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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamic maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of Region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicon carbide is the single stable solid phase in Region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4, and SiH. Analysis of the kinetics of reaction for Region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to Regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗
NASA NTRS1990

Hydrogen-silicon carbide interactions

A study of the thermochemistry and kinetics of hydrogen environmental attack of silicon carbide was conducted for temperatures in the range from 1100 C to 1400 C. Thermodynamics maps based on the parameters of pressure and oxygen/moisture content were constructed. With increasing moisture levels, four distinct regions of attack were identified. Each region is defined by the thermodynamically stable solid phases. The theoretically stable solid phases of region 1 are silicon carbide and silicon. Experimental evidence is provided to support this thermodynamic prediction. Silicone carbide is the single stable solid phase in region 2. Active attack of the silicon carbide in this region occurs by the formation of gases of SiO, CO, CH4, SiH4 and SiH. Analyses of the kinetics of reaction for region 2 at 1300 C show the attack of the silicon carbide to be controlled by gas phase diffusion of H2O to the sample. Silicon carbide and silica are the stable phases common to regions 3 and 4. These two regions are characterized by the passive oxidation of silicon carbide and formation of a protective silica layer.

Eckel, Andrew J.↗
NASA NTRS1988

On the prediction of equilibrium states in homogeneous turbulence

A comparison of several commonly used turbulence models (including the Kappa-epsilon and two second-order closures) is made for the test problem of homogeneous turbulent shear flow in a rotating frame. The time evolution of the turbulent kinetic energy and dissipation rate is calculated for a variety of models and comparisons are made with previously published experiments and numerical simulations. Particular emphasis is placed on examining the ability of each model to accurately predict equilibruim states for a range of the parameter Omega/S (the ratio of the rotation rate to the shear rate). It is found that none of the commonly used second-order closure models yield substantially improved predictions for the time evolution of the turbulent kinetic energy and dissipation rate over the somewhat defective results obtained from the simpler Kappa-epsilon model for the turbulent flow regime. There is also a problem with the equilibrium states predicted by the various models. For example, the Kappa-epsilon model erroneously yields equilibrium states that are independent of Omega/S while the Launder, Reece, and Rodi model predicts a flow relaminarization when Omega/S is greater than 0.39 - a result which is contrary to numerical simulations and linear spectral analysis which indicate flow instability for at least the range 0 less than or = Omega/S less than or = 0.5. The physical implications of the results obtained from the various turbulence models considered here are discussed in detail along with proposals to remedy the deficiencies based on a dynamical systems approach.

Speziale, Charles G.↗
NASA NTRS1988

On the prediction of equilibrium states in homogeneous turbulence

A comparison of several commonly used turbulence models (including the Kappa-epsilon and two second-order closures) is made for the test problem of homogeneous turbulent shear flow in a rotating frame. The time evolution of the turbulent kinetic energy and dissipation rate is calculated for a variety of models and comparisons are made with previously published experiments and numerical simulations. Particular emphasis is placed on examining the ability of each model to accurately predict equilibrium states for a range of the parameter Omega/S (the ratio of the rotation rate to the shear rate). It is found that none of the commonly used second-order closure models yield substantially improved predictions for the time evolution of the turbulent kinetic energy and dissipation rate over the somewhat defective results obtained from the simpler Kappa-epsilon model for the turbulent flow regime. There is also a problem with the equilibrium states predicted by the various models. For example, the Kappa-epsilon model erroneously yields equilibrium states that are independent of Omega/S while the Launder, Reece, and Rodi model predicts a flow relaminarization when Omega/S is greater than 0.39 - a result which is contrary to numerical simulations and linear spectral analysis which indicate flow instability for at least the range 0 less than or = Omega/S less than or = 0.5. The physical implications of the results obtained from the various turbulence models considered here are discussed in detail along with proposals to remedy the deficiencies based on a dynamical systems approach.

Speziale, C. G.↗
NASA NTRS2002

Sensitivities of Tropical Cyclones to Surface Friction and the Coriolis Parameter in a 2-D Cloud-Resolving Model

The sensitivities to surface friction and the Coriolis parameter in tropical cyclogenesis are studied using an axisymmetric version of the Goddard cloud ensemble model. Our experiments demonstrate that tropical cyclogenesis can still occur without surface friction. However, the resulting tropical cyclone has very unrealistic structure. Surface friction plays an important role of giving the tropical cyclones their observed smaller size and diminished intensity. Sensitivity of the cyclogenesis process to surface friction. in terms of kinetic energy growth, has different signs in different phases of the tropical cyclone. Contrary to the notion of Ekman pumping efficiency, which implies a preference for the highest Coriolis parameter in the growth rate if all other parameters are unchanged, our experiments show no such preference.

Chao, Winston C.↗
NASA NTRS1977

Sampling errors in the measurement of rain and hail parameters

Attention is given to a general derivation of the fractional standard deviation (FSD) of any integrated property X such that X(D) = cD to the n. This work extends that of Joss and Waldvogel (1969). The equation is applicable to measuring integrated properties of cloud, rain or hail populations (such as water content, precipitation rate, kinetic energy, or radar reflectivity) which are subject to statistical sampling errors due to the Poisson distributed fluctuations of particles sampled in each particle size interval and the weighted sum of the associated variances in proportion to their contribution to the integral parameter to be measured. Universal curves are presented which are applicable to the exponential size distribution permitting FSD estimation of any parameters from n = 0 to n = 6. The equations and curves also permit corrections for finite upper limits in the size spectrum and a realistic fall speed law.

Gertzman, H. S.↗
NASA NTRS1972

Kinetic theory analysis of rarefied gas flow through finite length slots

An analytic study is made of the flow a rarefied monatomic gas through a two dimensional slot. The parameters of the problem are the ratios of downstream to upstream pressures, the Knudsen number at the high pressure end (based on slot half width) and the length to slot half width ratio. A moment method of solution is used by assuming a discontinuous distribution function consisting of four Maxwellians split equally in angular space. Numerical solutions are obtained for the resulting equations. The characteristics of the transition regime are portrayed. The solutions in the free molecule limit are systematically lower than the results obtained in that limit by more accurate numerical methods.

Raghuraman, P.↗
NASA NTRS2020

Chemical kinetics and photochemical data for use in atmospheric studies; evaluation number 19

This is the nineteenth in a series of evaluated sets of rate constants, photochemical cross sections,heterogeneous parameters, and thermochemical parameters compiled by the NASA Panel for Data Evaluation.The data are used primarily to model stratospheric and upper tropospheric processes, with particularemphasis on the ozone layer and its possible perturbation by anthropogenic and natural phenomena.The evaluation is available in electronic form from the following Internet URL: http://jpldataeval.jpl.nasa.gov

Wine, P.H.↗
NASA NTRS2003

MHD Turbulence at Moderate Magnetic Reynolds Number

In the present article we will consider the decay of MHD turbulence under the influence of a strong external magnetic field at moderate magnetic Reynolds numbers. Typical values of R(sub m) that are considered here range from R(sub m) approx. 0.1 to R(sub m) approx. 20. As a comparison, the initial kinetic Reynolds number common to all our simulations is Re(sub L) = 199. This means that the range of Prandtl numbers explored is 5 x 10(exp -4) to 10(exp -1). Our motivation is mainly to exhibit how the transition from the QS approximation to FMHD occurs. At the lowest values of R(sub m) studied here, the QS approximation is shown to model the flow faithfully. However, for the higher values of R(sub m) considered, it is clearly inadequate but can be replaced by another approximation which will be referred to as the Quasi-Linear (QL) approximation. Another objective of the present study is to describe how variations in the magnetic Reynolds number (while maintaining all other parameters constant) affect the dynamics of the flow. This complements past studies where variations in either the strength of the external magnetic field or the kinetic Reynolds number were considered. This article is organized as follows. In section 2 we recall the definition of the quasi-static approximation. Section 3 is devoted to the description of the numerical experiments performed using the quasi-static approximation and full MHD. In section 4 we describe the quasi-linear approximation and test it numerically against full MHD. A concluding summary is given in section 5.

Knaepen, B.↗
NASA NTRS1974

Model calculations for diffuse molecular clouds

A local steady-state isobaric model of the interstellar clouds is developed and applied to the OAO-3 observations. The model allows for cooling by C II fine-structure transitions and for inhomogeneities resulting from attenuations in the external radiations which heat the cloud constituents. Factors affecting the thermal properties of the clouds are emphasized; these include H and H2 balance, interstellar grain heating, electron density, and calcium equilibrium. The thermodynamic consequences of the attenuation of the ultraviolet interstellar radiation field are studied. The effect of varying the most important parameters and their allowed ranges is considered. Results indicate that the model is capable of reproducing the H2 fractional abundances and kinetic temperatures observed by OAO-3.

Glassgold, A. E.↗
NASA NTRS1975

Theory and experiment of low transitions in CO discharge lasers

A self-consistent model which couples the kinetics of the electrons and heavy particles with the optical and fluid dynamic processes has been employed to identify the various parameters and explain the mechanism responsible for producing low-lying transitions in slow-flowing CO lasers. Both theory and experiment indicate that low-lying transitions can be achieved at low temperatures for low pressures (or low-flow rates) together with high partial pressures of He and N2. The role of N2 has been identified as an additive responsible for reducing the electron temperature to a range where the transfer of electrical power to the lower vibrational modes of CO is optimum.

Sidney, B.↗
NASA NTRS1984

A mathematical model for the iron/chromium redox battery

A mathematical model has been developed to describe the isothermal operation of a single anode-separator-cathode unit cell in a redox-flow battery and has been applied to the NASA iron/chromium system. The model, based on porous electrode theory, incorporates redox kinetics, mass transfer, and ohmic effects as well as the parasitic hydrogen reaction which occurs in the chromium electrode. A numerical parameter study was carried out to predict cell performance to aid in the rational design, scale-up, and operation of the flow battery. The calculations demonstrate: (1) an optimum electrode thickness and electrolyte flow rate exist; (2) the amount of hydrogen evolved and, hence, cycle faradaic efficiency, can be affected by cell geometry, flow rate, and charging procedure; (3) countercurrent flow results in enhanced cell performance over cocurrent flow; and (4) elevated temperature operation enhances cell performance.

Fedkiw, P. S.↗
NASA NTRS1987

Parabolic heavy ion flow in the polar magnetosphere

Recent observations by the Dynamics Explorer 1 satellite over the dayside polar cap magnetosphere have indicated downward flows of heavy ions such as O(+), O(2+), N(+), and N(2+) with flow velocities of the order 1 km/s (Lockwood et al., 1985). These downward flows were interpreted as the result of 'parabolic' flow of these heavy ionospheric ions from a source region associated with the polar cleft topside ionosphere. Here, a two-dimensional kinetic model is utilized to elicit features of the transport of very low energy O(+) ions from the cleft ionosphere. Bulk parameter (density, flux, thermal energies, etc.) distributions in the noon-midnight meridian plane illustrate the effects of varying convection electric fields and source energies. The results illustrate that, particularly under conditions of weak convection electric fields and weak ion heating in the cleft region, much of the intermediate altitude polar cap magnetosphere may be populated by downward flowing heavy ions. It is further shown how two-dimensional transport effects may alter the characteristic vertical profiles of densities and fluxes from ordinary profiles computed in one-dimensional steady-state models.

Horwitz, J. L.↗
NASA NTRS1987

MPD thruster plasma instability studies

Results of an ongoing experimental/theoretical effort to understand the influence of plasma waves and instabilities upon coaxial plasma thruster performance and longevity are discussed. An experiment which permits measurement of the plasma dispersion relation plus a suite of plasma parameters for each one millisecond quasi-steady discharge is described. This investigation is guided by a linearized Boltzmann-Poisson kinetic numerical model which can accommodate the effects of collisions, inhomogeneities and the magnetic field. Preliminary tests reveal the presence of the low-frequency branch of an ion cyclotron wave. Although the stability of these waves still has to be established through spatial growth rate measurements, it is well known that they are prone to 'current-driven' instabilities. 'Current-driven' instabilities in the collisional tensor conducting plasma of the MPD thruster are analytically discussed and their relevance to the MPD plasma is illustrated by estimating a critical total current at which their onset occurs.

Kelly, A. J.↗
NASA NTRS1992

Analysis of the effect of initial conditions on the initial development of a turbulent jet

The effect of the initial condition at the jet exit on the downstream evolution, particularly within the potential core length, were numerically investigated as well as with available experimental data. In order to select the most dependable computational model for the present numerical experiment, a comparative study has been performed with different turbulence models at k-epsilon level, and it was found that the k-epsilon-gammma model yields superior prediction accuracy over other conventional models. The calculated results show that the potential core length and the spreading rate the initial mixing layer are dependent on the initial length scale as well as the turbulent kinetic energy at the jet exit. Such effect of the initial length scale increases with higher initial turbulence level. An empirical parameter has been devised to collapse the calculated data of the potential core length and the spreading rate with various initial conditions onto a single curve.

Kim, Soong KI↗
NASA NTRS2004

Time-Average Measurement of Velocity, Density, Temperature, and Turbulence Using Molecular Rayleigh Scattering

Measurement of time-averaged velocity, density, temperature, and turbulence in gas flows using a nonintrusive, point-wise measurement technique based on molecular Rayleigh scattering is discussed. Subsonic and supersonic flows in a 25.4-mm diameter free jet facility were studied. The developed instrumentation utilizes a Fabry-Perot interferometer to spectrally resolve molecularly scattered light from a laser beam passed through a gas flow. The spectrum of the scattered light contains information about velocity, density, and temperature of the gas. The technique uses a slow scan, low noise 16-bit depth CCD camera to record images of the fringes formed by Rayleigh scattered light passing through the interferometer. A kinetic theory model of the Rayleigh scattered light is used in a nonlinear least squares fitting routine to estimate the unknown parameters from the fringe images. The ability to extract turbulence information from the fringe image data proved to be a challenge since the fringe is broadened by not only turbulence, but also thermal fluctuations and aperture effects from collecting light over a range of scattering angles. Figure 1 illustrates broadening of a Rayleigh spectrum typical of flow conditions observed in this work due to aperture effects and turbulence for a scattering angle, chi(sub s), of 90 degrees, f/3.67 collection optics, mean flow velocity, u(sub k), of 300 m/s, and turbulent velocity fluctuations, sigma (sub uk), of 55 m/s. The greatest difficulty in processing the image data was decoupling the thermal and turbulence broadening in the spectrum. To aid in this endeavor, it was necessary to seed the ambient air with smoke and dust particulates; taking advantage of the turbulence broadening in the Mie scattering component of the spectrum of the collected light (not shown in the figure). The primary jet flow was not seeded due to the difficulty of the task. For measurement points lacking particles, velocity, density, and temperature information could reliably be recovered, however the turbulence estimates contained significant uncertainty. Resulting flow parameter estimates are presented for surveys of Mach 0.6, 0.95, and 1.4 jet flows. Velocity, density, and temperature were determined with accuracies of 5 m/s, 1.5%, and 1%, respectively, in flows with no particles present, and with accuracies of 5 m/s, 1-4%, and 2% in flows with particles. Comparison with hotwire data for the Mach 0.6 condition demonstrated turbulence estimates with accuracies of about 5 m/s outside the jet core where Mie scattering from dust/smoke particulates aided in the estimation of turbulence. Turbulence estimates could not be recovered with any significant accuracy for measurement points where no particles were present.

Mielke, Amy F.↗
NASA NTRS1993

Comparison of kinetic models for atom recombination on high-temperature reusable surface insulation

Five kinetic models are compared for their ability to predict recombination coefficients for oxygen and nitrogen atoms over high-temperature reusable surface insulation (HRSI). Four of the models are derived using Rideal-Eley or Langmuir-Hinshelwood catalytic mechanisms to describe the reaction sequence. The fifth model is an empirical expression that offers certain features unattainable through mechanistic description. The results showed that a four-parameter model, with temperature as the only variable, works best with data currently available. The model describes recombination coefficients for oxygen and nitrogen atoms for temperatures from 300 to 1800 K. Kinetic models, with atom concentrations, demonstrate the influence of atom concentration on recombination coefficients. These models can be used for the prediction of heating rates due to catalytic recombination during re-entry or aerobraking maneuvers. The work further demonstrates a requirement for more recombination experiments in the temperature ranges of 300-1000 K, and 1500-1850 K, with deliberate concentration variation to verify model requirements.

Willey, Ronald J.↗
NASA NTRS1991

Effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammetry in a cylindrical-pore electrode

A means is presented to account for the effect of ohmic, mass-transfer, and kinetic resistances on linear-sweep voltammograms by modeling a pore in a porous matrix as a cylindrical-pore electrode, and solving the mass and charge conservation equations in the context of this geometry for the simply redox reaction O + ne(-) yield R where both O and R are soluble species. Both analytical and numerical techniques are used to solve the governing equations. The calculated peak currents and potentials are correlated by empirical formulas to the measurable parameters: sweep rate, concentration of the redox species, diffusion coefficient, conductivity of the electrolyte, and pore dimensions. Using the correlations, a methodology is established for determining if the redox reaction kinetics are irreversible or reversible (Nernstian). If the reaction is irreversible, it is shown how the standard rate constant and the transfer coefficient may be extracted from linear-sweep voltammetry data, or, if the reaction is reversible, how the number of electrons transferred may be deduced.

Weidner, John W.↗