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At least 325 records · Page 18

Probing Microstructure-induced Swelling & Thermal Property Changes in Ion-Irradiated Oxide Fuels using Laser-generated Surface Acoustic Waves

Radiation of fuel rods with neutrons during a fission reaction in a nuclear reactor is known to affect the material microstructure of the fuel as a result of fission fragment damage, and lead to the formation of atomic-level defects such as voids, dislocation loops, and lattice swelling from fission-gas release. A consequence of the radiation-induced damage in nuclear fuels is the drastic alteration of material properties, in particular, the reduction of the thermal conductivity – a key parameter that governs the transport of thermal energy released from fissile fuel atoms to the surrounding coolant. Swelling can induce high stresses and ultimate failure of the cladding. A fundamental understanding of the role of radiation-induced damage on the thermal transport and mechanical properties of nuclear fuels is therefore critical for efficient, reliable and safe operation of a nuclear power plant. As opposed to conventional post-irradiation examination techniques that are often time-consuming and require significant sample preparation, laser-based characterization methods have emerged as promising non-contact, non-destructive tools to measure the evolution of microstructure-induced material property changes. Moreover, laser methods offer the promise of in-situ characterization while the material is being irradiated. This project aims to develop an improved understanding of the impact of radiation-induced changes to material microstructure on the thermal and elastic properties of nuclear materials. A laser ultrasonic technique, known as the transient grating (TG) spectroscopy method, is used to simultaneously measure thermal diffusivity and elastic properties in unirradiated and ion-irradiated oxide nuclear fuel samples. The results will complement on-going investigations on electron- and phonon-mediated thermal transport in nuclear materials and will provide foundational work for incorporating the influence of defects in fuel performance codes.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Status Report on Fast Flux Test Facility Mechanistic Fuel Failure Experiment Analysis with BISON for Post Irradiation Examination Support

The renewed interest in metallic U-Zr nuclear fuel alloy has led to a drive for deeper understanding of the mechanisms driving the phenomena observed under irradiation conditions. The Department of Energy Advanced Fuel Campaign has developed infrastructure to support metallic fuel development, including Post Irradiation Examination (PIE) of legacy Fast Flux Test Facility (FFTF) Mechanistic Fuel Failure (MFF) experiments. The PIE performed on legacy FFTF MFF experiments gives insight on metallic fuel performance and can address the lack of knowledge and scarcity of reliable data identified in several studies over recent years. Unfortunately, PIE efforts can cost significant time and resources which can impede the progress of metallic U-Zr fuel development. Metallic U-Zr fuel performance modeling can be used to inform PIE efforts on regions of interest for relevant investigations and can help understand phenomena observed in PIE. This report demonstrates the current progress of FFTF MFF fuel performance simulations using the BISON fuel performance code and discusses the support provided by simulation to PIE efforts. Progress in temperature, profilometry, fission gas release, plenum pressure, and zirconium redistribution simulation results have been demonstrated.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Advances in Metallic Fuel Database Development and Data Qualification

The Fuels Irradiation and Physics Database (FIPD [1]) is a comprehensive repository of data and documents related to Uranium-Zirconium based metallic fuel test pins. This database stores operational conditions of these pins, calculated using a suite of Argonne National Laboratory analysis codes developed during the Integral Fast Reactor (IFR) program. Key calculated data include axial distributions of power, temperature, fluence, burnup, and isotopic densities. Additionally, the FIPD holds post-irradiation examination (PIE) data such as fission gas release, gas chemistry measurements, and axial distributions derived from profilometry, gamma scanning, and neutron radiography. Complementing these data is an extensive archive of documents related to various pins and experiments. These include raw PIE records, design details, safety analyses, and operational reports. More detail about FIPD can be found in ref. [2]. The database development is an ongoing effort covering metallic fuel experiments from the Experimental Breeder Reactor II (EBR-II) and the Fast Flux Test Facility (FFTF). The recent improvements to the database and the data QA status are summarized in this paper.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

High-burnup Experiments in Reactivity Initiated Accidents (HERA)

HERA is a joint experimental program (JEEP) operating within the Nuclear Energy Agency’s (NEA’s) framework for irradiation experiments (FIDES). HERA is dedicated to the understanding of light water reactor (LWR) fuel performance at high burnup under reactivity-initiated accidents (RIA). During RIAs the fuel cladding can be breached by one of two mechanisms; pellet-cladding mechanical interaction or high temperature balloon and rupture. Pellet-cladding mechanical interaction (PCMI) failure occurs in the early phase of an RIA transient where the fuel pellet expands rapidly into the cladding prior to any meaningful heat transfer from the pellet to the cladding. This results in high stresses in the cladding resulting in crack propagation through the base Zircaloy metal and axially along the cladding tube. Failure by PCMI is a brittle failure mode and occurs at low cladding strains, approximately 2% hoop strain. If the cladding survives the PCMI phase of the transient, it may still fail due to ballooning and rupture induced by extended exposure to high temperature. Thermal transport from the fuel pin to the coolant is significantly reduced if a transition to film boiling on the cladding surface occurs. This result in both a rapid increase in fuel temperature, which drives fission gas release, and a spike in cladding temperature, which results in loss of mechanical strength. If the internal pressure of the fuel rod is greater than the system pressure the cladding can inelastically deform and eventually rupture. Failure by swelling and rupture occurs at larger strains, generally greater than 5% hoop strain. While PCMI failures are generally seen as more limiting, the dominance of one failure mode over the other can be affected by both the cladding material conditions, and the transient evolution.

(HERA)↗

Recent Metallic Fuel Data Recovery in FIPD

The Metallic Fuels Irradiation and Physics Database (FIPD) [1] is an organized collection of metallic fuel test pin data (U-xPu-yZr, = 0 ~ 28; y = 2 ~ 10) and documentation available to industry. FIPD mainly contains three types of data: (1) Fuel pin fabrication data, including fuel slug diameter, fuel slug length, cladding diameter, smear density, etc. (2) Fuel pin operation conditions, including axial distributions for power, temperatures, fluences, burnup, and isotopic densities, etc. and (3) Fuel pin post-irradiation examination (PIE) data, including fission gas release and gas chemistry, profilometry, and neutron radiography, etc. The operating conditions for pins with PIE data available in FIPD span significant ranges across key parameters. The fuel peak burnup extends from less than 5% up to 20 at%. The cladding peak temperature varies from about 490°C to 660°C. Finally, the cladding peak DPA shows a wide range from less than 5 to 120. These broad ranges reflect the diverse testing conditions and operational parameters captured in the available PIE data. More detail about FIPD can be found in ref. [2]. The database development is an ongoing effort covering metallic fuel experiments from the Experimental Breeder Reactor II (EBR-II) and the Fast Flux Test Facility (FFTF). As reported in the ref. [3, 4], most of the PIE data generated during the IFR program [5] has been collected, reviewed, processed, and integrated into FIPD. The most recently added PIE data can be found in ref. [4], which shows the collection of over 95% of the PIE data by the time of this paper. The recent improvements to the database are summarized in this paper.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Refined BISON-Griffin Workflow For Designing Targeted TRISO Transient Experiments In The Transient Reactor Test Facility

U.S. industry is expected to deploy tristructural isotropic (TRISO) particle fuel technologies for commercial reactors within the next decade. In our previous work, we defined a preliminary transient design space for TRISO fuels, identified potential gaps in the available data, and began to develop multiphysics modeling tools that could be applied to design targeted Transient Reactor Test Facility (TREAT) experiments to fill these gaps. This work builds on that foundation by (1) updating BISON fuel performance and Griffin reactor physics models to reflect the current TREAT experiment tube and capsule designs,(2) coupling the codes to improve the accuracy and usability of the transient design analyses, and (3) demonstrating their use over an expanded design space that includes fuel burnup. The simulated mechanical responses of the TRISO particles were complex functions of fission product accumulation, fission gas release, and irradiation-induced dimensional change in the pyrolytic carbon layers. Predicted tangential stresses in particle silicon carbide layers were least compressive for preheated tests involving fresh fuels but remained compressive throughout the ranges of temperature, heat rate, and burnup considered in this work. Finally, comparisons between the potential TREAT transients and historical test reactor irradiations showed that the TREAT tests would produce significantly lower average energy deposition rates, yielding less severe transients with greater relevance to near-term commercial applications. Use of these predictive capabilities has the potential to increase the value of each test, improving the overall efficiency and cost effectiveness of transient testing for TRISO and other advanced fuels.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

AGR-5/6/7 Experiment Preliminary Findings

AGR-5/6/7 in-pile data have been published: Fuel irradiation conditions, Fission gas release-rate-to-birth-rate (R/B) ratios, PIE and safety testing are still in progress and only limited data have been published, and preliminary results.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

040226_AnnularFuel_FuelPerformance_LRSv2

This slide deck summarizes a comparative fuel performance assessment of four annular fuel concepts for pressurized water reactor applications against a reference 17×17 fuel design. Overall, annular fuel geometry improves several key thermal-mechanical performance metrics, with the large-annulus configuration providing the most favorable balance of benefits. Relative to the reference design, annular fuel reduces peak fuel temperature by lowering thermal resistance through a thinner fuel pellet and smaller heat-conduction path. At the same time, the reduced fuel volume raises local burnup and correspondingly increases fission gas release. Despite this, rod internal pressure at end of life decreases because the annular geometry provides greater internal void volume. Annular designs also tend to delay fuel-cladding gap closure, although this advantage diminishes in thin-gap configurations where the smaller initial gap accelerates closure. Similarly, hoop stress and hoop strain are generally reduced for annular fuel, but both increase as the initial gap becomes smaller, indicating a potential cladding integrity concern for thin-gap designs. Corrosion performance shows no meaningful variation among the concepts considered. Taken together, the results indicate that annular fuel can offer significant performance advantages in a PWR environment, with large-annulus designs emerging as the strongest candidate while thin-gap geometries introduce more challenging mechanical margins.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Combinatorial Approach to Testing and Characterization of Irradiated Fuels and Materials

•Combinatorial approaches to testing and characterization of materials is a very powerful tool to help explore some fundamentals of materials science.? •Three topics will be explored to help illustrate this:? •A fitness-for-service assessment of a CANDU component (this is work from my past)? •The use of small-scale mechanical testing of Cr-coated ATF cladding in support of qualification (this is work developed upon joining INL)? •A multi-scale characterization approach of TRISO fuel to investigate fission gas migration and microstructural features (this is work I now get to participate in on joining MFC)? •?

36 - MATERIALS SCIENCE↗

Fission Product Measurement and Off-Gas Scrubbing for Molten Salt Reactors

The Advanced Reactor Technology (ART) program within the US Department of Energy is developing understanding and technology to help facilitate molten salt reactor commercialization. The off-gas system for MSRs plays an important role in fission product confinement. The strategy used in MSRs is different from that used in pressurized water reactors, where the off-gas mainly mitigates severe accident conditions. Although the details vary depending on the reactor type, the off-gas system of MSRs must reduce radiological emissions to the environment to levels comparable with those mandated for non-MSRs. Systems with molten fuel salt will accumulate material in the headspace: volatile fission products, entrained salt particles, graphite fines, and material that has low solubility in the salt. Operators of thermal fluoride salt reactors with encapsulated fuel will also be concerned about tritium generation and migration. The fission and activation products include noble gases, their daughters, tritium, and aerosolized salt constituents. Their concentrations will generally increase with reactor burnup, depending on the various strategies used for mitigation. Additionally, tritium capture and removal has been reviewed by several groups.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Advanced nuclear thermal propulsion concepts

In 1989, a Presidential directive created the Space Exploration Initiative (SEI) which had a goal of placing mankind on Mars in the early 21st century. The SEI was effectively terminated in 1992 with the election of a new administration. Although the initiative did not exist long enough to allow substantial technology development, it did provide a venue, for the first time in 20 years, to comprehensively evaluate advanced propulsion concepts which could enable fast, manned transits to Mars. As part of the SEI based investigations, scientists from NASA, DoE National Laboratories, universities, and industry met regularly and proceeded to examine a variety of innovative ideas. Most of the effort was directed toward developing a solid-core, nuclear thermal rocket and examining a high-power nuclear electric propulsion system. In addition, however, an Innovative Concepts committee was formed and charged with evaluating concepts that offered a much higher performance but were less technologically mature. The committee considered several concepts and eventually recommended that further work be performed in the areas of gas core fission rockets, inertial confinement fusion systems, antimatter based rockets, and gas core fission electric systems. Following the committee's recommendations, some computational modeling work has been performed at Los Alamos in certain of these areas and critical issues have been identified.

Howe, Steven D.↗

Fission track astrology of three Apollo 14 gas-rich breccias

The three Apollo 14 breccias 14301, 14313, and 14318 all show fission xenon due to the decay of Pu-244. To investigate possible in situ production of the fission gas, an analysis was made of the U-distribution in these three breccias. The major amount of the U lies in glass clasts and in matrix material and no more than 25% occurs in distinct high-U minerals. The U-distribution of each breccia is discussed in detail. Whitlockite grains in breccias 14301 and 14318 found with the U-mapping were etched and analyzed for fission tracks. The excess track densities are much smaller than indicated by the Xe-excess. Because of a preirradiation history documented by very high track densities in feldspar grains, however, it is impossible to attribute the excess tracks to the decay of Pu-244. A modified track method has been developed for measuring average U-concentrations in samples containing a heterogeneous distribution of U in the form of small high-U minerals. The method is briefly discussed, and results for the rocks 14301, 14313, 14318, 68815, 15595, and the soil 64421 are given.

Graf, H.↗

Thermodynamic properties of a high pressure subcritical UF6/He gas volume (irradiated by an external source)

A computer simulation study concerning a compressed fissioning UF6 gas is presented. The compression is to be achieved by a ballistic piston compressor. Data on UF6 obtained with this compressor were incorporated in the simulation study. As a neutron source to create the fission events in the compressed gas, a fast burst reactor was considered. The conclusion is that it takes a neutron flux in excess of 10 to the 15th power n/sec sq cm to produce measurable increases in pressure and temperature, while a flux in excess of 10 to 19th power n/sq cm sec would probably damage the compressor.

Sterritt, D. E.↗

Characterization of a platform for the gas transport, collection, and identification of fission products in the high-intensity laser environment

Recent progress in the production of laser accelerated high flux proton beams opens new possibilities for the study of fission in unique environments. To this end, we are currently pursuing the development of a platform for the swift gas transport, collection, and identification of fission products. Fission is induced in targets fixed inside a sealed chamber through which a carrier gas flows, transporting fission products to a carbon filter for collection and online spectroscopy. This has been recently demonstrated using target normal sheath accelerated protons at the PHELIX laser facility. There were large discrepancies between measured rates and those expected based on established fission yields and measured beam parameters. These discrepancies prompted a large number of tests at the Idaho Accelerator Center (IAC), where fission in uranium is induced by bremsstrahlung photons generated by 21 MeV electrons from a linear electron accelerator. Here, the results are compared to a series of models that account for the slowing of energetic fission fragments in the carrier gas and the fluid dynamics of the gas flow that transports fission products to the collection filter. Characterization of the apparatus reveals a few mechanisms that together account for a portion of the previously observed discrepancies at the PHELIX laser facility. However, additional research is necessary before high-accuracy experiments can be performed with the apparatus. Work performed under the auspices of the U.S. Department of Energy by LLNL under contract DE-AC52-07NA27344.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Multi-Megawatt Gas Turbine Power Systems for Lunar Colonies

A concept for development of second generation 10 MWe prototype lunar power plant utilizing a gas cooled fission reactor supplying heated helium working fluid to two parallel 5 MWe closed cycle gas turbines is presented. Such a power system is expected to supply the energy needs for an initial lunar colony with a crew of up to 50 persons engaged in mining and manufacturing activities. System performance and mass details were generated by an author developed code (BRMAPS). The proposed pilot power plant can be a model for future plants of the same capacity that could be tied to an evolutionary lunar power grid.

Juhasz, Albert J.↗