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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Development of a modulator to measure water vapor selectively in a gaseous mixture

Selective thermal modulation (STM) is a technique which produces a concentration-dependent pulse by selectively modulating a sample in a gas stream. Several types of modulation techniques, both chemical and physical, using adsorption, decomposition, and catalytic and mechanical methods have been developed for use with multiplex gas chromatography. Two of these applications involve selective modulation of the components present in the sample gas stream. The selective modulation of the concentration of specific sample molecules or classes of molecules provides additional analytical selectivity which can lead to selective detection. For some specific applications, the column may even be eliminated. Chemical modulation by absorption of a substance from the sample stream by a stationary phase will also produce a change in the signal intensity. Removal of a substance from the sample stream results in a signal containing a vacancy peak. In the work reported here, a selective thermal modulation technique has been developed as a method for determination of water vapor for possible use in Mars' atmosphere.

NASA Center ARC↗
NASA NTRS2005

Time Resolved Spectroscopy of Eclipsing Polars

No changes have been made since the last annual progress report was submitted in conjunction with a unilateral NCX. Dr. Barrett was affected by an STScI Reduction in Force (RIF). He is now employed by the Johns Hopkins University and plans to continue his research there. No expenses have been charged to this grant, however the FUSE data for the eclipsing polar V1432 Aql has been received and processed using CALFWSE v3.0.6. The resulting summed spectrum has been used for a preliminary analysis of the interstellar absorption towards V1432 Aql. We find a hydrogen column density of less than 1.5e21 cm^-2. We have used this result in the paper "X-Ray Emission and Optical Polarization of V1432 Aquilae: An Asynchronous Polar" to fix the hydrogen column density in the soft (<0.5 keV) X-ray band when analyzing the XMM-Newton spectra of this polar. This has enabled us to find an accurate temperature for the blackbody component of 88+/-2 eV, which is significantly higher than that of other polars (20 - 40 eV). We hope to complete our analysis of the phase-resolved emission line spectra of V1432 Aql and to prepare the results for publication in a refereed journal. We hope to begin work on this star within the next few months.

Barrett, Paul↗
NASA NTRS2009

Comparison of Weekly Cycle of NO2 Satellite Retrievals and NO(x) Emission Inventories for the Continental United States

Spatially resolved weekly NO2 variations are obtained from 2003 to 2005 Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY) tropospheric NO2 columns for three different types of regions: urban, rural, and rural-point (rural with significant electricity generation unit (EGU) emissions). Regions are compared for magnitudes and weekly profiles. Rural regions do not show any weekly pattern, whereas urban areas show a distinct decrease on the weekends. Rural regions with EGUs show a slight decrease on Sundays. When compared with estimated mobile and stationary nitrogen oxides (NO(x)) emissions from the year 2004 for seven cities, the satellite data have greater variation during weekdays (Monday-Friday). Overall comparisons show that SCIAMACHY derived NO2 correlate well with estimated NO(x) emissions for urban and rural but less for rural-point regions.

Kaynak, B.↗
NASA NTRS2011

Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) Aircraft Measurements of CO2

The Jet Propulsion Laboratory Carbon Dioxide Laser Absorption Spectrometer (CO2LAS) utilizes Integrated Path Differential Absorption (IPDA) at 2.05 microns to obtain CO2 column mixing ratios weighted heavily in the boundary layer. CO2LAS employs a coherent detection receiver and continuous-wave Th:Ho:YLF laser transmitters with output powers around 100 milliwatts. An offset frequency-locking scheme coupled to an absolute frequency reference enables the frequencies of the online and offline lasers to be held to within 200 kHz of desired values. We describe results from 2009 field campaigns when CO2LAS flew on the Twin Otter. We also describe spectroscopic studies aimed at uncovering potential biases in lidar CO2 retrievals at 2.05 microns.

Lidar↗
NASA NTRS2017

Feeding and Feedback in the Powerful Radio Galaxy 3C 120

We present a spectral analysis of a 200-kilosecond observation of the broad-line radio galaxy 3C 120, performed with the high-energy transmission grating spectrometer on board the Chandra X-Ray Observatory. We find (i) a neutral absorption component intrinsic to the source with a column density of log N (sub H) equals 20.67 plus or minus 0.05 square centimeters; (ii) no evidence for a warm absorber (WA) with an upper limit on the column density of just log N (sub H) less than 19.7 square centimeters, assuming the typical ionization parameter log xi approximately equal to 2.5 ergs per second per centimeter; the WA may instead be replaced by (iii) a hot emitting gas with a temperature kT approximately equal to 0.7 kiloelectronvolts observed as soft X-ray emission from ionized Fe L-shell lines, which may originate from a kiloparsec-scale shocked bubble inflated by the active galactic nucleus (AGN) wind or jet with a shock velocity of about 1000 kilometers per second determined by the emission line width; (iv) a neutral Fe K alpha line and accompanying emission lines indicative of a Compton-thick cold reflector with a low reflection fraction R approximately equal to 0.2, suggesting a large opening angle of the torus; (v) a highly ionized Fe XXV emission feature indicative of photoionized gas with an ionization parameter log xi equal to 3.75 (sup plus 0.38) (sub minus 0.27) ergs per second per centimeter and a column density of log N (sub H) greater than 22 square centimeters localized within approximately 2 pc from the X-ray source; and (vi) possible signatures of a highly ionized disk wind. Together with previous evidence for intense molecular line emission, these results indicate that 3C 120 is likely a late-state merger undergoing strong AGN feedback.

black hole physics – galaxies: active – line: ↗
DOE OSTI2020

Ammonia capture and recovery system and method for removing ammonia from a wastewater stream

A wastewater stream including ammonia and water is fed to at least one packed column including packing material having a surface of solid magnesium phosphate or solid magnesium ammonium phosphate or both. Each of the packed columns is capable of cycling between an ammonia absorption operation and an ammonia regeneration operation. The magnesium phosphate compound reacts with the water and ammonia to form a magnesium ammonium phosphate compound. In one embodiment, this system provides for the regeneration of the magnesium ammonium phosphate compound for further use as an ammonia sorber. In another embodiment, the magnesium ammonium phosphate compound is used as fertilizer. Additionally, the ammonia capture and recovery system may be used in conjunction with other unit operations in an overall wastewater treatment system.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2016

Discovery of Rapidly Moving Partial X-Ray Absorbers Within Cassiopeiae

Gamma Cassiopeiae is an enigmatic Be star with unusually strong hard X-ray emission. The Suzaku observatory detected six rapid X-ray spectral hardening events called "softness dips" in a approx.100 ks observation in 2011. All the softness dip events show symmetric softness-ratio variations, and some of them have flat bottoms apparently due to saturation. The softness dip spectra are best described by either approx.40% or approx.70% partial covering absorption to kT approx.12 keV plasma emission by matter with a neutral hydrogen column density of approx.(2−8) ×10(exp 21)/sq cm, while the spectrum outside these dips is almost free of absorption. This result suggests the presence of two distinct X-ray-emitting spots in the gamma Cas system, perhaps on a white dwarf (WD) companion with dipole mass accretion. The partial covering absorbers may be blobs in the Be stellar wind, the Be disk, or rotating around the WD companion. Weak correlations of the softness ratios to the hard X-ray flux suggest the presence of stable plasmas at kT approx 0.9 and 5 keV, which may originate from the Be or WD winds. The formation of a Be star and WD binary system requires mass transfer between two stars; gamma Cas may have experienced such activity in the past.

tars: emission-line↗
NASA NTRS1981

Detection of Lyman continuum absorption in the BL Lacertae object PKS 0735+178

The detection of the Lyman edge in the BL Lac object PKS 0735+178 at the absorption red shift determined by optical measurements leads to a lower limit for the column density of atomic hydrogen, N(H I) not less than 4(17)/sq cm. The Lyman-alpha absorption line appears to have been detected, but only an approximate upper limit can be obtained from the data, of the order of 2(19)/sq cm. This amount of atomic hydrogen is less than that for a line of sight through the disk of a normal spiral galaxy. It is suggested that the absorbing material exists either in the halo of a galaxy or in the tenuous, extended, gaseous disk of a galaxy.

Bregman, J. N.↗
NASA NTRS2001

Experimental and Numerical Investigation of Two Dimensional CO2 Adsorption/Desorption in Packed Sorption Beds under Non-Ideal Flows

The experimental results of CO2 adsorption and desorption in a packed column indicated that the concentration wave front at the center of the packed column differs from those which are close to the wall of column filled with adsorbent material even though the ratio of column diameter to the particle size is greater than 20. The comparison of the experimental results with one dimensional model of packed column shows that in order to simulate the average breakthrough in a packed column a two dimensional (radial and axial) model of packed column is needed. In this paper the mathematical model of a non-slip flow through a packed column with 2 inches in diameter and 18 inches in length filled with 5A zeolite pellets is presented. The comparison of experimental results of CO2 absorption and desorption for the mixed and central breakthrough of the packed column with numerical results is also presented.

Mohamadinejad, H.↗
NASA NTRS1993

Damped Lyman-alpha absorption in Q0957+561A, B

A series of archival IUE low-dispersion spectral observations of the double quasar Q0957+561A, B are analyzed. The components of this gravitationally lensed quasar are separated by about 6 arcsec. Damped Ly-alpha absorption at redshift z(abs) = 1.3911 with neutral hydrogen column density N(H I) about 7 x 10 exp 19/sq cm is present in the spectra of both the A and B components. Using an accepted model by Young et al. for the gravitational lens, the damped Ly-alpha absorber is inferred to have a minimum size of about 0.5/h50 kpc. The standard interpretation is that a damped Ly-alpha absorber represents a galactic or protogalactic H I disk. In the context of this standard model, the absorption-line properties and evidence for Faraday rotation are discussed.

Turnshek, David A.↗
NASA NTRS2018

A Cloud Algorithm Based on the O2-O2 477 nm Absorption Band Featuring an Advanced Spectral Fitting Method and the Use of Surface Geometry-Dependent Lambertian-Equivalent Reflectivity

We discuss a new cloud algorithm that retrieves an effective cloud pressure, also known as cloud optical centroid pressure (OCP), from oxygen dimer (O2-O2) absorption at 477nm after determining an effective cloud fraction (ECF) at 466nm, a wavelength not significantly affected by trace-gas absorption and rotational Raman scattering. The retrieved cloud products are intended for use as inputs to the operational nitrogen dioxide (NO2) retrieval algorithm for the Ozone Monitoring Instrument (OMI) flying on the Aura satellite. The cloud algorithm uses temperature-dependent O2-O2 cross sections and incorporates flexible spectral fitting techniques that account for specifics of the surface reflectivity. The fitting procedure derives O2-O2 slant column densities (SCDs) from radiances after O3, NO2, and H2O absorption features have been removed based on estimates of the amounts of these species from independent OMI algorithms. The cloud algorithm is based on the frequently used mixed Lambertian-equivalent reflectivity (MLER) concept. A geometry-dependent Lambertian-equivalent reflectivity (GLER), which is a proxy of surface bidirectional reflectance, is used for the ground reflectivity in our implementation of the MLER approach. The OCP is derived from a match of the measured O2-O2 SCD to that calculated with the MLER method. Temperature profiles needed for computation of vertical column densities are taken from the Global Modeling Initiative (GMI) model. We investigate the effect of using GLER instead of climatological LER on the retrieved ECF and OCP. For evaluation purposes, the retrieved ECFs and OCPs are compared with those from the operational OMI cloud product, which is also based on the same O2-O2 absorption band. Impacts of the application of the newly developed cloud algorithm to the OMI NO2 retrieval are discussed.

cloud fraction and pressure↗
NASA NTRS1995

Intergalactic Helium Absorption toward High-Redshift Quasars

The recent Hubble Space Telescope (HST) observations of the z(q) = 3.286 quasar Q0302-003 (Jakobsen et at. 1994) and the z(q) = 3.185 quasar Q1935-67 by Tytler (1995) show absorption edges at the redshifted wavelength of He II 304 A. A key goal is to distinguish between contributions from discrete Ly-alpha forest clouds and a smoothly distributed intergalactic medium (IGM). We model the contributions from each of these sources of He II absorption, including the distribution of line Doppler widths and column densities, the 'He II proximity effect' from the quasar, and a self-consistent derivation of the He II opacity of the universe as a function of the spectrum of ionizing sources, with the assumption that both the clouds and the IGM are photoionized. The He II edge can be fully accounted for by He II line blanketing for reasonable distributions of line widths and column densities in the Ly-alpha forest, provided that the ionizing sources have spectral index alpha(s) greater than 1.5, and any He II proximity effect is neglected. Even with some contribution from a diffuse IGM, it is difficult to account for the edge observed by Jakobsen et al. (1994) with a 'hard' source spectrum (alpha(s) less than 1.3). The proximity effect modifies the relative contributions of the clouds and IGM to tau(He II) near the quasar (z approx. less than z(q)) and markedly increases the amount of He II absorption required. This implies, for example, that to account for the He II edge with line blanketing alone, the minimum spectral index alpha(s) must be increased from 1.5 to 1.9. We demonstrate the need for higher resolution observations that characterize the change in transmission as z approaches z(q) and resolve line-free gaps in the continuum. We set limits on the density of the diffuse IGM and suggest that the IGM and Ly-alpha clouds are likely to be a significant repository for dark baryons.

Giroux, Mark L.↗
NASA NTRS2015

Advances in High Energy Solid-State Pulsed 2-Micron Lidar Development for Ground and Airborne Wind, Water Vapor and CO2 Measurements

NASA Langley Research Center has a long history of developing 2-micron lasers. From fundamental spectroscopy research, theoretical prediction of new materials, laser demonstration and engineering of lidar systems, it has been a very successful program spanning around two decades. Successful development of 2-micron lasers has led to development of a state-of-the-art compact lidar transceiver for a pulsed coherent Doppler lidar system for wind measurement with an unprecedented laser pulse energy of 250 millijoules in a rugged package. This high pulse energy is produced by a Ho:Tm:LuLiF laser with an optical amplifier. While the lidar is meant for use as an airborne instrument, ground-based tests were carried out to characterize performance of the lidar. Atmospheric measurements will be presented, showing the lidar's capability for wind measurement in the atmospheric boundary layer and free troposphere. Lidar wind measurements are compared to a balloon sonde, showing good agreement between the two sensors. Similar architecture has been used to develop a high energy, Ho:Tm:YLF double-pulsed 2-micron Integrated Differential Absorption Lidar (IPDA) instrument based on direct detection technique that provides atmospheric column CO2 measurements. This instrument has been successfully used to measure atmospheric CO2 column density initially from a ground mobile lidar trailer, and then it was integrated on B-200 plane and 20 hours of flight measurement were made from an altitude ranging 1500 meters to 8000 meters. These measurements were compared to in-situ measurements and National Oceanic and Atmospheric Administration (NOAA) airborne flask measurement to derive the dry mixing ratio of the column CO2 by reflecting the signal by various reflecting surfaces such as land, vegetation, ocean surface, snow and sand. The lidar measurements when compared showed a very agreement with in-situ and airborne flask measurement. NASA Langley Research Center is currently developing a triple-pulsed 2-micron Integrated Differential Absorption Lidar (IPDA) instrument for simultaneous measurement of water vapor and carbon-dioxide column density measurement from an air-borne platform. This presentation will give an overview of the 2 decades of 2-micron coherent and direction detection of laser/lidar development at NASA Langley Research Center and will present the ground and airborne wind and column CO2 measurement intercomparison with in-situ, balloon and flask measurements.

Singh, Upendra N.↗
DOE OSTI2022

Multi-species temperature and number density analysis of a laser-produced plasma using dual-comb spectroscopy

Dual-comb spectroscopy (DCS) represents a novel method of using absorption spectroscopy as a diagnostic tool for multispecies analysis of excitation temperatures and column densities in laser-produced plasmas (LPPs). DCS was performed on a LPP generated by ablating a multielement alloy containing Nd, Gd, and Fe. Transitions from all three elements were observed in absorption spectra measured from 530.08 to 535.19 nm at seven time-delays from 31 to 250 μs after ablation. The spectra were fit using a nonlinear regression algorithm to determine peak areas, and excitation temperatures and column densities were determined for the three atomic species separately using Boltzmann plots. The measured excitation temperatures of Nd I and Gd I showed good agreement at all time-delays, whereas the Fe I temperature was found to be higher, and the ratios between the column densities varied with delay. The observations are understood via effects of LPP spatial averaging, elemental fractionation, and molecular formation and are compared and contextualized with previous work studying LPPs using other spectroscopic techniques. A brief discussion of the precision and accuracy of the determined excitation temperatures and column densities is also presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Benchmarking Hydrogen Isotope Separation Efficiency of Pd/k–Packed TCAP Columns

By leveraging the large isotope effect in the palladium hydrogen isotope system, the Thermal Cycling Absorption Process (TCAP) provides an efficient and advantageous means to separate protium, deuterium, and tritium. To meet increased future tritium processing demands, such as those needed for fusion power plants, current designs of the separation columns need to be adapted and optimized using the progress made in understanding hydrogen isotope science. One key to this optimization lies in understanding the baseline performance for currently employed separation packing materials. Pd/k and molecular sieves, as commonly used for the separation of hydrogen isotopes, are herein evaluated to establish a baseline for their separation efficiency. Van Deemter plots are formulated, and the influence of each parameter is evaluated to determine areas for improvement.

Thermal Cycling Absorption Process (TCAP)↗
NASA NTRS1998

Impact of Tropospheric Aerosol Absorption on Ozone Retrieval from buv Measurements

The impact of tropospheric aerosols on the retrieval of column ozone amounts using spaceborne measurements of backscattered ultraviolet radiation is examined. Using radiative transfer calculations, we show that uv-absorbing desert dust may introduce errors as large as 10% in ozone column amount, depending on the aerosol layer height and optical depth. Smaller errors are produced by carbonaceous aerosols that result from biomass burning. Though the error is produced by complex interactions between ozone absorption (both stratospheric and tropospheric), aerosol scattering, and aerosol absorption, a surprisingly simple correction procedure reduces the error to about 1%, for a variety of aerosols and for a wide range of aerosol loading. Comparison of the corrected TOMS data with operational data indicates that though the zonal mean total ozone derived from TOMS are not significantly affected by these errors, localized affects in the tropics can be large enough to seriously affect the studies of tropospheric ozone that are currently undergoing using the TOMS data.

Torres, O.↗
NASA NTRS1994

Observations of ultraviolet-bright stars in globular clusters with the Hopkins Ultraviolet Telescope

Two UV-bright stars in globular clusters, UV5 in NGC 1851 and vZ 1128 in M3, were observed with the Hopkins Ultraviolet Telescope (HUT) during the Astro-1 space shuttle mission in 1990 December. The stars' spectra show weak absorption features and no significant emission features other than well known geocoronal lines. Detailed fitting of Kurucz (1991) stellar atmosphere models using a chi(sup 2) minimization technique indicates T(sub eff) = 16 000 K, log g = 2.5, and abundance (-1.0) (logarithm of abundance of elements heavier than helium relative to solar) for UV5, and T(sub eff) = 35 000 K, log g = 4.0, and abundance (-3.5) for vZ 1128. The Kurucz model which best fits vZ 1128 overpredicts the flux in the region below approximately 1000 A, an effect seen in previous models of O-type stars. Our results are robust (to within approximately 1000 K) with respect to uncertainties in interstellar reddening and atomic and molecular hydrogen column densities. We do not see significant molecular hydrogen absorption, which might have indicated material in a circumstellar shell, in either star's spectrum. We estimate the stellar luminosities to be log L/solar luminosity = 3.33 +/- 0.15 for UV5 and log L/solar luminosity = 3.21 +/- 0.12 for vZ 1128. These atmospheric parameters place both stars on the Schoenberner (post-AGB) tracks, though the stellar masses derived from the best-fitting Kurucz models are somewhat less than those predicted by the Schoenberner models. Examination of individual absorption line strengths reveals no significant abundance anomalies in either star.

Van Dyke Dixon, W.↗
NASA NTRS1988

Infrared measurements of increased CF2Cl2 (CFC-12) absorption above the South Pole

An increase in the CF2Cl2 total vertical column above the South pole of 1.24 + or - 0.15 over a 6-year period from 1980 to 1986, corresponding to an average increase of 3.6 + or - 2.1 percent, is found by high-resolution, ground-based solar spectra analyzed in the nu(8) band Q branches at 1161/cm of CF2Cl. This rate of increase is lower than indicated by in situ measurements at the South Pole over the same period, but substantial agreement results when the rather large error margins of the spectral analysis results are considered.

Rinsland, Curtis P.↗