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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

Architecture Options for Navigation in Cislunar Space for Human Landing System Vehicles

As part of architecture studies and insight analysis focused on requirements development into Human Landing System lunar architecture designs, multiple studies are underway to understand the sensitivities and options for achieving high precision landing on the lunar surface. The baseline approach utilizes a combination of multiple sensors to capture autonomous state observations of the lander with respect to the lunar surface. These systems are typically constrained in terms of operational altitudes by parameters such as onboard map size, camera focus, or sensor transmitted power (for altimeter observations). While these sensor suites do enable high precision landing, they are typically very complex and expensive. For a human-rated vehicle, fault detection algorithms are needed in addition to redundant sensors drive additional design complexity. Conversely, for these early missions, mass performance is key, so extended analysis is required to identify numbers of sensors, their ideal placement, and integration algorithms. A key part of this analysis is to help identify key sensor suites and options to help alleviate this design tension. An alternate approach is to take advantage and build out in-situ assets to allow for GPS-like navigation within the lunar regime through the use of navigation references or beacons. This can be achieved through the integration of navigation services into potential relays and pre-placed lunar surface assets. This research focuses on the capability of this infrastructure to support navigation in all areas of cislunar space such as: approach to the moon, in orbit around the moon, and ascent/descent operations to the surface. An augmented state linear covariance analysis (LinCov) and navigation state covariance analysis (NavCov) tools were used to assess a variety of navigation reference locations and how they can support vehicle operations through both understanding of state uncertainties and trajectory dispersions. This research helps to supplement existing studies focused on communication link analysis by providing additional insight into specific vehicle operational scenarios that are tied closely to potential Human Landing System scenarios. Key aspect of this analysis focus on the sensitivity to state knowledge of the references, the accuracy of inter-asset measurements, and placement in support of the various scenarios.

Evan J Anzalone↗

Formation of a Tropopause Cirrus Layer Observed over Florida during CRYSTAL-FACE

On July 13, 2002 a widespread, subvisible tropopause cirrus layer occurred over the Florida region. This cloud was observed in great detail with the NASA Cirrus Regional Study of Tropical Anvils and Cirrus Layers-Florida Area Cirrus Experiment (CRYSTAL-FACE) instrumentation, including in situ measurements with the WB-57 aircraft. In this paper, we use the 13 July cloud as a case study to evaluate the physical processes controlling the formation and evolution of tropopause cirrus layers. Microphysics measurements indicate that ice crystal diameters in the cloud layer ranged from about 7 to 50 microns, and the peak number mode was about 10-25 microns. In situ water vapor and temperature measurements in the cloud indicated supersaturation with respect to ice throughout, with ice saturation ratios as large as 1.8. Even when the ice surface area density was as high as about 500 sq microns/cu cm, ice supersaturations of 20-30% were observed. Trajectory analysis shows that the air sampled near the tropopause on this day generally came from the north and cooled considerably during the previous few days. Examination of infrared satellite imagery along air parcel back trajectories from the WB-57 flight track indicates that the tropopause cloud layer formation was, in general, not simply left over ice from recently generated anvil cirrus. Simulations of cloud formation using time-height curtains of temperature along the trajectory paths show that the cloud could have formed in situ near the tropopause as the air was advected into the south Florida region and cooled to unusually low temperatures. If we assume a high threshold for ice nucleation via homogeneous freezing of aqueous sulfate aerosols, the model reproduces the observed cloud structure, ice crystal size distributions, and ice supersaturation statistics. Inclusion of observed gravity wave temperature perturbations in the simulations is essential to reproduce the observed cloud properties. Without waves, crystal number densities are too low, crystal sizes are too large, and the crystals fall out too fast, leaving very little cloud persisting at the end of the simulations. In the cloud simulations, coincidence of high supersaturations and high surface areas can be produced by either recent nucleation or sedimentation of crystals into supersaturated layers. The agreement between model results and observed supersaturations is improved somewhat if we assume that the steady state relative humidity within cirrus at T<200 K is enhanced by about 30%. The WB-57 measurements and the model results suggest that the cloud layer irreversibly dehydrated air near the tropopause.

Jensen, Eric↗

Nucleation and growth of molybdenum disulfide grown by thermal atomic layer deposition on metal oxides

To enable greater control over thermal atomic layer deposition (ALD) of molybdenum disulfide (MoS 2 ), here we report studies of the reactions of molybdenum hexafluoride (MoF 6 ) and hydrogen sulfide (H 2 S) with metal oxide substrates from nucleation to few-layer films. In situ quartz crystal microbalance experiments performed at 150, 200, and 250 °C revealed temperature-dependent nucleation behavior of the MoF 6 precursor, which is attributed to variations in surface hydroxyl concentration with temperature. In situ Fourier transform infrared spectroscopy coupled with ex situ x-ray photoelectron spectroscopy (XPS) indicated the presence of molybdenum oxide and molybdenum oxyfluoride species during nucleation. Density functional theory calculations additionally support the formation of these species as well as predicted metal oxide to fluoride conversion. Residual gas analysis revealed reaction by-products, and the combined experimental and computational results provided insights into proposed nucleation surface reactions. With additional ALD cycles, Fourier transform infrared spectroscopy indicated steady film growth after ~13 cycles at 200 °C. XPS revealed that higher deposition temperatures resulted in a higher fraction of MoS 2 within the films. Deposition temperature was found to play an important role in film morphology with amorphous films obtained at 200 °C and below, while layered films with vertical platelets were observed at 250 °C. Finally, these results provide an improved understanding of MoS 2 nucleation, which can guide surface preparation for the deposition of few-layer films and advance MoS 2 toward integration into device manufacturing.

36 MATERIALS SCIENCE↗

Measuring Sulfur Isotope Ratios from Solid Samples with the Sample Analysis at Mars Instrument and the Effects of Dead Time Corrections

The Sample Analysis at Mars (SAM) instrument suite comprises the largest science payload on the Mars Science Laboratory (MSL) "Curiosity" rover. SAM will perform chemical and isotopic analysis of volatile compounds from atmospheric and solid samples to address questions pertaining to habitability and geochemical processes on Mars. Sulfur is a key element of interest in this regard, as sulfur compounds have been detected on the Martian surface by both in situ and remote sensing techniques. Their chemical and isotopic composition can belp constrain environmental conditions and mechanisms at the time of formation. A previous study examined the capability of the SAM quadrupole mass spectrometer (QMS) to determine sulfur isotope ratios of SO2 gas from a statistical perspective. Here we discuss the development of a method for determining sulfur isotope ratios with the QMS by sampling SO2 generated from heating of solid sulfate samples in SAM's pyrolysis oven. This analysis, which was performed with the SAM breadboard system, also required development of a novel treatment of the QMS dead time to accommodate the characteristics of an aging detector.

Franz, H. B.↗

Single‐Step Deformation Processing of Ultrathin Lithium Foil and Strip

Abstract Next‐generation, high‐efficiency energy storage and conversion systems require development of lithium metal batteries. But the high cost of production and constraints on thickness of lithium (anode) foils continue to limit adoption for integration into battery cell architectures. Here, a novel lithium anode manufacturing solution is demonstrated – single‐step production of ultrathin gauge foil formats directly from solid ingot. Hybrid cutting‐based deformation processes, involving large plastic strains and strain rates, produce foil to sub‐10 µm thickness, with surface quality even superior to present Li anode processing routes. Energy analysis shows the single‐stage processing is ≈50% more efficient than conventional processing by extrusion‐rolling. Through in situ force measurements and high‐speed imaging of the cutting it also characterize – for the first time – the flow stress of Li to strain rates of 800 sec −1 , revealing a power‐law relationship. The results present a paradigm shift in manufacturing and integration of solid lithium anodes for energy applications.

24 POWER TRANSMISSION AND DISTRIBUTION↗

The ballistic Mars hopper - An alternative Mars mobility concept

The ballistic Mars hopper is proposed as an alternative mobility concept for unmanned exploration of the Martian surface. In the concept, oxygen and carbon monoxide produced from the Martian atmosphere are used as propellants in a rocket propulsion system for an unmanned vehicle on suborbital trajectories between landing sites separated by distances of up to 1000 km. This mobility concept is seen as uniquely capable of allowing both intensive and extensive exploration of the planet using only a single landed vehicle of mass approximately 2000 kg. The technical challenges associated with in-situ propellant production on the surface of Mars are reviewed. A rocket propulsion subsystem capable of using oxygen and carbon monoxide as propellants is described. Finally, results of mission analysis and a hopper landing hazard simulation are reported. It is concluded that an attractive Mars hopper can be developed based on relatively near-term technology.

Sercel, Joel C.↗

Rarefied-continuum gas dynamics transition for SUMS project

This program is to develop an analytic method for reducing SUMS data for the determination of the undisturbed atmosphere conditions ahead of the shuttle along its descending trajectory. It is divided into an internal flow problem, an external flow problem and their matching conditions. Since the existing method of Direct Simulation Monte Carlo (DSMC) failed completely for the internal flow problem, the emphasis is on the internal flow of a highly non-equilibrium, rarefied air through a short tube of a diameter much less than the gaseous mean free path. A two fluid model analysis of this internal flow problem has been developed and studied with typical results illustrated. A computer program for such an analysis and a technical paper published in Lecture Notes in Physics No. 323 (1989) are included as Appendices 3 and 4. A proposal for in situ determination of the surface accommodation coefficients sigma sub t and sigma e is included in Appendix 5 because of their importance in quantitative data reduction. A two fluid formulation for the external flow problem is included as Appendix 6 and a review article for AIAA on Hypersonic propulsion, much dependent on ambient atmospheric density, is also included as Appendix 7.

Cheng, Sin-I↗

Implementation of Coupled Skin Temperature Analysis and Bias Correction in a Global Atmospheric Data Assimilation System

The NASA/NCAR Finite Volume GCM (fvGCM) with the NCAR CLM (Community Land Model) version 2.0 was integrated into the NASA/GMAO Finite Volume Data Assimilation System (fvDAS). A new method was developed for coupled skin temperature assimilation and bias correction where the analysis increment and bias correction term is passed into the CLM2 and considered a forcing term in the solution to the energy balance. For our purposes, the fvDAS CLM2 was run at 1 deg. x 1.25 deg. horizontal resolution with 55 vertical levels. We assimilate the ISCCP-DX (30 km resolution) surface temperature product. The atmospheric analysis was performed 6-hourly, while the skin temperature analysis was performed 3-hourly. The bias correction term, which was updated at the analysis times, was added to the skin temperature tendency equation at every timestep. In this presentation, we focus on the validation of the surface energy budget at the in situ reference sites for the Coordinated Enhanced Observation Period (CEOP). We will concentrate on sites that include independent skin temperature measurements and complete energy budget observations for the month of July 2001. In addition, MODIS skin temperature will be used for validation. Several assimilations were conducted and preliminary results will be presented.

Radakovich, Jon↗

Manufacture of Solar Cells on the Moon

In support of the space exploration initiative a new architecture for the production of solar cells on the lunar surface is devised. The paper discusses experimental data on the fabrication and properties of lunar glass substrates, evaporated lunar regolith thin film (antireflect coatings and insulators), and preliminary attempts in the fabrication of thin film (silicon/II-VI) photovoltaic materials on lunar regolith substrates. A conceptual design for a solar powered robotic rover capable of fabricating solar cells directly on the lunar surface is provided. Technical challenges in the development of such a facility and strategies to alleviate perceived difficulties are discussed. Finally, preliminary cost benefit ratio analysis for different in situ solar cell production scenarios (using exclusively in-situ planetary resources or hybrid) are discussed.

Freundich, Alex↗

Tropical Cyclone Information System

The JPL Tropical Cyclone Infor ma tion System (TCIS) is a Web portal (http://tropicalcyclone.jpl.nasa.gov) that provides researchers with an extensive set of observed hurricane parameters together with large-scale and convection resolving model outputs. It provides a comprehensive set of high-resolution satellite (see figure), airborne, and in-situ observations in both image and data formats. Large-scale datasets depict the surrounding environmental parameters such as SST (Sea Surface Temperature) and aerosol loading. Model outputs and analysis tools are provided to evaluate model performance and compare observations from different platforms. The system pertains to the thermodynamic and microphysical structure of the storm, the air-sea interaction processes, and the larger-scale environment as depicted by ocean heat content and the aerosol loading of the environment. Currently, the TCIS is populated with satellite observations of all tropical cyclones observed globally during 2005. There is a plan to extend the database both forward in time till present as well as backward to 1998. The portal is powered by a MySQL database and an Apache/Tomcat Web server on a Linux system. The interactive graphic user interface is provided by Google Map.

Li, P. Peggy↗

Mars Surface Mobility Leading to Sustainable Exploration

A Mars rocket-propelled hopper concept was evaluated for feasibility through analysis and experiments. The approach set forth in this paper is to combine the use of in-situ resources in a new Mars mobility concept that will greatly enhance the science return while providing the first opportunity towards reducing the risk of incorporating ISRU into the critical path for the highly coveted, but currently unaffordable, sample return mission. Experimental tests were performed on a high-pressure, self-throttling gaseous oxygen/methane propulsion system to simulate a two-burn-with-coast hop profile. Analysis of the trajectory, production plant requirements, and vehicle mass indicates that a small hopper vehicle could hop 2 km every 30 days with an initial mass of less than 60 kg. A larger vehicle can hop 15 km every 30 to 60 days with an initial mass of 300 to 430 kg.

Linne, Diane L.↗

Improving Surface Soil Moisture Estimates in West Africa Through GRACE Data Assimilation

Recent annual trends of precipitation and terrestrial water storage (TWS) in West Africa have been increasing over the past decade. Despite a significant impact of soil moisture on the TWS in West Africa, there is little research on the recent spatial and temporal behaviors of surface soil moisture (SSM) along with the hydrological trends and variability in West Africa. In this study, we assimilate TWS estimates from the Gravity Recovery and Climate Experiment (GRACE) mission into the Catchment Land Surface Model (CLSM) and evaluate its impacts on SSM simulations for the years, 2002–2017. The evaluation is performed using reference datasets: the African Monsoon Multidisciplinary Analysis (AMMA) in situ soil moisture observations, three currently available microwave satellite SSM observations from the Advanced Scatterometer (ASCAT), the Soil Moisture Ocean Salinity (SMOS), and the Soil Moisture Active Passive (SMAP) satellites and also the triple collocation analysis (TCA). Overall, modeled SSM shows good agreement with the reference datasets in terms of the anomaly SSM correlations. However, both modeled and ASCAT SSM are limited in their representation of the drying rates, as observed by ground observations, SMOS and SMAP estimates. Further, GRACE data assimilation results in improved SSM simulations in the humid regions with large annual TWS variability. This study demonstrates the utility of land data assimilation to inform hydrological conditions in West Africa, where soil moisture monitoring is necessary for water resource and livestock management.

West Africa↗

Strategic Map for Exploring the Ocean-World Enceladus

Among the many "ocean worlds" of our solar system, Enceladus appears unique in its combination of astrobiologically relevant, exploration-worthy attributes: extensive liquid-water ocean with high-temperature hydrothermal activity, containing salts and organics expressed predictably into space. The Enceladus south polar plume allows direct access to telltale molecules, ions, isotopes, and potential cytofragments in space. Plume mass spectroscopy and sample return, in situ investigation of surface fallback deposits, direct vent exploration, and eventually oceanographic exploration can all be envisioned. However, building consensus to fund such ambitious exploration hinges on acquiring key new data. A roadmap is essential. It could start with cost-capped onramps: 1) flythrough analysis of the plume, following up on Cassini measurements with modern instruments; 2) sample return of plume material for analysis on Earth. A methodical mission sequence in which each step depends on emergent results from prior missions would push in situ oceanographic exploration into the second half of this century. Even for this scenario, prioritization by the next planetary Decadal Survey would be pivotal.

Cassini↗

Human Mars Surface Science Operations

Human missions to the surface of Mars will have challenging science operations. This paper will explore some of those challenges, based on science operations considerations as part of more general operational concepts being developed by NASA's Human Spaceflight Architecture (HAT) Mars Destination Operations Team (DOT). The HAT Mars DOT has been developing comprehensive surface operations concepts with an initial emphasis on a multi-phased mission that includes a 500-day surface stay. This paper will address crew science activities, operational details and potential architectural and system implications in the areas of (a) traverse planning and execution, (b) sample acquisition and sample handling, (c) in-situ science analysis, and (d) planetary protection. Three cross-cutting themes will also be explored in this paper: (a) contamination control, (b) low-latency telerobotic science, and (c) crew autonomy. The present traverses under consideration are based on the report, Planning for the Scientific Exploration of Mars by Humans1, by the Mars Exploration Planning and Analysis Group (MEPAG) Human Exploration of Mars-Science Analysis Group (HEM-SAG). The traverses are ambitious and the role of science in those traverses is a key component that will be discussed in this paper. The process of obtaining, handling, and analyzing samples will be an important part of ensuring acceptable science return. Meeting planetary protection protocols will be a key challenge and this paper will explore operational strategies and system designs to meet the challenges of planetary protection, particularly with respect to the exploration of "special regions." A significant challenge for Mars surface science operations with crew is preserving science sample integrity in what will likely be an uncertain environment. Crewed mission surface assets -- such as habitats, spacesuits, and pressurized rovers -- could be a significant source of contamination due to venting, out-gassing and cleanliness levels associated with crew presence. Low-latency telerobotic science operations has the potential to address a number of contamination control and planetary protection issues and will be explored in this paper. Crew autonomy is another key cross-cutting challenge regarding Mars surface science operations, because the communications delay between earth and Mars could as high as 20 minutes one way, likely requiring the crew to perform many science tasks without direct timely intervention from ground support on earth. Striking the operational balance between crew autonomy and earth support will be a key challenge that this paper will address.

Bobskill, Marianne R.↗

A Remote Sensing Technique to Upscale Methane Emission Flux in a Subtropical Peatland

Abstract Quantification of methane (CH 4 ) gas emission from peat is critical to understand CH 4 budget from natural wetlands under a climate warming scenario. Previous studies have focused on prediction and mapping of CH 4 emission flux using process‐based models, while application of statistical‐empirical models for upscaling spatially sparse in situ measurements is scarce. In this study, we developed an empirical remote sensing upscaling approach to estimate CH 4 emission flux in the Everglades using limited in situ point‐based CH 4 emission flux measurements and Landsat data during 2013–2018. We spatially and temporally linked in situ data with Landsat surface reflectance based on temporally composite data sets and developed an object‐based machine learning framework to model and map CH 4 emission flux. An ensemble analysis of two machine learning models, k ‐Nearest Neighbor ( k ‐NN) and Support Vector Machine (SVM), shows that the upscaling approach is promising for predicting CH 4 emission flux with a R 2 of 0.65 and 0.87 based on a fivefold cross‐validation for a dry season and wet season estimation, respectively. We generated emission flux map products that successfully revealed the spatial and temporal heterogeneity of CH 4 emission within the dominant freshwater marsh ecosystem in the Everglades. We conclude that Landsat is promising for upscaling and monitoring CH 4 emission flux and reducing the uncertainty in emission estimates from wetlands.

Zhang, Caiyun↗

In Situ Imaging of Faujasite Surface Growth Reveals Unique Pathways of Zeolite Crystallization

Zeolite crystallization occurs by complex processes involving a variety of possible mechanisms. The sol gel media used to prepare zeolites leads to heterogeneous mixtures of solution and solid states with diverse solute species. At later stages of zeolite synthesis when growth occurs predominantly from solution, classical two-dimensional nucleation and spreading of layers on crystal surfaces via the addition of soluble species is the dominant pathway. At earlier stages, these processes occur in parallel with nonclassical pathways involving crystallization by particle attachment (CPA). The relative roles of solution- and solid-state species in zeolite crystallization have been a subject of debate. Here, in this work, we investigate the growth mechanism of a commercially relevant zeolite, faujasite (FAU). In situ atomic force microscopy (AFM) measurements reveal that supernatant solutions extracted from a conventional FAU synthesis at various times do not result in growth, indicating that FAU growth predominantly occurs from the solid state through a disorder-to-order transition of amorphous precursors. Elemental analysis shows that supernatant solutions are significantly more siliceous than both the original growth mixture and the FAU zeolite product; however, in situ AFM studies using a dilute clear solution with a lower Si/Al ratio revealed three-dimensional growth of surfaces that is distinct from layer-by-layer and CPA pathways. This unique mechanism of growth differs from those observed in studies of other zeolites. Given that relatively few zeolite frameworks have been the subject of mechanistic investigation by in situ techniques, these observations of FAU crystallization raise the question whether its growth pathway is characteristic of other zeolite structures.

36 MATERIALS SCIENCE↗

Surface Analysis and Hydrogen Permation Measurements for Super-Permeating Membrane Materials

In this report, we summarize preliminary surface characterization results for Nb surfaces, using low energy ion scattering, direct recoil spectrometry, and Auger electron spectroscopy. While most surface analysis tools cannot detect hydrogen, the low energy ion beam techniques described here are among the few techniques that are directly sensitive to it. For this study, we examined chemisorption using both molecular and atomic hydrogen (using an heated tungsten capillary to dissociate the hydrogen.) To complement these results, we have been performing ex-situ spectroscopic ellipsometry as a means of detecting the surface oxide.

36 MATERIALS SCIENCE↗

Assessment of Clear Sky Radiative Forcing in the Caribbean Region Using an Aerosol Dispersion Model and Ground Radiometry During Puerto Rico Dust Experiment

This study investigates the surface and top of the atmosphere solar radiative forcing by long-range transport of Saharan dust. The calculations of radiative forcing are based on measurements collected in the Puerto Rico Dust Experiment (PRIDE) carried out during July, 2000. The purpose of the experiment was the characterization of the Saharan dust plume, which frequently reaches the Caribbean region during the summer. The experiment involved the use of three approaches to study the plume: space and ground based remote sensing, airborne and ground based in-situ measurements and aerosol dispersion modeling. The diversity of measuring platforms provides an excellent opportunity for determination of the direct effect of dust on the clear sky radiative forcing. Specifically, comparisons of heating rates, surface and TOA fluxes derived from the Navy global aerosol dispersion model NAAPS (NRL Aerosol Analysis and Prediction System) and actual measurements of fluxes from ground and space based platforms are shown. In addition, the direct effect of dust on the clear sky radiative forcing is modeled. The extent and time of evolution of the radiative properties of the plume are computed with the aerosol concentrations modeled by NAAPS. Standard aerosol parameterizations, as well as in-situ composition and size distributions measured during PRIDE, are utilized to compute the aerosol optical depth, single scattering albedo and asymmetry factor. Radiative transfer computations are done with an in-house modified spectral radiative transfer code (Fu-Liou). The code includes gas absorption and cloud particles (ice and liquid phase) and it allows the input of meteorological data. The code was modified to include modules for the aerosols contribution to the calculated fluxes. This comparison study helps to narrow the current uncertainty in the dust direct radiative forcing, as recently reported in the 2001 IPCC assessment.

Gasso, Santiago↗