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NASA NTRS2014

New Martian Meteorite Is One of the Most Oxidized Found to Date

As of 2013, about 60 meteorites from the planet Mars have been found and are being studied. Each time a new Martian meteorite is found, a wealth of new information comes forward about the red planet. The most abundant type of Martian meteorite is a shergottite; its lithologies are broadly similar to those of Earth basalts and gabbros; i.e., crustal igneous rocks. The entire suite of shergottites is characterized by a range of trace element, isotopic ratio, and oxygen fugacity values that mainly reflect compositional variations of the Martian mantle from which these magmas came. A newly found shergottite, NWA 5298, was the focus of a study performed by scientists within the Astromaterials Research and Exploration Science (ARES) Directorate at the Johnson Space Center (JSC) in 2012. This sample was found in Morocco in 2008. Major element analyses were performed in the electron microprobe (EMP) laboratory of ARES at JSC, while the trace elements were measured at the University of Houston by laser inductively coupled plasma mass spectrometry (ICPMS). A detailed analysis of this stone revealed that this meteorite is a crystallized magma that comes from the enriched end of the shergottite spectrum; i.e., trace element enriched and oxidized. Its oxidation comes in part from its mantle source and from oxidation during the magma ascent. It represents a pristine magma that did not mix with any other magma or see crystal accumulation or crustal contamination on its way up to the Martian surface. NWA 5298 is therefore a direct, albeit evolved, melt from the Martian mantle and, for its lithology (basaltic shergottite), it represents the oxidized end of the shergottite suite. It is thus a unique sample that has provided an end-member composition for Martian magmas.

Hui, Hejiu↗
NASA NTRS2022

The Zn, S, and Cl Isotope Compositions of Mare Basalts: Implications for the Effects of Eruption Style and Pressure on Volatile Element Stable Isotope Fractionation on the Moon

We compare the stable isotope compositions of Zn, S, and Cl for Apollo mare basalts to better constrain the sources and timescales of lunar volatile loss. Mare basalts have broadly elevated yet limited ranges in δ(66)Zn, δ(34)S, and δ(37)Cl_(SBC+WSC) values of 1.27 ± 0.71, 0.55 ± 0.18, and 4.1 ± 4.0‰, respectively, compared to the silicate Earth at 0.15, –1.28, and 0‰, respectively. We find that the Zn, S, and Cl isotope compositions are similar between the low- and high-Ti mare basalts, providing evidence of a geochemical signature in the mare basalt source region that is inherited from lunar formation and magma ocean crystallization. The uniformity of these compositions implies mixing following mantle overturn, as well as minimal changes associated with subsequent mare magmatism. Degassing of mare magmas and lavas did not contribute to the large variations in Zn, S, and Cl isotope compositions found in some lunar materials (i.e., 15‰ in δ(66)Zn, 60‰ in δ(34)S, and 30‰ in δ(37)Cl). This reflects magma sources that experienced minimal volatile loss due to high confining pressures that generally exceeded their equilibrium saturation pressures. Alternatively, these data indicate effective isotopic fractionation factors were near unity. Our observations of S isotope compositions in mare basalts contrast to those for picritic glasses (Saal and Hauri 2021), which vary widely in S isotope compositions from –14.0 to 1.3‰, explained by extensive degassing of picritic magmas under high-P/P_(Sat) values (>0.9) during pyroclastic eruptions. The difference in the isotope compositions of picritic glass beads and mare basalts may result from differences in effusive (mare) and explosive (picritic) eruption styles, wherein the high-gas contents necessary for magma fragmentation would result in large effective isotopic fractionation factors during degassing of picritic magmas. Additionally, in highly vesiculated basalts, the δ(34)S and δ(37)Cl values of apatite grains are higher and more variable than the corresponding bulk-rock values. The large isotopic range in the vesiculated samples is explained by late-stage low-pressure “vacuum” degassing (P/P-(Sat) ~ 0) of mare lavas wherein vesicle formation and apatite crystallization took place post-eruption. Bulk-rock mare basalts were seemingly unaffected by vacuum degassing. Degassing of mare lavas only became important in the final stages of crystallization recorded in apatite—potentially facilitated by cracks/fractures in the crystallizing flow. We conclude that samples with wide-ranging volatile element isotope compositions are likely explained by localized processes, which do not represent the bulk Moon.

Halogens↗
NASA NTRS2024

Revisiting the petrogenesis of pyroclastic glass bead deposits at the Apollo 15 and 17 sites

The Apollo 15 low-titanium and Apollo 17 high-titanium pyroclastic glass beads are amongst the most primitive magmatically derived samples obtained from the Moon. Two key samples, the low-Ti Apollo 15426 green glass clod and the high-Ti Apollo 74220 orange glass are morphologically distinct, where the Apollo 15 beads are larger (~ 107 μm along maximum axis) and more fractured, and the Apollo 17 are smaller (~42 μm) and less fractured. In this study, holohyaline beads as well as crystallized beads were examined from both samples. Crystallized beads show compositional variability in major, minor, and trace elements and enable examination of magmatic mineral fractionation processes during cooling of both deposits. The Apollo 15426 beads experienced variable olivine crystallization, whereas the Apollo 74220 beads experienced both olivine and ilmenite crystallization. Holohyaline beads from both deposits show more limited major, minor, and trace element variability than their crystallized counterparts. Trace element abundance data for individual holohyaline beads show that in Apollo 74220, they are tightly clustered at ~30 × Carbonaceous Ivuna chondrite [CI] with negative Eu anomalies and subchondritic Nb/Ta, and interpreted to reflect the presence of late-stage magma ocean cumulate overturned into an otherwise primitive mantle source. Incompatible trace element abundances for holohyaline beads in 15426 are supra-chondritic from ~8 × CI, to >80 × CI, with pronounced relative depletions in Sr and Eu for the most incompatible element enriched beads, which represent a distinct bead group within the deposit. Apollo 15426 beads have elevated Ni and Co abundances at the edges of the beads compared to their centers. These data are interpreted to reflect a more complex magmatic evolution of the 15426 deposit, beginning with: (i) initial magma generation, storage and assimilation within shallower low-Ca and high-Ca pyroxene bearing magma ocean cumulates (15B,C); (ii) mobilization of the earlier magmas by more recently generated primitive magmas (15A); (iii) eruption and crystallization of some beads (15D,E), and (iv) later jumbling of the deposit, possible impact contamination and addition of exotic bead components (J Group). In contrast, the 74220 data shows no discernable difference between Ni and Co abundances at the edges and centers supporting prior observations for limited melt fractionation and an absence of meteoritic components. It is further suggested that both deposits are likely to have been formed in the presence of a transient atmosphere. Using 74220 melt compositions from this study, post-entrapment crystallization abundances range from 266 to 1130 micrograms/g for H 2 O, 36 to 68 micrograms/g for F, 441 to 832 micrograms/g for S, and zero to 2.31 micrograms/g for Cl, consistent with prior studies and suggesting up to ~0.1 wt.% H 2 O in the melt, with considerably less in the source. The role that late-stage magma ocean cumulates rich in ilmenite, apatite and high-Ca pyroxene might play in modifying this volatile element estimate, however, casts remaining doubt on the volatile element abundance and evolution of the primitive Moon.

Moon↗
NASA NTRS2022

Effect of Sulfur on siderophile element partitioning between olivine and martian mantle primary melt

Ni and Co variations in primary martian magmas exhibit anomalous incompatible behavior, which has remained an unexplained conundrum. Because martian magmas are S-rich, and some trace metals are reported to have enhanced solubility in S-bearing magmas, we have carried out a series of experiments to evaluate the effect of high-S melts on the olivine/melt partitioning of Ni, Co, Mn, V, and Cr. Near-liquidus experiments on a synthetic primary martian mantle melt (Yamato-980459 [Y98]) were completed in a piston-cylinder apparatus at 0.75 GPa. Previous studies in S-free systems illustrate that the partition coefficients for these elements are dependent chiefly on D(Mg(Ol/melt)) (the partition coefficient defined as wt% Mg in olivine/wt% Mg in melt, a proxy for temperature), and were used to calibrate a predictive expression that includes the effects of temperature [i.e., D(Mg(Ol/melt))], melt composition, and oxygen fugacity. These predictive expressions are then used to isolate any effect in DM olivine/melt due to dissolved sulfur. The results show that S might have a small effect for Co, but not enough to change Co partitioning from compatible to incompatible in our experiments. The addition of a sulfur term to the D(Co) predictive expressions shows that nearly 8000 ppm of sulfur would be required in the melt (at liquidus temperature of Y98) for D(Co) to become <1. These S contents are two times higher than those of a sulfide-saturated melt at the P-T conditions of a martian mantle source region. Therefore, the anomalous incompatible behavior observed in these primary magma suites must be due to another mechanism. High temperature, oxygen fugacity, and diffusion are not viable mechanisms, but magma mixing, assimilation, or kinetic crystallization effects remain possibilities.

shergottite↗
NASA NTRS1986

Evidence of ongoing crustal deformation related to magmatic activity near Socorro, New Mexico

Leveling measurements conducted in 1980-1981 by the National Geodetic Survey in the Socorro area of the Rio Grande rift are analyzed. Crustal uplift related to magma inflation in the midcrustal magma body is detected; an uplift of 0.18 cm/yr is measured for the time between 1951-1980. The survey data of 1911 and 1959 are compared to the present data and good correlation is observed. The systematic leveling errors including height-dependence and refraction errors are studied. The 30-km-wide subsidence in the area is examined. The spatial correlation between seismic activity, the Socorro magma body, and crustal deformation in Socorro is investigated. The crustal movement from magma reservior activities is modeled using the formulations of Dieterich and Decker (1975). The modeling of the deformation reveals that the movement in the Socorro area is associated with the 19-km deep Socorro magma body.

Larsen, S.↗
NASA NTRS1988

Catastrophic volcanism as a cause of shocked features found at the K/T boundary and in cryptoexplosion structures

The presence of quartz grains containing shock lamellae at the Cretaceous/Tertiary (K/T) boundary is viewed by many as the single most compelling evidence of meteoritic or cometary impact because there is no known endogenous mechanism for producing these features. Similarly the presence of shocked quartz, shatter cones, coesite and stishovite at cryptoexplosion structures is comonly taken as conclusive evidence of impact. However, several recent studies have cast doubt on this interpretation. It is argued that basaltic volcanism, although not normally explosive, can under exceptional circumstances produce overpressures sufficiently high to produce shock features. The exceptional circumstances include a high content of volatiles, usually CO2, and no preestablished pathway to the surface. Rapid cooling of the saturated basaltic magma can occur if it underlies a cooler more evolved magma in a chamber. Initial slow cooling and partial exsolution of the volatiles will cause the density of the basaltic magma to become less than that of the overlying magma, leading to overturning and mixing. Gas will escape the magma chamber along planar cracks once the pressure becomes sufficiently high. In the vicinity of the crack tip there is a smallscale deviatoric stress pattern which is thought to be sufficiently high to produce transient cracks along secondary axes in the quartz crystals, causing the planar features. The CO2-rich fluid inclusions which have been found along planar elements of quartz in basement rocks of the Vredefort Dome were likely to have been emplaced by such a process. If the mechanism described is capable of producing shocked features as above, it would require a reassessment of the origin of many cryptoexplosion structures as well as seriously weakening the case for an impact origin of the K/T event.

Loper, D. E.↗
NASA NTRS1991

Lunar ferroan anorthosites and mare basalt sources - The mixed connection

Global overturn of a hot, gravitationally unstable lunar mantle immediately following the solidification of a magma ocean explains several characteristics of lunar petrology. Lunar mare basalt sources are inferred to be depleted in europium and alumina. These depletions are consensually attributed to complementary plagioclase floating from a magma ocean. However, in contrast to the mare basalt source parent magma, the ferroan anorthosite parent magma was more evolved by virtue of its lower Mg/Fe ratio and Ni abundances, although less evolved in its poverty of clinopyroxene constituents, flat rare earth pattern, and lower incompatible element abundances. The europium anomaly in mare sources is inferred to be present at 400 km depth, too deep to have been directly influenced by plagioclase crystallization. Massive overturning of the post-magma ocean mantle would have carried down clinopyroxene, ilmenite, and phases containing fractionated rare earths, europium anomalies, and some heat-producing radionuclides.

Ryder, Graham↗
NASA NTRS1992

Venus steep-sided domes: Relationships between geological associations and possible petrogenetic models

Venus domes are characterized by steep sides, a circular shape, and a relatively flat summit area. In addition, they are orders of magnitude larger in volume and have a lower height/diameter ratio than terrestrial silicic lava domes. The morphology of the domes is consistent with formation by lava with a high apparent viscosity. Twenty percent of the domes are located in or near tessera (highly deformed highlands), while most other (62 percent) are located in and near coronae (circular deformational features thought to represent local mantle upwelling). These geological associations provide evidence for mechanisms of petrogenesis and several of these models are found to be plausible: remelting of basaltic or evolved crust, differentiation of basaltic melts, and volatile enhancement and eruption of basaltic foams. Hess and Head have shown that the full range of magma compositions existing on the Earth is plausible under various environmental conditions on Venus. Most of the Venera and Vego lander compostional data are consistent with tholeiitic basalt; however, evidence for evolved magmas was provided by Venera 8 data consistent with a quartz monzonite composition. Pieters et al. have examined the color of the Venus surface from Venera lander images and interpret the surface there to be oxidized. Preliminary modeling of dome growth has provided some interpretations of lava rheology. Viscosity values obtained from these models range from 10(exp 14) - 10(exp 17) pa*s, and the yield strength has been calculated to be between 10(exp 4) and 10(exp 6) Pa, consistent with terrestrial silicic rocks. The apparent high viscosity of the dome lavas suggests that the domes have a silicic composition or must augment their viscosity with increased visicularity or crystal content. Sixty-two percent of the Venus domes are associated with coronae, circular features that have been proposed as sites of mantle upwelling, and 20 percent of the domes are located near tessera, relatively high areas of complex deformed terrain. We have investigated several models that are consistent with these geologic associations. The first case involves the differentiation of basalt in a magma reservoir in the crust, perhaps produced by partial melting within a mantle plume. The second case is melting at the base of thickened basaltic crust, and the final case is volatile exsolution and enhancement within a basaltic magma reservoir. The association of domes with tessera might be explained by crustal remelting, while the association with coronae may be consistent with chemical differentiation of a magma reservoir or the exsolution and concentration of volatiles in the reservoir before eruption.

Pavri, B.↗
NASA NTRS1992

Thermal and dynamical regimes of single- and two-phase magmatic flow in dikes

The coupling between thermal and dynamical regimes of single- and two-phase magmatic flow in dikes, due to temperature-dependent viscosity and dissipation, was investigated using finite element calculations of magma flow in dikelike channels with length-to-width ratios of 1000:1 or more. Solutions of the steady state equations governing magma flow are obtained for a variety of conditions ranging from idealized plane-parallel models to cases involving nonparallel geometry and two-phase flows. The implications of the numerical simulations for the dynamics of flow in a dike-reservoir system and the consequences of dike entrance conditions on magmatic storage are discussed. Consideration is also given to an unmixing/self-lubrication mechanism which may be important for the lubrication of silicic magmas rising to the earth's surface in mixed magma ascent scenarios, which naturally segregates magma mixtures of two components with differing viscosities to minimize the driving pressure gradient.

Carrigan, Charles R.↗
NASA NTRS1994

Basalt generation at the Apollo 12 site. Part 2: Source heterogeneity, multiple melts, and crustal contamination

The petrogenesis of Apollo 12 mare basalts has been examined with emphasis on trace-element ratios and abundances. Vitrophyric basalts were used as parental compositions for the modeling, and proportions of fractionating phases were determined using the MAGFOX prograqm of Longhi (1991). Crystal fractionation processes within crustal and sub-crustal magma chambers are evaluated as a function of pressure. Knowledge of the fractionating phases allows trace-element variations to be considered as either source related or as a product of post-magma-generation processes. For the ilmenite and olivine basalts, trace-element variations are inherited from the source, but the pigeonite basalt data have been interpreted with open-system evolution processes through crustal assimilation. Three groups of basalts have been examined: (1) Pigeonite basalts-produced by the assimilation of lunar crustal material by a parental melt (up to 3% assimilation and 10% crystal fractionation, with an 'r' value of 0.3). (2) Ilmenite basalts-produced by variable degrees of partial melting (4-8%) of a source of olivine, pigeonite, augite, and plagioclase, brought together by overturn of the Lunar Magma Ocean (LMO) cumulate pile. After generation, which did not exhaust any of the minerals in the source, these melts experienced closed-system crystal fractionation/accumulation. (3) Olivine basalts-produced by variable degrees of partial melting (5-10%) of a source of olivine, pigeonite, and augite. After generation, again without exhausting any of the minerals in the source, these melts evolved through crystal accumulation. The evolved liquid counterparts of these cumulates have not been sampled. The source compositions for the ilmenite and olivine basalts were calculated by assuming that the vitrophyric compositions were primary and the magmas were produced by non-modal batch melting. Although the magnitude is unclear, evaluation of these source regions indicates that both be composed of early- and late-stage Lunar Magma Ocean (LMO) cumulates, requiring an overturn of the cumulate pile.

Neal, Clive R.↗
NASA NTRS1995

Processes involved in the formation of magnesian-suite plutonic rocks from the highlands of the Earth's Moon

The earliest evolution of the Moon likely included the formation of a magma ocean and the subsequent development of anorthositic flotation cumulates. This primary anorthositic crust was then intruded by mafic magmas which crystallized to form the lunar highlands magnesian suite. The present study is a compilation of petrologic, mineral-chemical, and geochemical information on all pristine magnesian-suite plutonic rocks and the interpretation of this data in light of 18 'new' samples. Of these 18 clasts taken from Apollo 14 breccias, 12 are probably pristine and include four dunites, two norites, four troctolites, and two anorthosites. Radiogenic isotopic whole rock data also are reported for one of the 'probably pristine' anorthositic troctolites, sample 14303,347. The relatively low Rb content and high Sm and Nd abundances of 14303,347 suggest that this cumulate rock was derived from a parental magma which had these chemical characteristics. Trace element, isotopic, and mineral-chemical data are used to interpret the total highlands magnesian suite as crustal precipitates of a primitive KREEP (possessing a K-, rare earth element (REE)-, and P-enriched chemical signature) basalt magma. This KREEP basalt was created by the mixing of ascending ultramafic melts from the lunar interior with urKREEP (the late, K-, REE-, and P-enriched residuum of the lunar magma ocean). A few samples of the magnesian suite with extremely elevated large-ion lithophile elements (5-10x other magnesian-suite rocks) cannot be explained by this model or any other model of autometasomatism, equilibrium crystallization, or 'local melt-pocket equilibrium' without recourse to an extremely large-ion lithophile element-enriched parent liquid. It is difficult to generate parental liquids which are 2-4 x higher in the REE than average lunar KREEP, unless the liquids are the basic complement of a liquid-liquid pair, i.e., the so-called 'REEP-fraction,' from the silicate liquid immiscibility of urKREEP. Scarce age information on lunar rocks suggests that magnesian-suite magmatism was initiated at progressively more recent time from the northeast to the southwest on the lunar nearside from 4.45 to 4.25 Ga.

Snyder, Gregory A.↗
NASA NTRS1997

Studies of Magmatic Inclusions in the Basaltic Martian Meteorites Shergotty, Zagami, EETA 79001 and QUE 94201

Currently there are 12 meteorites thought by planetary scientists to be martian samples, delivered to the Earth after violent impacts on that planet's surface. Of these 12 specimens, 4 are basaltic: Shergotty, Zagami, EETA 79001 and QUE 94201. Basalts are particularly important rocks to planetary geologists- they are the most common rocks found on the surfaces of the terrestrial planets, representing volcanic activity of their parent worlds. In addition, because they are generated by partial melting of the mantle and/or lower crust, they can serve as guide posts to the composition and internal processes of a planet. Consequently these four meteorites can serve as 'ground-truth' representatives of the predominant volcanic surface rocks of Mars, and offer researchers a glimpse of the magmatic history of that planet. Unfortunately, unraveling the parentage of a basaltic rock is not always straightforward. While many basalts are simple, unaltered partial melts of the mantle, others have undergone secondary processes which change the original parental chemistry, such as assimilation of other crustal rocks, mixing with other magmas, accumulation, re-equilibration between mineral species after crystallization, loss of late-stage magmatic fluids and alteration by metamorphic or metasomatic processes. Fortunately, magmatic inclusions can trap the evolving magmatic liquid, isolating it from many of these secondary processes and offering a direct look at the magma during different stages of development. These inclusions form when major or minor phases grow skeletally, surrounding small amounts of the parental magma within pockets in the growing crystal. The inclusion as a whole (usually consisting of glass with enclosed crystals) continues to represent the composition of the parental magma at the time the melt pocket closed, even when the rock as a whole evolves under changing conditions. The four basaltic martian meteorites contain several distinct generations of melt inclusions; those found within early-forming pigeonite, intermediate and late-forming Ti, Fe-oxides and sulfides, and intermediate to late-forming phosphates. In this summer' s study we have made a detailed study of all of the various forms of inclusions found within the 4 basaltic martian meteorites listed above. Glasses and minerals within the inclusions were analyzed using the Camera SX-100 Electron Microprobe in Building 31. The mineralogy and textural context of the inclusions will then be used to explore the crystallization history of these specimens, and to investigate any differences in crystallization history or parental magma compositions between these rocks. In this manner, the magmatic inclusions provide a road map backwards toward the 'parental' compositions for the basaltic martian meteorites and provide significant insight into the igneous processes found within the crust of Mars.

Harvey, Ralph P.↗
NASA NTRS1996

Experimental Constraints on the Origin of Lunar High-Ti Ultramafic Glasses

Phase equilibria and dissolution rate experiments are used to develop a petrogenetic model for the high-Ti lunar ultramafic glasses. Near-liquidus phase relations of the Apollo 14 black glass, the most Ti-rich lunar ultramafic glass, are determined to 2.2-GPa. The liquidus is saturated with Cr-spinel at 1-atm, olivine between approximately 0.5- and 1.5-GPa, and low-Ca pyroxene + Cr-spinel above 1.5-GPa. Ilmenite does not crystallize near the liquidus and implies that high-Ti ultramafic glasses are not produced by melting of an ilmenite-saturated source. We infer that high-Ti ultramafic magmas are derived from low-Ti ultramafic parent magmas by assimilation of ilmenite +/- clinopyroxene +/- urKREEP +/- pigeonite in the shallow lunar interior. Heat is provided by adiabatic ascent of the low-Ti ultramafic primary magmas from the deeper lunar interior and crystallization of olivine during assimilation. The assimilation reaction is modeled by mass balance and requires that ilmenite and high-Ca pyroxene are assimilated in a approximately 3:1 ratio, a much higher ratio than the proportion in which these minerals are thought to exist in the lunar interior. In an effort to understand the kinetic controls on this reaction, the dissolution of ilmenite is examined experimentally in both low- and high-Ti lunar magmas. We find that ilmenite dissolves incongruently to Cr-spinel and a high-Ti melt. The dissolution reaction proceeds by a diffusion-controlled mechanism. An assimilation model for the origin of high-Ti melts is developed that leaves the magma ocean cumulates in their initial stratigraphic positions and obviates source hybridization models that require lunar overturn.

Wagner, T. P.↗
NASA NTRS1999

Compositions of Mars Rocks: SNC Meteorites, Differentiates, and Soils

The 13 samples from Mars identified in the terrestrial meteorite collections vary from dunite to pyroxenite to microgabbro or basalt. All of these rocks appear to have formed from primitive melts with similar major element compositional characteristics; i.e., FeO-rich and Al2O3-Poor melts relative to terrestrial basalt compositions. Although all of the SNC rocks can be derived by melting of the same Al-depleted mantle, contamination of SNC's by a Rb-enriched mantle or crustal source is required to explain the different REE characteristics of SNC rocks. Thus, there are indications of an old crustal rocktype on Mars, and this rock does not appear to have been sampled. This paper focuses primarily on the composition of the SNC basalts, however, and on the compositions of rocks which could be derived from SNC basaltic melt by magmatic processes. In particular, we consider the possible compositions which could be achieved through accumulation of early-formed crystals in the SNC primitive magma. Through a set of experiments we have determined (1) melt (magma) compositions which could be produced by melt evolution as crystals are removed from batches of this magma cooling at depth, and (2) which evolved (Si02enriched, MgO-depleted) rock compositions could be produced from the SNC magma, and how these compare with the Pathfinder andesite composition. Finally, we compare the SNC magma compositions to the Mars soil composition in order to determine whether any source other than SNC is required.

Rutherford, M. J.↗
NASA NTRS1999

Massive Chromite in the Brenham Pallasite and the Fractionation of Cr During the Crystallization of Asteroidal Cores

Large (greater than or equal to 2 mm) chromite grains are present in IIIAB iron meteorites and in the main-group a pallasites (PMG), closely related to high-Au IIIAB irons, Pallasites seem to have formed by the intrusion of a highly evolved metallic magma from a IIIAB-like core into fragmented olivine of the overlying dunite mantle. High Cr contents are commonly encountered during the analyses of metallic samples of high-Au IIIAB irons and main-group pallasites, an indication that Cr contents were high in the intruding liquid and that Cr behaved as an incompatible element during the crystallization of the IIIAB magma, contrary to expectations based on the negative IIIAB Cr-Ni and Cr-Au trends among low-Au IIIAB irons. In a region about 10 cm across in the Brenham main-group pallasite massive chromite fills the interstices between olivine grains, the site normally occupied by metal in Brenham and other pallasites. The massive chromite may have formed as a late cumulus phase; because Fe-Ni was also crystallizing, its absence in the chromite-rich region suggests a separation associated with differences in liquid buoyancy. The coexisting chromite and olivine are zoned; in the olivine FeO is highest in pallasitic (olivine-metal) regions, lowest in rims adjacent to chromite, and intermediate in the cores of these olivines. Chromite shows the opposite zoning, with the highest FeO contents at grain edges adjacent to olivine. The observed gradients are those expected to form by Fe-Mg exchange between olivine and chromite during slow cooling at subsolidus temperatures. Compared to normal Brenham, contents of phosphoran olivine and phosphates are higher in the chromitic pallasitic region. We also report data for large-to-massive chromites present in PMG Molong and in high-Au IIIAB Bear Creek that, like Brenham, formed from a highly evolved magma. The Bear Creek chromite has a much lower Mg content than that in the pallasites, implying that, in the PMG, the Mg was extracted from the olivine during high-temperature reaction with the precipitating chromite. There are other circumstantial arguments indicating that Cr was incompatible in the metal during the crystallization of the IIIAB magma, with the concentration in die residual magma rising from an initial value of about 300 micrograms/g to a value around 700 micrograms/g when Bear Creek and Brenham were formed. We consider possible explanations for these negative Cr-Au and Cr-Ni trends and find the most probable one to be that they reflect sampling artefacts resulting from analysts avoiding visible chromite (and the commonly associated phase FeS) when choosing metal samples.

Wasson, John T.↗
NASA NTRS2007

Liquidus Phases of the Richardson H5 Chondrite at High Pressures and Temperatures

Part of early mantle evolution may include a magma ocean, where core formation began before the proto-Earth reached half of its present radius. Temperatures were high and bombardment and accretion were still occurring, suggesting that the proto-Earth consisted of a core and an at least partially liquid mantle, the magma ocean. As the Earth accreted, pressure near the core increased and the magma ocean decreased in volume and became shallower as it began to cool and solidify. As crystals settled, or floated, the composition of the magma ocean could change significantly and begin to crystallize different minerals from the residual liquid. Therefore, the mantle may be stratified following the P-T phase diagram for the bulk silicate Earth. To understand mantle evolution, it is necessary to know liquidus phase relations at high pressures and temperatures. In order to model the evolution of the magma ocean, high pressure and temperature experiments have been conducted to simulate the crystallization process using a range of materials that most likely resemble the bulk composition of the early Earth.

Channon, M.↗
NASA NTRS2002

Sulfur Saturation Limits in Silicate Melts and their Implications for Core Formation Scenarios for Terrestrial Planets

This study explores the controls of temperature, pressure, and silicate melt composition on S solubility in silicate liquids. The solubility of S in FeO-containing silicate melts in equilibrium with metal sulfide increases significantly with increasing temperature but decreases with increasing pressure. The silicate melt structure also exercises a control on S solubility. Increasing the degree of polymerization of the silicate melt structure lowers the S solubility in the silicate liquid. The new set of experimental data is used to expand the model of Mavrogenes and O'Neill(1999) for S solubility in silicate liquids by incorporating the influence of the silicate melt structure. The expected S solubility in the ascending magma is calculated using the expanded model. Because the negative pressure dependence of S solubility is more influential than the positive temperature dependence, decompression and adiabatic ascent of a formerly S-saturated silicate magma will lead to S undersaturation. A primitive magma that is S-saturated in its source region will, therefore, become S-undersaturated as it ascends to shallower depth. In order to precipitate magmatic sulfides, the magma must first cool and undergo fractional crystallization to reach S saturation. The S content in a metallic liquid that is in equilibrium with a magma ocean that contains approx. 200 ppm S (i.e., Earth's bulk mantle S content) ranges from 5.5 to 12 wt% S. This range of S values encompasses the amount of S (9 to 12 wt%) that would be present in the outer core if S is the light element. Thus, the Earth's proto-mantle could be in equilibrium (in terms of the preserved S abundance) with a core-forming metallic phase.

Holzheid, Astrid↗
NASA NTRS2014

Geologic History of Asteroid 4 Vesta

Some types of meteorites - most irons, stony irons, some achondrites - hail from asteroids that were heated to the point where magmatism occurred within a very few million years of the formation of the earliest solids in the solar system. The largest clan of achondrites, the howardite, eucrite and diogenite (HED) meteorites, represent the crust of their parent asteroid]. Diogenites are cumulate harzburgites and orthopyroxenites from the lower crust whilst eucrites are basalts, diabases and cumulate gabbros from the upper crust. Howardites are impact-engendered breccias mostly of diogenites and eucrites. There remains only one large asteroid with a basaltic crust, 4 Vesta, which is thought to be the source of the HED clan. Differentiation models for Vesta are based on HED compositions. Proto-Vesta consisted of chondritic materials containing Al-26, a potent, short-lived heat source. Inferences from compositional data are that Vesta was melted to high degree (≥50%) allowing homogenization of the silicate phase and separation of a metallic core. Convection of the silicate magma ocean allowed equilibrium crystallization, forming a harzburgitic mantle. After convective lockup occurred, melt collected between the mantle and the cool thermal boundary layer and underwent fractional crystallization forming an orthopyroxene-rich (diogenite) lower crust. The initial thermal boundary layer of chondritic material was replaced by a mafic upper crust through impact disruption and foundering. The mafic crust thickened over time as additional residual magma intrudes and penetrates the mafic crust forming plutons, dikes, sills and flows of cumulate and basaltic eucrite composition. This magmatic history may have taken only 2-3 Myr. This magma ocean scenario is at odds with a model of heat and magma transport that indicates that small degrees of melt would be rapidly expelled from source regions, precluding development of a magma ocean. Constraints from radiogenic Mg-26 distibutions suggest that the parent asteroid of HEDs was much smaller than Vesta. Thus, first-order questions regarding asteroid differentiation remain.

Mittlefehldt, David W.↗