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TRACER-CAT-UCDAVIS Aerosol Optical Properties and Sizing - smps

Aerosol size distribution and optical properties collected in La Port TX, during TRACER-CAT-UCDavis, July 2022. Speciated particle composition measurements are reported separately. All sampling was conducted with an identical aerosol inlet as the standard ARM-AOS systems. The TRacking Aerosol Convection interactions ExpeRiment Carbonaceous Aerosols Thrust by UC Davis (TRACER-CAT-UCDavis, July 2022) was designed to complement the larger ARM TRACER science goals to understand convective cloud lifecycles and aerosol-convection interactions. TRACER-CAT-UCDavis is focused on understanding the relationship between particle composition and light absorption and the influence of water uptake on this relationship. This aerosol data can be used to understand the relationship between particle composition and light absorption and the influence of water uptake on this relationship. Instruments include: UC Davis two-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS); Brechtel scanning electrical mobility sizer (SEMS); modified humidified cavity attenuated phase shift spectrometer with single scatter albedo (H-CAPS-SSA)

54 ENVIRONMENTAL SCIENCES↗

TRACER-CAT-UCDAVIS Aerosol Optical Properties and Sizing - crdps

Aerosol size distribution and optical properties collected in La Port TX, during TRACER-CAT-UCDavis, July 2022. Speciated particle composition measurements are reported separately. All sampling was conducted with an identical aerosol inlet as the standard ARM-AOS systems. The TRacking Aerosol Convection interactions ExpeRiment Carbonaceous Aerosols Thrust by UC Davis (TRACER-CAT-UCDavis, July 2022) was designed to complement the larger ARM TRACER science goals to understand convective cloud lifecycles and aerosol-convection interactions. TRACER-CAT-UCDavis is focused on understanding the relationship between particle composition and light absorption and the influence of water uptake on this relationship. This aerosol data can be used to understand the relationship between particle composition and light absorption and the influence of water uptake on this relationship. Instruments include: UC Davis two-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS); Brechtel scanning electrical mobility sizer (SEMS); modified humidified cavity attenuated phase shift spectrometer with single scatter albedo (H-CAPS-SSA)

54 ENVIRONMENTAL SCIENCES↗

The surface albedo of the earth in the near ultraviolet /330-340 nm/

Satellite-borne measurements of solar radiation backscattered by the earth and atmosphere allow a determination of the surface albedo in the near ultraviolet. The data yielded albedos at tropical latitudes during a 15-month period in 1979-1980. The wavelengths studied are 331.2 and 339.8 nm. Sixty-nine percent of the measurements imply albedos less than 0.3. Higher values include a contribution due to reflection from clouds and are consistent with previous estimates of the fractional cloudover in the tropics. An albedo histogram based on a bin width of 0.1 shows results in the range 0.1-0.2 to be the most frequent, appearing in 29% of the cases, although values which span the entire range 0.0-1.0 are present. The derived albedos show no correlation with solar zenith angle. This result is consistent with the fact that, at the wavelengths considered, the diffuse integrated intensity is larger than the attenuated direct solar beam near the ground.

Frederick, J. E.↗

The development of rainfall retrievals from radar at Darwin

Abstract. The U.S. Department of Energy Atmospheric Radiation Measurement program Tropical Western Pacific site hosted a C-band polarization (CPOL) radar in Darwin, Australia. It provides 2 decades of tropical rainfall characteristics useful for validating global circulation models. Rainfall retrievals from radar assume characteristics about the droplet size distribution (DSD) that vary significantly. To minimize the uncertainty associated with DSD variability, new radar rainfall techniques use dual polarization and specific attenuation estimates. This study challenges the applicability of several specific attenuation and dual-polarization-based rainfall estimators in tropical settings using a 4-year archive of Darwin disdrometer datasets in conjunction with CPOL observations. This assessment is based on three metrics: statistical uncertainty estimates, principal component analysis (PCA), and comparisons of various retrievals from CPOL data. The PCA shows that the variability in R can be consistently attributed to reflectivity, but dependence on dual-polarization quantities was wavelength dependent for 1 10mmh-1. Rainfall estimates during these conditions primarily originate from deep convective clouds with median drop diameters greater than 1.5 mm. An uncertainty analysis and intercomparison with CPOL show that a Colorado State University blended technique for tropical oceans, with modified estimators developed from video disdrometer observations, is most appropriate for use in all cases, such as when 1 10mmh-1 (deeper convective rain).

54 ENVIRONMENTAL SCIENCES↗

Results from Three Years of Ka-band Propagation Characterization at Svalbard, Norway

Over the next several years, NASA plans to launch several earth science missions which are expected to achieve data throughputs of 5-40 terabits per day transmitted from low earth orbiting spacecraft to ground stations. The current S-band and X-band frequency allocations in use by NASA, however, are incapable of supporting the data rates required to meet this demand. As such, NASA is in the planning stages to upgrade its existing Near Earth Network (NEN) polar ground stations to support Ka-band (25.5-27 GHz) operations. Consequently, it installed and operated a Ka-band radiometer at the Svalbard site. Svalbard was chosen as the appropriate site for two primary reasons: (1) Svalbard will be the first site to be upgraded to Ka-band operations within the NEN Polar Network enhancement plan, and (2) there exists a complete lack of Ka-band propagation data at this site (as opposed to the Fairbanks, AK NEN site, which has 5 years of characterization collected during the Advanced Communications Technology becomes imperative that characterization of propagation effects at these NEN sites is conducted to determine expected system Satellite (ACTS) campaign). processing and provide the Herein, we discuss the data three-year measurement results performance, particularly at low elevation angles ((is) less than 10 deg) from the ongoing Ka-band propagation characterization where spacecraft signal acquisition typically occurs. Since May 2011, NASA Glenn Research Center has installed and operated a Ka-band radiometer at the NEN site located in Svalbard, Norway. The Ka-band radiometer monitors the water vapor line, as well as 4 frequencies around 26.5 GHz at a fixed 10 deg elevation angle. Three-year data collection results indicate good campaign at Svalbard, Norway. Comparison of these results with the ITU models and existing ERA profile data indicates very good agreement when the 2010 rain maps and cloud statistics are used. Finally, the Svalbard data is used to derive the expected atmospheric margin requirements for this site agreement with models and comparable performance to necessary to maintain total system availability levels for the previously characterized northern latitude sites in the United States, i.e., Fairbanks, Alaska. The Svalbard data is used to upcoming Joint Polar Satellite System (JPSS) launch in the derive availability results for an upcoming earth-observation 2017/2022 timeframes. mission, JPSS-1, and indicate a requirement of 4 dB of atmospheric attenuation margin necessary to close the link with 99% overall system availability for the expected LEO orbital cycle, as observed from the Svalbard location.

Ka-band↗

Results from Three Years of Ka-Band Propagation Characterization at Svalbard, Norway

Over the next several years, NASA plans to launch several earth science missions which are expected to achieve data throughputs of 5-40 terabits per day transmitted from low earth orbiting spacecraft to ground stations. The current S-band and X-band frequency allocations in use by NASA, however, are incapable of supporting the data rates required to meet this demand. As such, NASA is in the planning stages to upgrade its existing Near Earth Network (NEN) polar ground stations to support Ka-band (25.5-27 GHz) operations. Consequently, it installed and operated a Ka-band radiometer at the Svalbard site. Svalbard was chosen as the appropriate site for two primary reasons: (1) Svalbard will be the first site to be upgraded to Ka-band operations within the NEN Polar Network enhancement plan, and (2) there exists a complete lack of Ka-band propagation data at this site (as opposed to the Fairbanks, AK NEN site, which has 5 years of characterization collected during the Advanced Communications Technology becomes imperative that characterization of propagation effects at these NEN sites is conducted to determine expected system Satellite (ACTS) campaign). processing and provide the Herein, we discuss the data three-year measurement results performance, particularly at low elevation angles ((is) less than 10 deg) from the ongoing Ka-band propagation characterization where spacecraft signal acquisition typically occurs. Since May 2011, NASA Glenn Research Center has installed and operated a Ka-band radiometer at the NEN site located in Svalbard, Norway. The Ka-band radiometer monitors the water vapor line, as well as 4 frequencies around 26.5 GHz at a fixed 10 deg elevation angle. Three-year data collection results indicate good campaign at Svalbard, Norway. Comparison of these results with the ITU models and existing ERA profile data indicates very good agreement when the 2010 rain maps and cloud statistics are used. Finally, the Svalbard data is used to derive the expected atmospheric margin requirements for this site agreement with models and comparable performance to necessary to maintain total system availability levels for the previously characterized northern latitude sites in the United States, i.e., Fairbanks, Alaska. The Svalbard data is used to upcoming Joint Polar Satellite System (JPSS) launch in the derive availability results for an upcoming earth-observation 2017/2022 timeframes. mission, JPSS-1, and indicate a requirement of 4 dB of atmospheric attenuation margin necessary to close the link with 99% overall system availability for the expected LEO orbital cycle, as observed from the Svalbard location.

near earth network↗

Radio-wave propagation for space communications systems

The most recent information on the effects of Earth's atmosphere on space communications systems is reviewed. The design and reliable operation of satellite systems that provide the many applications in space which rely on the transmission of radio waves for communications and scientific purposes are dependent on the propagation characteristics of the transmission path. The presence of atmospheric gases, clouds, fog, precipitation, and turbulence causes uncontrolled variations in the signal characteristics. These variations can result in a reduction of the quality and reliability of the transmitted information. Models and other techniques are used in the prediction of atmospheric effects as influenced by frequency, geography, elevation angle, and type of transmission. Recent data on performance characteristics obtained from direct measurements on satellite links operating to above 30 GHz have been reviewed. Particular emphasis has been placed on the effects of precipitation on the Earth/space path, including rain attenuation, and ice particle depolarization. Other factors are sky noise, antenna gain degradation, scintillations, and bandwidth coherence. Each of the various propagation factors has an effect on design criteria for communications systems. These criteria include link reliability, power margins, noise contribution, modulation and polarization factors, channel cross talk, error rate, and bandwidth limitations.

Ippolito, L. J.↗

Assimilation of Active MW and Radar Observations in the NWP Models

Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. This talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Precipitation -17 O-Excess Altered During Tropical Convection: Evidence From Monsoon Cold Surges in Singapore

Despite the recent recognition of -17 O-excess as a promising new tracer for hydrological processes, our knowledge of the control mechanisms underlying -17 O-excess in tropical regions remains limited. To understand how microphysical processes during tropical convection affect precipitation isotope ratios, particularly -17 O-excess, in Singapore, we collected precipitation samples at minute intervals from six rain events associated with cold surges during the Northeast Monsoon seasons and analyzed their triple oxygen isotopes. Our results show that precipitation δ -18 O decreases in the convective zones and then gradually increases in the stratiform zones, while d-excess exhibits an inverse trend. This correlation between δ -18 O and d-excess indicates that rain evaporation plays a crucial role in regulating precipitation isotopes. Moreover, the rain events with a higher upstream rainout amount have lower δ -18 O and higher -17 O-excess values, suggesting that precipitation δ -18 O and -17 O-excess likely reflect the integrated upstream convective activity. Microphysical processes associated with upstream convection, such as rain evaporation and vapor recycling, are potential mechanisms that increase -17 O-excess values along moisture transport pathways for a rain event, and hence, undermine the effectiveness of -17 O-excess as a tracer of moisture source humidity. Contrary to the negative correlation observed in monthly precipitation, there is generally a positive correlation between d-excess and -17 O-excess at the event scale. However, this correlation weakens as convective rain intensifies, suggesting that stronger convection can attenuate the positive correlation between d-excess and -17 O-excess. Therefore, it is crucial to consider how tropical convection alters -17 O-excess when utilizing this tracer to interpret atmospheric dynamics and hydrological processes.

tropical weather systems↗

Microphysical Retrievals Over Stratiform Rain Using Measurements from an Airborne Dual-Wavelength Radar-Radiometer

The need to understand the complementarity of the radar and radiometer is important not only to the Tropical Rain Measuring Mission (TRMM) program but to a growing number of multi-instrumented airborne experiment that combine single or dual-frequency radars with multichannel radiometers. The method of analysis used in this study begins with the derivation of dual-wavelength radar equations for the estimation of a two-parameter drop size distribution (DSD). Defining a "storm model" as the set of parameters that characterize snow density, cloud water, water vapor, and features of the melting layer, then to each storm model there will usually correspond a set of range-profiled drop size distributions that are approximate solutions of the radar equations. To test these solutions, a radiative transfer model is used to compute the brightness temperatures for the radiometric frequencies of interest. A storm model or class of storm models is considered optimum if it provides the best reproduction of the radar and radiometer measurements. Tests of the method are made for stratiform rain using simulated storm models as well as measured airborne data. Preliminary results show that the best correspondence between the measured and estimated radar profiles usually can be obtained by using a moderate snow density (0.1-0.2 g/cu cm), the Maxwell-Garnett mixing formula for partially melted hydrometeors (water matrix with snow inclusions), and low to moderate values of the integrated cloud liquid water (less than 1 kg/sq m). The storm-model parameters that yield the best reproductions of the measured radar reflectivity factors also provide brightness temperatures at 10 GHz that agree well with the measurements. On the other hand, the correspondence between the measured and modeled values usually worsens in going to the higher frequency channels at 19 and 34 GHz. In searching for possible reasons for the discrepancies, It is found that changes in the DSD parameter Mu, the radar constants, or the path-integrated attenuation can affect the high frequency channels significantly. In particular, parameters that cause only modest increases in the median mass diameter of the snow, and which have a minor effect on the radar returns or the low frequency brightness temperature, can produce a strong cooling of the 34 GHz brightness temperature.

Meneghini, Robert↗

Enhancing Radiative Transfer Models for Optimized Assimilation of Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Optimizing Assimilation of Microwave and Radar Observations in the NWP Models

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Assimilation of Spaceborne Microwave and Radar Observations

Radiative transfer models are extensively used for the assimilation of satellite observations into NWP models as well as retrieving geophysical products from satellite measurements. The Community Radiative Transfer Model (CRTM) is a community model developed by NOAA JCSDA and widely used for different purposes requiring RT calculations. CRTM requires bulk optical properties of hydrometeors in the form of lookup tables in order to perform all-sky RT calculations. However, the current cloud scattering lookup tables in CRTM assume spherical shapes for all frozen hydrometeors, whereas actual clouds contain frozen particles with diverse shapes. The first part of this talk presents the implementation and validation of a comprehensive Discrete Dipole Approximation (DDA) cloud scattering database into CRTM, specifically targeting microwave frequencies. The DDA technique proves effective in simulating the optical properties of non-spherical hydrometeors in the microwave region. The original DDA database assumes total random orientation in calculating single scattering properties. To generate the required mass scattering parameters for CRTM, the single scattering properties and water content dependent particle size distributions are used. The evaluation of results involved a collocated dataset comprising short-term forecasts from the Integrated Forecast System of the European Center for Medium-Range Weather Forecasts and satellite microwave data. The findings demonstrate that the DDA lookup tables significantly reduce discrepancies between simulated and observed values when compared to the Mie tables. Passive instruments lack the ability to provide vertically resolved measurements of clouds and precipitation, which can be obtained by active radar instruments. However, incorporating these active measurements into data assimilation systems presents challenges due to the absence of fast forward radiative transfer models and difficulties in error modeling. The second part of the talk focuses on the development, evaluation, and sensitivity analysis of a forward radar model integrated into CRTM. The forward radar model utilizes scattering properties obtained from hydrometeor lookup tables generated using the discrete dipole approximation. By utilizing CRTM instrument-specific coefficients, the model can calculate both reflectivity and attenuated reflectivity for any given radar instrument and zenith angles. Evaluation using CloudSat measurements demonstrates a strong agreement between simulations and observations when the input profiles of hydrometeors align with the measured reflectivity profiles.

Isaac Moradi↗

Spectrally Simplified Approach for Leveraging Legacy Geostationary Oceanic Observations

The use of multispectral geostationary satellites to study aquatic ecosystems improves the temporal frequency of observations and mitigates cloud obstruction, but no operational capability presently exists for the coastal and inland waters of the United States. The Advanced Baseline Imager (ABI) on the current iteration of the Geostationary Operational Environmental Satellites, termed the R Series (GOES-R), however, provides sub-hourly imagery and the opportunity to overcome this deficit and to leverage a large repository of existing GOES-R aquatic observations. The fulfillment of this opportunity is assessed herein using a spectrally simplified, two-channel aquatic algorithm consistent with ABI wave bands to estimate the diffuse attenuation coefficient for photosynthetically available radiation, K(d)(PAR). First, an in situ ABI dataset was synthesized using a globally representative dataset of above- and in-water radiometric data products. Values of K(d)(PAR) were estimated by fitting the ratio of the shortest and longest visible wave bands from the in situ ABI dataset to coincident, in situ K(d)(PAR) data products. The algorithm was evaluated based on an iterative cross-validation analysis in which 80% of the dataset was randomly partitioned for fitting and the remaining 20% was used for validation. The iteration producing the median coefficient of determination (R2) value (0.88) resulted in a root mean square difference of 0.319 m−1, or 8.5% of the range in the validation dataset. Second, coincident mid-day images of central and southern California from ABI and from the Moderate Resolution Imaging Spectroradiometer (MODIS) were compared using Google Earth Engine (GEE). GEE default ABI reflectance values were adjusted based on a near infrared signal. Matchups between the ABI and MODIS imagery indicated similar spatial variability (R2 = 0.60) between ABI adjusted blue-to-red reflectance ratio values and MODIS default diffuse attenuation coefficient for spectral downward irradiance at 490 nm, K(d)(490), values. This work demonstrates that if an operational capability to provide- ABI aquatic data products was realized, the spectral configuration of ABI would potentially support a sub-hourly, visible aquatic data product that is applicable to water-mass tracing and physical oceanography research.

Advanced Baseline Imager↗

Shocks propagate in a 2D dusty plasma with less attenuation than due to gas friction alone

In a dusty plasma, an impulsively generated shock, i.e., blast wave, was observed to decay less than would be expected due to gas friction alone. In the experiment, a single layer of microparticles was levitated in a radio frequency glow-discharge plasma. In this layer, the microparticles were self-organized as a 2D solid-like strongly coupled plasma, which was perturbed by the piston-like mechanical movement of a wire. To excite a blast wave, the wire's motion was abruptly stopped, so that the input of mechanical energy ceased at a known time. It was seen that, as it propagated across the layer, the blast wave's amplitude persisted with little decay. This result extends similar findings, in previous experiments with 3D microparticle clouds, to the case of 2D clouds. In our cloud, out-of-plane displacements were observed, lending support to the possibility that an instability, driven by wakes in the ion flow, provides energy that sustains the blast wave's amplitude despite the presence of gas damping.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Spatial sampling errors for a satellite-borne scanning radiometer

The Clouds and Earth's Radiant Energy System (CERES) scanning radiometer is planned as the Earth radiation budget instrument for the Earth Observation System, to be flown in the late 1990's. In order to minimize the spatial sampling errors of the measurements, it is necessary to select design parameters for the instrument such that the resulting point spread function will minimize spatial sampling errors. These errors are described as aliasing and blurring errors. Aliasing errors are due to presence in the measurements of spatial frequencies beyond the Nyquist frequency, and blurring errors are due to attenuation of frequencies below the Nyquist frequency. The design parameters include pixel shape and dimensions, sampling rate, scan period, and time constants of the measurements. For a satellite-borne scanning radiometer, the pixel footprint grows quickly at large nadir angles. The aliasing errors thus decrease with increasing scan angle, but the blurring errors grow quickly. The best design minimizes the sum of these two errors over a range of scan angles. Results of a parameter study are presented, showing effects of data rates, pixel dimensions, spacecraft altitude, and distance from the spacecraft track.

Manalo, Natividad D.↗

The PACE-MAPP Algorithm: Coupled Ocean/Aerosol Products

The PACE-MAPP algorithm, under development for combined SPEXone, HARP2 and OCI observations from NASA’s future Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) satellite mission, directly inverts the coupled atmosphere-ocean system to retrieve aerosol optical and microphysical properties and ocean optical properties simultaneously. PACE-MAPP thus retrieves the spectrally-resolved inherent optical properties of the Earth’s waters: the spectral particulate scattering coefficient, b_p (λ), the spectral absorption coefficient for particulates and color-dissolved matter, a_tot (λ), and the spectral particulate backscatter efficiency, b ̃_"bp". From these three spectrally-resolved components, we can derive the spectral particulate hemispherical backscattering coefficient b_bp (λ) and the spectral diffuse attenuation coefficient K_"d" (λ). Direct comparisons of b_"bp" (532) and K_"d" (532) are made to collocated High-Spectral Resolution Lidar (HSRL) in-water measurements. The PACE-MAPP algorithm was tested using PACE-analog datasets collected by Research Scanning Polarimeter (RSP) observations during the NASA NAAMES (The North Atlantic Aerosols and Marine Ecosystems Study) and SABOR (Ship-Aircraft Bio-Optical Research) airborne campaigns, both of which also include ship-based in situ measurements.

Snorre Alfred Moen Stamnes↗

TRACER Carbonaceous Aerosols Thrust – University of California, Davis Field Campaign Report

The broader U.S. Department of Energy Atmospheric Radiation Measurement (ARM) user facility’s TRacking Aerosol Convection interactions ExpeRiment (TRACER) campaign aims to increase our understanding of convective cloud life cycles and aerosol-convection interactions. Our TRACER Carbonaceous Aerosols Thrust-University of California, Davis (TRACER-CAT-UCDavis) study complemented these broader aims by characterizing and quantifying the optical properties and composition of carbonaceous aerosols during part of the TRACER intensive sampling period (July 1- July 31, 2022) at the first ARM Mobile Facility (AMF1) main site (M1) in La Porte, Texas. Our measurements complemented the suite of instrumentation already provided by the AMF1, expanding the capabilities through deployment of unique, state-of-the-science instrumentation. The instrumentation included: (i) two cavity-attenuated phase shift spectroscopy single-scatter albedo (CAPS-SSA) instruments operating at 530 nm and 630 nm, and that were modified to characterize particle light absorption, extinction, and scattering at elevated humidities; (ii) the UC Davis dual-wavelength cavity ringdown-photoacoustic spectrometer (CRD-PAS), which characterizes dry particle extinction and absorption at 405 nm and 532 nm; (iii) a soot particle aerosol mass spectrometer (SP-AMS) that operated in “laser only” mode that characterized the size-dependent compositions of black carbon (BC)-containing particles; (v) a thermal denuder, to remove coatings on particles; and (vi) a scanning electrical mobility sizer (SEMS), to characterize particle mobility diameters from 10-1300 nm. Our measurements occurred alongside complementary observations made by Los Alamos National Laboratory (LANL) during the TRACER-CAT-LANL study, including a humidified CAPS-SSA instrument operating at 450 nm. Our primary scientific interest is in understanding the relationship between particle composition and light absorption, with a particular focus on the influence of water uptake. While it is known that coatings on BC can enhance absorption, the extent to which this occurs in the atmosphere and the specific role that water plays as a coating remain unclear. The TRACER-CAT-UCDavis measurements were made with near-complete coverage for the CRD-PAS, SP-AMS, and SEMS throughout the intensive period. The UC Davis humidified CAPS-SSA instruments had significant challenges with operation owing to the demanding conditions (large temperature fluctuations, high humidity), exacerbated by supply chain issues that delayed resolution of these challenges. However, the humidified CAPS-SSA instrument operated by LANL operated throughout the intensive period with near-complete coverage. The dry light extinction measurements from the CRD-PAS measurements and the LANL CAPS-SSA exhibited a good correlation, although the CAPS-SSA systematically measured greater extinction values than expected. While all instruments, with the exception of an aerodynamic particle sizer (APS), measured behind a common particulate matter (PM)2.5 μm cyclone, the greater extinction measured by the LANL CAPS-SSA compared to the CRD-PAS may have resulted from different losses of larger particles in the sampling lines from the cyclone to the instruments; the tubing length was shorter from the cyclone to the LANL CAPS-SSA, consistent with this idea. A summary of the TRACER-CAT-UCDavis measurements, along with some of the TRACER-CAT-LANL measurements, are shown in the figure below. Notably, there were periods when the contributions of presumed dust were substantial and even dominated the observed light extinction and absorption. Also, there was a clear shift in the behavior of submicron particles from before July 16, 2022 to after, with the prior period exhibiting regular episodes of new particle formation and the latter period exhibiting rapid variations in the concentrations of small particles.

54 ENVIRONMENTAL SCIENCES↗