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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Variations in ion composition at middle and low latitudes from Isis 2 satellite

The paper describes absolute ion concentration measurements with an ion mass spectrometer on the Isis 2 satellite and discusses features of the ion composition near a fixed altitude of 1400 km as they relate to longitudinal and latitudinal variations at low and middle latitudes. Two distinct classes of daytime ionospheric behavior are observed. The data obtained confirm the strong solar-geomagnetic seasonal control over the topside ion distribution. The new phenomena associated with the observed longitudinal dependence of the ion composition at 1400 km demonstrate the existence of complex physical processes which take place in this region of the ionosphere.

Breig, E. L.↗
DOE OSTI2021

Toward white light emission from plasmonic-luminescent hybrid nanostructures

We study the light emission of plasmonic-luminescent hybrid nanostructures consisting of Ag nanoparticles (NPs) embedded in europium oxide (EuO X ). The Ag NPs present a bidimensional organization in the nanostructures and they optically behave as oblate spheroids. The photoluminescence (PL) spectral response of the nanostructures evolves from a narrow red emission characteristic of Eu 3+ ions in absence of Ag NPs to a broad blue-green emission band associated with Eu 2+ ions when the layer of Ag NPs is present. This behavior is not related to a change in the Eu 2+ /Eu 3+ ratio, which is verified by compositional analysis. Instead, a detailed investigation of the PL emission of the nanostructures suggests that the coupling of the Ag NPs to the Eu 2+ ions present in the EuO X layer, which manifests itself in an efficient sensitization of these ions, enhances their broad visible emission. In particular, the longitudinal mode of the Ag NPs surface plasmon is considered to be responsible for the efficient energy transfer for the non-normal incidence excitation PL configuration used. Finally, the use of a capping amorphous Al 2 O 3 layer allows improving the robustness of hybrid nanostructures and further enhances their PL emission. These findings provide a new path to actively control the selective excitation of Eu 2+ and Eu 3+ ions via a controlled coupling with the surface plasmon resonance modes of the Ag NPs and points to these nanostructures as promising building blocks for the development of integrable white light sources.

36 MATERIALS SCIENCE↗
NASA NTRS1995

Plasmas in the outer heliosphere

We review the observed properties of the solar wind in the outer heliosphere, including observations from Voyager and the Pioneers, as well as from inner heliospheric probes as appropriate. These observations are crucial to modeling of the heliosphere and its interactions with the interstellar medium, since the wind ram pressure and its temporal variations are important in understanding the distance to the termination shock and heliopause and how those boundaries might vary in time. We focus on results since Solar Wind 7. Among the issues we will discuss are: (1) the time scales for and statistical properties of variations in the ram pressure in the outer heliosphere, and how those variations might affect the morphology of the heliospheric/interstellar medium interface; (2) the question of possible solar wind slowing in the outer heliosphere due to the pick-up of interstellar ions; (3) the issue of whether there is bulk heating of the solar wind associated either with interstellar ion pick-up or with continued heating due to stream-stream interactions; (4) evidence for latitudinal variations in solar wind properties; and (5) the 1.3 year periodicities apparent in the outer heliosphere, and the close correspondence with similar variations seen with inner heliospheric probes.

Belcher, J. W.↗
NASA NTRS2011

Preliminary Performance of Lithium-ion Cell Designs for Ares I Upper Stage Applications

NASA's Ares I Crew Launch Vehicle (CLV) baselined lithium-ion technology for the Upper Stage (US). Under this effort, the NASA Glenn Research Center investigated three different aerospace lithium-ion cell suppliers to assess the performance of the various lithium-ion cell designs under acceptance and characterization testing. This paper describes the overall testing approaches associated with lithium-ion cells, their ampere-hour capacity as a function of temperature and discharge rates, as well as their performance limitations for use on the Ares I US vehicle.

Miller, Thomas B.↗
NASA NTRS2006

A Lunar-Based Spacecraft Propulsion Concept - The Ion Beam Sail

We describe a concept for spacecraft propulsion by means of an energetic ion beam, with the ion source fixed at the spacecraft starting point (e.g., a lunar-based ion beam generator) and not onboard the vessel. This approach avoids the substantial mass penalty associated with the onboard ion source and power supply hardware, and vastly more energetic ion beam systems can be entertained. We estimate the ion beam parameters required for various scenarios, and consider some of the constraints limiting the concept. We find that the "ion beam sail' approach can be viable and attractive for journey distances not too great, for example within the Earth-Moon system, and could potentially provide support for journeys to the inner planets.

Brown, Ian G.↗
NASA NTRSDate not supplied

Key Observations and Discoveries from the Vector Electric Field Investigation on the C/NOFS Satellite

Launched in 2008 and operating for 7.5 years, the Air Force Communication /Navigation Outage Forecasting System (C/NOFS) satellite included the Vector Electric Field Investigation (VEFI) designed and built at NASA’s Goddard Space Flight Center. VEFI successfully met its objectives: 1) investigate the role of ambient electric fields in initiating nighttime density depletions and turbulence; 2) determine the quasi-DC electric fields associated with abrupt density depletions, and 3) quantify the spectrum of the irregularities associated with density depletions, providing many key observations and discoveries including: -- Global (low latitude) vector DC electric fields at 16 s/sec revealing variations with local time, longitude, and season between extremely low and moderate solar activity-- Reversed zonal E x B drifts below the F-region ledge at sunset and simultaneous observations of large scale Kelvin-Helmholtz instabilities as seeds of spread-F -- Large expanses of quasi-coherent kilometer-scale vector wave observations (electric field and density) below 450 km and their discovery as a source of scintillations using the C/NOFS GPS -- Reversed zonal DC electric fields and simultaneous observations of afternoon counter electrojet-- Enhanced zonal DC electric fields at sunrise and full vector plasma flow continuity at the terminator-- Vector electric field and density irregularities extending to meter-scales within equatorial plasma depletions -- Intense electric field structure within the equatorial ionosphere at night in the absence of density depletions -- First observations of the westward equatorial electrojet in post-midnight ionosphere and possible association with downward meridional drifts-- Spaceborne Dst observations and implications for ring current asymmetries-- Vector electric and magnetic field Poynting flux within depletions and TIDs-- Measurements of ionospheric reflectance and Alfvenic waves associated with TIDs-- Observations of Alfven resonators -- ULF magnetic field structure within the nightime equatorial ionosphere-- Discovery of Schumman resonances in space and implications of ELF radiowave propagation-- Vector observations of 50-60 Hz powerline radiation without harmonics-- Ion cyclotron resonance absorption lines associated with ELF hiss and the identification of ambient ions-- Parallel electric fields associated with lower hybrid waves driven by thunderstorm lightning-related sferics-- Discovery of Z-mode radiation in the equatorial ionosphere including its associated with density depletions-- Optical lightning detector waveforms and electric field sferics observed up to altitudes of 800 km

Robert F Pfaff↗
NASA NTRS1974

In-situ observations of irregular ionospheric structure associated with the plasmapause

Additional studies of the ion composition results obtained from the OGO-6 satellite support earlier observations of irregularities in the distribution of H(+) and He(+) within the light ion trough near L = 4, which has been associated with the plasmapause. These irregularities are in the form of sub-troughs superimposed upon the major midlatitude decrease of the light ions. In the sub-troughs, ionization depletions and recoveries of as much as an order of magnitude are observed within a few degrees of latitude, usually exhibited in a pattern which changes significantly with longitude as the earth rotates beneath the relatively fixed satellite orbit. The location and properties exhibited by these sub-troughs appear to be consistent with the concept of a plasmasphere distortion in the form of 'plasmatails' resulting from the combined effects of magnetospheric convection plus corotation.

Taylor, H. A., Jr.↗
NASA NTRS1979

Association of low-frequency waves with suprathermal ions in the upstream solar wind

Observations obtained upstream of the earth's bowshock with the LASL/MPI plasma instruments and the UCLA magnetometers on ISEE-1 and 2 have revealed a striking relationship between the presence of low-frequency fluctuations in solar wind density and field strength and the different types of distribution functions of upstream ions. Waves are absent when the ions have the beamlike distribution of the 'reflected' ions. Large-amplitude waves are present only in conjunction with the 'diffuse' ions, which are characterized by flat energy spectra and broad angular distributions. The waves are largely compressive, showing very good correlation between oscillations in magnetic field strength and plasma density.

Paschmann, G.↗
NASA NTRS2004

Lithium-Ion rechargeable batteries on Mars Rover

NASA's Mars Rovers, Spirit and Opportunity, have been roving on the surface of Mars, capturing impressive images of its terrain and analyzing the drillings from Martian rocks, to answer the ever -puzzling questions of life beyond Earth and origin of our planets. These rovers are being enabled by an advanced rechargeable battery system, lithium-ion, for the first time on a space mission of this scale, for keeping the rover electronics warm, and for supporting nighttime experimentation and communications. These rover Li-ion batteries are characterized by their unique low temperature capability, in addition to the usual advantages associated with Li-ion chemistry in terms of mass, volume and energy efficiency. To enable a rapid insertion of this advanced Li-ion chemistry into flight missions, we have performed several performance assessment studies on several prototype cells over the last few years. These tests mainly focused primarily on the long-term performance characteristics, such as cycling and storage, as described in our companion paper. In addition, various tests have been performed on MER cells and engineering and proto flight batteries; under conditions relevant to these missions. For example, we have examined the performance of the cells in: a) an inverted orientation, as during integration and launch, and b) conditions of low rate discharge, between 3.0-2.5 V to support the mission clock. Likewise, we have determined the impedance of the proto-flight Rover battery assembly unit in detail, with a view to asses whether a current-limiting resistor would be unduly stressed, in the event of a shorting induced by a failed pyro. In this paper we will describe these studies in detail, as well as the performance of Li-ion batteries in Spirit and Opportunity rovers, during cruise and on Mars.

2003 Mars Exploration Rover (MER)↗
NASA NTRS1988

Alfven ion-cyclotron heating of ionospheric O(+) ions

Transversely heated ionospheric ions, in particular O(+) ions, are often observed flowing upward along auroral field lines. Currents observed in association with the transversely heated ions can drive shear Alfven waves and electrostatic ion-cyclotron waves unstable which can, in turn, be resonantly absorbed by the ions to produce the heating. Particle simulations are used to examine self-consistently the excitation of these waves and the associated heating. It is shown that the growth of the electrostatic ion-cyclotron waves quickly becomes suppressed as the ions become heated and the dominant wave fields are those of the shear Alfven wave. The resultant transverse ion heating is larger and faster than that produced by solely electrostatic ion-cyclotron wave heating. Due to trapping of ions by the shear Alfven wave, the temperature of the O(+) ions remains comparable to that of the H(+) ions.

Winglee, R. M.↗
NASA NTRS1987

On the role of the quasi-parallel bow shock in ion pickup - A lesson from Venus?

Previous observations at Venus show convincing evidence of planetary O(+) ion pickup by the largescale motional -V x B electric field in the magnetosheath when the interplanetary magnetic field is perpendicular to the solar wind flow. However, the presence of magnetic field fluctuations in the magnetosheath downstream from the quasi-parallel bow shock should allow pickup to occur even when the upstream magnetic field B and plasma velocity V are practically coaligned. Single-particle calculations are used to demonstrate the convecting magnetic field fluctuations similar to those observed in the Venus magnetosheath when the subsolar bow shock is quasi-parallel can efficiently accelerate cold planetary ions by means of the electric field associated with their transverse components. This ion pickup process, which is characterized by a spatial dependence determined by the bow shock shape and the orientation of the upstream magnetic field, is likely also to occur at Mars and may be effective at comets.

Luhmann, J. G.↗
DOE OSTI2023

In Situ Structural Observation of a Substrate- and Peroxide-Bound High-Spin Ferric-Hydroperoxo Intermediate in the P450 Enzyme CYP121

The P450 enzyme CYP121 from Mycobacterium tuberculosis catalyzes a carbon–carbon (C–C) bond coupling cyclization of the dityrosine substrate containing a diketopiperazine ring, cyclo(l-tyrosine-l-tyrosine) (cYY). An unusual high-spin (S = 5/2) ferric intermediate maximizes its population in less than 5 ms in the rapid freeze-quenching study of CYP121 during the shunt reaction with peracetic acid or hydrogen peroxide in acetic acid solution. Here, we show that this intermediate can also be observed in the crystalline state by EPR spectroscopy. By developing an on-demand-rapid-mixing method for time-resolved serial femtosecond crystallography with X-ray free-electron laser (tr-SFX-XFEL) technology covering the millisecond time domain and without freezing, we structurally monitored the reaction in situ at room temperature. After a 200 ms peracetic acid reaction with the cocrystallized enzyme–substrate microcrystal slurry, a ferric-hydroperoxo intermediate is observed, and its structure is determined at 1.85 Å resolution. The structure shows a hydroperoxyl ligand between the heme and the native substrate, cYY. The oxygen atoms of the hydroperoxo are 2.5 and 3.2 Å from the iron ion. The end-on binding ligand adopts a near-side-on geometry and is weakly associated with the iron ion, causing the unusual high-spin state. This compound 0 intermediate, spectroscopically and structurally observed during the catalytic shunt pathway, reveals a unique binding mode that deviates from the end-on compound 0 intermediates in other heme enzymes. The hydroperoxyl ligand is only 2.9 Å from the bound cYY, suggesting an active oxidant role of the intermediate for direct substrate oxidation in the nonhydroxylation C–C bond coupling chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Chemical composition, coordination, and stability of Ca–organic associations in the presence of dissolving calcite

Environmental biotic and abiotic factors and soil physical, mineralogical, and chemical properties control the chemical composition of soil organic matter (SOM). Particularly, soil mineralogy and the presence of multivalent cations affect SOM labile fraction composition, stability, and environmental persistence. The persistence of SOM in aridic or limestone deposit derived soils, i.e., calcareous soils, has been partially attributed to SOM stabilization through adsorption or inclusion into the calcite mineral structure. Recently, however, it was shown that Ca(aq) released during calcite dissolution formed aqueous Ca–organic associations with OM components, which were unbound to mineral surface sites. This study investigates the structure, composition, and coordination of these associations by characterizing lyophilized Ca–organic containing solutions with spectromicroscopy [Scanning Transmission X-ray Microscopy (STXM)] and with a nanoimaging chemical probe [Infrared scattering-Scanning Nearfield Optical Microscopy (IR s-SNOM)]. Chemical stability of Ca–organic associations is furthermore determined with pyrolysis mass spectrometry analysis. The results demonstrate that Ca–organic associations are formed in the presence of dissolving calcite and OM components relevant to soil chemistry, i.e., lignin and amino acids. This study further reveals a spatial homogeneity of solution-derived (bi) carbonate in Ca–organic associations indicating for the first time that an inorganic anion, such as (bi)carbonate, may be part of these associations. Most likely, Ca ions are bound to both the (bi)carbonate and the organic components. These Ca (bi)carbonate–organic associations seem to have greater chemical stability than the pristine organic mixtures and, possibly, a higher environmental stability and reduced mineralization rate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Ion-beam radiation-induced Eshelby transformations: The mean and variance in hydrostatic and shear residual stresses

Ion beam plays a pivotal role in ion implantations and the fabrication of nanostructures. However, there lacks a quantitative model to describe the residual stresses associated with the ion-beam radiation. Radiation-induced residual stress/transformation strain have been mostly recognized in the hydrostatic sub strain space. Here, in this study, we use molecular dynamics (MD) simulations to show that the response of a material to irradiation is generally anisotropic that depends on the ion-beam direction, and should be described using tensorial quantities. We demonstrate that accelerator-based ion beam irradiation, combined with the intrinsic lattice anisotropy and externally induced anisotropy (such as anisotropic mechanical loadings), causes radiation-actuated shear transformation strains in addition to hydrostatic expansion. We map out these complex correlations for several materials. Radiation-induced defects are shown to be responsible for residual shear stresses in the manner of Eshelby inclusion transformation. We propose such tensorial response model should be considered for accurate nanoscale fabrication using ion-beam irradiation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Ion Pairing and Redissociaton in Low-Permittivity Electrolytes for Multivalent Battery Applications

Detailed speciation of electrolytes as a function of chemical system and concentration provides the foundation for understanding bulk transport as well as possible decomposition mechanisms. In particular, multivalent electrolytes have shown a strong coupling between anodic stability and solvation structure. Furthermore, solvents that are found to exhibit reasonable stability against alkaline-earth metals generally exhibit low permittivity, which typically increases the complexity of the electrolyte species. To improve our understanding of ionic population and associated transport in these important classes of electrolytes, the speciation of Mg(TFSI)2 in monoglyme and diglyme systems is studied via a multiscale thermodynamic model using first-principles calculations for ion association and molecular dynamics simulations for dielectric properties. The results are then compared to Raman and dielectric relaxation spectroscopies, which independently confirm the modeling insights. We find that the significant presence of free ions in the low-permittivity glymes in the concentration range from 0.02 to 0.6 M is well-explained by the low-permittivity redissociation hypothesis. Here, salt speciation is largely dictated by long-range electrostatics, which includes permittivity increases due to polar contact ion pairs. The present results suggest that other low-permittivity multivalent electrolytes may also reach high conductivities as a result of redissociation.

25 ENERGY STORAGE↗
NASA NTRS1999

What We Don't Understand About Ion Acceleration Flares

There are now strong associations between the (3)He-rich, Fe-rich ions in "impulsive" solar energetic particle (SEP) events and the similar abundances derived from gamma-ray lines from flares. Compact flares, where wave energy can predominate, are ideal sites for the study of wave-particle physics. Yet there are nagging questions about the magnetic geometry, the relation between ions that escape and those that interact, and the relative roles of cascading Alfven waves and the EMIC waves required to enhance He-3. There are also questions about the relative timing of ion and electron acceleration and of heating; these relate to the variation of ionization states before and during acceleration and during transport out of the corona. We can construct a model that addresses many of these issues, but problems do remain. Our greatest lack is realistic theoretical simulations of element abundances, spectra, and their variations. By contrast, we now have a much better idea of the acceleration at CME-driven shock waves in the rare but large "gradual" SEP events, largely because of their slow temporal evolution and great spatial extent.

Reames, Donald V.↗