical properties than anticipated from in situ measurements. Dust is dominated by particles with effective radius of 2 to 2.5 micron, refractive index for wavelengths less then 1 micron of 1.53-0.001i and nonsphericity that increases the phase function at 120 deg above that of spheres by 1.8 and 1.7 at 673 nm down to 1.2 and 1.3 for 1020 nm for Cap Verde and Sede Boker respectively. No significant nonsphericity effect is noticed for scattering angle of 150 deg. This agrees with a mixture of 30% and 45% respectively of Mishchenko et al (JGR, 102, 1997: plate 5 on page 16,841) "polydisperse equiprobable shape mixture of prolate and oblate spheroids with aspect ratios ranging from 1.4 to 2.21, with the rest being spherical particles.

Kaufman, Yoram J.↗

Compton Gamma Ray Observatory Guest Investigator Program

This paper presents a final report for the Compton Gamma Ray Observatory Guest Investigator Program from 06/01/91-07/31/97. The topics include: 1) Solar Flare Neutron Spectra and Accelerated Ions; 2) Gamma Ray Lines From The Orion Complex; 3) Implications of Nuclear Line Emission From The Orion Complex; 4) Possible Sites of Nuclear Line Emission From Massive OB Associations; 5) Gamma-Ray Burst Repitition and BATSE Position Uncertainties; 6) Effects of Compton Scattering on BATSE Gamma-Ray Burst Spectra; and 7) Selection Biases on the Spectral and Temporal Distribution of Gamma Ray Bursts.

Lingenfelter, Richard E.↗

Key Differences in Operating a Rover on the Moon vs. Mars

The command and control model for spacecraft operations, as well as the distribution of tasks between ground assets and in space assets, whether with a crew or solely robotic, is fundamentally constrained by the round trip light time between the space asset and the control facility (presumably on Earth, though not required). For an asset on Mars, the round trip light time varies, from roughly fourteen minutes to up to forty minutes. For a Lunar asset the round-trip light time is measured in only a few seconds, but current communications systems may more than double the latency with system overhead. For a Lunar Asset the total command latency may range from six seconds to more than forty, depending on communications overhead and data rates. Further, these variables are not always predictable, thus complicating operations. There are several differentiating factors for Lunar vs. Mars operations, Round trip light time/Atmosphere/Lighting and ShadowsTerrain type and knowledge/Round trip light time has implications for the distribution of tasks between ground and in space assets. Even at Lunar Distances, the combination of round trip light time plus communications systems overhead does not enable joy stick driving of a rover. The best that can be done, if driving from Earth, is near real time command and control. By 2030, driving from in space may be possible. Productivity on Mars requires either long operational sequences of commands, as is done for current rovers such as Curiosity, significant autonomous capability or, as may be possible by 2030, command and control support from space. Another implication of the long round trip light time from Earth to Mars, is that flight software functions must be resident on the in space asset. On the Moon, there is considerably more flexibility, enabling processing functions, to be resident on Earth or in space. This provides the opportunity to take advantage of the considerable processing power available on the ground, but may be constrained by data rates. On the Moon, for practical operational purposes, there is no atmosphere. Hence there is no scattering of light in the shadows. This has implications for image interpretation and driving near the poles. The Moon has permanently shadowed regions (PSR), unique terrain with unknown surface properties. With no scattering of light in shadows, driving on the Moon, particularly at the poles, where we have strong evidence of water, may prove to be hazardous and complex, requiring non-optical sensors, such as LIDAR.

Trimble, Jay↗

PIV and Rotational Raman-Based Temperature Measurements for CFD Validation of a Perforated Plate Cooling Flow: Part 1

Film cooling is used in a wide variety of engineering applications for protection of surfaces from hot or combusting gases. The design of more efficient film cooling geometries/configurations could be facilitated by an ability to accurately model and predict the effectiveness of current designs using computational fluid dynamics (CFD) code predictions. Hence, a benchmark set of flow field property data were obtained for use in assessing current CFD capabilities and for development of better modeling approaches for these turbulent flow fields where accurate calculation of turbulent heat flux is important. Both Particle Image Velocimetry (PIV) and spontaneous rotational Raman scattering (SRS) spectroscopy were used to acquire high quality, spatially-resolved measurements of the mean velocity, turbulence intensity as well as the mean temperature and root mean square (rms) temperatures in a film cooling flow field. In addition to off-body flow field measurements, infrared thermography (IR) and thermocouple measurements on the plate surface enabled estimates of the film effectiveness. Raman spectra in air were obtained across a matrix of axial locations downstream from a 68.07 mm square nozzle blowing heated air over a range of temperatures (up to TR = 2.7) and Mach numbers (up to M0.9), across a 30.48 cm long plate equipped with three patches of 45 small (~1 mm) diameter cooling holes arranged in a staggered configuration. In addition, both centerline streamwise 2-component PIV and cross-stream 3-component Stereo PIV data at 14 axial stations were collected in the same flows. Only a subset of the data collected in the test program is included in this Part I report and are available from the NASA STI office. The final portion of the data will be published in a future report, Part II, along with CFD predictions of the complex cooling film flow.

Raman Scattering↗

Time-dependent treatment of scattering - Integral equation approaches using the time-dependent amplitude density

The time-dependent form of the Lippmann-Schwinger integral equation is used as the basis of several new wave packet propagation schemes. These can be formulated in terms of either the time-dependent wave function or a time-dependent amplitude density. The latter is nonzero only in the region of configuratiaon space for which the potential is nonzero, thereby in principle obviating the necessity of large grids or the use of complex absorbing potentials when resonances cause long collision times (leading, consequently, to long propagation times). Transition amplitudes are obtained in terms of Fourier transforms of the amplitude density from the time to the energy domain. The approach is illustrated by an application to a standard potential scattering model problem where, as in previous studies, the action of the kinetic energy operator is evaluated by fast Fourier transform (FFT) techniques.

Hoffman, David K.↗

Near-Field Spectroscopy with Nanoparticles Deposited by AFM

An alternative approach to apertureless near-field optical spectroscopy involving an atomic-force microscope (AFM) entails less complexity of equipment than does a prior approach. The alternative approach has been demonstrated to be applicable to apertureless near-field optical spectroscopy of the type using an AFM and surface enhanced Raman scattering (SERS), and is expected to be equally applicable in cases in which infrared or fluorescence spectroscopy is used. Apertureless near-field optical spectroscopy is a means of performing spatially resolved analyses of chemical compositions of surface regions of nanostructured materials. In apertureless near-field spectroscopy, it is common practice to utilize nanostructured probe tips or nanoparticles (usually of gold) having shapes and dimensions chosen to exploit plasmon resonances so as to increase spectroscopic-signal strengths. To implement the particular prior approach to which the present approach is an alternative, it is necessary to integrate a Raman spectrometer with an AFM and to utilize a special SERS-active probe tip. The resulting instrumentation system is complex, and the tasks of designing and constructing the system and using the system to acquire spectro-chemical information from nanometer-scale regions on a surface are correspondingly demanding.

Anderson, Mark S.↗

D-Wave Resonances in Positronium Hydride

The problem of calculating the position and width of the lowest-lying (L = 0, 1) resonances in the Ps + H scattering system has recently been re-examined by the authors [1]. In the model used, resonances axe assumed generated by bound Rydberg states in the closed re-arranged channel [e(+) + H(-)]. This infinite series of Coulomb bound states are shifted somewhat by the coupling with the open scattering channel [Ps + H]. Estimates using this approach, first carried out by one of the authors [2] using a simple form of scattering wavefunction, indicated an anticipated small shift of resonance away from the Rydberg energy in the S-wave (L = 0). More recent results by Ho and Yan [3] using the complex-rotation method showed unexpected significant shifting in the P (L = 1) and D (L = 2)-wave resonance energies from their respective unperturbed values. Our re-calculation of the resonances [I I for L = 0 and I indicates that, in each case, reasonably consistent resonance energies are obtained by coupling the two lowest lying states (IS and 2S for L = 0 and 2P and 3P for L = 1). For each L it is the higher state (2S and 3P, respectively) that produces the resonance. The lower state (1S and 2P, respectively) is effective only in increasing the non-resonant phase shift. In this work we extend the model to L = 2 (D-waves). Our results show that, unlike the S and P-waves, the 313-state alone produces a resonant energy that is very close to the result of Yan and Ho [3]. Inclusion of the 4D-state produces a second resonance in the scattering system shifted up slightly from its unperturbed Rydberg energy.

Drachman, Richard J.↗

Interferometry of Cyg A and Cas A - Source noise at 327 MHz

Interferometric observations of Cyg A and Cas A at 327 MHz confirm predictions for the characteristics of noise in synthesis images of very bright sources. On a single baseline, the noise variances of the real and imaginary components of the complex visibility are not equal. The noise in an image is larger for positions on-source than off-source. The on-source noise is scattered into the off-source region by the sidelobes of the synthesized beam. Part of this contribution to the off-source noise can be removed by judicious deconvolution.

Mccullough, Peter R.↗