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Lunar bases and space activities of the 21st century

The present conference gives attention to such major aspects of lunar colonization as lunar base concepts, lunar transportation, lunar science research activities, moon-based astronomical researches, lunar architectural construction, lunar materials and processes, lunar oxygen production, life support and health maintenance in lunar bases, societal aspects of lunar colonization, and the prospects for Mars colonization. Specific discussions are presented concerning the role of nuclear energy in lunar development, achromatic trajectories and the industrial scale transport of lunar resources, advanced geologic exploration from a lunar base, geophysical investigations of the moon, moon-based astronomical interferometry, the irradiation of the moon by particles, cement-based composites for lunar base construction, electrostatic concentration of lunar soil minerals, microwave processing of lunar materials, a parametric analysis of lunar oxygen production, hydrogen from lunar regolith fines, metabolic support for a lunar base, past and future Soviet lunar exploration, and the use of the moons of Mars as sources of water for lunar bases.

Mendell, W. W.↗

Remote Science at Sea With Remotely Operated Vehicles

Conducting sea-going ocean science no longer needs to be limited to the number of berths on a ship given that telecommunications, computing, and networking technologies onboard ships have become familiar mechanisms for expanding scientists’ reach from onshore. The oceanographic community routinely works with remotely operated vehicles (ROVs) and pilots to access real-time video and data from the deep sea, while onboard a ship. The extension of using an ROV and its host vessel’s live-streaming capabilities has been popularized for almost 3 decades as a telepresence technology. Telepresence-enabled vessels with ROVs have been employed for science, education, and outreach, giving a greater number of communities viewing access to ocean science. However, the slower development of technologies and social processes enabling sustained real-time involvement between scientists on-ship and onshore undermines the potential for broader access, which limits the possibility of increasing inclusivity and discoveries through a diversity of knowledge and capabilities. This article reviews ocean scientists’ use of telepresence for ROV-based deep-sea research and funded studies of telepresence capabilities. The authors summarize these studies findings and conditions that lead to defining the use of telepresence-enabled vessels for “remote science at sea.” Authors define remote science at sea as a type of ocean expedition, an additional capability, not a replacement for all practices by which scientists conduct ocean research. Remote science for ocean research is an expedition at-sea directed by a distributed science team working together from at least two locations (on-ship and onshore) to complete their science objectives for which primary data is acquired by robotic technologies, with connectivity supported by a high-bandwidth satellite and the telepresence-enabled ship’s technologies to support the science team actively engaged before, during, and after dives across worksites. The growth of productive ocean expeditions with remote science is met with social, technical, and logistical challenges that impede the ability of remote scientists to succeed. In this article, authors review telepresence-enabled ocean science, define and situate the adjoined model of remote science at sea, and some infrastructural, technological and social considerations for conducting and further developing remote science at sea.

marine technology↗

[Activities of Dept. of Geological Sciences, Colorado University]

Using remotely sensed data and GPS observations we completed a study of neotectonic processes responsible for landscape changes in an area of active extensional deformation and volcanism. The findings from this study describe the extensional processes operating in the region of the Afar triple junction and the northern Ethiopian rift.

Bilham, Roger↗

Interaction of Iron with Alumina Refractory Under Flash Ironmaking Conditions

A novel flash ironmaking technology (FIT) based on the direct reduction of iron ore concentrate by a reducing gas such as hydrogen, natural gas, or coal gas has been developed at the University of Utah. A proper choice of refractories is expected to play an important role in the development of FIT and its scale-up. In this work, the interaction of iron with alumina refractory under flash ironmaking conditions has been investigated. A thermodynamic basis for the interaction phenomena has been developed by considering the Fe-Al-O system, and a kinetic model based on solid-state diffusion is proposed to describe the growth of the hercynite (FeAl{sub 2}O{sub 4}) spinel formed as a result of the interaction between Fe, O (from H{sub 2}O and CO{sub 2}), and Al{sub 2}O{sub 3}. Experiments were conducted with Fe powders and pure Al{sub 2}O{sub 3} in the temperature range 1200 to 1500 °C under gas atmospheres relevant to flash ironmaking, and the reacted samples were analyzed using XRD, SEM-EDX, and EPMA techniques. The analyses of reacted samples confirmed the formation of the hercynite (FeAl{sub 2}O{sub 4}) spinel phase and the thickness of the FeAl{sub 2}O{sub 4} spinel as measured using elemental line scans in SEM-EDX and EPMA varied in the range of 0.5 to 1.3 mm. Results showed that the proposed model suitably describes the growth of the hercynite spinel layer, which obeyed the parabolic rate law at all temperatures. The parabolic rate constants were obtained and the diffusion-controlled growth of the FeAl{sub 2}O{sub 4} layer strongly depended on temperature. Furthermore, using the kinetic model, an expression for the effective diffusivity ( (D{sub eff})-bar ) was obtained and its values at the experimental temperatures were determined. The solid-state diffusion was an activated process, as expected, with an activation energy value of 231 kJ/mol.

36 MATERIALS SCIENCE↗

Kinetics of lime/bentonite pozzolanic reactions at 20 and 50 °C: Batch tests and modeling

The effects of duration (1–100 days) and temperature (20 and 50 °C) were assessed from batch tests for Ca-bentonite mixed with 10 wt.% lime. The pozzolanic processes were monitored over time by {sup 29}Si NMR (Cement Concr. Res. 42, 2012), TGA-DTA, XRD and chemical analysis. Modeling considered kinetics and thermodynamics of mineralogical transformations and cation exchange. Kinetic laws were dependent on pH and temperature (Arrhenius energy). Lime hydration occurs within hours, modifying the bentonite exchangeable population and increasing the pH. These alkaline conditions initiate the pozzolanic reactions in a second stage. The rate-limiting step is the dissolution kinetics of the bentonite minerals, i.e. a relatively fast and total consumption of cristobalite in parallel to a long-term slower dissolution of montmorillonite. First C–S–H and then C–A–S–H are formed consequently. Temperature speeds up the pozzolanic reaction kinetics by a factor 5 from 20 to 50 °C, corresponding to an apparent activation energy of 40–50 kJ/mol.

36 MATERIALS SCIENCE↗

Energy-Efficient Self-Organization and Swarm Behavior in Active Matter

Living systems have the unique ability to form hierarchical assemblies, in which individual constituents can perform tasks cooperatively and emergently. Harnessing such properties is a long-standing challenge for the rational design of dynamic materials, that can respond to their environment, communicate with one another, and undergo a rapid, reversible, assembly through the transduction of energy. Recent developments in the design of smart and active colloidal building blocks have led to tremendous breakthroughs, with, for instance, the onset of synthetic photoactivated active assemblies. In this project, we develop a combined experimental, computational, theoretical and Machine Learning framework to shed light on the physical underpinnings of such assembly processes and program the assembly of smart active materials.

36 MATERIALS SCIENCE↗

Active Layer Hydrology in an Arctic Tundra Ecosystem: Quantifying Water Sources and Cycling Using Water Stable Isotopes: Supporting Data

Data include results from water isotope analyses (one *.csv file) for samples collected in Utqiagvik (Barrow), Alaska during August and September 2012. Samples were from surface and soil pore waters from 17 drainages that could be interlake (basins with polygonal terrain), different-aged drain thaw lake basins (young, medium, old, or ancient), or a combination of different aged basins. Samples taken in different drainage flow types at three different depths at each location in and around the Barrow Environmental Observatory. Precipitation stable isotope data are also included (added in October 2019 with no changes to previously released data). This dataset used in Throckmorton, et.al. 2016.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a 10-year research effort (2012-2022) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Kinetics Analysis of Boron Removal from Silicon through Reactions with CaO-SiO{sub 2} and CaO-SiO{sub 2}-Al{sub 2}O{sub 3} Slags

Different types of slags have been used to refine silicon, particularly for removing boron impurity from metallurgical grade (MG) silicon. Although a number of slags have been used for silicon refining, there is limited information about boron removal kinetics, particularly during the refining reaction with CaO-SiO{sub 2}-Al{sub 2}O{sub 3} slags. This article investigates the boron removal kinetics using the CaO-SiO{sub 2}-Al{sub 2}O{sub 3} slag systems in the temperature range 1773 K to 1873 K (1500 °C to 1600 °C). All the results obtained in the present study provide a strong indication that the rate limiting step of the slag-silicon reaction kinetics was mass transport in the liquid slag. It was also shown in the study that as the reaction temperature is increased, the mass transfer coefficient is also increased. At any particular reaction temperature, adding alumina in the CaO-SiO{sub 2} slag was shown to decrease the mass transfer coefficient, which is consistent with the substantially higher viscosity of the alumina bearing slags over the CaO-SiO{sub 2} slag. The mass transfer coefficients were determined to be between 1.23 × 10{sup −6} and 2.82 × 10{sup −6} ms{sup −1}, with activation energies between 64 and 109 kJ/mol, respectively.

36 MATERIALS SCIENCE↗

Phase Diagram of Active Brownian Spheres: Crystallization and the Metastability of Motility-Induced Phase Separation

Motility-induced phase separation (MIPS), the phenomenon in which purely repulsive active particles undergo a liquid-gas phase separation, is among the simplest and most widely studied examples of a nonequilibrium phase transition. Here, we show that states of MIPS coexistence are in fact only metastable for three-dimensional active Brownian particles over a very broad range of conditions, decaying at long times through an ordering transition we call active crystallization. At an activity just above the MIPS critical point, the liquid-gas binodal is superseded by the crystal-fluid coexistence curve, with solid, liquid, and gas all coexisting at the triple point where the two curves intersect. Nucleating an active crystal from a disordered fluid, however, requires a rare fluctuation that exhibits the nearly close-packed density of the solid phase. The corresponding barrier to crystallization is surmountable on a feasible timescale only at high activity, and only at fluid densities near maximal packing. The glassiness expected for such dense liquids at equilibrium is strongly mitigated by active forces, so that the lifetime of liquid-gas coexistence declines steadily with increasing activity, manifesting in simulations as a facile spontaneous crystallization at incredibly high activity.

36 MATERIALS SCIENCE↗

A Model of Ice Wedge Polygon Drainage in Changing Arctic Terrain

As ice wedge degradation and the inundation of polygonal troughs become increasingly common processes across the Arctic, lateral export of water from polygonal soils may represent an important mechanism for the mobilization of dissolved organic carbon and other solutes. However, drainage from ice wedge polygons is poorly understood. We constructed a model which uses cross-sectional flow nets to define flow paths of meltwater through the active layer of an inundated low-centered polygon towards the trough. The model includes the effects of evaporation and simulates the depletion of ponded water in the polygon center during the thaw season. In most simulations, we discovered a strong hydrodynamic edge effect: only a small fraction of the polygon volume near the rim area is flushed by the drainage at relatively high velocities, suggesting that nearly all advective transport of solutes, heat, and soil particles is confined to this zone. Estimates of characteristic drainage times from the polygon center are consistent with published field observations.

54 ENVIRONMENTAL SCIENCES↗

Atomic steps on an ultraflat Si(111) surface upon sublimation

The kinetics of atomic steps on an ultraflat Si(111) surface is studied by in situ ultrahigh-vacuum reflection electron microscopy at temperatures of 1050–1350°C. For the first time it is experimentally shown that the rate of displacement of an atomic step during sublimation nonlinearly depends on the width of the adjacent terrace. It is established that the atomic mechanism of mass-transport processes at the surface at temperatures higher than 1200°C is controlled by nucleation and the diffusion of surface vacancies rather than of adsorbed Si atoms. The studies make it possible to estimate the activation energy of the dissolution of vacancies from the surface into the bulk of Si. The estimated activation energy is (4.3 ± 0.05) eV.

36 MATERIALS SCIENCE↗

A review of metasurfaces: Physics and applications

Metamaterials are composed of periodic subwavelength metal/dielectric structures that resonantly couple to the electric and/or magnetic components of the incident electromagnetic fields, exhibiting properties that are not found in nature. This class of micro- and nano-structured artificial media have attracted great interest during the past 15 years and yielded ground-breaking electromagnetic and photonic phenomena. However, the high losses and strong dispersion associated with the resonant responses and the use of metallic structures, as well as the difficulty in fabricating the micro- and nanoscale 3D structures, have hindered practical applications of metamaterials. Planar metamaterials with subwavelength thickness, or metasurfaces, consisting of single-layer or few-layer stacks of planar structures, can be readily fabricated using lithography and nanoprinting methods, and the ultrathin thickness in the wave propagation direction can greatly suppress the undesirable losses. Metasurfaces enable a spatially varying optical response (e.g. scattering amplitude, phase, and polarization), mold optical wavefronts into shapes that can be designed at will, and facilitate the integration of functional materials to accomplish active control and greatly enhanced nonlinear response. This paper reviews recent progress in the physics of metasurfaces operating at wavelengths ranging from microwave to visible. We provide an overview of key metasurface concepts such as anomalous reflection and refraction, and introduce metasurfaces based on the Pancharatnam–Berry phase and Huygens' metasurfaces, as well as their use in wavefront shaping and beam forming applications, followed by a discussion of polarization conversion in few-layer metasurfaces and their related properties. An overview of dielectric metasurfaces reveals their ability to realize unique functionalities coupled with Mie resonances and their low ohmic losses. In addition, we also describe metasurfaces for wave guidance and radiation control, as well as active and nonlinear metasurfaces. Finally, we conclude by providing our opinions of opportunities and challenges in this rapidly developing research field.

36 MATERIALS SCIENCE↗

An Integrated and Collaborative Approach for NASA Earth Science Data

Earth science research requires coordination and collaboration across multiple disparate science domains. Data systems that support this research are often as disparate as the disciplines that they support. These distinctions can create barriers limiting access to measurements, which could otherwise enable cross-discipline Earth science. NASA's Earth Observing System Data and Information System (EOSDIS) is continuing to bridge the gap between discipline-centric data systems with a coherent and transparent system of systems that offers up to date and engaging science related content, creates an active and immersive science user experience, and encourages the use of EOSDIS earth data and services. The new Earthdata Coherent Web (ECW) project encourages cohesiveness by combining existing websites, data and services into a unified website with a common look and feel, common tools and common processes. It includes cross-linking and cross-referencing across the Earthdata site and NASA's Distributed Active Archive Centers (DAAC), and by leveraging existing EOSDIS Cyber-infrastructure and Web Service technologies to foster re-use and to reduce barriers to discovering Earth science data (http://earthdata.nasa.gov).

Murphy, K.↗

EOS Laser Atmosphere Wind Sounder (LAWS) investigation

The related activities of the contract are outlined for the first year. These include: (1) attend team member meetings; (2) support EOS Project with science related activities; (3) prepare and Execution Phase plan; and (4) support LAWS and EOSDIS related work. Attached to the report is an appendix, 'LAWS Algorithm Development and Evaluation Laboratory (LADEL)'. Also attached is a copy of a proposal to the NASA EOS for 'LAWS Sampling Strategies and Wind Computation Algorithms -- Storm-Top Divergence Studies. Volume I: Investigation and Technical Plan, Data Plan, Computer Facilities Plan, Management Plan.'

Emmitt, George D.↗

Spontaneous topological charging of tactoids in a living nematic

Abstract Living nematic is a realization of an active matter combining a nematic liquid crystal with swimming bacteria. The material exhibits a remarkable tendency towards spatio-temporal self-organization manifested in formation of dynamic textures of self-propelled half-integer topological defects (disclinations). Here we report on the study of such living nematic near normal inclusions, or tactoids, naturally realized in liquid crystals close to the isotropic-nematic (I–N) phase transition. On the basis of the computational analysis, we have established that tactoid’s I–N interface spontaneously acquire negative topological charge which is proportional to the tactoid’s size and depends on the concentration of bacteria. The observed negative charging is attributed to the drastic difference in the mobilities of +1/2 and −1/2 topological defects in active systems. The effect is described in the framework of a kinetic theory for point-like weakly-interacting defects with different mobilities. Our dedicated experiment fully confirmed the theoretical prediction. The results hint into new strategies for control of active matter.

59 BASIC BIOLOGICAL SCIENCES↗

Activities in planetary geology for the physical and earth sciences

A users guide for teaching activities in planetary geology, and for physical and earth sciences is presented. The following topics are discussed: cratering; aeolian processes; planetary atmospheres, in particular the Coriolis Effect and storm systems; photogeologic mapping of other planets, Moon provinces and stratigraphy, planets in stereo, land form mapping of Moon, Mercury and Mars, and geologic features of Mars.

Dalli, R.↗

Frost Tables, NGEE Areas B, C and D, Utqiagvik (Barrow), Alaska, 2012-2014

This dataset represents spatially intensive thaw depth surveys with individual point measurements spaced ~0.5 m apart. The three ~10x10m grids cover an ice wedge and a portion of its two neighboring polygons. The data contain thaw depth, frost table elevation, ground surface elevation, active layer depth and surface water inundation across three seasons (2012, 2013 and 2014) at Utqiagvik (Barrow) NGEE Areas B, C and D. There are a total of 69 extracted files separated by month, year, and area. The data were originally provided in excel workbooks, these files have been preserved within the zip "Original_Files." The files were transformed for archiving with images pulled out into JPEGs, data preserved as CSV files and some methodological information preserved as TXT files. Some functions, features, and formatting were lost during the transformation. Missing data were defined with blank cells. Additional documentation can be found in files labelled with "information.txt" file endings.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).[2024-07-15] Renamed BEO_Thaw_Depth_Frost_Table_Area_*_*_*.csv, BEO_Thaw_Depth_Frost_Table_Area_*_*_*_Plot_1.JPEG, and BEO_Thaw_Depth_Frost_Table_Area_*_*_*_Plot_2.JPEG names that had E or L to be Early or Late. Renamed BEO_Thaw_Depth_Frost_Table_Area_*_*_*_Plot_1.JPEG, BEO_Thaw_Depth_Frost_Table_Area_*_*_*_Plot_2.JPEG, and BEO_Thaw_Depth_Frost_Table_Area_*_information_Plot_1.JPEG to BEO_Thaw_Depth_Frost_Table_Area_*_*_*_Gridpoints.JPEG, BEO_Thaw_Depth_Frost_Table_Area_*_*_*_3Dgraphic.JPEG, and BEO_Thaw_Depth_Frost_Table_Area_*_information_LiDAR_DEM.JPEG, respectively. Updated BEO_Thaw_Depth_Frost_Table_flmd.csv file to reflect above updates.

54 ENVIRONMENTAL SCIENCES↗

Analysis of Observed Contamination Through SAGE III's First Year on Orbit

SAGE III is a payload on the International Space Station that conducts measurements of ozone and other atmospheric constituents through the use of a moderate resolution spectrometer with an operating wavelength range of 290 nm to 1550 nm. Because of the optically sensitive nature of the payload, a suite of eight Thermoelectric Quartz Crystal Microbalances (TQCMs) were included to monitor the operating environment. During the rst year of operation, the SAGE III TQCMs were instrumental in detecting several periods of higher contamination and localizing their sources. A clear window made from quartz crystal covers the instrument assembly's aperture. Under nominal operating conditions, this window is only open during science gathering activities. However, if the rates of contamination accumulation are detected to be above the background rate, the window will be kept closed during science gathering to protect the optically sensitive instrument mirror. An analysis of the signal transmissions through the window for the wavelengths of 290 nm to 1550 nm has been conducted to determine any possible degradation of the window and potential in uence on science data collected to date, and established a baseline for future analysis.

Thompson, Michael P.↗