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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

Ethynylated aromatics as high temperature matrix resins

Difunctional and trifunctional arylacetylenes were used as monomers to form thermoset matrix resin composites. Composites can be hot pressed at 180 C to react 80 percent of the acetylene groups. Crosslinking is completed by postcuring at 350 C. The postcured resins are thermally stable to nominally 460 C in air. As a result of their high crosslink density, the matrix exhibits brittle failure when unaxial composites are tested in tension. Failure of both uniaxial tensile and flexural specimens occurs in shear at the fiber matrix interface. Tensile fracture stresses for 0 deg composites fabricated with 60 v/o Celion 6K graphite fiber were 827 MPa. The strain to failure was 0.5 percent. Composites fabricated with 8 harness satin Celion cloth (Fiberite 1133) and tested in tension also failed in shear at tensile stresses of 413 MPa.

Hurwitz, Frances I.↗

Bending testing and characterization of surrogate nuclear fuel rods made of Zircaloy-4 cladding and aluminum oxide pellets

We studied behavior of surrogate nuclear fuel rods made of Zircaloy-4 (Zry-4) cladding with alumina pellets under reversed cyclic bending. Tests were performed under load or moment control at 5 Hz, and an empirical correlation was established between rod fatigue life and amplitude of the applied moment. Fatigue response of Zry-4 cladding was further characterized by using flexural rigidity. Degradation of flexural rigidity was shown to depend on the moment applied and the prefatigue condition of specimens. Pellet-to-pellet interface (PPI), pellet-to-cladding interface (PCI), and pellet condition all affect surrogate rod failure. Bonding/debonding of PPI/PCI and pellet fracturing contribute to surrogate rod bending fatigue. Also, the effect of sensor spacing on curvature measurement using three-point deflections was studied; the method based on effective specimen gauge length is effective in sensor spacing correction. Finally, we developed the database and gained understanding in this study such that it will serve as input to analysis of SNF vibration integrity.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Elastic NaxMoS2-carbon-BASE triple interface direct robust solid-solid interface for all-solid-state Na-S batteries

The promises of all-solid-state (ASS) sodium batteries for the next generation energy storage are widely recognized but their developments have been severely constrained by the difficulties to design favorable solid-solid interfaces for unhindered Na-ion transport. Using the most promising ß?-Al2O3 solid state electrolyte (BASE) as a platform, we demonstrate here a triple nanojunction strategy that provides simultaneous strong Na adhesion and continuous Na-ions diffusion at solid-solid interface. Such triple junctions (NaxMoS2-carbon-BASE) were constructed by adhering ternary composite Na anodes containing dispersed 3 wt% MoS2 and 3 wt% carbon on BASE, and provide nearly complete adhesion of Na on BASE with a much smaller contact angle (~ 45o vs. 120o of pristine Na). The composite Na anodes exhibited ~ 3 times improved elastic property and the synergy of NaxMoS2 and carbon provides the required ionic and electronic diffusion channels at solid-solid interface, which significantly improve Na utilization and resist premature failure due to loss of solid-solid contact as Na shrink during high capacity stripping. As a result, Na metal at the triple junction exhibited more than five time reduced charge transfer resistance and at least 200 hours stable battery cycling at practical current densities. The novel anode architecture also enabled high capacity cycling of prototype ASS sodium sulfur batteries when coupled with advanced sulfur cathodes containing intrinsic Na-ions diffusion channels and redox catalytic mediators, leading to stable cycling with specific capacity of 1110 mAh g-1.

ß”-Al2O3 solid electrolyte, solid state batteries,↗

Insights into Na + Diffusion in Silicon Modules under Operating Conditions: Measuring Low Concentrations by D-SIMS

Sodium induced shunting under an electric field is a challenging reliability issue in crystalline Si solar modules. The source of this Potential-Induced Degradation of the Shunting type (PID-s) is well understood and its influence on power loss has been intensively studied based on phenomenological models on cell or module level relating the experimental power-loss to stressing parameters (time, temperature, voltage). However, little is known about the Na ion migration kinetics, responsible for PID on a microscopic level, and its quantitative relation to the efficiency degradation. In this paper we present our investigations of sodium ion migration in Ethylene-Vinyl Acetate (EVA) and silicon through Dynamic Secondary Ion Mass Spectroscopy (D-SIMS). Each sample was annealed at field relevant temperatures from 60-90 °C to address typical migration mechanisms of common PV installations. Analysis of the SIMS migration profiles revealed a diffusivity constant D 0,EVA = 0.09 ± 0.14 cm 2 /s and an activation energy E A,EVA = 0.85 ± .04 eV for Na in EVA and diffusivities higher than extrapolated literature values in silicon (D 0,Si = (3.03 ± 2.42)x10 -5 cm 2 /s, and E A,Si = 0.98 ± 0.02 eV). The new insight will be included in a drift-diffusion based degradation model accounting for the partition coefficient across all relevant interfaces. This model can assist in predicting PID-failure in the field based on the given model stack and the diffusion of Na + through each material. Furthermore, this tool can be used for process optimization as well as material selection significantly reducing the cost and time to validate a technology.

14 SOLAR ENERGY↗

The axisymmetric elasticity problem for a laminated plate containing a circular hole

The elasticity problem for a laminated thick plate which consists of two bonded dissimilar layers and which contains a circular hole is considered. The problem is formulated for arbitrary axisymmetric tractions on the hole surface by using the Love strain function. Through the expansion of the boundary conditions into Fourier series the problem is reduced to an infinite system of algebraic equations which is solved by the method of reduction. Of particular interest in the problem are the stresses along the interface as they relate to the question of delamination failure of the composite plate. These stresses are calculated and are observed to become unbounded at the hole boundary. An approximate treatment of the singular behavior of the stress state is presented and the stress intensity factors are calculated.

Delale, F.↗

NASA V/STOL Propulsion Control Analysis - Phase I and II program status

NASA-Lewis Research Center initiated the V/STOL Propulsion Control Analysis Program in 1979 in order to take advantage of advanced electronic control technology for the next generation of V/STOL aircraft. The rationale, methods, and criteria developed during Phase I and Phase II of the program are discussed first. The development of an integrated flight and propulsion control system is then described. Most V/STOL aircraft under consideration depend on reaction thrusters or separate lift engines for attitude control and on engine thrust variations for height control. S/CTOL aircraft vector-thrust for pitch control during low speed operation. The baseline propulsion control system provides a thrust level response of 10 rad/sec and a vectoring response of 22 rad/sec. The requirements of the control components include: (1) redundant electronic control computers with minimum software and 100% Fault Coverage; (2) prime reliable electromechanical actuator interfaces; (3) miniature, digitally compatible sensors with easily detected failure modes; and (4) dual element, fail operational fuel pumps.

Miller, R. J.↗

Intergranular fracture of lithium fluoride-22 percent calcium fluoride hypereutectic salt at 800 K

Substantial strain-hardening was noted during the initial stages of deformation in constant-velocity compression tests conducted on as-cast samples of the LiF-22 mol pct CaF2 hypereutectic salt at 800 K. The deformed specimens exhibited extensive grain-boundary cracking and cavitation, suggesting that such cracking, in conjunction with interfacial sliding, is important for cavity nucleation at grain boundaries and at the LiF-CaF2 interfaces. Cavity growth and interlinkage occur through the preferential failure of the weaker LiF phase.

Raj, Subramanium V.↗

More About Detecting Sensor Failures In A Turbofan Engine

Advanced Detection, Isolation, and Accommodation (ADIA) algorithm helps digital electronic multivariable-control system of advanced turbofan engine cope with failures of sensors in real time. Algorithm includes four major elements: hard-sensor-failure detection-and-isolation logic, soft-sensor-failure detection-and-isolation logic, accommodation filter, and interface switch matrix.

Delaat, John C.↗

On 'large-scale' stable fiber displacement during interfacial failure in metal matrix composites

Experimental results are presented to show that interfacial failure in sapphire-reinforced niobium is characterized by 'large-scale' (5-15 microns) plasticity-controlled fiber displacements occurring under increasing loads. The results are based on the responses during thin-slice fiber pushout tests wherein the fiber is supported over a hole twice the fiber diameter. The results describe an interfacial failure process that should also occur near fiber ends during pullout when a fiber is well-bonded to a soft, ductile matrix, such that eventual failure occurs by shear within the matrix near the interface.

Petrich, R. R.↗

Design and Integration of an Actuated Nose Strake Control System

Aircraft flight characteristics at high angles of attack can be improved by controlling vortices shed from the nose. These characteristics have been investigated with the integration of the actuated nose strakes for enhanced rolling (ANSER) control system into the NASA F-18 High Alpha Research Vehicle. Several hardware and software systems were developed to enable performance of the research goals. A strake interface box was developed to perform actuator control and failure detection outside the flight control computer. A three-mode ANSER control law was developed and installed in the Research Flight Control System. The thrust-vectoring mode does not command the strakes. The strakes and thrust-vectoring mode uses a combination of thrust vectoring and strakes for lateral- directional control, and strake mode uses strakes only for lateral-directional control. The system was integrated and tested in the Dryden Flight Research Center (DFRC) simulation for testing before installation in the aircraft. Performance of the ANSER system was monitored in real time during the 89-flight ANSER flight test program in the DFRC Mission Control Center. One discrepancy resulted in a set of research data not being obtained. The experiment was otherwise considered a success with the majority of the research objectives being met.

Flick, Bradley C.↗

International Space Station Nickel-Hydrogen Battery Startup and Initial Performance

The Battery Orbital Replacement Unit (ORU) was designed to meet the following requirements: a 6.5-year design life, 38,000 charge/discharge Low Earth Orbit cycles, 81-Amp-hr nameplate capacity, 4 kWh nominal storage capacity, contingency orbit capability, an operating temperature of 5 +/- 5 C standard orbit and 5+5/-10 C contingency orbit, a non-operating temperature of -25 to +30 C, a five-year Mean Time between failure, an on-orbit replacement using ISS robotic interface, and one launch to orbit and one return to ground. The ISS electrical power system is successfully maintaining power for all on-board loads. ISS Eclipse power is currently supplied by six Ni-H2 batteries (12 ORUs), which are operating nominally.

Dalton, Penni↗

Integrated System Health Management (ISHM) for Test Stand and J-2X Engine: Core Implementation

ISHM capability enables a system to detect anomalies, determine causes and effects, predict future anomalies, and provides an integrated awareness of the health of the system to users (operators, customers, management, etc.). NASA Stennis Space Center, NASA Ames Research Center, and Pratt & Whitney Rocketdyne have implemented a core ISHM capability that encompasses the A1 Test Stand and the J-2X Engine. The implementation incorporates all aspects of ISHM; from anomaly detection (e.g. leaks) to root-cause-analysis based on failure mode and effects analysis (FMEA), to a user interface for an integrated visualization of the health of the system (Test Stand and Engine). The implementation provides a low functional capability level (FCL) in that it is populated with few algorithms and approaches for anomaly detection, and root-cause trees from a limited FMEA effort. However, it is a demonstration of a credible ISHM capability, and it is inherently designed for continuous and systematic augmentation of the capability. The ISHM capability is grounded on an integrating software environment used to create an ISHM model of the system. The ISHM model follows an object-oriented approach: includes all elements of the system (from schematics) and provides for compartmentalized storage of information associated with each element. For instance, a sensor object contains a transducer electronic data sheet (TEDS) with information that might be used by algorithms and approaches for anomaly detection, diagnostics, etc. Similarly, a component, such as a tank, contains a Component Electronic Data Sheet (CEDS). Each element also includes a Health Electronic Data Sheet (HEDS) that contains health-related information such as anomalies and health state. Some practical aspects of the implementation include: (1) near real-time data flow from the test stand data acquisition system through the ISHM model, for near real-time detection of anomalies and diagnostics, (2) insertion of the J-2X predictive model providing predicted sensor values for comparison with measured values and use in anomaly detection and diagnostics, and (3) insertion of third-party anomaly detection algorithms into the integrated ISHM model.

Figueroa, Jorge F.↗

Making Human Spaceflight Practical and Affordable: Spacecraft Designs and their Degree of Operability

As we push toward new and diverse space transportation capabilities, reduction in operations cost becomes increasingly important. Achieving affordable and safe human spaceflight capabilities will be the mark of success for new programs and new providers. The ability to perceive the operational implications of design decisions is crucial in developing safe yet cost competitive space transportation systems. Any human spaceflight program - government or commercial - must make countless decisions either to implement spacecraft system capabilities or adopt operational constraints or workarounds to account for the lack of such spacecraft capabilities. These decisions can benefit from the collective experience that NASA has accumulated in building and operating crewed spacecraft over the last five decades. This paper reviews NASA s history in developing and operating human rated spacecraft, reviewing the key aspects of spacecraft design and their resultant impacts on operations phase complexity and cost. Specific examples from current and past programs - including the Space Shuttle and International Space Station - are provided to illustrate design traits that either increase or increase cost and complexity associated with spacecraft operations. These examples address factors such as overall design performance margins, levels of redundancy, degree of automated failure response, type and quantity of command and telemetry interfaces, and the definition of reference scenarios for analysis and test. Each example - from early program requirements, design implementation and resulting real-time operations experience - to tell the end-to-end "story" Based on these experiences, specific techniques are recommended to enable earlier and more effective assessment of operations concerns during the design process. A formal method for the assessment of spacecraft operability is defined and results of such operability assessments for recent spacecraft designs are provided. Recent experience in applying these techniques to Orion spacecraft development is reviewed to highlight the direct benefits of early operational assessment and collaborative development efforts.

Crocker, Alan R.↗

Airplane Capabilities: Translating Non-Normal Information for Operational Decision-Making

We consider how a jet transport airplane interface supports the flight crew in managing airplane system failures (or non-normals) for continued safe flight and landing. The existing state of the art starts with a list of airplane system component failures and asks the flight crew to determine, with the help of non-normal procedures, the operational consequences of those failures. As airplane systems become more complex and interconnected, the flight crew's ability to determine operational consequences will become inadequate. We describe an approach that attempts to translate airplane system failures directly into airplane "capabilities," which is a set of basic airplane functions, such as the ability to stop after landing. This paper describes the overall framework for supporting flight crews in operational decision making and the initial efforts to develop a language and display concepts.

managing airplane system non-normals↗

Role of tilt grain boundaries on the structural integrity of WSe 2 monolayers

Transition metal dichalcogenides (TMDCs) are potential materials for future optoelectronic devices. Grain boundaries (GBs) can significantly influence the optoelectronic properties of TMDC materials. Here, we have investigated the mechanical characteristics of tungsten diselenide (WSe 2 ) monolayers and failure process with symmetric tilt GBs using ReaxFF molecular dynamics simulations. In particular, the effects of topological defects, loading rates, and temperatures are investigated. We considered nine different grain boundary structures of monolayer WSe 2 , of which six are armchair (AC) tilt structures, and the remaining three are zigzag (ZZ) tilt structures. Our results indicate that both tensile strength and fracture strain of WSe 2 with symmetric tilt GBs decrease as the temperature increases. We revealed an interfacial phase transition for high-angle GBs reduces the elastic strain energy within the interface at finite temperatures. Furthermore, brittle cracking is the dominant failure mode in the WSe 2 monolayer with tilted GBs. WSe 2 GB structures showed more strain rate sensitivity at high temperatures than at low temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Spaceflight Ground Support Equipment Reliability & System Safety Data

Presented were Reliability Analysis, consisting primarily of Failure Modes and Effects Analysis (FMEA), and System Safety Analysis, consisting of Preliminary Hazards Analysis (PHA), performed to ensure that the CoNNeCT (Communications, Navigation, and Networking re- Configurable Testbed) Flight System was safely and reliably operated during its Assembly, Integration and Test (AI&T) phase. A tailored approach to the NASA Ground Support Equipment (GSE) standard, NASA-STD-5005C, involving the application of the appropriate Requirements, S&MA discipline expertise, and a Configuration Management system (to retain a record of the analysis and documentation) were presented. Presented were System Block Diagrams of selected GSE and the corresponding FMEA, as well as the PHAs. Also discussed are the specific examples of the FMEAs and PHAs being used during the AI&T phase to drive modifications to the GSE (via "redlining" of test procedures, and the placement of warning stickers to protect the flight hardware) before being interfaced to the Flight System. These modifications were necessary because failure modes and hazards were identified during the analysis that had not been properly mitigated. Strict Configuration Management was applied to changes (whether due to upgrades or expired calibrations) in the GSE by revisiting the FMEAs and PHAs to reflect the latest System Block Diagrams and Bill Of Material. The CoNNeCT flight system has been successfully assembled, integrated, tested, and shipped to the launch site without incident. This demonstrates that the steps taken to safeguard the flight system when it was interfaced to the various GSE were successful.

Fernandez, Rene↗

Transverse Strength of SCS-6 Silicon Carbide Fibers

A diametral compression test was used to measure the transverse strength of SCS-6 SiC fibers before and after heat treatment. Subjecting fibers to diametral compression successfully produced transverse tensile failure in the form of fiber cracking along the same diametral plane in which the compressive load was applied. An analysis of the hoop stress along the diametral plane, in which the effects of the C core were included, showed that there is a large tensile hoop stress concentration in the SiC sheath at the interface between the C core and the SiC sheath, where the stress is 6.3 times greater than the stress present in a solid SiC fiber under identical loading. This high tensile hoop stress concentration promotes crack initiation near the core and significantly limits the capability of these fibers to withstand transverse compressive loading. The maximum tensile hoop stresses, located at the interface between the C core and SiC sheath, at the measured failure loads were 850 MPa for the as-received SCS-6 fiber and 1210 MPa for fibers exposed to a 1-h heat treatment at 1850°C in 138 MPa of Ar.

Jeffrey I. Eldridge↗

Wireless Avionics Packet to Support Fault Tolerance for Flight Applications

In this protocol and packet format, data traffic is monitored by all network interfaces to determine the health of transmitter and subsystems. When failures are detected, the network inter face applies its recover y policies to provide continued service despite the presence of faults. The protocol, packet format, and inter face are independent of the data link technology used. The current demonstration system supports both commercial off-the-shelf wireless connections and wired Ethernet connections. Other technologies such as 1553 or serial data links can be used for the network backbone. The Wireless Avionics packet is divided into three parts: a header, a data payload, and a checksum. The header has the following components: magic number, version, quality of service, time to live, sending transceiver, function code, payload length, source Application Data Interface (ADI) address, destination ADI address, sending node address, target node address, and a sequence number. The magic number is used to identify WAV packets, and allows the packet format to be updated in the future. The quality of service field allows routing decisions to be made based on this value and can be used to route critical management data over a dedicated channel. The time to live value is used to discard misrouted packets while the source transceiver is updated at each hop. This information is used to monitor the health of each transceiver in the network. To identify the packet type, the function code is used. Besides having a regular data packet, the system supports diagnostic packets for fault detection and isolation. The payload length specifies the number of data bytes in the payload, and this supports variable-length packets in the network. The source ADI is the address of the originating interface. This can be used by the destination application to identify the originating source of the packet where the address consists of a subnet, subsystem class within the subnet, a subsystem unit, and the local ADI number. The destination ADI is used to route the packet to its ultimate destination. At each hop, the sending interface uses the destination address to determine the next node for the data. The sending node is the node address of the interface that is broadcasting the packet. This field is used to determine the health of the subsystem that is sending the packet. In the case of a packet that traverses several intermediate nodes, it may be the node address of the intermediate node. The target node is the node address of the next hop for the packet. It may be an intermediate node, or the final destination for the packet. The sequence number is used to identify duplicate packets. Because each interface has multiple transceivers, the same packet will appear at both receivers. The sequence number allows the interface to correlate the reception and forward a single, unique packet for additional processing. The subnet field allows data traffic to be partitioned into segregated local networks to support large networks while keeping each subnet at a manageable size. This also keeps the routing table small enough so routing can be done by a simple table lookup in an FPGA device. The subsystem class identifies members of a set of redundant subsystems, and, in a hot standby configuration, all members of the subsystem class will receive the data packets. Only the active subsystem will generate data traffic. Specific units in a class of redundant units can be identified and, if the hot standby configuration is not used, packets will be directed to a specific subsystem unit.

Block, Gary L.↗