Surface Mass Loss Rates of Carbonaceous Particles in a Shock Tube
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The pyrolysis of cyclopentanone, a promising biofuel candidate identified by the Department of Energy’s Co-Optima program, is investigated in this work. Time resolved measurements of carbon monoxide, ethylene, and cyclopentanone are provided to gain a detailed understanding of the unimolecular decomposition pathway of the fuel. Experiments were conducted between 1156-1312 K near 9 atm with 0.1% fuel loading balanced in argon. A strategy to report species concentration with interference is presented and the measurements obtained are crucial validation targets for the development of detailed chemical kinetic mechanisms used to predict fuel chemistry.
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Dimethyl ether (DME) is a biofuel that has the potential to replace diesel in heavy-duty engines. A blend of propane (C3H8) and DME could reduce emissions when compared to diesel at heavy-duty compression engine-relevant conditions. Testing a potential new mixture in a compression engine requires a high-fidelity chemical kinetics model that accurately predicts autoignition delay times, which is especially necessary for a compression engine. In this work, autoignition data has been gathered at an equivalence ratio of 2.0 for pressures of 60 and 80 bar. DME and propane were combusted in synthetic air while excited hydroxyl (OH*) chemiluminescence was used to gather ignition delay times. Data was compared to recent chemical kinetic mechanisms for the two different pressures. Using the mechanism with the best fit of autoignition data, a sensitivity analysis was conducted to analyze the chemical kinetics of the DME/C3H8 combustion at elevated pressures.
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Gas spectroscopic tube and component equipment instrumentation for radiative transfer experiments
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