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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The role of moisture and hydrogen in hot-salt cracking of titanium alloys
Role of moisture and hydrogen in hot salt stress corrosion cracking of titanium alloys
Space evacuation of NRC-2 insulation for liquid hydrogen tankage.
Space evacuation of NRC-2 insulation for liquid hydrogen tankage, noting vacuum test apparatus and cold plate test
Thermodynamic effects of cavitation of an 80.6 deg helical inducer operated in hydrogen
Thermodynamic effects of cavitation in liquid hydrogen over range of liquid temperatures and flow coefficients at two rotating speeds
Temperatures of Titan and the Galilean satellites at 20 microns.
Determination of the effective temperatures of the satellites by means of broad-band observations made at Mauna Kea in 1971. The temperatures of the Galilean satellites are in fair agreement with observations at shorter wavelengths and with theory. The 20-micron flux of Titan is nearly an order of magnitude lower than expected, suggesting either low surface emissivity or high atmospheric opacity between 18 and 25 micron. Hydrogen could produce the required opacity, but the abundance needed is large.
Exchange Forces in Dispersion Relations Investigated Using Circuit Relations
We propose a novel method to compute in an exact manner the left-hand cut discontinuity of the electron-Atom partial wave scattering amplitude in the complex energy plane within the static stage approximation. Zero energy dispersion relations for electron-Hydrogen scattering are computed numerically for illustration.
3.4-Billion-year-old biogenic pyrites from Barberton, South Africa: sulfur isotope evidence
Laser ablation mass spectroscopy analyses of sulfur isotopic compositions of microscopic-sized grains of pyrite that formed about 3.4 billion years ago in the Barberton Greenstone Belt, South Africa, show that the pyrite formed by bacterial reduction of seawater sulfate. These data imply that by about 3.4 billion years ago sulfate-reducing bacteria had become active, the oceans were rich in sulfate, and the atmosphere contained appreciable amounts (>>10(-13) of the present atmospheric level) of free oxygen.
Fabrication of Diamond Membranes for MEMS using Reactive Ion Etching of Silicon
Polycrystalline diamond thin film has been grown on a silicon substrate using high pressure microwave plasma-assisted chemical vapor deposition from a gas mixture of methane and hydrogen at a substrate temperature of 950 degrees celcius.
Measurements of seeded argon-hydrogen plasma properties.
Seeded argon-hydrogen plasmas have been produced at Georgia Tech in order to experimentally measure composition, temperature, radiant heat output and opacity. The plasma, seeded with submicron tungsten particles, simulates the propellant of a gaseous core nuclear rocket. These measurements are needed to predict the dynamic behavior of the operating gas core reactor. The temperature range in which the seed has vaporized but the hydrogen itself has not yet become opaque is known as the seed-hydrogen opacity window. Preliminary opacity data in this temperature range will be presented.
A survey of interstellar molecular hydrogen. I
Data from the Copernicus satellite's ultraviolet telescope were used to survey column densities of atomic and molecular hydrogen from a large sample of early-type stars; these data have bearing on an eventual understanding of diffuse and dense interstellar clouds. Column densities are derived by fitting damping profiles to the observed spectra, most of which exhibit strong damping lines in the lower rotational levels surveyed. Plots of dust column density, fractional abundance of molecular hydrogen, and the logarithm of fractional abundance versus total gas column density are given for many of the stars; stars with abnormally large or small hydrogen column densities, as well as some distant stars at high galactic latitudes, are considered. Equilibrium and nonequilibrium theories accounting for the abundance of interstellar hydrogen are compared, and support is found in the data for an account which balances hydrogen formation on interstellar grains with destruction through photodissociation. Overall averages for atomic and molecular hydrogen levels in the galactic plane are also calculated.
Hydrogen fueled subsonic aircraft - A prospective
The performance characteristics of hydrogen-fueled subsonic transport aircraft are compared with those of aircraft using conventional aviation kerosene. Results of the Cryogenically Fueled Aircraft Technology Program sponsored by NASA indicate that liquid hydrogen may be particularly efficient for subsonic transport craft when ranges of 4000 km or more are involved; however, development of advanced cryogenic tanks for liquid hydrogen fuel is required. The NASA-sponsored program also found no major technical obstacles for international airports converting the liquid hydrogen fueling systems. Resource utilization efficiency and fuel production costs for hydrogen produced by coal gasification or for liquid methane or synthetic aviation kerosene are also assessed.
Geocoronal imaging with Dynamics Explorer
The ultraviolet photometer of the University of Iowa spin-scan auroral imaging instrumentation on board Dynamics Explorer-1 has returned numerous hydrogen Lyman alpha images of the geocorona from altitudes of 570 km to 23,300 km (1.09 R sub E to 4.66 R sub E geocentric radial distance). The hydrogen density gradient is shown by a plot of the zenith intensities throughout this range, which decrease to near celestial background values as the spacecraft approaches apogee. Characterizing the upper geocorona as optically thin (single-scattering), the zenith intensity is converted directly to vertical column density. This approximation loses its validity deeper in the geocorona, where the hydrogen is demonstrated to be optically thick in that there is no Lyman alpha limb brightening. Further study of the geocoronal hydrogen distribution will require computer modeling of the radiative transfer.
Lunar neutron leakage fluxes as a function of composition and hydrogen content
Areas of the moon that might have enhanced concentrations of hydrogen are discussed. The fluxes of thermal, epithermal, and fast neutrons escaping from the lunar surface were calculated for eight different compositions and several hydrogen contents. These flux ratios depend on composition and are very sensitive to the hydrogen content. Their measurement using flight-proven techniques from lunar orbit should allow detection and identification of hydrogen residing in either permanently shaded cold traps near the lunar poles or mature regoliths. Knowledge of composition, especially of Fe and Ti, improves the thresholds for hydrogen detection and also could allow identification of Gd and Sm.
Simulating the Diffusion of Hydrogen in Amorphous Silicates: A ‘Jumping’ Migration Process and its Implications for Solar Wind Implanted Lunar Volatiles
We use molecular dynamics (MD) simulations to better explain the movement of atomic hydrogen in amorphous silica and quantify the planetary science implications of these findings. Previous MD simulations had a large range of predicted values and did not agree well with experiment. Our simulations sample atomic motion for a longer duration and consider a wider range of temperatures than previous simulations. In contrast to constant atomic motion, the hydrogen atoms were shown to undergo random intermittent jumps from one oxygen atom to another, the number of which increase with temperature. Predicted diffusion coefficients had a better agreement to experimental values than previous MD simulations, suggesting the importance of longer simulation durations for better statistics. The low activation energy and jumps observed at lunar temperatures do not support the theory of diurnal variations in OH content for an undamaged amorphous silica surface. Instead, we conclude that energetic solar wind impacts can induce two competing atomic hydrogen motion processes in the exposed surface: A prompt effect that induces jumps in the temperature spike volume, but also a long term effect of damage in the structure that traps atomic hydrogen. We then use SDTrimSP to quantify the damage created during exposure and MD to demonstrate the H retention and trapping near these defects. Damage was shown to be dependent on impact energy, with defects easily retaining implanted hydrogen. MD results like those presented herein on unweathered surfaces are therefore most relevant to magnetic anomalies. As a result, we demonstrate the importance of lunar volatile models to account for the damage state of the substrate when modelling hydrogen diffusion, retention, and subsequent OH/water production.
Multipole correction of atomic monopole models of molecular charge distribution. I. Peptides
The defects in atomic monopole models of molecular charge distribution have been analyzed for several model-blocked peptides and compared with accurate quantum chemical values. The results indicate that the angular characteristics of the molecular electrostatic potential around functional groups capable of forming hydrogen bonds can be considerably distorted within various models relying upon isotropic atomic charges only. It is shown that these defects can be corrected by augmenting the atomic point charge models by cumulative atomic multipole moments (CAMMs). Alternatively, sets of off-center atomic point charges could be automatically derived from respective multipoles, providing approximately equivalent corrections. For the first time, correlated atomic multipoles have been calculated for N-acetyl, N'-methylamide-blocked derivatives of glycine, alanine, cysteine, threonine, leucine, lysine, and serine using the MP2 method. The role of the correlation effects in the peptide molecular charge distribution are discussed.
Development of liquid oxygen/liquid hydrogen thrust chamber for the M-1 engine
Design and performance of liquid oxygen-liquid hydrogen thrust chamber for M-1 engine
A hydrogen energy carrier. Volume 1: Summary
The production, technology, transportation, and implementation of hydrogen into the energy system are discussed along with the fossil fuel cycle, hydrogen fuel cycle, and the demands for energy. The cost of hydrogen production by coal gasification; electrolysis by nuclear energy, and solar energy are presented. The legal aspects of a hydrogen economy are also discussed.
Spatial Atomic Layer Deposition to Scale Manufacturing of Robust Catalysts for Biomass Conversion Applications: Cooperative Research and Development Final Report, CRADA Number CRD-17-715
This CRADA will facilitate technology maturation for NREL-developed ALD-coated catalyst materials that are tailored for durability during harsh biomass conversion chemistries. This project will address optimizing process parameters for scale-up of Al2O3 ALD-coated catalysts, demonstrating ALD-coated catalyst performance for muconic acid hydrogenation, and validating economic models that project significant cost benefits for ALD-enhanced catalytic processes. This work will strengthen private-public partnerships in the area of advanced catalyst manufacturing for energy-related technology. Critical information will be collected to elevate the Technology Readiness Level and increase our competitiveness for cooperative R&D agreements and licensing. Success of this work will be crosscutting as it can facilitate advanced catalyst development for both renewable and conventional processes.