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At least 325 records · Page 18

Plasma Enhanced Growth of Carbon Nanotubes For Ultrasensitive Biosensors

The multitude of considerations facing nanostructure growth and integration lends itself to combinatorial optimization approaches. Rapid optimization becomes even more important with wafer-scale growth and integration processes. Here we discuss methodology for developing plasma enhanced CVD growth techniques for achieving individual, vertically aligned carbon nanostructures that show excellent properties as ultrasensitive electrodes for nucleic acid detection. We utilize high throughput strategies for optimizing the upstream and downstream processing and integration of carbon nanotube electrodes as functional elements in various device types. An overview of ultrasensitive carbon nanotube based sensor arrays for electrochemical biosensing applications and the high throughput methodology utilized to combine novel electrode technology with conventional MEMS processing will be presented.

Cassell, Alan M.↗

Progress on the Plasmoid Thruster Experiment (PTX)

A plasmoid, also called a compact toroid, is a compact plasma structure with an integral magnetic field, that may be categorized according to the relative strength of the poloidal and toroidal magnetic field (Bp and Bt, respectively). An object with Bp/Bt much greater than 1 is called a Field Reverse Configuration (FRC); if Bp = Bt, it is called a Spheromak. The plasmoid thruster is a pulsed inductive device which operates by repetitively producing plasmoids that are accelerated and ejected at high velocity. As the process is inductive, this thruster avoids the problem of electrode erosion. Also, the magnetic structure of the plasmoid should suppress thermal and mass losses to the wall, and improve detachment of the plasma exhaust from the thruster. This concept should be capable of producing an Isp of 5,000 seconds and greater, with thrust densities of order 10(exp 5) N/sq m. The plasmoid thruster consists chiefly of a conical theta-pinch coil. Propellant is introduced onto a bias magnetic field, produced by an auxiliary coil, and is then pre-ionized, freezing in the magnetic field. The theta-pinch coil is then energized producing a field aligned anti- parallel to the bias field. The reversed field reconnects with the bias field to form the plasmoid. The magnetic pressure of the reversed field accelerates the plasmoid out of the thruster . A series of experiments have been conducted on the PTX device, which consisted of a single turn conical theta-pinch coil, driven by a 560 nF, 35 kV capacitor bank, which rang at a frequency of 500 kHz, and served all three functions required for formation: pre-ionization, bias field loading, and field reversal. Initial ionization was found to occur in an annular region at the exit plane of the coil, and was found to be reproducible with a variety of gases, including H2, D2, Ar, and an H2/N2 mixture (75% / 25%). A fast gas valve for injecting propellant has been tested, as well as a ringing pre-ionization circuit (operating at 5 Mhz) to better control the plasmoid formation. Velocities as high as 20 km/s have been measured for a plasmoid propagating into a static back-fill of neutral gas. Magnetic field and density measurements indicate that the plasmoid retains its structure well into the down-stream exhaust region, and that it is capable of pushing a dense cloud of neutral gas in front of it. Further experiments will focus on the effects of coil geometry and bias-field strength on the performance of the device. A high-power solid-state switching system is being developed in order to replace the spark-gap switch.

Martin, Adam↗

Laboratory experiments on the electrodynamic behavior of tethers in space

The transient current systems between tethered plasmas in a large magnetoplasma are investigated experimentally for extrapolation to electrodynamic tethers in space. The studies measure the perturbed magnetic fields and the current density associated with pulsed currents to electrodes in three-dimensional space and time. The electrodes excite electron whistlers because they produce fields that dominantly couple to electrons, allowing pulsed currents to propagate and disperse as whistler wave packets. The wave packets evolve into force-free, flux-ropelike field configurations, and a whistler 'wedge' is formed in the plasma due to 'eddy' currents caused by insulated tethers with dc currents. Substantial radiation into the whistler mode happens with moving VLF antennas as well as tethers, and the wave spread within the ray cone is the most significant characteristic event. The wave spread widens the current channel, incites current closure, and is also associated with a 'phantom loop' phenomenon.

Stenzel, Reiner L.↗

An octahedral Mach B-dot probe for 3D flows and magnetic fields in the edge of reversed field pinches

Measurements and simulations show that plasma relaxation processes in the reversed field pinch drive and redistribute both magnetic flux and momentum. To examine this relaxation process, a new 3D Mach B-dot probe has been constructed. This probe collects ion saturation currents through six molybdenum electrodes arranged on the flattened vertices of an octahedron made of boron nitride (BN). The ion saturation current flows through configurable voltage dividers for measurement and returns through one of six selectable return electrodes equally spaced along the 12 cm BN probe arm. In addition, the probe arm houses three B-dot magnetic pickup coils in the BN stalk immediately below to the octahedron, to measure the local magnetic field. Inserted in the Madison Symmetric Torus (MST) during deuterium discharges with 220 kA plasma current, density of 0.8 × 10 13 cm –3 , the probe collects ion saturation currents with sawtooth-like peaks correlated with relaxation events. This compact octahedral design fitting six Mach electrode surfaces within a 1 cm3 cube will enable future multi-point, multi-field probes compatible with the 1.5 in. ports of MST. Such probes will allow for flow circulation, current, and canonical vorticity to be calculated in the center of the finite difference stencil formed by the measurement locations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Plasma polymerization of an ethylene-nitrogen gas mixture

A procedure has been developed whereby nitrogen can be incorporated into an organic film from an ethylene-nitrogen gas mixture using an internal electrode capacitively coupled radio frequency reactor. The presence of nitrogen has been shown directly by infrared transmittance spectra and electron spectroscopic chemical analysis data, and further indirect evidence was provided by dielectric measurements and by the reverse osmosis properties of the film. Preparation of a nitrogen containing film did not require vapor from an organic nitrogen containing liquid monomer. Some control over the bonding and stoichiometry of the polymer film was provided by the added degree of freedom of the nitrogen partial pressure in the gas mixture. This new parameter strongly affected the dielectric properties of the plasma polymerized film and could affect the reverse osmosis behavior.

Hudis, M.↗

A review of research and development on the microwave-plasma electrothermal rocket

The microwave-plasma electrothermal rocket (MWPETR) shows promise for spacecraft propulsion and maneuvering, without some of the drawbacks of competitive electric propulsion systems. In the MWPETR, the electric power is first converted to microwave-frequency radiation. In a specially-designed microwave cavity system, the electromagnetic energy of the radiation is transferred to the electrons in a plasma sustained in the working fluid. The resulting high-energy electrons transfer their energy to the atoms and molecules of the working fluid by collisions. The working fluid, thus heated, expands through a nozzle to generate thrust. In the MWPETR, no electrodes are in contact with the working fluid, the energy is transferred into the working fluid by nonthermal mechanisms, and the main requirement for the materials of construction is that the walls of the plasma chamber be insulating and transparent to microwave radiation at operating conditions. In this survey of work on the MWPETR, several experimental configurations are described and compared. Diagnostic methods used in the study are described and compared, including titration, spectroscopy, calorimetry, electric field measurements, gas-dynamic methods, and thrust measurements. Measured and estimated performance efficiencies are reported. Results of computer modeling of the plasma and of the gas flowing from the plasma are summarized.

Hawley, Martin C.↗

On the modes of nanosecond pulsed plasmas for combustion ignition of quiescent CH 4 -air mixtures

The effect of transient plasma modes on ignition kernel development are discussed here for a quiescent CH 4 -air combustion model system. A 10 ns high-voltage pulse was applied to a pin-to-pin electrode in lean fuel-air mixtures at room temperature and atmospheric pressure. High-impedance streamer, transient spark and low-impedance spark discharges were identified based on pulse waveforms of voltage and current. A sustained ignition kernel expansion was observed when the plasma discharge transitioned into a transient spark or spark discharge. The minimum ignition energy was obtained at the transient spark mode, which has less than a third of the energy or Coulomb transfer compared to the low-impedance spark. Employing repetitive 10-pulse sequence at 10 kHz, the lean-fuel limit was extended from an equivalence ratio of 0.6 for the single pulse ignition to 0.5. The use of repetitive pulses also allowed streamer breakdown or spark initiation to occur at a lower voltage.

CH 4↗

Electrodes for the thermionic converters, phase 2 - 3

The characteristics of electrodes for thermionic converters are discussed. A metal/ceramic Marchuk tube was constructed and operated with a quiescent cesium vapor plasma corresponding to cesium liquid reservoir temperatures from 376 to 427 K. The work function characteristics of tantalum test emitters coated with anodic films were measured to evaluate the applicability of the materials as the collector surface in a plasma mode thermionic converter. Work function minimum values between 1.4 and 1.5 electron volts were observed. The effect of the electronegative surface layers was partially obscured by additive vapor impurities detected by the clean tantalum reference emitter.

Desteese, J. G.↗

Transport of time-varying plasma currents by whistler wave packets

The relationship between pulsed currents and electromagnetic waves is examined in a regime characterized by electron MHD. Pulsed currents are generated by (1) collection/emission of charged particles by/from biased electrodes and (2) induction of currents by time-varying and moving magnetic fields. Pulsed currents are observed to propagate at the speed of whistler wave packets. Their field structure forms ropelike configurations which are electromagnetically force-free. Moving sources induce 'eddy' currents which excite waves and form Cerenkov-like whistler 'wings'. The radiation patterns of moving magnetic antennas and electrodynamic tethers are investigated. Nonlinear effects of large-amplitude, antenna-launched whistler pulses are observed. These involve a new modulational instability in which a channel of high conductivity which permits the wave/currents to penetrate deeply into a collisional plasma is formed.

Stenzel, R. L.↗

Design for megavolt inverse-pinch plasma switch

To meet the requirements for the output switch of an ultra-high-power (greater than 30 GW) pulser, an upgrading design for an inverse-pinch plasma switch (INPIS) is considered. The hold-off voltage of 1 MV is met by adopting multistage rim-fire electrodes and using SF6 as the dielectric gas of the switch. The inductance and capacitance of the switch, which are restricted by the short rise-time (less than 0.1 microsec) requirement, were met by adjusting the dimensions of the coaxial electrodes of the switch. The input/output transmission lines attached to the switch will be immersed in oil to meet the high voltage insulation and impedance-matching requirements. Since the forwarding current is relatively low with respect to the switch capability, the lifetime of the switch is expected to exceed the requirement of 10,000 shots.

Lee, Ja H.↗

Improved plasma torch for ignition and flame holding in supersonic combustion

A plasma torch system designed for ignition and flame-holding in supersonic combustion studies has been modified, in order to decrease electrode wear and increase stability, through the incorporation of a flow swirler in the gas inlet that adds vortex-stabilization to the arc. The torch body was redesigned in order to achieve superior alignment of the electrodes; the electrode gap was made continuously adjustable, thereby allowing fine tuning during torch operation. Table operation of the improved torch has been demonstrated in pure nitrogen, eliminating the requirement of argon gas for arc stabilization.

O'Brien, W. F.↗

Patterning of Indium Tin Oxide Films

A relatively rapid, economical process has been devised for patterning a thin film of indium tin oxide (ITO) that has been deposited on a polyester film. ITO is a transparent, electrically conductive substance made from a mixture of indium oxide and tin oxide that is commonly used in touch panels, liquid-crystal and plasma display devices, gas sensors, and solar photovoltaic panels. In a typical application, the ITO film must be patterned to form electrodes, current collectors, and the like. Heretofore it has been common practice to pattern an ITO film by means of either a laser ablation process or a photolithography/etching process. The laser ablation process includes the use of expensive equipment to precisely position and focus a laser. The photolithography/etching process is time-consuming. The present process is a variant of the direct toner process an inexpensive but often highly effective process for patterning conductors for printed circuits. Relative to a conventional photolithography/ etching process, this process is simpler, takes less time, and is less expensive. This process involves equipment that costs less than $500 (at 2005 prices) and enables patterning of an ITO film in a process time of less than about a half hour.

Immer, Christopher↗

Low-Temperature Production of Cosmic Grains Analogs From Gas-Phase Molecular Precursors with the NASA Ames' COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of carbonaceous cosmic dust grains, ultimately contributing to the formation of planets. Here, we report the first experimental investigations of the low temperature chemical pathways leading to the production of cosmic grain analogs from gas phase molecular precursors in order to better understand the evolution of cosmic carbon. The experiments were performed using the COsmic SImulation Chamber (COSmIC) to generate and characterize grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized gas phase hydrocarbons and PAHs [2], to carbon grains [3, 4]. This is achieved by using a discharge nozzle to (1) produce an adiabatic jet expansion and cool down Ar-hydrocarbon/PAH gas mixtures to astrophysically relevant temperature (150 K) before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma-induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains. Solid grains are produced in-situ in the plasma expansion, carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced at low temperature in COSmIC from gas mixtures including molecular precursors of cosmic carbon grains, i.e., such as CH4 and C2H2 found in circumstellar ejecta of late C stars [3] as well as PAHs ubiquitously detected in IR emission bands seen in galactic and extragalactic environments [4] will be discussed. Scanning Electron Microscopy imaging was used to provide insight on the morphology and growth structure of the grains produced in COSmIC, and to investigate how the precursors used to produce the grains affect these parameters [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4]. NIR to FIR optical properties are characterized to provide critical information (functional groups, optical constants) to the scientific community, for use in radiative transfer models in particular, and to help decipher and enhance the return data from space observations.

F. Salama↗

Mass spectrometer for measurements of relative ion concentrations in plasmas

A mass spectrometer which can be used to measure relative ion concentrations in a multiion component plasma has been designed for use in a strong (1-4-kG) uniform magnetic field. The spectrometer features an acceleration region which accelerates thermal ions through a series of three tantalum electrodes at a 30 deg angle to the B field, and a collection region in which ions are selectively collected, depending on the size of their gyroradii, by a cylindrical collector. Relative ion concentrations are determined from measurements of the collector current as a function of accelerating voltage. Results obtained using this instrument in a Q-machine device operated with a two-ion (Cs+/K+) component plasma are presented.

Suszcynsky, David M.↗

In situ studies of a molten metal anode ablation in a nearly atmospheric pressure DC arc

A DC arc with a meltable metal anode in a near-atmospheric pressure hydrocarbon gas is an emerging method for producing single-walled carbon nanotubes (SWCNTs). In these systems, evaporation of the molten metal anode determines the formation of catalyst seed particles needed for SWCNT growth, and therefore, should be monitored, controlled, and optimized. Evaluating the anode ablation rate by weighing the anode before and after a synthesis run is unfeasible due to anode carburization in the hydrocarbon atmosphere. To overcome this, we implemented a high-speed, 2D, 2-color pyrometry for reliable temperature measurements of the molten anode in a DC arc. The obtained temperature fields were used to calculate the anode ablation rates. Results showed the importance of resolving the arc and molten pool dynamics, as well as addressing the issue of reflections. Furthermore, significant changes in ablation rates were revealed upon addition of CH 4 , which must be considered when scaling up the production of SWCNTs.

Marangoni↗

Pulsed electromagnetic gas accelleration

Direct measurement with thermocouples of the power deposited in the anode of a multi-megawatt magnetoplasmadynamic discharge has shown the fractional anode power to decrease from 50% at 200 kW to 10% at 20 MW. Using local measurements of current density, electric potential, and electron temperature, the traditional model for heat conduction to the anode is found to be inadequate. Other experiments in which the voltage-current characteristics and exhaust velocities of MPD arcs using Plexiglas and boron nitride chamber insulators and various mass injection configurations show that ablation can affect nominal accelerator operation in several distinct ways. The incorporation of a hollow cathode in a 7 kA plasma discharge has shown that a stable current attachment can be realized in the cavity without the aid of cathode heaters, keeper electrodes, or emissive coatings.

Jahn, R. G.↗

Impedance characteristics of coaxial and planar magnetoplasma capacitors

A theory has been developed for the impedance of a homogeneous magnetoplasma enclosed between two specular reflecting coaxial electrodes, with a static magnetic field parallel to the electrode axes. The parallel-plate magnetoplasma capacitor is treated as a sub-case. Starting with the Vlasov equation, an integral equation is derived for the electric field. Solving this equation, and integrating to obtain the voltage, gives the capacitor impedance. This includes a capacitive component, and a resistive component expressing the Landau damping associated with the open orbits of electrons reflected at the electrodes. A direct numerical solution of the field integral equation has been carried out for a range of values of magnetic field, plasma density, and signal frequency. The values of impedance so obtained are compared with the predictions of macroscopic theory, and of an approximate microscopic theory in which open orbits are ignored and solutions are obtained using finite Fourier transform methods. The mathematical relations between these theories are demonstrated.

Harker, K. J.↗