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Presentation for CCUS 2025 Conference held in Houston, Texas March 3-5, 2025. Offshore geologic carbon storage (GCS) efforts are accelerating worldwide. As additional projects come online and site characterizations take place, project information and data need to be aggregated into central locations to improve understanding of the success criteria for GCS.
As part of a general review of recent high-resolution seismological data, constraints are established for the distribution of mass in the continental crust and upper mantle of the earth. It is shown that the densities of mantle magmas such as MORB-like tholeiites, oicrites, and komatites at 10 kilobars are greater than densities in the continental crust. In order to explain the deviation, a mechanism is proposed for the control of mass transfer during igneous and metamorphic processes throughout geological time. Within the context of a description of the mechanism, the continental crust is characterized as a density filter through which only highly evolved magmas with H2O may pass. It is shown that the removal of less evolved magmas can lead to an over accretion (penetration) or an under accretion (underplating) of magmas in the continental Moho. Some implications of the proposed mechanism for current theoretical models of crust formation are discussed in detail.
Finding evidence for first the existence, and then the nature of life on the early Earth or early Mars requires both the recognition of subtle biosignatures and the elimination of false positives. The history of the search for fossils in increasingly older Precambrian strata illustrates these difficulties very clearly, and new observational and theoretical approaches are both needed and being developed. At the microscopic level of investigation, three-dimensional morphological characterization coupled with in situ chemical (isotopic, elemental, structural) analysis is the desirable first step. Geological context is paramount, as has been demonstrated by the controversies over AH84001, the Greenland graphites, and the Apex chert microfossils . At larger scales, the nature of sedimentary bedforms and the structures they display becomes crucial, and here the methods of condensed matter physics prove most useful in discriminating between biological and non-biological constructions. Ultimately, a combination of geochemical, morphological, and contextural evidence may be required for certain life detection on the early Earth or elsewhere.
The ChemCam instrument selected for the Curiosity rover is capable of remote laser-induced breakdown spectroscopy (LIBS).[1] We used a remote LIBS instrument similar to ChemCam to analyze 197 geologic slab samples and 32 pressed-powder geostandards. The slab samples are well-characterized and have been used to validate the calibration of previous instruments on Mars missions, including CRISM [2], OMEGA [3], the MER Pancam [4], Mini-TES [5], and Moessbauer [6] instruments and the Phoenix SSI [7]. The resulting dataset was used to compare multivariate methods for quantitative LIBS and to determine the effect of grain size on calculations. Three multivariate methods - partial least squares (PLS), multilayer perceptron artificial neural networks (MLP ANNs) and cascade correlation (CC) ANNs - were used to generate models and extract the quantitative composition of unknown samples. PLS can be used to predict one element (PLS1) or multiple elements (PLS2) at a time, as can the neural network methods. Although MLP and CC ANNs were successful in some cases, PLS generally produced the most accurate and precise results.
The presence of allophane and other nanophase materials on Mars indicates a time when water was intermittent and short lived. These materials likely represent partially altered or leached basaltic ash and therefore, could represent a geologic marker for where water was present on the Martian surface. Further, they may indicate regions of climate change, where surface water was not present long enough to form clays. Characterization of these materials is important for increasing spectral recognition capacities of our current Martian science array. Ongoing work suggests that variability in the Al:Si ratio of allophane can dictate the amount of both structural and adsorbed water in the crystalline structure.
The objectives of this study were to: 1) develop a global data base of aeolian features by searching Magellan coverage for possible time-variable wind streaks, 2) analyze the data base to characterize aeolian features and processes on Venus, 3) apply the analysis to assessments of wind patterns near the surface and for comparisons with atmospheric circulation models, 4) analyze shuttle radar data acquired for aeolian features on Earth to determine their radar characteristics, and 5) conduct geological mapping of two quadrangles. Wind, or aeolian, features are observed on Venus and aeolian processes play a role in modifying its surface. Analysis of features resulting from aeolian processes provides insight into characteristics of both the atmosphere and the surface. Wind related features identified on Venus include erosional landforms (yardangs), depositional dune fields, and features resulting from the interaction of the atmosphere and crater ejecta at the time of impact. The most abundant aeolian features are various wind streaks. Their discovery on Venus afforded the opportunity to learn about the interaction of the atmosphere and surface, both for the identification of sediments and in mapping near-surface winds.
The recently selected missions to Venus opened a new era for the exploration of the Earth’s hellish twin sister. One of the key questions that the selected missions to Venus will address is whether the planet is volcanically active. The identification of ongoing volcanic activity on Venus can indeed unveil important clues on the geologic evolution of the planet, also helping us to better understand how volcanic and atmospheric processes work on Earth, especially those related to the climate change produced by greenhouse gases. To fully contextualize the higher resolution datasets to be provided by the future missions to Venus, we need to be able to exploit the wealth of data to be produced in the best possible way. Different types of instruments will indeed perform unprecedent orbiting and in-situ investigations of the surface and subsurface of Venus. To this regard, the Project “Analogs for VENus’s GEologically Recent Surfaces” (AVENGERS) aims to build a comprehensive database of Terrestrial active volcanoes which may act as suitable analogs for identifying ongoing volcanic activity on Venus. To do this, the project AVENGERS will combine the implementation of terrestrial orbiter radar data analysis techniques (i.e., radar interferometry) with infrared and laboratory analyses of lava flow samples from Terrestrial active volcanoes. As a first suitable analog of the Project AVENGERS, we selected Mount Etna in Sicily for a direct comparison with potentially active volcanic structures of Venus, and with Idunn Mons, one of the most promising possibly active volcanoes of Venus. Given its composite nature, Mount Etna offers the opportunity to identify and study multiple types of eruptive products (both effusive and explosive) from the analysis of high-resolution radar images. The frequent eruptions characterizing this volcano will also allow to test techniques of radar interferometry. Moreover, its ease of access facilitates geologic field trips and in-situ investigations with related sample retrieving. Ongoing infrared laboratory analysis on several altered and unaltered samples retrieved by Mount Etna will help to distinguish spectral signatures of fresh vs weathered volcanic deposits.
The author has identified the following significant results. Three major tectonic provinces have been mapped by geologic photointerpretation of ERTS-1 imagery over the Ok Tedi test site. These areas can be characterized as follows: (1) A broad area of low relief and mature topography suggesting a history of relative tectonic stability. (2) A narrow belt of moderate to high relief, broad open folds and prominent linear features. The Mount Fubilan-type porphyry copper deposits and recent volcanic effusive centers occur in this province. (3) A heterogeneous zone of high relief and high drainage density suggestive of relative structural complexity.
The size and temperature, morphology and distribution, variability, possible absorption features, and processes of hot spots on Io are discussed, and an estimate of the global heat flux is made. Size and temperature information is deconvolved to obtain equivalent radius and temperature of hot spots, and simultaneously obtained Voyager thermal and imaging data is used to match hot sources with specific geologic features. In addition to their thermal output, it is possible that hot spots are also characterized by production of various gases and particulate materials; the spectral signature of SO2 has been seen. Origins for relatively stable, low temperature sources, transient high temperature sources, and relatively stable, high-tmperature sources are discussed.
Geologic mapping and stratigraphic analyses of MTM -30247, -35247, and -40247 quadrangles are being used to characterize the Reull Vallis (RV) system and to determine the history of the eastern Hellas region of Mars. Studies of RV examine the roles and timing of volatile-driven erosional and depositional processes and provide constraints on potential associated climatic changes. This study complements earlier investigations of the eastern Hellas region, including regional analyses [1-6], mapping studies of circum-Hellas canyons [7-10], and volcanic studies of Hadriaca and Tyrrhena Paterae [11-13]. Key scientific objectives for these quadrangles include 1) characterization of RV in its "fluvial zone," 2) analysis of channels in the surrounding plains and potential connections to and interactions with RV, 3) examination of young (?), presumably sedimentary plains along RV that embay the surrounding highlands, and 4) determination of the nature of the connection between segments 1 and 2 of RV.
Recently developed CRISM parameters and newly available DTMs are enabling refined characterization of the mineralogy at Mawrth Vallis. A stratigraphy including 5 units is mapped using HRSC DTMs across 100s of kms and using HiRISE DTMs across 100s of meters. Transitions in mineralogic units were characterized using spectral properties and surface morphology. The observations point to an ancient wet and warm geologic record that formed the thick nontronite unit, a period of wet/dry cycling to create acid alteration, followed by leaching or pedogenesis to result in Al-phyllosilicates, and finally a drier, colder climate that left the altered ash in the form of nanophase aluminosilicates, rather than crystalline clays.
Wichita, Kansas is facing a host of climate threats, one being extreme heat that is manifested through the urban heat island (UHI) effect. The uneven distribution of heat risk in Wichita across socioeconomic status is an environmental justice issue. We worked with the City of Wichita to map heat exposure, tree canopy, and heat risk in order to support the City's climate resilience initiatives. To visualize heat exposure, we quantified and mapped average summer heat from 2013–2021 using Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) Land Surface Temperature (LST) and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) night-time LST. To understand tree canopy cover gaps, we created a tree canopy map using 2021 PlanetScope imagery, which identified 20% more trees than the US Geological Survey’s (USGS) National Land Cover Database (NLCD) tree canopy coverage estimates for Wichita. To characterize high risk areas, we used socioeconomic census data and existing social vulnerability indices, highlighting populations that were exposed and vulnerable to extreme heat. The spatial analyses demonstrated that heat exposure is concentrated in the city center and southwest Wichita, areas that are also low in tree canopy coverage. The three census block groups and 17 census tracts with the highest heat risk primarily circle the city center, in areas home to more socially vulnerable populations and near enough to the dense urban center to feel significant urban heat island effects.
Wichita, Kansas is facing a host of climate threats, one being extreme heat that is manifested through the urban heat island (UHI) effect. The uneven distribution of heat risk in Wichita across socioeconomic status is an environmental justice issue. We worked with the City of Wichita to map heat exposure, tree canopy, and heat risk in order to support the City's climate resilience initiatives. To visualize heat exposure, we quantified and mapped average summer heat from 2013–2021 using Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS) Land Surface Temperature (LST) and Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) night-time LST. To understand tree canopy cover gaps, we created a tree canopy map using 2021 PlanetScope imagery, which identified 20% more trees than the US Geological Survey’s (USGS) National Land Cover Database (NLCD) tree canopy coverage estimates for Wichita. To characterize high risk areas, we used socioeconomic census data and existing social vulnerability indices, highlighting populations that were exposed and vulnerable to extreme heat. The spatial analyses demonstrated that heat exposure is concentrated in the city center and southwest Wichita, areas that are also low in tree canopy coverage. The three census block groups and 17 census tracts with the highest heat risk primarily circle the city center, in areas home to more socially vulnerable populations and near enough to the dense urban center to feel significant urban heat island effects.
Imaging radar is an important contributing source of information for a range of geological problems and environments. Airborne SAR and ERS-1 data integrated with other geoscience datasets are being used in an attempt to characterize the crustal fracturing associated with the Sudbury structure. This presentation highlights examples of integrated and composite images aimed at facilitating the interpretation of the Sudbury structure. This work is the result of an ongoing cooperative multidisciplinary SAR study of the basin carried out by the Canada Center for Remote Sensing, Ontario's provincial Remote Sensing Office, the Ontario Geological Survey, and the Geological Survey of Canada.
2001 Mars Odyssey has three experiments. GRS will map the surface elemental composition. MARIE will characterize the Mars radiation environment for risk to humans. THEMIS will map the mineralogy and morphology with a camera and thermal IR imaging. Additional information is contained in the original extended abstract.
Rover missions to the surface of Mars after MER 2003, are likely to be centered around focused geologic field mapping. One objective with high priority in selecting landing sites for these missions will be to characterize the nature, spatial distribution, internal structure, composition, and depositional history of exposed sedimentary layered deposits by visiting a number of distributed outcrops identified previously (and with a high degree of certainty) from orbit. These deposits may contain prebiotic material, even fossil organisms, but their primary value will be to enable an assessment of the planet's climate at the time they were emplaced. High resolution imaging from a mobile rover will enable the detailed study of these deposits over a wide area, their internal structure and mineralogy at distributed localities, and could resolve biologically-derived structures (such as stromatolite-like textures) if they are present. With the addition of a spectrometer, it should be possible to ascertain the presence of carbonates, sulfates, organics, water (liquid, frost, and bound water), as well as a variety of silicate minerals in the context of the collected imagery. Such a mission approach is directly relevant to future exploration of Mars, because it provides the geologic context comparable to what a field geologist visiting a site for the first time would acquire. Rover missions after MER will likely have much better targeting and hazard avoidance landing systems, enabling access to planimetrically-challenged sites of high scientific interest. These vehicles will also likely have greater mobility than MER, capable of driving greater distances in a shorter amount of time. Many scientists and mission planners have realized the need to design a rover whose mobility can be comparable to the dimensions of its 3-sigma landing error ellipse.
The SuperCam instrument on the PerseveranceMars 2020 rover uses a pulsed 1064 nm laser to ablate targets at a distance and conduct laser induced breakdown spectroscopy (LIBS) by analyzing the light from the resulting plasma. SuperCam LIBS spectra are preprocessed to remove ambient light, noise, and the continuum signal present in LIBS observations. Prior to quantification, spectra are masked to remove noisier spectrometer regions andspectra are normalized to minimize signal fluctuations and effectsof target distance.In some cases, the spectra are also standardized or binned prior to quantification. To determine quantitative elemental compositionsof diverse geologic materials at Jezero crater, Mars, we use a suite of 1198 laboratory spectra of 334 well-characterized reference samples. The samples were selected to span a wide range of compositions and include typical silicate rocks, pure minerals (e.g.,silicates, sulfates, carbonates, oxides),more unusual compositions (e.g.,Mn oreand sodalite), andreplicates of the sintered SuperCam calibration targets (SCCTs) onboardthe rover. For each major element (SiO2, TiO2, Al2O3, FeOT, MgO, CaO, Na2O, K2O), the database was subdivided into five“folds” with similar distributions of the element of interest. One fold was held out as an independent test set, and the remaining fourfolds were used to optimize multivariate regression models relating the spectrum to the composition. We considered a variety of models, and selected several for further investigation for each element, based primarily on the root mean squared error of prediction (RMSEP) on the test set, when analyzed at 3m. In cases with several models of comparable performance at 3 m, we incorporated the SCCT performance at different distances to choose the preferred model. Shortly after landing on Mars and collecting initial spectra of geologic targets, we selected one model per element. Subsequently, with additional data from geologic targets, some models were revised to ensure results that are more consistent with geochemical constraints. The calibration discussed here is a snapshot of an ongoing effort to deliver the most accurate chemical compositions with SuperCam LIBS.
Groundwater dependent ecosystems in areas with industrial and military land use are at risk of direct exposure to a wide range of contaminants, including PFAS chemicals. Glaciated terrain often has mixed high and low permeability sediments coupled with groundwater flow-through lake features. These hydrogeologic attributes create highly complex ‘source to seep’ dynamics that make spatiotemporal contaminant transport patterns difficult to predict. We investigated one such system in detail using a suite of heat-tracing and chemical methods. Numerous (n=57) preferential groundwater discharge zones (vertical flux rates ranging 0.2 to 3.2 m/d) were identified across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, adjacent to an Air Force Base with several known PFAS source areas. Surface-water and groundwater samples were collected and analyzed (n=145) for precursors and terminal PFAS compounds between March and September 2022. Samples were collected at identified seeps along the Quashnet River (n=59), from wells upgradient from the stream-wetland system (n= 44), from contributing flow-through kettle lakes (n=8), and at multiple locations along the Quashnet River (n=34). Samples from seeps and wells had measured PFAS concentrations ranging from non-detect to approximate 3,500 ng/L (mean= 1,650 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to emergence at the discharge zones. Groundwater-lake interaction along flowpaths that sourced the sampled seeps was farther supported by significant correlations (p < 0.01) between deuterium excess and %PFAS precursors, and between %PFAS precursors and multiple terminal PFAS compounds (e.g., PFPeS, PFBS, PFHxS). However, some sampled seeps contributing groundwater to the stream-wetland system had much higher total PFAS concentrations (>1000 ng/L) than the upgradient kettle lakes, despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. PFAS compounds and water isotopic composition at sampled multilevel groundwater wells, rivers, lakes, and seeps suggest that a complex mixture of source groundwater and flowpath characteristics are responsible for diverse observed PFAS mixtures at preferential discharge zones across the stream-wetland system. Further, total PFAS loading patterns to the Quashnet River via groundwater discharge remained remarkably similar from winter to summer to fall conditions, despite a regional dry period in late summer 2022 with the upper river channel completely drying. This work addresses gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations in controlling contaminant mass loading in preferential groundwater discharge zones and presents a transferrable field toolkit for efficient characterization of spatially preferential PFAS transport dynamics.