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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

Exploring the Structural Origins of Optically Efficient One-Dimensional Lead Halide Perovskite Nanostructures

Metal halide perovskites have excellent optoelectronic properties. This study aims to determine how the optoelectronic properties of a model perovskite, cesium lead bromide (CsPbBr3), change with length and thickness in one dimension (1D). By examining the photophysics of CsPbBr3 quantum dots (QDs), nanowires (NWs), and nanorods (NRs), we observe the influence of confinement, exciton diffusion, and trapping on their optical properties. Our findings reveal that exciton diffusion to trap states limits the photoluminescence quantum yield (PLQY) of 1D CsPbBr3 in the weakly confined regime (8-14 nm) and explains their long-lived exciton dynamics, while enhanced radiative rates contribute to achieving near-unity PLQY in the strongly confined regime (<7 nm). Consequently, blue-emitting, 2.4 nm-thick CsPbBr3 NRs were 3.6X more emissive than the conventional CsPbBr3 QDs. This study underscores how structural optimization can improve the optoelectronic performance of CsPbBr3 and provides insight into the complex interplay of radiative and nonradiative processes in 1D ionic semiconductors.

Oddo, Alexander M↗

Trapped-ion quantum simulation of electron transfer models with tunable dissipation

Electron transfer is at the heart of many fundamental physical, chemical, and biochemical processes essential for life. The exact simulation of these reactions is often hindered by the large number of degrees of freedom and by the essential role of quantum effects. Here, we experimentally simulate a paradigmatic model of molecular electron transfer using a multispecies trapped-ion crystal, where the donor-acceptor gap, the electronic and vibronic couplings, and the bath relaxation dynamics can all be controlled independently. By manipulating both the ground-state and optical qubits, we observe the real-time dynamics of the spin excitation, measuring the transfer rate in several regimes of adiabaticity and relaxation dynamics. Our results provide a testing ground for increasingly rich models of molecular excitation transfer processes that are relevant for molecular electronics and light-harvesting systems.

Science & Technology - Other Topics↗

Options for Meeting Data Center Demand in Virginia: Focus on GETs and Reconductoring [Slides]

Data center demand growth in Virginia will need to met with many options - GETs and/or reconductoring have the potential to be part of the solution suite in the short-term and medium-term. Almost all GETs and reconductoring technologies have more favorable economics than transmission wires investments considering relatively low levels of existing wide-scale deployment. Deployment of GETs and/or reconductoring is not a one size fits all - requires detailed analysis. The complementary nature of GETs and/or reconductoring impacts have the potential to be synergistic (more congestion relief, more transfer capability, more cost savings - when implemented together).

24 POWER TRANSMISSION AND DISTRIBUTION↗

Strong Coupling of Hydrodynamics and Reactions in Nuclear Statistical Equilibrium for Modeling Convection in Massive Stars

We build on the simplified spectral deferred corrections (SDC) coupling of hydrodynamics and reactions to handle the case of nuclear statistical equilibrium (NSE) and electron/positron captures/decays in the cores of massive stars. Our approach blends a traditional reaction network on the grid with a tabulated NSE state from a very large, ${\mathcal O }(100)$ nuclei network. We demonstrate how to achieve second-order accuracy in the simplified-SDC framework when coupling NSE to hydrodynamics, with the ability to evolve the star on the hydrodynamics time step. We discuss the application of this method to convection in massive stars leading up to core collapse. We also show how to initialize the initial convective state from a 1D model in a self-consistent fashion. All of these developments are done in the publicly available Castro simulation code and the entire simulation methodology is fully GPU-accelerated.

Explosive nucleosynthesis↗

An assessment of ocean alkalinity enhancement using aqueous hydroxides: kinetics, efficiency, and precipitation thresholds

Abstract. Ocean alkalinity enhancement (OAE) is a promising approach to marine carbon dioxide removal (mCDR) that leverages the large surface area and carbon storage capacity of the oceans to sequester atmospheric CO2 as dissolved bicarbonate (HCO3-). One OAE method involves the conversion of salt in seawater into aqueous alkalinity (NaOH), which is returned to the ocean. The resulting increase in seawater pH and alkalinity causes a shift in dissolved inorganic carbon (DIC) speciation toward carbonate and a decrease in the surface ocean pCO2. The shift in the pCO2 results in enhanced uptake of atmospheric CO2 by the seawater due to gas exchange. In this study, we systematically test the efficiency of CO2 uptake in seawater treated with NaOH at aquarium (15 L) and tank (6000 L) scales to establish operational boundaries for safety and efficiency in advance of scaling up to field experiments. CO2 equilibration occurred on the order of weeks to months, depending on circulation, air forcing, and air bubbling conditions within the test tanks. An increase of ∼0.7–0.9 mol DIC per mol added alkalinity (in the form of NaOH) was observed through analysis of seawater bottle samples and pH sensor data, consistent with the value expected given the values of the carbonate system equilibrium calculations for the range of salinities and temperatures tested. Mineral precipitation occurred when the bulk seawater pH exceeded 10.0 and Ωaragonite exceeded 30.0. This precipitation was dominated by Mg(OH)2 over hours to 1 d before shifting to CaCO3,aragonite precipitation. These data, combined with models of the dilution and advection of alkaline plumes, will allow the estimation of the amount of carbon dioxide removal expected from OAE pilot studies. Future experiments should better approximate field conditions including sediment interactions, biological activity, ocean circulation, air–sea gas exchange rates, and mixing zone dynamics.

Ringham, Mallory C. (ORCID:0000000348020185)↗

Mathematical characterization of mechanical behavior of porous frictional granular media

A new definition of loading and unloading along the yield surface of Roscoe and Burland is introduced. This is achieved by noting that the strain-hardening parameter in the plastic potential function is deduced from the yield locus equation of Roscoe and Burland. The analytical results are compared with the experimental results for plate-bearing and cone-penetrometer problems and close agreements are demonstrated. The wheel-soil interaction is studied under dynamic loading. The rate-dependent plasticity or viscoelastoplastic behavior is considered. This is accomplished by the internal (hidden) variables associated with time-dependent viscous properties directly superimposed with inelastic behavior governed by the yield criteria of Roscoe and Burland. Effects of inertia and energy dissipation are properly accounted for. Example problems are presented.

Chung, T. J.↗

The dynamic behavior of articulated pipes conveying fluid with periodic flow rate.

The plane motion of two rigid, straight articulated pipes conveying fluid is examined. In contrast to previous work, the flow rate is not taken as constant, but is allowed to have small periodic oscillations about a mean value, as would be expected in a pump-driven system. It is shown that in the presence of such disturbances, both parametric and combination resonances are possible. When the system can also admit loss of stability by static buckling or by flutter, it is found that the presence of small periodic disturbances constitutes a destabilizing effect. Floquet theory and converging infinite determinant expansions are used to illustrate a basic difference between systems which lose stability by divergence and those that lose stability by flutter. An algebraic criterion is obtained for the minimum amplitude of flow-rate oscillation required for the system to be affected by the presence of small disturbances.

Bohn, M. P.↗

Multi-mode optical sensor (B) evaluation test report

An evaluation test series was performed on the unit to develop realistic specifications for a similar device for use on the orbiter vehicle. Tests included sensitivity, target dynamic range, tracking angular rate, external magnetic field effects, and photocathode uniformity. Several demonstrations of operation under automatic control were also prepared, using a desk calculator for numerical control and for subsequent reduction of data derived from the test.

Smith, R. A.↗

Energy requirements of a biosphere

The question is considered of whether a biosphere similar to that on earth could exist in the region of the outer planets, where relatively little light is available for photosynthetic processes. The type of photosynthesis most abundant on earth is discussed along with light conversion in photosynthesis, the light-harvesting system in plants, photosynthetic efficiency, and carbon production in nature. The dynamic range of metabolic rates is examined, and photosynthesis in anaerobic organisms is described. It is suggested that organisms having very large photosynthetic pigment units would thrive in the light intensities prevailing on Titan and that the surface of Titan might well be able to maintain a biosphere driven by oxygen-generating photosynthesis.

Kok, B.↗

Self-scanned anode array with a microchannel plate electron multiplier - The SSANACON

A photoelectron counting detector utilizing a 128-element linear self-scanned anode array to collect the output of a dual microchannel plate electron multiplier is described. The operation of the detector, its spatial resolution and detection efficiency, and radiation behavior are discussed. The low-noise detector was developed for the Mariner Jupiter/Saturn mission UV spectrometer, and offers a large dynamic range and count rate of 0.003 per anode-sec. It can measure simultaneously two spatially separated signals differing by more than six orders of magnitude in count rate.

Broadfoot, A. L.↗

120 MB/S and 240 MB/S bit synchronizer-signal conditioners for NASA high data rate applications

Two bit synchronizer-signal conditioners (BSSC) developed for NASA high data rate applications such as earth resources monitoring are described. One BSSC is centered at 120 MB/s and the other at 240 Mb/s. These subsystems are featured out of the total hardware developed because the BSSC is such a key subsystem in determining overall system statistical performance. These units represent an evolution of high data rate BSSC's available at low data rates. Numerous inputs/outputs, control functions, indicators, plus the ability to minimize the effects of various signal perturbations are provided. Examples of allowed perturbations are input level variations, bit rate variance static and dynamic, baseline, transition density, bandlimiting, etc., as well as noise. Emphasis in the past has been primarily concerned only with noise.

Gray, J. S.↗

Reliability measurement for operational avionics software

Quantitative measures of reliability for operational software in embedded avionics computer systems are presented. Analysis is carried out on data collected during flight testing and from both static and dynamic simulation testing. Failure rate is found to be a useful statistic for estimating software quality and recognizing reliability trends during the operational phase of software development.

Thacker, J.↗

Optimum damper locations for a free-free beam

Algorithms to optimally locate and design dampers for large space structures were developed. The requirements for distributed sensing and actuation in control of structural systems were determined. Mathematical programming was used to solve for optimum damping rate and location. Actuator dynamics were considered to solve for optimum actuator mass.

Horner, G. C.↗

Thrust and ignition transients of the Space Shuttle solid rocket motor

Techniques developed for predicting and analyzing ignition, pressurization, and thrust transients in large segmented motors were applied to the four developmental Space Shuttle solid rocket motors. Following the first test, attention was focused on understanding dynamic thrust and the rate of thrust increase during pressurization and predicting effects of reduced igniter mass flow rate and gas temperature. The close coupling between the igniter and the head-end segment and the high length-to-diameter ratio make understanding of the longitudinal pressure waves essential. The igniter performance along with igniter to head-end segment geometry govern the induction interval and head-end segment ignition. Following ignition of the head-end segment, subsequent flame spreading and pressurization tend to be motor properties which are not appreciably altered by changes in the head-end igniter mass flow rate.

Caveny, L. H.↗

Solar wind energy transfer through the magnetopause of an open magnetosphere

An expression is derived for the total power, transferred from the solar wind to an open magnetosphere, which consists of the electromagnetic energy rate and the particle kinetic energy rate. The total rate of energy transferred from the solar wind to an open magnetosphere mainly consists of kinetic energy, and the kinetic energy flux is carried by particles, penetrating from the solar wind into the magnetosphere, which may contribute to the observed flow in the plasma mantle and which will eventually be convected slowly toward the plasma sheet by the electric field as they flow down the tail. While the electromagnetic energy rate controls the near-earth magnetospheric activity, the kinetic energy rate should dominate the dynamics of the distant magnetotail.

Lee, L. C.↗

Hydrology team

General problems faced by hydrologists when using historical records, real time data, statistical analysis, and system simulation in providing quantitative information on the temporal and spatial distribution of water are related to the limitations of these data. Major problem areas requiring multispectral imaging-based research to improve hydrology models involve: evapotranspiration rates and soil moisture dynamics for large areas; the three dimensional characteristics of bodies of water; flooding in wetlands; snow water equivalents; runoff and sediment yield from ungaged watersheds; storm rainfall; fluorescence and polarization of water and its contained substances; discriminating between sediment and chlorophyll in water; role of barrier island dynamics in coastal zone processes; the relationship between remotely measured surface roughness and hydraulic roughness of land surfaces and stream networks; and modeling the runoff process.

Ragan, R.↗

Lidar observations of mixed layer dynamics - Tests of parameterized entrainment models of mixed layer growth rate

Ground based lidar measurements of the atmospheric mixed layer depth, the entrainment zone depth and the wind speed and wind direction were used to test various parameterized entrainment models of mixed layer growth rate. Six case studies under clear air convective conditions over flat terrain in central Illinois are presented. It is shown that surface heating alone accounts for a major portion of the rise of the mixed layer on all days. A new set of entrainment model constants was determined which optimized height predictions for the dataset. Under convective conditions, the shape of the mixed layer height prediction curves closely resembled the observed shapes. Under conditions when significant wind shear was present, the shape of the height prediction curve departed from the data suggesting deficiencies in the parameterization of shear production. Development of small cumulus clouds on top of the layer is shown to affect mixed layer depths in the afternoon growth phase.

Boers, R.↗