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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

How Precisely Can Individual Molecules Be Analyzed? A Case Study on Locally Quantifying Forces and Energies Using Scanning Probe Microscopy

Recent advances in scanning probe microscopy methodology have enabled the measurement of tip-sample interactions with picometer accuracy in all three spatial dimensions, thereby providing a detailed site-specific and distance-dependent picture of the related properties. This paper explores the degree of detail and accuracy that can be achieved in locally quantifying probe-molecule interaction forces and energies for adsorbed molecules. Toward this end, cobalt phthalocyanine (CoPc), a promising CO 2 reduction catalyst, was studied on Ag(111) as a model system using low-temperature, ultrahigh vacuum noncontact atomic force microscopy. Data were recorded as a function of distance from the surface, from which detailed three-dimensional maps of the molecule's interaction with the tip for normal and lateral forces as well as the tip-molecule interaction potential were constructed. The data were collected with a CO molecule at the tip apex, which enabled a detailed visualization of the atomic structure. Determination of the tip-substrate interaction as a function of distance allowed isolation of the molecule-tip interactions; when analyzing these in terms of a Lennard-Jones-type potential, the atomically resolved equilibrium interaction energies between the CO tethered to the tip and the CoPc molecule could be recovered. Interaction energies peaked at less than 160 meV, indicating a physisorption interaction. As expected, the interaction was weakest at the aromatic hydrogens around the periphery of the molecule and strongest surrounding the metal center. In conclusion, the interaction, however, did not peak directly above the Co atom but rather in pockets surrounding it.

36 MATERIALS SCIENCE↗

In-flight acoustic results from an advanced-design propeller at Mach numbers to 0.8

Acoustic data for the advanced-design SR-3 propeller at Mach numbers to 0.8 and helical tip Mach numbers to 1.14 are presented. Several advanced-design propellers, previously tested in wind tunnels at the Lewis Research Center, are being tested in flight at the Dryden Flight Research Facility. The flight-test propellers are mounted on a pylon on the top of the fuselage of a JetStar airplane. Instrumentation provides near-field acoustic data for the SR-3. Acoustic data for the SR-3 propeller at Mach numbers up to 0.8, for propeller helical tip Mach numbers up to 1.14, and comparison of wind tunnel to flight data are included. Flowfield profiles measured in the area adjacent to the propeller are also included.

Mackall, K. G.↗

Tension fracture of laminates for transport fuselage. Part 2: Large notches

Tests were conducted on over 200 center-crack specimens to evaluate: (a) the tension-fracture performance of candidate materials and laminates for commercial fuselage applications; and (b) the accuracy of several failure criteria in predicting response. Crack lengths of up to 12 inches were considered. Other variables included fiber/matrix combination, layup, lamination manufacturing process, and intraply hybridization. Laminates fabricated using the automated tow-placement process provided significantly higher tension-fracture strengths than nominally identical tape laminates. This confirmed earlier findings for other layups, and possibly relates to a reduced stress concentration resulting from a larger scale of repeatable material inhomogeneity in the tow-placed laminates. Changes in material and layup result in a trade-off between small-notch and large-notch strengths. Toughened resins and 0 deg-dominate layups result in higher small-notch strengths but lower large-notch strengths than brittle resins, 90 deg and 45 deg dominated layups, and intraply S2-glass hybrid material forms. Test results indicate that strength-prediction methods that allow for a reduced order singularity of the crack-tip stress field are more successful at predicting failure over a range of notch sizes than those relying on the classical square-root singularity. The order of singularity required to accurately predict large-notch strength from small-notch data was affected by both material and layup. Measured crack-tip strain distributions were generally higher than those predicted using classical methods. Traditional methods of correcting for finite specimen width were found to be lacking, confirming earlier findings with other specimen geometries. Fracture tests of two stiffened panels, identical except for differing materials, with severed central stiffeners resulted in nearly identical damage progression and failure sequences. Strain-softening laws implemented within finite element models appear attractive to account for load redistribution in configured structure due to damage-induced crack tip softening

Walker, Tom H.↗

Two-dimensional aerodynamic characteristics of the OLS/TAAT airfoil

Two flight tests have been conducted that obtained extension pressure data on a modified AH-1G rotor system. These two tests, the Operational Loads Survey (OLS) and the Tip Aerodynamics and Acoustics Test (TAAT) used the same rotor set. In the analysis of these data bases, accurate 2-D airfoil data is invaluable, for not only does it allow comparison studies between 2- and 3-D flow, but also provides accurate tables of the airfoil characteristics for use in comprehensive rotorcraft analysis codes. To provide this 2-D data base, a model of the OLS/TAAT airfoil was tested over a Reynolds number range from 3 x 10 to the 6th to 7 x 10 to the 7th and between Mach numbers of 0.34 to 0.88 in the NASA Langley Research Center's 6- by 28-Inch Transonic Tunnel. The 2-D airfoil data is presented as chordwise pressure coefficient plots, as well as lift, drag, and pitching moment coefficient plots and tables.

Watts, Michael E.↗

Modeling Macro- and Micro-Scale Turbulent Mixing and Chemistry in Engine Exhaust Plumes

Simulation of turbulent mixing and chemical processes in the near-field plume and plume-vortex regimes has been successfully carried out recently using a reduced gas phase kinetics mechanism which substantially decreased the computational cost. A detailed mechanism including gas phase HOx, NOx, and SOx chemistry between the aircraft exhaust and the ambient air in near-field aircraft plumes is compiled. A reduced mechanism capturing the major chemical pathways is developed. Predictions by the reduced mechanism are found to be in good agreement with those by the detailed mechanism. With the reduced chemistry, the computer CPU time is saved by a factor of more than 3.5 for the near-field plume modeling. Distributions of major chemical species are obtained and analyzed. The computed sensitivities of major species with respect to reaction step are deduced for identification of the dominant gas phase kinetic reaction pathways in the jet plume. Both the near field plume and the plume-vortex regimes were investigated using advanced mixing models. In the near field, a stand-alone mixing model was used to investigate the impact of turbulent mixing on the micro- and macro-scale mixing processes using a reduced reaction kinetics model. The plume-vortex regime was simulated using a large-eddy simulation model. Vortex plume behind Boeing 737 and 747 aircraft was simulated along with relevant kinetics. Many features of the computed flow field show reasonable agreement with data. The entrainment of the engine plumes into the wing tip vortices and also the partial detrainment of the plume were numerically captured. The impact of fluid mechanics on the chemical processes was also studied. Results show that there are significant differences between spatial and temporal simulations especially in the predicted SO3 concentrations. This has important implications for the prediction of sulfuric acid aerosols in the wake and may partly explain the discrepancy between past numerical studies (that employed parabolic or temporal approximations) and the measured data. Finally to address the major uncertainty in the near-field plume modeling related to the plume processing of sulfur compounds and advanced model was developed to evaluate its impact on the chemical processes in the near wake. A comprehensive aerosol model is developed and it is coupled with chemical kinetics and the axisymmetric turbulent jet flow models. The integrated model is used to simulate microphysical processes in the near-field jet plume, including sulfuric acid and water binary homogeneous nucleation, coagulation, non-equilibrium heteromolecular condensation, and sulfur-induced soot activation. The formation and evolution of aerosols are computed and analyzed. The computed results show that a large number of ultra-fine (0.3--0.6 nm in radius) volatile HSO4 - HO embryos are generated in the near-field plume. These embryos further grow in size by self coagulation and condensation. Soot particles can be activated by both heterogeneous nucleation and scavenging of H2SO4-H2O aerosols. These activated soot particles can serve as water condensation nuclei for contrail formation. Conditions under which ice contrails can form behind aircrafts are studied. The sensitivities of the threshold temperature for contrail formation with respect to aircraft propulsion efficiency, relative humidity, and ambient pressure are evaluated. The computed aerosol properties for different extent of fuel sulfur conversion to S(VI) (SO3 and H2SO4) in engine are examined and the results are found to be sensitive to this conversion fraction.

Menon, Suresh↗

A Comparison of Measured and Predicted XV-15 Tiltrotor Surface Acoustic Pressures

Predicted XV-15 exterior surface acoustic pressures are compared with previously published experimental data. Surface acoustic pressure transducers were concentrated near the tip-path-plane of the rotor in airplane mode. The comparison emphasized cruise conditions which are of interest for tiltrotor interior noise - level flight for speeds ranging from 72 m/s to 113 m/s. The predictions were produced by components of the NASA Langley Tiltrotor Aeroacoustic Code (TRAC) system of computer codes. Comparisons between measurements and predictions were made in both the time and frequency domains, as well as overall sound pressure levels. In general, the predictions replicated the measured data well. Discrepancies between measurements and predictions were noted. Some of the discrepancies were due to poor correlation of the measured data with the rotor tach signal. In other cases limitations of the predictive methodology have been indicated.

Lyle, Karen H.↗

Rotary balance data for a single-engine agricultural airplane configuration for an angle-of-attack range of 8 deg to 90 deg

Aerodynamic characteristics obtained in a helical flow environment utilizing a rotary balance located in the Langley spin tunnel are presented in plotted form for a 1/10 scale single engine agricultural airplane model. The configurations tested include the basic airplane, various wing leading edge and wing tip devices, elevator, aileron, and rudder control settings, and other modifications. Data are presented without analysis for an angle of attack range of 8 deg to 90 deg, and clockwise and counter-clockwise rotations covering a spin coefficient range from 0 to .9.

Mulcay, W. J.↗

Fatigue Behavior of a Third Generation PM Disk Superalloy

The fatigue behavior of a 3rd generation PM disk alloy, LSHR, was studied at 1300 F. Tensile, creep, and fatigue tests were run on smooth and notched (Kt = 2) bars under a variety of conditions. Analysis of smooth bar fatigue data, run under strain and load control with R ratios of 0 and -1, showed that a stress based Smith-Watson-Topper approach could collapse the data set. While the tensile and creep data showed substantial notch strengthening at 1300 F, the fatigue data showed a life deficit for the notch specimens. A viscoplastic finite element model, which accounted for stress relaxation at the notch tip, provided the best correlation between the notched and smooth bar behavior, although the fatigue data was not fully rationalized based on this simplified viscoplastic model of the stresses at the notch tip.Inclusion of a 90 sec dwell at peak load was found to dramatically decrease notch fatigue life. This result was shown to be consistent with a simple linear creep-fatigue damage rule, where creep damage dominated at low stresses and fatigue damage was more prevalent at higher stresses.

Gayda, John↗

Effects of Nose Radius and Extreme Cooling on Boundary-Layer Transition for Three Smooth 15°-Cone-Cylinders in Free Flight at Mach Numbers to 8.50

Three highly polished 15°- included- angle cone- cylinders with hemispherical tips of several diameters ( 2, 3, and 4 in.) have been flown in order to obtain boundary- layer transition data at very low wall to local stream temperature ratios, and heat- transfer data. All surfaces had a 2-microinch average roughness height. Laminar flow existed over the entire hemispherical nose of the 2- and 3-inch-tip- diameter models throughout the complete flight history. Extreme cooling to wall to local stream temperature ratios at the sonic point as low as 0.20 did not cause transition on the nose for diameters as large as 3 inches. However, extreme cooling did cause early transition on the 4-inch model where it appears probable that transition occurred forward of the 45° station at a wall to local stream temperature ratio of about 0.26. Variations in tip diameter influenced transition downstream of the nose under conditions of extreme cooling. The 2-inch- tip model was laminar at all cone- cylinder stations at temperature ratios as low as 0.32 whereas the 3- and 4-inch-tip models were turbulent at the same local flow conditions but at higher wall to local temperature ratios. Transition on the cone and cylinder of the 3- and 4-inch- tip bodies appeared to be sensitive to local Mach number, and occurred at higher local temperature ratios when values of local Mach number were higher. Increasing the nose diameter from 2 to 3 inches significantly changed the local flow conditions for which laminar flow existed on the cone- cylinder afterbody. However, a further increase in tip size t o a 4-inch diameter had no discernable effect on the local flow conditions at transition. The transition results of the 3- and 4-inch-nose-diameter smooth bodies are similar to those observed on a 7/8-inch-nose-diameter body with roughened surfaces. Turbulent boundary layers resulted in both cases at very low wall to local stream temperature ratios. Both laminar and turbulent heat-transfer data were in good agreement with theoretical Stanton numbers when heat-transfer reduction due to tip blunting was considered.

CYLINDRICAL AFTERBODY↗

Analysis of Free-Flight Laminar, Transitional, and Turbulent Heat-Transfer Results at Free-Stream Mach Numbers Near 20 (Reentry F)

Laminar, transitional, and turbulent heat-transfer data were measured during a reentry flight at a Mach number of 20 on a 5 deg half-angle cone 3.962 m (13 ft) long with an initial nose tip radius of 0.254 cm (0.1 in.). The free-stream Reynolds number increased during the prime data period from 7.0 x 10(exp 6) to 51.5 x 10(exp 6) per meter (2.1 x 10(exp 6) to 15.7 x 10(exp 6) per foot) and the ratio of wall to total temperature varied from 0.053 to 0.12. The angle of attack was less than 1deg for the prime data period. The experimental laminar and turbulent heating rates are compared with results from existing flat-plate prediction methods. At conditions of minimal tip blunting and angle of attack (above 26.8 km (88 000 ft)), values from a flat-plate laminar method agreed within 20 percent with the laminar data. The Schultz-Grunow skin-friction equation with reference enthalpy; conditions, with the Reynolds number based on distance from the transition location, and with the Colburn Reynolds analogy agreed within 10 percent with the experimental turbuleiit heating data. The Van Driest n skin-friction equation with Reynolds number greater than 10(exp 7) based on distance from the peak heating point and the Colburn Reynolds analogy was also within approximately 10 percent of the experimental turbulent heating data. A data correlation jbf the extent of transition and a simple empirical transition-zone heating correlation were also presented.

Zoby, Ernest V.↗

Alteration in micro-mechanical characteristics of wellbore cement fracture surfaces due to fluid exposure

The stiffness of wellbore cement fracture surfaces was measured after exposing to the advective flow of nitrogen, silicone oil, and medium sweet dead crude oil for different exposure periods. The test specimens were extracted from fractured cement cylinders, where the cement fracture surfaces were exposed to the different fluids up to 15 weeks. A nanoindenter with a Berkovich indenter tip was used to measure load-indentation depth data, which was used to extract the elastic modulus (E) and nano-hardness (H) of the cement fracture surfaces. A reduction in the elastic modulus compared with an unexposed specimen were observed in all the specimens. Both elastic modulus and nano-hardness for the specimens exposed to silicone oil were lower than specimens exposed to nitrogen gas and varied with the period of exposure. The elastic modulus and nano-hardness of the specimens exposed to crude oil were the lowest with a significant decrement with the exposure period. The frequency distribution of the nanoindentation measurements shows that the volume-fraction ratio of the two types of cement hydrated nanocomposites for both the unexposed and test specimens is about 70:30%. Phase transformation beneath the indenter is observed for all of the specimens, with more obvious plastic deformation in specimens exposed to crude oil. Analytical measurements (SEM, EDS, FT-IR, and XRD) on exposed cement fracture surfaces reveal different levels of physical and chemical alteration that are consistent with the reduction in stiffness measured by nanoindentation. Furthermore, the study suggests that cement stiffness will decrease due to crude oil exposure, and the fracture will be sensitive to stress and pore pressure with time.

42 ENGINEERING↗

A two color, dual beam backscattering laser Doppler velocimeter

A laser Doppler velocimeter has been developed which uses two of the colors emitted from an argon ion laser for the simultaneous measurement of orthogonal velocities. Designed for use in a 2.13 m by 3.05 m wind tunnel, it is capable of traversing its focal volume across spatially unstable flows at scan speeds of up to 1.15 m/sec. Its optical layout and principles of operation are discussed and the data from a typical traversal of a trailing wing tip vortex are presented.

Grant, G. R.↗

A study of fatigue crack closure using electric potential and compliance techniques

Compared are closure data produced on the same specimen by the crack tip compliance gage and electric potential techniques. Experiments on 7075-T651 aluminum center cracked panels produced equivalent results on closure using the two techniques. The results also indicated that closure is a function of stress ratio, specimen thickness and maximum applied stress intensity. Maximum stress intensity had a strong effect on closure in the range of applied stresses used. This dependence of closure on specimen thickness and maximum stress intensity accounts for many of the discrepencies in closure behavior reported in the literature.

Clarke, C. K.↗

Configuration heating for a hypersonic research airplane concept having a 70 deg swept double-delta wing

The heating on a candidate hypersonic research airplane configuration has been examined experimentally at Mach 6 by the phase-change-paint technique. The configuration has a double-delta wing with tip fins. Phase-change-paint diagrams give heating data for the model top, side, and bottom, with and without deflected elevons for an angle-of-attack range of 0 deg to 24 deg. Nominal Reynolds numbers are on the order of 15,000,000 with supplementary data at length Reynolds number of 4,000,000, which moves the model from the predominantly turbulent into the predominantly laminar regime. Also, intermediate Reynolds numbers were investigated on the lee side for one angle of attack.

Lawing, P. L.↗

X-wing noise data acquisition program

The X-wing circulation controlled rotor system model was tested for hover performance. During these performance tests, noise data from 12 microphones was recorded on magnetic tape for subsequent data reduction. The rotor system was operated at 4 tip speeds ranging from 529 to 650 ft./sec. (404 to 497 rpm), collective angles of attack fro 0 deg to 8.5 deg (maximum), and blade pressure ratios from 1.0 (no blowing) to a maximum of 2.1. The 12 microphones included 11 in the far field, and one in the transmission area. Following completion of the rotor and subsystem noise measurements, sound field calibration measurements were made of both the rotor 'bowl' and the loudspeaker system used in the 'bowl' calibration measurements. The location of 10 far field microphones was measured by a surveyor. Additionally, detailed tape logs were prepared for the six reels of tape used for the program.

Healy, G. J.↗

Fixed pitch rotor performance of large horizontal axis wind turbines

Experimental fixed pitch wind turbine performance data is presented for both the DOE/NASA Mod-0 and the Danish Gedser wind turbines. Furthermore, a method for calculating the output power from large fixed pitch wind turbines is presented. Modifications to classical blade element momentum theory are given that improve correlation with measured data. Improvement is particularly evident in high winds (low tip speed ratios) where aerodynamic stall occurs as the blade experiences high angles of attack.

Viterna, L. A.↗

Mast flight system beam structure and beam structural performance

An overall understanding of the beam assembly and data with which potential experimenters can begin to conduct analyses relevant to their experiments is given. Data is given on the beam structural concept, the tip remote station layout, the intermediate remote station layout with and without actuators, beam element materials, equivalent beam characteristics, beam element properties, remote station mass properties, and MAST Flight System modal characteristics.

Lenzi, David C.↗