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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Structure of Laminar Permanently Blue, Opposed-Jet Ethylene-Fueled Diffusion Flames

The structure and state relationships of laminar soot-free (permanently blue) ethylene-fueled diffusion flames at various strain rates were studied both experimentally and computationally using an opposed-jet configuration. Measurements of gas velocities, temperatures, and compositions were carried out along the stagnation stream line. Corresponding predictions of flame structure were obtained, based on numerical simulations using several contemporary reaction mechanisms for methane oxidation. Flame conditions studied included ethylene-fueled opposed-jet diffusion flames having stoichiometric mixture fractions of 0.7 with measurements involving strain rates of 60-240/s and predictions involving strain rates of 0-1140/s at normal temperature and pressure. It was found that measured major gas species concentrations and temperature distributions were in reasonably good agreement with predictions using mechanisms due to GRI-Mech and Peters and that effects of preferential diffusion significantly influence flame structure even when reactant mass diffusivities are similar. Oxygen leakage to fuel-rich conditions and carbon monoxide leakage to fuel-lean conditions both increased as strain rates increased. Furthermore, increased strain rates caused increased fuel concentrations near the flame sheet, decreased peak gas temperatures, and decreased concentrations of carbon dioxide and water vapor throughout the flames. State relationships for major gas species and gas temperatures were found to exist over a broad range of strain rates, providing potential for significant computational simplifications for modeling purposes in some instances.

Lin, K.-C.↗
NASA NTRS2001

Structure and Soot Properties of Nonbuoyant Ethylene/Air Laminar Jet Diffusion Flames

The structure and soot properties of round, soot-emitting, nonbuoyant, laminar jet diffusion flames are described, based on long-duration (175-230-s) experiments at microgravity carried out on orbit in the Space Shuttle Columbia. Experimental conditions included ethylene-fueled flames burning in still air at nominal pressures of 50 and 100 kPa and an ambient temperature of 300 K with luminous flame lengths of 49-64 mm Measurements included luminous flame shapes using color video imaging soot concentration (volume fraction) distributions using deconvoluted laser extinction imaging, soot temperature distributions using deconvoluted multiline emission imaging, gas temperature distributions at fuel-lean (plume) conditions using thermocouple probes, soot structure distributions using thermophoretic sampling and analysis by transmission electron microscopy, and flame radiation using a radiometer.The present flames were larger, and emitted soot more readily, than comparable flames observed during ground-based microgravity experiments due to closer approach to steady conditions resulting from the longer test times and the reduced gravitational disturbances of the space-based experiments.

Urban, D. L.↗
NASA NTRS2003

Sounding Rocket Microgravity Experiments Elucidating Diffusive and Radiative Transport Effects on Flame Spread over Thermally-Thick Solids

A series of 6-minute microgravity combustion experiments of opposed flow flame spread over thermally-thick PMMA has been conducted to extend data previously reported at high opposed flows to almost two decades lower in flow. The effect of flow velocity on flame spread shows a square root power law dependence rather than the linear dependence predicted by thermal theory. The experiments demonstrate that opposed flow flame spread is viable to very low velocities and more robust than expected from the numerical model, which predicts that at very low velocities (less than 5 centimeters per second), flame spread rates fall off more rapidly as flow is reduced. It is hypothesized that the enhanced flame spread observed in the experiments may be due to three- dimensional hydrodynamic effects, which are not included in the zero-gravity, two-dimensional hydrodynamic model. The effect of external irradiation was found to be more complex that the model predicted over the 0-2 Watts per square centimeter range. In the experiments, the flame compensated for the increased irradiation by stabilizing farther from the surface. A surface energy balance reveals that the imposed flux was at least partially offset by a reduced conductive flux from the increased standoff distance, so that the effect on flame spread was weaker than anticipated.

Olson, Sandra L.↗
NASA NTRS2003

Transport And Chemical Effects On Concurrent And Opposed-Flow Flame Spread At Microgravity

Flame spread over flat solid fuel beds is a useful means of understanding more complex two-phase non-premixed spreading flames, such as those that may occur due to accidents in inhabited buildings and orbiting spacecraft. The role of buoyant convection on flame spread is substantial, especially for thermally-thick fuels. With suitable assumptions, deRis showed that the spread rate (S(sub f)) is proportional to the buoyant or forced convection velocity (U) and thus suggests that S(sub f) is indeterminate at mu g (since S(sub f) = U) unless a forced flow is applied. (In contrast, for thermally thin fuels, the ideal S(sub f) is independent of U.) The conventional view, as supported by computations and space experiments, is that for quiescent g conditions, S(sub f) must be unsteady and decreasing until extinction occurs due to radiative losses. However, this view does not consider that radiative transfer to the fuel surface can enhance flame spread. In recent work we have found evidence that radiative transfer from the flame itself can lead to steady flame spread at mu g over thick fuel beds. Our current work focuses on refining these experiments and a companion modeling effort toward the goal of a space flight experiment called Radiative Enhancement Effects on Flame Spread (REEFS) planned for the International Space Station (ISS) c. 2007.

Son, Y.↗
NASA NTRS2003

Sooting Limits Of Diffusion Flames With Oxygen-Enriched Air And Diluted Fuel

Oxygen-enhanced combustion permits certain benefits and flexibility that are not otherwise available in the design of practical combustors, as discussed by Baukal. The cost of pure and enriched oxygen has declined to the point that oxygen-enhanced combustion is preferable to combustion in air for many applications. Carbon sequestration is greatly facilitated by oxygen enrichment because nitrogen can be eliminated from the product stream. For example, when natural gas (or natural gas diluted with CO2) is burned in pure oxygen, the only significant products are water and CO2. Oxygen-enhanced combustion also has important implications for soot formation, as explored in this work. We propose that soot inception in nonpremixed flames requires a region where C/O ratio, temperature, and residence time are above certain critical values. Soot does not form at low temperatures, with the threshold in nonpremixed flames ranging from about 1250-1650 K, a temperature referred to here as the critical temperature for soot inception, Tc. Soot inception also can be suppressed when residence time is short (equivalently, when the strain rate in counterflow flames is high). Soot induction times of 0.8-15 ms were reported by Tesner and Shurupov for acetylene/nitrogen mixtures at 1473 K. Burner stabilized spherical microgravity flames are employed in this work for two main reasons. First, this configuration offers unrestricted control over convection direction. Second, in steady state these flames are strain-free and thus can yield intrinsic sooting limits in diffusion flames, similar to the way past work in premixed flames has provided intrinsic values of C/O ratio associated with soot inception limits.

Sunderland, P. B.↗
NASA NTRS2003

Gravity Effects Observed In Partially Premixed Flames

Partially premixed flames (PPFs) contain a rich premixed fuel air mixture in a pocket or stream, and, for complete combustion to occur, they require the transport of oxidizer from an appropriately oxidizer-rich (or fuel-lean) mixture that is present in another pocket or stream. Partial oxidation reactions occur in fuel-rich portions of the mixture and any remaining unburned fuel and/or intermediate species are consumed in the oxidizer-rich portions. Partial premixing, therefore, represents that condition when the equivalence ratio (phi) in one portion of the flowfield is greater than unity, and in another section its value is less than unity. In general, for combustion to occur efficiently, the global equivalence ratio is in the range fuel-lean to stoichiometric. These flames can be established by design by placing a fuel-rich mixture in contact with a fuel-lean mixture, but they also occur otherwise in many practical systems, which include nonpremixed lifted flames, turbulent nonpremixed combustion, spray flames, and unwanted fires. Other practical applications of PPFs are reported elsewhere. Although extensive experimental studies have been conducted on premixed and nonpremixed flames under microgravity, there is a absence of previous experimental work on burner stabilized PPFs in this regard. Previous numerical studies by our group employing a detailed numerical model showed gravity effects to be significant on the PPF structure. We report on the results of microgravity experiments conducted on two-dimensional (established on a Wolfhard-Parker slot burner) and axisymmetric flames (on a coannular burner) that were investigated in a self-contained multipurpose rig. Thermocouple and radiometer data were also used to characterize the thermal transport in the flame.

Puri, Ishwar K.↗
NASA NTRS2003

Buoyancy Effects in Fully-Modulated, Turbulent Diffusion Flames

Pulsed combustion appears to have the potential to provide for rapid fuel/air mixing, compact and economical combustors, and reduced exhaust emissions. The objective of this experiment (PuFF, for Pulsed-Fully Flames) is to increase the fundamental understanding of the fuel/air mixing and combustion behavior of pulsed, turbulent diffusion flames by conducting experiments in microgravity. In this research the fuel jet is fully-modulated (i.e., completely shut off between pulses) by an externally controlled valve system. This gives rise to drastic modification of the combustion and flow characteristics of flames, leading to enhanced fuel/air mixing compared to acoustically excited or partially-modulated jets. Normal-gravity experiments suggest that the fully-modulated technique also has the potential for producing turbulent jet flames significantly more compact than steady flames with no increase in exhaust emissions. The technique also simplifies the combustion process by avoiding the acoustic forcing generally present in pulsed combustors. Fundamental issues addressed in this experiment include the impact of buoyancy on the structure and flame length, temperatures, radiation, and emissions of fully-modulated flames.

Hermanson, J. C.↗
NASA NTRS2003

Microgravity Apparatus And Ground-Based Study Of The Flame Propagation And Quenching In Metal Dust Suspensions

Due to particle sedimentation and relatively low laminar flame speeds in dust suspensions, microgravity environment is essential for the observation of laminar dust flames in a wide range of particle sizes and fuel concentrations [1]. The capability of a reduced-gravity environment to facilitate study of dust combustion was realized by researchers long before current microgravity programs were established by the various national Space Agencies. Thus, several experimentalists even built their own, albeit very short-duration, drop tower facilities to study flames in particle and droplet suspensions [2,3]. About ten years ago, authors of the present paper started their dust combustion reduced gravity research with the investigation of the constant volume dust flames in a spherical-bomb on board a parabolic flight aircraft [4]. However it was soon realized that direct observation of the constant-pressure flame might be more beneficial. Thus, microgravity apparatus, permitting examination of the freely propagating flames in open-end tubes, was tested in parabolic flights three years later [5]. The improved design of the newlyconstructed apparatus for the experiments on board the NASA KC-135 aircraft is also based on the observation of the dust flame propagating in semi-opened tubes with free expansion of the combustion products that are continuously vented overboard. The apparatus design and results of its extensive ground-based testing are presented below.

Goroshin, Sam↗
NASA NTRS2004

Transition from Forward Smoldering to Flaming in Small Polyurethane Foam Samples

Experimental observations are presented of the effect of the flow velocity and oxygen concentration, and of a thermal radiant flux, on the transition from smoldering to flaming in forward smoldering of small samples of polyurethane foam with a gas/solid interface. The experiments are part of a project studying the transition from smolder to flaming under conditions encountered in spacecraft facilities, i.e., microgravity, low velocity variable oxygen concentration flows. Because the microgravity experiments are planned for the International Space Station, the foam samples had to be limited in size for safety and launch mass reasons. The feasible sample size is too small for smolder to self propagate because of heat losses to the surrounding environment. Thus, the smolder propagation and the transition to flaming had to be assisted by reducing the heat losses to the surroundings and increasing the oxygen concentration. The experiments are conducted with small parallelepiped samples vertically placed in a wind tunnel. Three of the sample lateral-sides are maintained at elevated temperature and the fourth side is exposed to an upward flow and to a radiant flux. It is found that decreasing the flow velocity and increasing its oxygen concentration, and/or increasing the radiant flux enhances the transition to flaming, and reduces the delay time to transition. Limiting external ambient conditions for the transition to flaming are reported for the present experimental set-up. The results show that smolder propagation and the transition to flaming can occur in relatively small fuel samples if the external conditions are appropriate. The results also indicate that transition to flaming occurs in the char left behind by the smolder reaction, and it has the characteristics of a gas-phase ignition induced by the smolder reaction, which acts as the source of both gaseous fuel and heat.

Bar-Ilan, A.↗
NASA NTRS2004

Structure of Flame Balls at Low Lewis-Number (SOFBALL): New Results from STS-107

Experiments on steady, spherically-symmetric premixed-gas flames ("flame balls") performed on STS-107 are described. These experiments were motivated by results obtained on earlier Space Shuttle missions. The motivation and objectives for the STS-107 experiments are described, along with the results obtained. Among the highlights of STS-107 were the weakest flames ever burned either on earth or in space (about 0.5 Watt of heat release), the leanest flames ever burned either on earth or in space, and the longest-lived flame ever burned in space. While many of the questions left unresolved from the earlier space flights were answered, some new and as yet unexplained phenomena were found, for example flame balls migrating in spiral patterns. Nonetheless, flame ball experiments have provided an insight into the interactions of the two most important phenomena in combusting materials, namely chemical reaction and transport processes, in the unequivocally simplest possible configuration.

Abid, Mohamed↗
NASA NTRS2003

Presumed PDF Modeling of Early Flame Propagation in Moderate to Intense Turbulence Environments

The present paper describes the results obtained from a one-dimensional time dependent numerical technique that simulates early flame propagation in a moderate to intense turbulent environment. Attention is focused on the development of a spark-ignited, premixed, lean methane/air mixture with the unsteady spherical flame propagating in homogeneous and isotropic turbulence. A Monte-Carlo particle tracking method, based upon the method of fractional steps, is utilized to simulate the phenomena represented by a probability density function (PDF) transport equation. Gaussian distributions of fluctuating velocity and fuel concentration are prescribed. Attention is focused on three primary parameters that influence the initial flame kernel growth: the detailed ignition system characteristics, the mixture composition, and the nature of the flow field. The computational results of moderate and intense isotropic turbulence suggests that flames within the distributed reaction zone are not as vulnerable, as traditionally believed, to the adverse effects of increased turbulence intensity. It is also shown that the magnitude of the flame front thickness significantly impacts the turbulent consumption flame speed. Flame conditions studied have fuel equivalence ratio s in the range phi = 0.6 to 0.9 at standard temperature and pressure.

Carmen, Christina↗
NASA NTRS2004

Structure of Propagating and Attached Hydrocarbon Flames

Direct numerical simulations with C3-chemistry and radiative heat-loss models have been performed to reveal the internal structure of propagating and attached flames in an axisymmetric fuel jet of methane, ethane, ethylene, acetylene, or propane in air under normal and zero gravity. Observations of the flames were also made at the NASA Glenn 2.2-Second Drop Tower. In computations, the fuel issued into quasi-quiescent air for a fixed mixing time before it was ignited along the centerline at stoichiometry. The edge of the flame propagated through a flammable layer at the laminar flame speed of the stoichiometric fuel-air mixture independent of gravity. For all cases, a peak reactivity spot, i.e., reaction kernel, was formed in the flame base, thereby holding a trailing diffusion flame. The location of the reaction kernel in the attached flames depended inversely on the reactivity. The reaction-kernel correlations between the reactivity and the velocity were developed further using variables related to local Damkahler and Peclet numbers.

Takahashi, Fumiaki↗
NASA NTRS1997

Plural-wavelength flame detector that discriminates between direct and reflected radiation

A flame detector employs a plurality of wavelength selective radiation detectors and a digital signal processor programmed to analyze each of the detector signals, and determine whether radiation is received directly from a small flame source that warrants generation of an alarm. The processor's algorithm employs a normalized cross-correlation analysis of the detector signals to discriminate between radiation received directly from a flame and radiation received from a reflection of a flame to insure that reflections will not trigger an alarm. In addition, the algorithm employs a Fast Fourier Transform (FFT) frequency spectrum analysis of one of the detector signals to discriminate between flames of different sizes. In a specific application, the detector incorporates two infrared (IR) detectors and one ultraviolet (UV) detector for discriminating between a directly sensed small hydrogen flame, and reflections from a large hydrogen flame. The signals generated by each of the detectors are sampled and digitized for analysis by the digital signal processor, preferably 250 times a second. A sliding time window of approximately 30 seconds of detector data is created using FIFO memories.

Hall, Gregory H.↗
NASA NTRS2012

Quantitative Infrared Image Analysis Of Thermally-Thin Cellulose Surface Temperatures During Upstream and Downstream Microgravity Flame Spread from A Central Ignition Line

Surface view calibrated infrared images of ignition and flame spread over a thin cellulose fuel were obtained at 30 Hz during microgravity flame spread tests in the 10 second Japan Microgravity Center (JAMIC). The tests also used a color video of the surface view and color images of the edge view using 35 millimeter 1600 Kodak Ektapress film at 2 Hz. The cellulose fuel samples (50% long fibers from lumi pine and 50% short fibers from birch) were made with an area density of 60 grams per square meters. The samples were mounted in the center of a 12 centimeter wide by 16 centimeter tall flow duct that uses a downstream fan to draw the air through the flow duct. Samples were ignited after the experiment package was released using a straight hot wire across the center of the 7.5 centimeter wide by 14 centimeter long samples. One case, at 1 atmosphere 35%O2 in N2, at a forced flow of 10 centimeters per second, is presented here. In this case, as the test progresses, the single flame begins to separate into simultaneous upstream and downstream flames. Surface temperature profiles are evaluated as a function of time, and temperature gradients for upstream and downstream flame spread are measured. Flame spread rates from IR image data are compared to visible image spread rate data. IR blackbody temperatures are compared to surface thermocouple readings to evaluate the effective emissivity of the pyrolyzing surface. Preheat lengths are evaluated both upstream and downstream of the central ignition point. A surface energy balance estimates the net heat flux from the flame to the fuel surface along the length of the fuel.

Olson, Sandra L.↗
NASA NTRS2017

Spontaneous Ignition of Hydrothermal Flames in Supercritical Ethanol Water Solutions

Results are reported from recent tests where hydrothermal flames spontaneously ignited in a Supercritical Water Oxidation (SCWO) Test Cell. Hydrothermal flames are generally categorized as flames that occur when appropriate concentrations of fuel and oxidizer are present in supercritical water (SCW); i.e., water at conditions above its critical point (218 atm and 374 C). A co-flow injector was used to inject fuel, comprising an aqueous solution of 30-vol to 50-vol ethanol, and air into a reactor held at constant pressure and filled with supercritical water at approximately 240 atm and 425 C. Hydrothermal flames auto-ignited and quickly stabilized as either laminar or turbulent diffusion flames, depending on the injection velocities and test cell conditions. Two orthogonal views, one of which provided a backlit shadowgraphic image, provided visual observations. Optical emission measurements of the steady state flame were made over a spectral range spanning the ultraviolet (UV) to the near infrared (NIR) using a high-resolution, high-dynamic-range spectrometer. Depending on the fuel air flow ratios varying degrees of sooting were observed and are qualitatively compared using light absorption comparisons from backlit images.

hydrothermal flame↗
NASA NTRS1973

Flame inhibition by hydrogen halides - Some spectroscopic measurements

The far-ultraviolet absorption spectrum of an air-propane diffusion flame inhibited with hydrogen halides has been studied. Plots of the absorption of light by hydrogen halides as a function of position in the flame and also as a function of the amount of hydrogen halide added to the flame have been obtained. The hydrogen halides are shown to be more stable on the fuel side of the reaction zone than they are on the air side. Thermal diffusion is seen to be important in determining the concentration distribution of the heavier hydrogen halides in diffusion flames. The relationship between the concentration distribution of the hydrogen halides in the flame and the flame inhibition mechanism is discussed.

Lerner, N. R.↗
NASA NTRS1975

Statistical model for premixed turbulent flames

Statistical concepts and physical arguments are used to develop closure models for the mean energy equation governing one-dimensional, premixed, intense turbulent flames. It is proposed that the turbulent transport terms can be modeled by a turbulent conductivity based on turbulence kinetic energy (k) and energy dissipation rate (epsilon). The models obtained are used to derive correlations for the turbulent flame speed. Results show that there are three different flame regimes: a low-intensity turbulence, wrinkled flame; a high-intensity, fast-chemistry flame; and a high-intensity, finite-rate-chemistry flame.

Gouldin, F. C.↗
NASA NTRS1977

Premixed flame propagation characteristics in a supersonic airstream

Measured values of flame angles are presented to aid the design of premixed combustion chambers and prediction of flame propagation. Flame spread, velocity, and dependence of burning rate on the properties of unburned flow and on turbulence levels are compared with the measured values. The premixed flame angle is found proportional to the amount of heat released, and correlates readily with the fuel mixture ratio through the rate of heat release or rate of water formation. Finite rate combustion affects flame angle mostly at off-stoichiometric conditions. The pilot affects the flame angle if abundant unburnt fuel is present in the pilot hot gases. Viscosity runs several times over the rated level.

Agnone, A. M.↗