DOE OSTI2015
Single crystals of EuCu 2 As 2 and EuCu 2 Sb 2 were grown from CuAs and CuSb self-flux, respectively. The crystallographic, magnetic, thermal, and electronic transport properties of the single crystals were investigated by room-temperature x-ray diffraction (XRD), magnetic susceptibility χ versus temperature T, isothermal magnetization M versus magnetic field H, specific heat C p (T), and electrical resistivity ρ(T) measurements. EuCu 2 As 2 crystallizes in the body-centered tetragonal ThCr 2 Si 2 -type structure (space group I4/mmm), whereas EuCu 2 Sb 2 crystallizes in the related primitive tetragonal CaBe 2 Ge 2 -type structure (space group P4/nmm). The energy-dispersive x-ray spectroscopy and XRD data for the EuCu 2 Sb 2 crystals showed the presence of vacancies on the Cu sites, yielding the actual composition EuCu 1.82 Sb 2 . The ρ(T) and C p (T) data reveal metallic character for both EuCu 2 As 2 and EuCu 1.82 Sb 2 . Antiferromagnetic (AFM) ordering is indicated from the χ(T),C p (T), and ρ(T) data for both EuCu 2 As 2 (T N = 17.5 K) and EuCu 1.82 Sb 2 (T N = 5.1 K). In EuCu 1.82 Sb 2 , the ordered-state χ(T) and M(H) data suggest either a collinear A-type AFM ordering of Eu +2 spins S = 7/2 or a planar noncollinear AFM structure, with the ordered moments oriented in the tetragonal ab plane in either case. This ordered-moment orientation for the A-type AFM is consistent with calculations with magnetic dipole interactions. As a result, the anisotropic χ(T) and isothermal M(H) data for EuCu 2 As 2 , also containing Eu +2 spins S = 7/2, strongly deviate from the predictions of molecular field theory for collinear AFM ordering and the AFM structure appears to be both noncollinear and noncoplanar.