Results for “Short range order” — Page 18

NASA NTRS2000

Physics of Hard Spheres Experiment: Significant and Quantitative Findings Made

Direct examination of atomic interactions is difficult. One powerful approach to visualizing atomic interactions is to study near-index-matched colloidal dispersions of microscopic plastic spheres, which can be probed by visible light. Such spheres interact through hydrodynamic and Brownian forces, but they feel no direct force before an infinite repulsion at contact. Through the microgravity flight of the Physics of Hard Spheres Experiment (PHaSE), researchers have sought a more complete understanding of the entropically driven disorder-order transition in hard-sphere colloidal dispersions. The experiment was conceived by Professors Paul M. Chaikin and William B. Russel of Princeton University. Microgravity was required because, on Earth, index-matched colloidal dispersions often cannot be density matched, resulting in significant settling over the crystallization period. This settling makes them a poor model of the equilibrium atomic system, where the effect of gravity is truly negligible. For this purpose, a customized light-scattering instrument was designed, built, and flown by the NASA Glenn Research Center at Lewis Field on the space shuttle (shuttle missions STS 83 and STS 94). This instrument performed both static and dynamic light scattering, with sample oscillation for determining rheological properties. Scattered light from a 532- nm laser was recorded either by a 10-bit charge-coupled discharge (CCD) camera from a concentric screen covering angles of 0 to 60 or by sensitive avalanche photodiode detectors, which convert the photons into binary data from which two correlators compute autocorrelation functions. The sample cell was driven by a direct-current servomotor to allow sinusoidal oscillation for the measurement of rheological properties. Significant microgravity research findings include the observation of beautiful dendritic crystals, the crystallization of a "glassy phase" sample in microgravity that did not crystallize for over 1 year in 1g (Earth's gravity), and the emergence of face-centered-cubic (FCC) crystals late in the coarsening process (as small crystallites lost particles to the slow ripening of large crystallites). Significant quantitative findings from the microgravity experiments have been developed describing complex interactions among crystallites during the growth process, as concentration fields overlap in the surrounding disordered phase. Time-resolved Bragg scattering under microgravity captures one effect of these interactions quite conclusively for the sample at a volume fraction of 0.528. From the earliest time until the sample is almost fully crystalline, the size and overall crystallinity grow monotonically, but the number of crystallites per unit volume (number density) falls. Apparently nucleation is slower than the loss of crystallites because of the transfer of particles from small to large crystals. Thus, coarsening occurs simultaneously with growth, rather than following the completion of nucleation and growth as is generally assumed. In the same sample, an interesting signature appears in the apparent number density of crystallites and the volume fraction within the crystallites shortly before full crystallinity is reached. A brief upturn in both indicates the creation of more domains of the size of the average crystallite simultaneous with the compression of the crystallites. Only the emergence of dendritic arms offers a reasonable explanation. The arms would be "seen" by the light scattering as separate domains whose smaller radii of curvature would compress the interior phase. In fiscal year 1999, numerous papers, a doctoral dissertation, and the PHaSE final report were produced. Although this flight project has been completed, plans are in place for a follow-on colloid experiment by Chaikin and Russel that employs a light microscope within Glenn's Fluids and Combustion Facility on the International Space Station. PHaSE is providing us with a deeper understanding of the nure of phase transitions. The knowledge derived has added to the understanding of condensed matter. In addition, the burgeoning study of the dynamics of colloidal self-assembly may lead to the development of a range of photonic materials that control the desirable properties of light. Thus, applications of ordered colloidal structures include not only ultrastructure ceramics, but also photonic crystals and photothermal nanosecond light-switching devices. Industries dealing with semiconductors, electro-optics, ceramics, and composites stand to benefit from such advancements.

Doherty, Michael P.↗

NASA NTRS2003

Low-Power SOI CMOS Transceiver

The work aims at developing a low-power Silicon on Insulator Complementary Metal Oxide Semiconductor (SOI CMOS) Transceiver for deep-space communications. RF Receiver must accomplish the following tasks: (a) Select the desired radio channel and reject other radio signals, (b) Amplify the desired radio signal and translate them back to baseband, and (c) Detect and decode the information with Low BER. In order to minimize cost and achieve high level of integration, receiver architecture should use least number of external filters and passive components. It should also consume least amount of power to minimize battery cost, size, and weight. One of the most stringent requirements for deep-space communication is the low-power operation. Our study identified that two candidate architectures listed in the following meet these requirements: (1) Low-IF receiver, (2) Sub-sampling receiver. The low-IF receiver uses minimum number of external components. Compared to Zero-IF (Direct conversion) architecture, it has less severe offset and flicker noise problems. The Sub-sampling receiver amplifies the RF signal and samples it using track-and-hold Subsampling mixer. These architectures provide low-power solution for the short- range communications missions on Mars. Accomplishments to date include: (1) System-level design and simulation of a Double-Differential PSK receiver, (2) Implementation of Honeywell SOI CMOS process design kit (PDK) in Cadence design tools, (3) Design of test circuits to investigate relationships between layout techniques, geometry, and low-frequency noise in SOI CMOS, (4) Model development and verification of on-chip spiral inductors in SOI CMOS process, (5) Design/implementation of low-power low-noise amplifier (LNA) and mixer for low-IF receiver, and (6) Design/implementation of high-gain LNA for sub-sampling receiver. Our initial results show that substantial improvement in power consumption is achieved using SOI CMOS as compared to standard CMOS process. Potential advantages of SOI CMOS for deep-space communication electronics include: (1) Radiation hardness, (2) Low-power operation, and (3) System-on-Chip (SOC) solutions.

Fujikawa, Gene↗

NASA NTRS2002

The narrow pulse approximation and long length scale determination in xenon gas diffusion NMR studies of model porous media

We report a systematic study of xenon gas diffusion NMR in simple model porous media, random packs of mono-sized glass beads, and focus on three specific areas peculiar to gas-phase diffusion. These topics are: (i) diffusion of spins on the order of the pore dimensions during the application of the diffusion encoding gradient pulses in a PGSE experiment (breakdown of the narrow pulse approximation and imperfect background gradient cancellation), (ii) the ability to derive long length scale structural information, and (iii) effects of finite sample size. We find that the time-dependent diffusion coefficient, D(t), of the imbibed xenon gas at short diffusion times in small beads is significantly affected by the gas pressure. In particular, as expected, we find smaller deviations between measured D(t) and theoretical predictions as the gas pressure is increased, resulting from reduced diffusion during the application of the gradient pulse. The deviations are then completely removed when water D(t) is observed in the same samples. The use of gas also allows us to probe D(t) over a wide range of length scales and observe the long time asymptotic limit which is proportional to the inverse tortuosity of the sample, as well as the diffusion distance where this limit takes effect (approximately 1-1.5 bead diameters). The Pade approximation can be used as a reference for expected xenon D(t) data between the short and the long time limits, allowing us to explore deviations from the expected behavior at intermediate times as a result of finite sample size effects. Finally, the application of the Pade interpolation between the long and the short time asymptotic limits yields a fitted length scale (the Pade length), which is found to be approximately 0.13b for all bead packs, where b is the bead diameter. c. 2002 Elsevier Sciences (USA).

NASA Discipline Life Sciences Technologies↗

NASA NTRS1982

Frequency and Time Domain Modeling of Acoustic Liner Boundary Conditions

As part of a research program directed at the acoustics of advanced subsonic propulsion systems undertaken at NASA Langley, Duke University was funded to develop a boundary condition model for bulk-reacting nacelle liners. The overall objective of the Langley program was to understand and predict noise from advanced subsonic transport engines and to develop related noise control technology. The overall technical areas included: fan and propeller source noise, acoustics of ducts and duct liners, interior noise, subjective acoustics, and systems noise prediction. The Duke effort was directed toward duct liner acoustics for the development of analytical methods to characterize liner behavior in both frequency domain and time domain. A review of duct acoustics and liner technology can be found in Reference [1]. At that time, NASA Langley was investigating the propulsion concept of an advanced ducted fan, with a large diameter housed inside a relatively short duct. Fan diameters in excess of ten feet were proposed. The lengths of both the inlet and exhaust portions of the duct were to be short, probably less than half the fan diameter. The nacelle itself would be relatively thin-walled for reasons of aerodynamic efficiency. The blade-passage frequency was expected to be less than I kHz, and very likely in the 200 to 300 Hz range. Because of the design constraints of a short duct, a thin nacelle, and long acoustic wavelengths, the application of effective liner technology would be especially challenging. One of the needs of the NASA Langley program was the capability to accurately and efficiently predict the behavior of the acoustic liner. The traditional point impedance method was not an adequate model for proposed liner designs. The method was too restrictive to represent bulk reacting liners and to allow for the characterization of many possible innovative liner concepts. In the research effort at Duke, an alternative method, initially developed to handle bulk reacting layers as described in Reference [2], was extended to apply to a broad range of liner types. This method included the effect of local gradients along the liner surface, and was particularly appropriate for situations with flow over the liner and grazing incidence acoustic fields. In order to utilize time domain computational methods to solve for the propfan acoustic field, corresponding liner boundary conditions were developed for time domain solutions rather than frequency domain solutions.

Bliss, Donald B.↗

NASA NTRSDate not supplied

Enhancing Radiative Transfer Models for Optimized Assimilation of Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

NASA NTRSDate not supplied

Optimizing Assimilation of Microwave and Radar Observations in the NWP Models

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

NASA NTRSDate not supplied

Assimilation of Spaceborne Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

NASA NTRS2014

Dynamic Responses of the Earth's Outer Core to Assimilation of Observed Geomagnetic Secular Variation

Assimilation of surface geomagnetic observations and geodynamo models has advanced very quickly in recent years. However, compared to advanced data assimilation systems in meteorology, geomagnetic data assimilation (GDAS) is still in an early stage. Among many challenges ranging from data to models is the disparity between the short observation records and the long time scales of the core dynamics. To better utilize available observational information, we have made an effort in this study to directly assimilate the Gauss coefficients of both the core field and its secular variation (SV) obtained via global geomagnetic field modeling, aiming at understanding the dynamical responses of the core fluid to these additional observational constraints. Our studies show that the SV assimilation helps significantly to shorten the dynamo model spin-up process. The flow beneath the core-mantle boundary (CMB) responds significantly to the observed field and its SV. The strongest responses occur in the relatively small scale flow (of the degrees L is approx. 30 in spherical harmonic expansions). This part of the flow includes the axisymmetric toroidal flow (of order m = 0) and non-axisymmetric poloidal flow with m (is) greater than 5. These responses can be used to better understand the core flow and, in particular, to improve accuracies of predicting geomagnetic variability in future.

secular variation↗

NASA NTRS1986

Theory of idealized two-dimensional ballute in Newtonian hypersonic flow

A differential equation governing the geometry of a two-dimensional ballute in hypersonic flow and its constraining boundary conditions are derived under idealized assumptions. By solving these equations, the shape of the ballute is determined over a range of conditions. Lift, drag, pitching moment, and the allowed limit of center-of-gravity location for stability (meta-center) are then calculated using Newtonian hypersonic approximation. It is shown that the meta-center occurs near the forward end because of compliance of the ballute membrane to the shock layer pressures, especially at low free-stream densities. In order for the vehicle employing the ballute to be stable at all densities, the center of gravity must be within approximately the forward 20 percent of overall length of the vehicle. However, typical flight trajectories of an aeroassisted orbital transfer vehicle employing the ballute for aerobraking show that the vehicle may be able to complete its atmospheric flight without tumbling provided that the center of gravity is located within the forward 43 percent of the vehicle length because of the relatively short duration of flight through the destabilizing low-density regime.

Park, C.↗

NASA NTRSDate not supplied

A Machine Learning Ready Dataset of Acoustic Power Maps for Detection of Active Region Emergence

The development of an accurate forecast for solar eruptive activity has become increasingly important in order to prevent any potential impact on activities in space and the Earth's environment. It is therefore crucial to detect active regions before they appear on the solar surface and create early warning capabilities for upcoming Space Weather disturbances. In this work, 9TB of solar data (SDO/HMI dopplergrams, magnetograms and continuum intensity maps) involving the emergence of 61 NOAA solar active regions since 2010 were processed using the NASA HECC capabilities. An acoustic power maps time-series dataset was created (for four different frequency ranges and processed to take into account the solar sphere geometric effect ) which can be used for understanding the dynamics of the solar surface and train a variety of ML models. The calculated acoustic power maps carry precursor information associated with the decrease in continuum intensity on the solar surface, verifying older helioseismology research. Our results show that a Long Short-Term Memory (LSTMs) model, with a modest layer depth and the right hyperparameters tuned, when trained on this solar acoustic power maps dataset can predict without false negatives a drop in intensity (associated with the emergence of the active region), up to 18 hours in advance.

SMD↗

NASA NTRS1995

The rate of pyrite decomposition on the surface of Venus

We report the results of a detailed experiment study of the kinetics and mechanism of pyrite (FeS2) chemical weathering under Venus surface conditions. Pyrite is thermodynamically unstable on the surface of Venus and will spontaneously decompose to pyrrhotite (Fe7S8) because the observed S2 partial pressure in the lower atmosphere of Venus is lower than the S2 vapor pressure over coexisting pyrite and pyrrhotite. Pyrite decomposition kinetics were studied in pure CO2 and CO2 gas mixtures along five isotherms in the temperature range 390-531 C. In all gas mixtures studied, pyrite thermally decomposes to pyrrhotite (Fe7S8), which on continued heating loses sulfur to form more Fe-rich pyrrhotites. During this process the pyrrhotites are also being oxidized to form magnetite (Fe3O4), which converts to maghemite (gamma-Fe2O3), and then to hematite (alpha-Fe2O3). The reaction rates for pyrite thermal decomposition to pyrrhotite were determined by measuring the weight loss. The thickness of the unreacted pyrite in the samples provided a second independent reaction rate measurement. Finally, Mossbauer spectra done on 42 of the 115 experimental samples provided a third set of independent reaction rate data. Pyrite decomposition follows zero-order kinetics and is independent of the amount of pyrite present. The rate of pyrite decomposition is apparently independent of the gas compositions used and of the CO2 number density over a range of a factor of 40. The derived activation energy of approximately 150 kJ/mole is the same in pure CO2, two different CO-CO2 mixtures, and a ternary CO-SO2-CO2 mixture. Based on data for a CO-CO2-SO2 gas mixture with a CO number density approximately 10 times higher than at the surface of Venus and a SO2 number density approximately equal to that at the surface of Venus, the rate of pyrite destruction on the surface of Venus varies from about 1225 +/- 238 days/cm at the top of Maxwell Montes (approximately 660 K) to about 233 +/- 133 days/cm in the plains of Venus (approximately 740 K). These lifetimes are very short on a geological time scale and show that pyrite cannot exist on the surface of Venus for any appreciable length of time.

Fegley, B., Jr.↗

NASA NTRS2008

Hand-Held Units for Short-Range Wireless Biotelemetry

Special-purpose hand-held radiotransceiver units have been proposed as means of short-range radio powering and interrogation of surgically implanted microelectromechanical sensors and actuators. These units are based partly on the same principles as those of the units described in "Printed Multi- Turn Loop Antennas for RF Biotelemetry" (LEW-17879-1), NASA Tech Briefs, Vol. 31, No. 6 (June 2007), page 48. Like the previously reported units, these units would make it unnecessary to have wire connections between the implanted devices and the external equipment used to activate and interrogate them. Like a unit of the previously reported type, a unit of the type now proposed would include a printed-circuit antenna on a dielectric substrate. The antenna circuitry would include integrated surface-mount inductors for impedance tuning. Circuits for processing the signals transmitted and received by the antenna would be included on the substrate. During operation, the unit would be positioned near (but not in electrical contact with) a human subject, in proximity to a microelectromechanical sensor or actuator that has been surgically implanted in the subject. It has been demonstrated that significant electromagnetic coupling with an implanted device could be established at a distance of as much as 4 in. (.10 cm). During operation in the interrogation mode, the antenna of the unit would receive a radio telemetry signal transmitted by the surgically implanted device. The antenna substrate would have dimensions of approximately 3.25 by 3.75 inches (approximately 8.3 by 9.5 cm). The substrate would have a thickness of the order of 30 mils (of the order of a somewhat less than a millimeter). The substrate would be made of low-radiofrequency- loss dielectric material that could be, for example, fused quartz, alumina, or any of a number of commercially available radio-frequency dielectric composite materials. The antenna conductors would typically be made of copper or a combination of chromium and gold. The choice of metal and the thickness of the metal layer(s) would depend on the choice of substrate material. For example, on a quartz or alumina substrate, one would typically use a layer of chromium 150 A thick and a layer of gold 2 m thick. The proposed units and the implanted devices that they would interrogate or activate would be inherently safe to use. They would operate at low radiated-power levels for short interrogation times (typically, milliseconds). Hence, there would be little local heating of tissues surrounding the implanted devices and little absorption of radio energy by such sensitive body parts as the eyes and the brain. Because the implanted devices would not depend on battery power and would be activated only during short interrogation intervals and would otherwise be in the goff h state most of the time, the useful lifetimes of the implanted devices would be greater than those of comparable battery-powered implanted devices. The compactness of the hand-held transceiver units would facilitate transport and storage and would facilitate self-diagnosis by patients able to handle the units while away from medical facilities.

Miranda, Felix A.↗

NASA NTRS2020

A Sensitive Quantitative Analysis of Abiotically Synthesized Short Homopeptides using Ultraperformance Liquid Chromatography and Time-of-Flight Mass Spectrometry

In the origins of life field understanding the abiotic polymerization of simple organic monomers (e.g., amino acids) into larger biomolecules (e.g., oligopeptides), remains a seminal challenge. Recently, preliminary observations showed a limited set of peptides formed in the presence of the plausible prebiotic phosphorylating agent, diamidophosphate (DAP), highlighting the need for an analytical tool to critically evaluate the ability of DAP to induce oligomerization of simple organics under aqueous conditions. However, performing accurate and precise, targeted analyses of short oligopeptides remains a distinct challenge in the analytical chemistry field. Here, we developed a new technique to detect and quantitate amino acids and their homopeptides in a single run using ultraperformance liquid chromatography-fluorescence detection/time of flight mass spectrometry. Over an 8-minute retention time window, 18 target analytes were identified and quantitated, 16 of which were chromatographically separated at, or near baseline resolution. Compound identity was confirmed by accurate mass analysis using a 10 ppm mass tolerance window. This method featured limits of detection < 5 nM (< 1 fmol on column) and limits of quantitation (LOQs) <15 nM (< 3 fmol on column). The LODs and LOQs were upwards of ∼28x and ∼788x lower, respectively, than previous methods for the same analytes, highlighting the quantifiable advantages of this new method. Both detectors provided good quantitative linearity (R(exp 2) > 0.985) for all analytes spanning concentration ranges ∼3 - 4 orders of magnitude. We performed a series of laboratory experiments to investigate DAP-mediated oligomerization of amino acids and peptides and analyzed experimental products with the new method. DAP readily polymerized amino acids and peptides under a range of simulated environmental conditions. This research underscores the potential of DAP to have generated oligopeptides on the primordial Earth, enhancing prebiotic chemical diversity and complexity at or near the origin of life.

Prebiotic Chemistry and Analytical Chemistry↗

NASA NTRS2006

Constraints on the Formation of the Moon from High-Precision ND-Isotopic Measurements of Lunar Basalts

The most widely accepted theory for the formation of the Earth-Moon system proposes a giant impact model, where Earth collided in its later stages of accretion with a body of the approximate size of Mars [1, 2]. In this model, the Moon ultimately formed from hot debris generated during this giant impact. Short-lived radioisotopes such as Sm-146 (t(sub 1/2) = 103 Ma) may be useful in determining the chronology of the events that formed the Earth-Moon system and for how these terrestrial bodies evolved following accretion. New high-precision samarium-neodymium data showed that chondritic meteorites are on average 20 ppm lower in 142Nd/144Nd than terrestrial samples [3]. These data suggest that if the bulk silicate Earth (BSE) has a Sm/Nd ratio within the range measured for chondrites, the higher-than-chondritic Nd-142/Nd-144 ratio of terrestrial materials requires that the silicate Earth experienced a global chemical differentiation during the lifetime of Sm-146. If the Moon has super-chondritic Nd-142/Nd-144 identical to the Earth, as suggested by available data [4], then the giant impact must have occurred into an already differentiated Earth, predominantly sampling the Nd-depleted reservoir. In order to test this hypothesis, high-precision Nd-isotope ratios were obtained on a Thermo-Finnigan Triton TIMS for six lunar basalts that span the compositional range of lavas from the Moon: Samples 15555 and LAP 02205 represent low-Ti basalts; 70017 and 74275 are high-Ti basalts; 15386 and SAU 169 are KREEP basalts.

Rankenburg, K.↗

NASA NTRS1994

A processing centre for the CNES CE-GPS experimentation

CNES is involved in a GPS (Global Positioning System) geostationary overlay experimentation. The purpose of this experimentation is to test various new techniques in order to select the optimal station synchronization method, as well as the geostationary spacecraft orbitography method. These new techniques are needed to develop the Ranging GPS Integrity Channel services. The CNES experimentation includes three transmitting/receiving ground stations (manufactured by IN-SNEC), one INMARSAT 2 C/L band transponder and a processing center named STE (Station de Traitements de l'Experimentation). Not all the techniques to be tested are implemented, but the experimental system has to include several functions; part of the future system simulation functions, such as a servo-loop function, and in particular a data collection function providing for rapid monitoring of system operation, analysis of existing ground station processes, and several weeks of data coverage for other scientific studies. This paper discusses system architecture and some criteria used in its design, as well as the monitoring function, the approach used to develop a low-cost and short-life processing center in collaboration with a CNES sub-contractor (ATTDATAID), and some results.

Suard, Norbert↗

NASA NTRS2015

Transition, Training, and Assessment of Multispectral Composite Imagery in Support of the NWS Aviation Forecast Mission

The NASA/Short‐term Prediction, Research, and Transition (SPoRT) Program works closely with NOAA/NWS weather forecasters to transition unique satellite data and capabilities into operations in order to assist with nowcasting and short‐term forecasting issues. Several multispectral composite imagery (i.e. RGB) products were introduced to users in the early 2000s to support hydrometeorology and aviation challenges as well as incident support. These activities lead to SPoRT collaboration with the GOES‐R Proving Ground efforts where instruments such as MODIS (Aqua, Terra) and S‐NPP/VIIRS imagers began to be used as near‐realtime proxies to future capabilities of the Advanced Baseline Imager (ABI). One of the composite imagery products introduced to users was the Night‐time Microphysics RGB, originally developed by EUMETSAT. SPoRT worked to transition this imagery to NWS users, provide region‐specific training, and assess the impact of the imagery to aviation forecast needs. This presentation discusses the method used to interact with users to address specific aviation forecast challenges, including training activities undertaken to prepare for a product assessment. Users who assessed the multispectral imagery ranged from southern U.S. inland and coastal NWS weather forecast offices (WFOs), to those in the Rocky Mountain Front Range region and West Coast, as well as highlatitude forecasters of Alaska. These user‐based assessments were documented and shared with the satellite community to support product developers and the broad users of new generation satellite data.

Fuell, Kevin↗

NASA NTRS1995

Winds in hot main-sequence stars near the static limit

This project began with the acquisition of short-wavelength, high-dispersion IUE spectra of selected late O- and early B-type stars that are near the main sequence in open clusters and associations. The profiles of the resonance lines of N(V), Si(IV), and C(IV) were studied, and we found that the C(IV) lines are the most sensitive indicators of mass loss (stellar winds) in stars of this type. The mass loss manifests itself as an extension of the short-wavelength absorption wing of the doublet, while there is no P Cygni-type emission on the long-wavelength side of the line profile. We investigated whether the short-wavelength extension could be caused by blended lines of other ionic species formed in the photosphere. Although blending is present and introduces uncertainty into the estimation of the precise location on the main sequence of the onset of the mass-loss signature, it is a crucial issue only in a few marginal cases. Mass loss certainly overwhelms blending in its influence on the spectrum between spectral types B0 and B1 (effective temperatures in the range 25,000-27,000 K). We defined a parameter called P(sub w), to describe the degree of asymmetry of the C(IV) resonance-line profile, and we studied the dependence of this parameter on the fundamental stellar parameters. For this purpose, we derived new estimates of the stellar T(eff) and log g from a non-LTE, line-blanketed model-atmosphere analysis of these stars (Grigsby, Morrison, and Anderson 1992). In order to estimate the stellar luminosities, we performed an exhaustive search of the literature for the most reliable available estimates of the distances of the clusters and associations to which the program stars belong. The dependence of P(sub w) on stellar temperature and luminosity is also studied.

Morrison, Nancy D.↗

NASA NTRS1997

Documentation of Atmospheric Conditions During Observed Rising Aircraft Wakes

Flight tests were conducted in the fall of 1995 off the coast of Wallops Island, Virginia in order to determine characteristics of wake vortices at flight altitudes. A NASA Wallops Flight Facility C130 aircraft equipped with smoke generators produced visible wakes at altitudes ranging from 775 to 2225 m in a variety of atmospheric conditions, orientations (head wind, cross wind), and airspeeds. Meteorological and aircraft parameters were collected continuously from a Langley Research Center OV-10A aircraft as it flew alongside and through the wake vortices at varying distances behind the C130. Meteorological data were also obtained from special balloon observations made at Wallops. Differential GPS capabilities were on each aircraft from which accurate altitude profiles were obtained. Vortices were observed to rise at distances beyond a mile behind the C130. The maximum altitude was 150 m above the C130 in a near neutral atmosphere with significant turbulence. This occurred from large vertical oscillations in the wakes. There were several cases when vortices did not descend after a very short initial period and remained near generation altitude in a variety of moderately stable atmospheres and wind shears.

Zak, J. Allen↗