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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1987

Thermal-infrared spectral observations of geologic materials in emission

The thermal-infrared spectra of geologic materials in emission were studied using the prototype Thermal Emission Spectrometer (TES). A variety of of processes and surface modifications that may influence or alter the spectra of primary rock materials were studied. It was confirmed that thermal emission spectra contain the same absorption features as those observed in transmission and reflection spectra. It was confirmed that the TES instrument can be used to obtain relevant spectra for analysis of rock and mineral composition.

Christensen, Philip R.↗
NASA NTRS1993

Application of a two-stream radiative transfer model for leaf lignin and cellulose concentrations from spectral reflectance measurements, part 1

Lignin and nitrogen contents of leaves constitute the primary rate-limiting parameters for the decomposition of forest litter, and are determinants of nutrient- and carbon-cyclic rates in forest ecosystems (Melillo et al., 1982). Wessman et al. (1988a) developed empirical multivariate relationships between forest canopy lignin amount and the (first-difference) AIS spectral response in three bands spread over the wavelength interval 1256-1555 nm. Wessman et al. (1988b) and McLellan et al. (1991) developed similar regression relationships from laboratory reflectance measurements on dried samples prepared in a standard fashion. They used four to six infrared bands for analysis of nitrogen, lignin and cellulose content of foliage in forest and prairie species. In the present article (Parts 1 and 2) the feasibility of compositional determinations is explored using positions of composite absorption bands that originate from mixtures of lignin, cellulose, and possibly other chemical constituents in the spectral reflectance of green leaves. To carry out this program, we employ full-spectral-resolution single-leaf diffuse reflectance measurements made with a laboratory spectrometer and integrating sphere. The leaf and other chemical reflectance data compiled by Elvidge (1990) have also been utilized extensively.

Conel, James E.↗
NASA NTRS2022

Mapping Phyllosilicates on the Asteroid Bennu Using Thermal Emission Spectra and Machine Learning Model Applications

Bennu, the target of the OSIRIS-REx mission, is an asteroid with compositions analogous to low petrologic type CI, CM, CR, and/or ungrouped carbonaceous chondrites. Asteroids like Bennu provide information about the building blocks of the early Solar System. Analysis of the mid-infrared remote sensing data informs mineral quantification. We apply a phyllosilicate specific model, developed by Breitenfeld et al. (2021) that distinguishes between Mg and Fe serpentines, to Baseball Diamond 1 (BBD1), Equatorial Station 3 (EQ3), and Touch-And-Go OSIRIS-REx Thermal Emission Spectrometer data. The average total phyllosilicate predictions are 73 (BBD1) and 72 vol% (EQ3). We observe higher Fe-cronstedtite and lower Mg-rich serpentine content in the equatorial region of Bennu than average. Mid-infrared spectral variability may be explained by sorting effects through mass movement.

Bennu↗
NASA NTRS1981

Concurrent radio, infrared, optical and X-ray observations of the nucleus of the Seyfert galaxy NGC 4151

The nucleus of the Seyfert galaxy NGC 4151 was observed during May and June 1977 at X-ray energies from 20 to 200 keV using the high-energy X-ray spectrometer on OSO 8 at radio frequencies of 2695 and 8085. Data were also taken in the visual, and at infrared wavelengths of 1 to 2 microns, and from 2 to 6 keV using the OSO 8 proportional counter. Optical data showed variability by a factor of 2 within the observing period, which is comparable to the variability in the 2 to 6 keV X-ray flux. No variability, however, was measured at infrared or radio frequencies. The composite spectrum from radio to gamma-ray is plotted, and it is found that the optical and X-ray fluxes varied during the observing period, although it is not known if they varied concurrently.

Beall, J. H.↗
NASA NTRS2014

First Results from the Mojave Volatiles Prospector (MVP) Field Campaign, a Lunar Polar Rover Mission Analog

The Mojave Volatiles Prospector (MVP) project is a science-driven field program with the goal to produce critical knowledge for conducting robotic exploration of the Moon. MVP will feed science, payload, and operational lessons learned to the development of a real-time, short-duration lunar polar volatiles prospecting mission. MVP achieves these goals through a simulated lunar rover mission to investigate the composition and distribution of surface and subsurface volatiles in a natural and a priori unknown environment within the Mojave Desert, improving our understanding of how to find, characterize, and access volatiles on the Moon. The MVP field site is the Mojave Desert, selected for its low, naturally occurring water abundance. The Mojave typically has on the order of 2-6% water, making it a suitable lunar analog for this field test. MVP uses the Near Infrared and Visible Spectrometer Subsystem (NIRVSS), Neutron Spectrometer Subsystem (NSS), and a downward facing GroundCam camera on the KREX-2 rover to investigate the relationship between the distribution of volatiles and soil crust variation. Through this investigation, we mature robotic in situ instruments and concepts of instrument operations, improve ground software tools for real time science, and carry out publishable research on the water cycle and its connection to geomorphology and mineralogy in desert environments. A lunar polar rover mission is unlike prior space missions and requires a new concept of operations. The rover must navigate 3-5 km of terrain and examine multiple sites in in just ~6 days. Operational decisions must be made in real time, requiring constant situational awareness, data analysis and rapid turnaround decision support tools. This presentation will focus on the first science results and operational architecture findings from the MVP field deployment relevant to a lunar polar rover mission.

Heldmann, Jennifer L.↗
NASA NTRSDate not supplied

Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE)

The mid-infrared (MIR) spectral range (3-5 μm) is of particular interest for remotely sensing gaseous molecules such as H2O, CO2, CH4, N2O, CO, NH3, and other compounds. The infrared spectra of planets, moons, comets, and asteroids are rich in information, including gas composition and surface mineralogy. Significant advances in technology have emerged for ground-based telescopes, including the higher spectral resolution permitted by cross-dispersed instruments and heterodyne techniques. New technologies offer the opportunity to break this barrier, by using solid- state photonics. In the past three years, under the NASA ROSES PICASSO program, we have been developing key components for a revolutionary MIR spectrometer: Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE), which is based on integrated photonics technology that offers ultra-small size, weight, and power (SWaP) with non-moving parts and low cost for future planetary missions. In this paper, we will describe our science and technology development progress leading to demonstrating the concept and functionalities of the PICTURE instrument. The photonic integrated circuit spectrometer (PICS) of the PICTURE instrument uses an integrated heterodyne detection scheme to significantly reduce SWaP and improve sensitivity. Our program goals are to advance the building blocks needed for the PICS, which include arrayed waveguide gratings (AWGs), quantum cascade lasers (QCLs) as local oscillators, and quantum cascade detectors (QCDs) as heterodyne detectors. In addition, we are leveraging a NASA SBIR program to develop the toolsets needed to fabricate MIR photonics lanterns (PL). The PL is a critical component that enables PICTURE to bring a signal from the collecting telescope to the PICS, which requires single optical mode inputs. PICTURE focuses on the CO spectral band at 4.6-4.8 μm that is of key importance to cometary science. We also continue to explore future instrument concepts that exploit the broad wavelength potential of the PICS design to perform spectroscopy spanning the full MIR and longwave IR (LWIR) bands. This will have wide applicability in planetary science, for example, to probe the strongest CO2, H2O, and CH4 transitions that are difficult (CH4) or impossible (CO2, H2O) to detect using Earth-based telescopes due to atmospheric opacity. Each integrated-photonics-spectrometer chip will feature a single heterodyne room-temperature laser with a wide wavelength tuning range, or multiple local-oscillator lasers for much broader spectral coverage. The fully developed PICTURE instrument will provide a cost-effective, high-resolution spectrometer for future space applications.

Anthony W Yu↗
NASA NTRS2000

Laboratory Astrophysics Using a Spare XRS Microcalorimeter

The XRS instrument on Astro-E is a fully self-contained microcalorimeter x-ray instrument capable of acquiring optimally filtering, and characterizing events for 32 independent pixels. With the launch of the Astro-E spacecraft, a full flight spare detector system has been integrated into a laboratory cryostat for use on the electron beam ion trap (EBIT) at Lawrence Livermore National Laboratory. The detector system contains a microcalorimeter array with 32 instrumented pixels heat sunk to 60 mK using an adiabatic demagnetization refrio,erator. The instrument has a composite resolution of 8eV at 1 keV and 12eV at 6 keV with a minimum of 95% quantum efficiency. This will allow high spectral resolution, broadband observations of collisionally excited plasmas which are produced in the EBIT experiment. Unique to our instrument are exceptionally well characterized 1000 Angstrom thick aluminum on polyimide infrared blocking filters. The detailed transmission function including the edc,e fine structure of these filters has been measured in our laboratory using an erect field grating spectrometer. This will allow the instrument to perform the first broadband absolute flux measurements with the EBIT instrument. The instrument performance as well as the results of preliminary measurements will be discussed. Work performed under the auspices of the U.S. D.o.E. by Lawrence Livermore National Laboratory under contract W-7405-ENG-48 and was supported by the NASA High Energy Astrophysics Supporting Research and Technology Program.

Audley, M. Damian↗
NASA NTRS2005

Mercury: First Spectra from 8 to 25 Microns Using MIRSI

Spectral measurements from 8 to 25 microns of Mercury's surface were taken using MIRSI (Mid-InfraRed Spectrometer and Imager) mounted on the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii [1]. Few spectral observations of Mercury have been made between 8 and 14 m and these are the first to be made between 17 and 25 m. The goal for these observations is to measure the emission from Mercury in the Restrahllen Bands in the 8 to 25 micron region in an effort to identify spectral features that may give clues to Mercury s composition. These observations will be compared to previous observations [2] [3] [4], and future observations made with instrumentation on Messenger at other spectral regions [5]. Spectra from the Moon were also obtained with the same instrumentation and telescope during the same observing periods.

Hanna, K. L. Donaldson↗
NASA NTRSDate not supplied

Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE)

The mid-infrared (MIR) spectral range (3-5 μm) is of particular interest for remotely sensing gaseous molecules such as H2O, CO2, CH4, N2O, CO, NH3, and other compounds. The infrared spectra of planets, moons, comets, and asteroids are rich in information, including gas composition and surface mineralogy. Significant advances in technology have emerged for ground-based telescopes, including the higher spectral resolution permitted by cross-dispersed instruments and heterodyne techniques. New technologies offer the opportunity to break this barrier, by using solid-state photonics. In the past three years, under the NASA ROSES PICASSO program, we have been developing key components for a revolutionary MIR spectrometer: Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE), which is based on integrated photonics technology that offers ultra-small size, weight, and power (SWaP) with non-moving parts and low cost for future planetary missions. In this paper, we will describe our science and technology development progress leading to demonstrating the concept and functionalities of the PICTURE instrument. The photonic integrated circuit spectrometer (PICS) of the PICTURE instrument uses an integrated heterodyne detection scheme to significantly reduce SWaP and improve sensitivity. Our program goals are to advance the building blocks needed for the PICS, which include arrayed waveguide gratings (AWGs), quantum cascade lasers (QCLs) as local oscillators, and quantum cascade detectors (QCDs) as heterodyne detectors. In addition, we are leveraging a NASA SBIR program to develop the toolsets needed to fabricate MIR photonics lanterns (PL). The PL is a critical component that enables PICTURE to bring a signal from the collecting telescope to the PICS, which requires single optical mode inputs. PICTURE focuses on the CO spectral band at 4.6-4.8 μm that is of key importance to cometary science. We also continue to explore future instrument concepts that exploit the broad wavelength potential of the PICS design to perform spectroscopy spanning the full MIR and longwave IR (LWIR) bands. This will have wide applicability in planetary science, for example, to probe the strongest CO2, H2O, and CH4 transitions that are difficult (CH4) or impossible (CO2, H2O) to detect using Earth-based telescopes due to atmospheric opacity. Each integrated-photonics-spectrometer chip will feature a single heterodyne room-temperature laser with a wide wavelength tuning range, or multiple local-oscillator lasers for much broader spectral coverage. The fully developed PICTURE instrument will provide a cost-effective, high-resolution spectrometer for future space applications.

Anthony W Yu↗
NASA NTRSDate not supplied

Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE)

The mid-infrared (MIR) spectral range (3-5 μm) is of particular interest for remotely sensing gaseous molecules such as H2O, CO2, CH4, N2O, CO, NH3, and other compounds. The infrared spectra of planets, moons, comets, and asteroids are rich in information, including gas composition and surface mineralogy. Significant advances in technology have emerged for ground-based telescopes, including the higher spectral resolution permitted by cross-dispersed instruments and heterodyne techniques. New technologies offer the opportunity to break this barrier, by using solid-state photonics. In the past three years, under the NASA ROSES PICASSO program, we have been developing key components for a revolutionary MIR spectrometer: Photonic Integrated Circuit TUned for Reconnaissance and Exploration (PICTURE), which is based on integrated photonics technology that offers ultra-small size, weight, and power (SWaP) with non-moving parts and low cost for future planetary missions. In this paper, we will describe our science and technology development progress leading to demonstrating the concept and functionalities of the PICTURE instrument. The photonic integrated circuit spectrometer (PICS) of the PICTURE instrument uses an integrated heterodyne detection scheme to significantly reduce SWaP and improve sensitivity. Our program goals are to advance the building blocks needed for the PICS, which include arrayed waveguide gratings (AWGs), quantum cascade lasers (QCLs) as local oscillators, and quantum cascade detectors (QCDs) as heterodyne detectors. In addition, we are leveraging a NASA SBIR program to develop the toolsets needed to fabricate MIR photonics lanterns (PL). The PL is a critical component that enables PICTURE to bring a signal from the collecting telescope to the PICS, which requires single optical mode inputs. PICTURE focuses on the CO spectral band at 4.6-4.8 μm that is of key importance to cometary science. We also continue to explore future instrument concepts that exploit the broad wavelength potential of the PICS design to perform spectroscopy spanning the full MIR and longwave IR (LWIR) bands. This will have wide applicability in planetary science, for example, to probe the strongest CO2, H2O, and CH4 transitions that are difficult (CH4) or impossible (CO2, H2O) to detect using Earth-based telescopes due to atmospheric opacity. Each integrated-photonics-spectrometer chip will feature a single heterodyne room-temperature laser with a wide wavelength tuning range, or multiple local-oscillator lasers for much broader spectral coverage. The fully developed PICTURE instrument will provide a cost-effective, high-resolution spectrometer for future space applications.

Anthony W. Yu↗
NASA NTRS2012

NASA Tech Briefs, March 2012

The topics include: 1) Spectral Profiler Probe for In Situ Snow Grain Size and Composition Stratigraphy; 2) Portable Fourier Transform Spectroscopy for Analysis of Surface Contamination and Quality Control; 3) In Situ Geochemical Analysis and Age Dating of Rocks Using Laser Ablation-Miniature Mass Spectrometer; 4) Physics Mining of Multi-Source Data Sets; 5) Photogrammetry Tool for Forensic Analysis; 6) Connect Global Positioning System RF Module; 7) Simple Cell Balance Circuit; 8) Miniature EVA Software Defined Radio; 9) Remotely Accessible Testbed for Software Defined Radio Development; 10) System-of-Systems Technology-Portfolio-Analysis Tool; 11) VESGEN Software for Mapping and Quantification of Vascular Regulators; 12) Constructing a Database From Multiple 2D Images for Camera Pose Estimation and Robot Localization; 13) Adaption of G-TAG Software for Validating Touch and Go Asteroid Sample Return Design Methodology; 14) 3D Visualization for Phoenix Mars Lander Science Operations; 15) RxGen General Optical Model Prescription Generator; 16) Carbon Nanotube Bonding Strength Enhancement Using Metal Wicking Process; 17) Multi-Layer Far-Infrared Component Technology; 18) Germanium Lift-Off Masks for Thin Metal Film Patterning; 19) Sealing Materials for Use in Vacuum at High Temperatures; 20) Radiation Shielding System Using a Composite of Carbon Nanotubes Loaded With Electropolymers; 21) Nano Sponges for Drug Delivery and Medicinal Applications; 22) Molecular Technique to Understand Deep Microbial Diversity; 23) Methods and Compositions Based on Culturing Microorganisms in Low Sedimental Fluid Shear Conditions; 24) Secure Peer-to-Peer Networks for Scientific Information Sharing; 25) Multiplexer/Demultiplexer Loading Tool (MDMLT); 26) High-Rate Data-Capture for an Airborne Lidar System; 27) Wavefront Sensing Analysis of Grazing Incidence Optical Systems; 28) Foam-on-Tile Damage Model; 29) Instrument Package Manipulation Through the Generation and Use of an Attenuated-Fluent Gas Fold; 30) Multicolor Detectors for Ultrasensitive Long-Wave Imaging Cameras; 31) Lunar Reconnaissance Orbiter (LRO) Command and Data Handling Flight Electronics Subsystem; and 32) Electro-Optic Segment-Segment Sensors for Radio and Optical Telescopes.

Source record↗
NASA NTRS2013

Towards Calibrating the Vestan Regolith: Correlating the Petrology, Chemistry and Spectroscopy of Howardites

The Dawn spacecraft carries a visible and infrared mapping spectrometer (VIR) [1] that has acquired spectra for the wavelength range 0.25-5.0 μm at various spatial resolutions covering much of the vestan surface [2]. Through comparison of VIR spectra with laboratory spectra of howardite, eucrite and diogenite meteorites, the distribution of more diogenite-rich and more eucrite-rich terranes on Vesta have been mapped [3], but these maps are qualitative in nature. The available laboratory spectra are not well-integrated with detailed sample petrology or composition limiting their utility for lithologic mapping. Importantly, howardites are now recognized to come in two subtypes, regolithic and fragmental [4]. The former are breccias assembled in part from true regolith, while the latter have had much less exposure to the space environment. We are attempting to develop a more quantitative basis for mapping the distribution of lithologic types on Vesta through acquiring laboratory spectra on splits of howardites that have been petrologically and chemically characterized [5]. Noble gas analyses have been done on some allowing identification of those howardites that have been exposed in the true regolith of Vesta [6].

Mittlefehldt, D. W.↗
NASA NTRS2010

Discovery of Carbonate-Rich Outcrops in the Gusev Crater Columbia Hills by the MER Rover Spirit

The chemical composition, global abundance, distribution, and formation pathways of carbonates are central to understanding aqueous processes, climate, and habitability of early Mars. The Mars Exploration Rover (MER) Spirit analyzed a series of olivine-rich outcrops while descending from the summit region of Husband Hill into the Inner Basin of the Columbia Hills of Gusev Crater to the eastern edge of the El Dorado ripple field in late 2005. Reanalysis of Spirit s mineralogical data from the Moessbauer Spectrometer (MB) and the Miniature Thermal Emission Spectrometer (Mini-TES) and chemical data from the Alpha Particle X-Ray Spectrometer (APXS) in 2010, coupled with new laboratory data for carbonate-bearing samples, lead to identification of carbonate in one of the outcrops (Comanche) [Morris, R.V., et al., Science, 329, 421-424]. The carbonate is rich in magnesium and iron (Mc62Sd25Cc11Rh2, assuming all Ca and Mn is associated with the carbonate) and is a major component of the Comanche outcrops (16 to 34 wt.%). The mineralogical, chemical, and abundance data are constrained in multiple, mutually consistent ways by the MER analyses. For example, a low-Ca carbonate is required by the MB and APXS data and is consistent with Mini-TES data. Three spectral features attributable to fundamental infrared vibrational modes of low-Ca carbonate are present in the Mini-TES spectra of Comanche outcrops. The average composition of Comanche carbonate approximates the average composition of the carbonate globules in Martian meteorite ALH 84001. Analogy with ALH 84001, terrestrial, and synthetic carbonate globules suggests that Comanche carbonate precipitated from aqueous solutions under hydrothermal conditions at near neutral pH in association with volcanic activity during the Noachian era. Comanche outcrop morphology suggests they are remnants of a larger carbonate-bearing formation that evolved in ultramafic rock and then preferentially eroded by a combination of aeolian abrasion and chemical decomposition by exposure to acid-sulfate vapors/solutions. The high carbonate concentration in the Comanche outcrops supports climate models involving a CO2 greenhouse gas on a wet and warm early Mars and subsequent sequestering of at least part of that atmosphere in carbonate minerals.

Morris, Richard V.↗
NASA NTRS2010

Pyroelectric Materials for Uncooled Infrared Detectors: Processing, Properties, and Applications

Uncooled pyroelectric detectors find applications in diverse and wide areas such as industrial production; automotive; aerospace applications for satellite-borne ozone sensors assembled with an infrared spectrometer; health care; space exploration; imaging systems for ships, cars, and aircraft; and military and security surveillance systems. These detectors are the prime candidates for NASA s thermal infrared detector requirements. In this Technical Memorandum, the physical phenomena underlying the operation and advantages of pyroelectric infrared detectors is introduced. A list and applications of important ferroelectrics is given, which is a subclass of pyroelectrics. The basic concepts of processing of important pyroelectrics in various forms are described: single crystal growth, ceramic processing, polymer-composites preparation, and thin- and thick-film fabrications. The present status of materials and their characteristics and detectors figures-of-merit are presented in detail. In the end, the unique techniques demonstrated for improving/enhancing the performance of pyroelectric detectors are illustrated. Emphasis is placed on recent advances and emerging technologies such as thin-film array devices and novel single crystal sensors.

Aggarwal, M. D.↗
NASA NTRS1991

An evaluation of short-wave-infrared (SWIR) data from the AVIRIS and GEOSCAN instruments for mineralogical mapping at Cuprite, Nevada

An evaluation was performed on SWIR (2000-2400 nm) data from two airborne remote sensing systems for discriminating and identifying alteration minerals at Cuprite, Nevada. The data were acquired by the NASA Airborne Visible/InfraRed Imaging Spectrometer (AVIRIS) and the GEOSCAN Mk II multispectral scanner. The evaluation involved comparison of processed imagery and image-derived spectra with existing alteration maps and laboratory spectra of rock samples from Cuprite. Results indicate that both the AVIRIS and GEOSCAN data permit the discrimination of areas of alunite, buddingtonite, kaolinite, and silicification using color composite images formed from three SWIR bands processed with either the decorrelation stretch or a log residual algorithm. The laboratory spectral features alunite, kaolinite and buddingtonite could be seen clearly only in the log residual processed AVIRIS data. However, this does not preclude their identification with the GEOSCAN data.

Hook, Simon J.↗
NASA NTRS2019

Requirements for Portable Instrument Suites during Human Scientific Exploration of Mars

Human explorers on the surface of Mars will have access to a far wider array of scientific tools than previous crewed planetary exploration missions, but not every tool will be compatible with the restrictions of this exploration. Spectrometers on flyby, orbital, and landed missions are currently used to determine the composition and mineralogy of geological materials of various types and sizes, from small fragments to celestial bodies in the solar system. Handheld spectrometers that are capable of in situ analyses are already used for geological exploration on Earth; however, their usefulness for human exploration missions and how data from multiple handheld instruments could be combined to enhance scientific return must be further evaluated. As part of the Biologic Analog Science Associated with Lava Terrains (BASALT) research project, we incorporated two handheld instruments, a visible-near infrared spectrometer and an X-Ray Fluorescence spectrometer, into simulated Mars exploration missions conducted on basaltic terrains in Idaho and Hawai'i. To understand the data quality provided by these handheld spectrometers, we evaluated their performance under varying conditions of measurement time, distance, angle, atmosphere, and sample matrix, and we compared data quality between handheld instruments and laboratory techniques. Here, we summarize these findings, provide guidelines and requirements on how to effectively incorporate these instruments into human exploration missions to Mars, and posit that future iterations of these instruments will be beneficial for enhancing science returned from human exploration missions.

Alexander Sehlke↗
NASA NTRS2008

Near-Field Spectroscopy with Nanoparticles Deposited by AFM

An alternative approach to apertureless near-field optical spectroscopy involving an atomic-force microscope (AFM) entails less complexity of equipment than does a prior approach. The alternative approach has been demonstrated to be applicable to apertureless near-field optical spectroscopy of the type using an AFM and surface enhanced Raman scattering (SERS), and is expected to be equally applicable in cases in which infrared or fluorescence spectroscopy is used. Apertureless near-field optical spectroscopy is a means of performing spatially resolved analyses of chemical compositions of surface regions of nanostructured materials. In apertureless near-field spectroscopy, it is common practice to utilize nanostructured probe tips or nanoparticles (usually of gold) having shapes and dimensions chosen to exploit plasmon resonances so as to increase spectroscopic-signal strengths. To implement the particular prior approach to which the present approach is an alternative, it is necessary to integrate a Raman spectrometer with an AFM and to utilize a special SERS-active probe tip. The resulting instrumentation system is complex, and the tasks of designing and constructing the system and using the system to acquire spectro-chemical information from nanometer-scale regions on a surface are correspondingly demanding.

Anderson, Mark S.↗