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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

Passive Thermal Coating Observatory Operating in Low-Earth Orbit (PATCOOL) – Cubesat Design to Test Passive Thermal Coatings in Space

The PATCOOL is a NASA sponsored, University of Florida developed 3U Cu-beSat meant to investigate the feasibility of using a cryogenic selective surface coating as a new, more efficient way of passively cooling components in space. Initial tests on the ground demonstrate that this coating should provide a much higher reflectance of the Sun’s irradiant power than any existing coating, while still providing far-infrared power emission. The ultimate validation of this tech-nology requires on-orbit testing. PATCOOL hosts a 4-sample housing, with the samples shaped as thin cylinders (coin-like). Two samples are coated with state-of-the-art material, while the other pair uses the new coating to be evaluated. The temperatures of all samples during the mission (minimum 72 hours of data col-lection) are measured via thermistors. The samples are connected via thin Kevlar strings to the housing, to minimize heat transfer. The housing is designed to shield the samples from Earth’s thermal radiation, and the CubeSat is attitude stabilized and controlled via a gravity gradient boom, magnetorquers and a reaction wheel set. Thermal Desktop simulations show PATCOOL’s ability to thermally isolate the samples from heat exchanges other than with Sun and deep space, thanks to its thermal design and the chosen attitude profile.

Ojeda, Carlos↗

A New Method for Simulating Photoprocesses in Astrochemical Models

We propose a new model for treating solid-phase photoprocesses in interstellar ice analogues. In this approach, photoionization and photoexcitation are included in more detail, and the production of electronically-excited (suprathermal) species is explic- itly considered. In addition, we have included non-thermal, non-diffusive chemistry to account for the low-temperature characteristic of cold cores. As an initial test of our method, we have simulated two previous experimental studies involving the UV irradiation of pure solid O2. In contrast to previous solid-state astrochemical model calculations which have used gas-phase photoabsorption cross-sections, we have em- ployed solid-state cross-sections in our calculations. This method allows the model to be tested using well-constrained experiments rather than poorly constrained gas-phase abundances in ISM regions. Our results indicate that inclusion of non-thermal reac- tions and suprathermal species allows for reproduction of low-temperature solid-phase photoprocessing that simulate interstellar ices within cold ( 10 K) dense cores such as TMC-1.

astrochemical modeling↗

Feasibility of Ultraviolet Light Emitting Diodes as an Alternative Light Source for Photocatalysis

The objective of this study was to determine whether ultraviolet light emitting diodes (UV-LEDs) could serve as an alternative photon source efficiently for heterogeneous photocatalytic oxidation (PCO). An LED module consisting of 12 high-power UV-A LEDs was designed to be interchangeable with a UV-A fluorescent black light blue (BLB) lamp in a Silica-Titania Composite (STC) packed bed annular reactor. Lighting and thermal properties were characterized to assess the uniformity and total irradiant output. A forward current of (I(sub F)) 100 mA delivered an average irradiance of 4.0 m W cm(exp -2), which is equivalent to the maximum output of the BLB, but the irradiance of the LED module was less uniform than that of the BLB. The LED- and BLB-reactors were tested for the oxidization of 50 ppmv ethanol in a continuous flow-through mode with 0.94 sec space time. At the same irradiance, the UV-A LED reactor resulted in a lower PCO rate constant than the UV-A BLB reactor (19.8 vs. 28.6 nM CO2 sec-I), and consequently lower ethanol removal (80% vs. 91%) and mineralization efficiency (28% vs. 44%). Ethanol mineralization increased in direct proportion to the irradiance at the catalyst surface. This result suggests that reduced ethanol mineralization in the LED- reactor could be traced to uneven irradiance over the photocatalyst, leaving a portion of the catalyst was under-irradiated. The potential of UV-A LEDs may be fully realized by optimizing the light distribution over the catalyst and utilizing their instantaneous "on" and "off' feature for periodic irradiation. Nevertheless, the current UV-A LED module had the same wall plug efficiency (WPE) of 13% as that of the UV-A BLB. These results demonstrated that UV-A LEDs are a viable photon source both in terms of WPE and PCO efficiency.

Levine, Langanf H.↗

Global Mapping of Underwater UV Irradiances and DNA-Weighted Exposures using TOMS and SeaWiFS Data Products

The global stratospheric ozone-layer depletion results In an increase in biologically harmful ultraviolet (UV) radiation reaching the surface and penetrating to ecologically significant depths in natural waters. Such an increase can be estimated on a global scale by combining satellite estimates of UV irradiance at the ocean surface from the Total Ozone Mapping Spectrometer (TOMS) satellite instrument with the SeaWIFS satellite ocean-color measurements in the visible spectral region. In this paper we propose a model of seawater optical properties in the UV spectral region based on the Case I water model in the visible range. The inputs to the model are standard monthly SeaWiFS products: chlorophyll concentration and the diffuse attenuation coefficient at 490nm. Penetration of solar UV radiation to different depths in open ocean waters is calculated using the RT (radiative transfer) quasi-single scattering approximation (QSSA). The accuracy of the QSSA approximation in the water is tested using more accurate codes. The sensitivity study of the underwater UV irradiance to atmospheric and oceanic optical properties have shown that the main environmental parameters controlling the absolute levels of the UVB (280-320nm) and DNA-weighted irradiance underwater are: solar-zenith angle, cloud transmittance, water optical properties, and total ozone. Weekly maps of underwater UV irradiance and DNA-weighted exposure are calculated using monthly-mean SeaWiFS chlorophyll and diffuse attenuation coefficient products, daily SeaWiFS cloud fraction data, and the TOMS-derived surface UV irradiance daily maps. The final products include global maps of weekly-average UVB irradiance and DNA-weighted daily exposures at 3m and 10m, and depths where the UVB irradiance and DNA-weighted dose rate at local noon are equal to 10% of their surface values.

Vasilkov, Alexander↗

Ultraviolet irradiation at elevated temperatures and thermal cycling in vacuum of FEP-A covered silicon solar cells

Experiments were designed and performed on silicon solar cells covered with heat-bonded FEP-A in an effort to explain the rapid degeneration of open-circuit voltage and maximum power observered on cells of this type included in an experiment on the ATS-6 spacecraft. Solar cells were exposed to ultraviolet light in vacuum at temperatures ranging from 30 to 105 C. The samples were then subjected to thermal cycling from 130 to -130 C. Inspection following irradiation indicated that all the covers remained physically intact. However, during the temperature cycling heat-bonded covers showed cracking. The test showed that heat-bonded FEP-A covers embrittle during UV exposure and the embrittlement is dependent upon sample temperature during irradiation. The results of the experiment suggest a probable mechanism for the degradation of the FEP-A cells on ATS-6.

Broder, J. D.↗

Materials and techniques for spacecraft static charge control

An overview of the design, development, fabrication, and testing of transparent conductive coatings and conductive lattices deposited or formed on high resistivity spacecraft dielectric materials to obtain control static charge buildup on spacecraft external surfaces is presented. Fabrication techniques for the deposition of indium/tin oxide coatings and copper grid networks on Kapton and FEP Teflon films and special frit coatings for OSR and solar cell cover glasses are discussed. The techniques include sputtering, photoetching, silkscreening, and mechanical processes. A facility designed and built to simulate the electron plasma at geosynchronous altitudes is described along with test procedures. The results of material characterizations as well as electron irradiation aging effects in this facility for spacecraft polymers treated to control static charge are presented. The data presents results for electron beam energies up to 30 kV and electron current densities of 30 nA/cm squared. Parameters measured include secondary emission, surface leakage, and through the sample currents as a function of primary beam energy and voltage.

Amore, L. J.↗

Infrared analysis of polyethylene wear specimens using attenuated total reflection spectroscopy

Attenuated total reflection infrared spectroscopy was used to analyze ultrahigh molecular weight polyethylene wear test specimens. Three different specimens were analyzed. One specimen was gamma irradiated to a dose of 5.0 MRad, another to a dose of 2.5 MRad, and the final specimen was unirradiated. There was no conclusive evidence of chemical changes (i.e., unsaturation or oxidation) in the surface regions of any of the polyethylene samples. Therefore, it was concluded that the gamma irradiation sterilization procedure shoud not alter the boundary lubricating properties of the polyethylene.

Jones, W. R.↗

Radiation damage in high-voltage silicon solar cells

Three types of open circuit high voltage solar cells were tested to determine their performance after exposure to 1 MeV electron irradiations. The cells with a relatively deep n-type emitter were more susceptible to radiation damage than other high open circuit high voltage cells. The use of diffused or ion implanted junctions leads to open circuit high voltage cell designs that are less susceptible to radiation damage. These latter two types of cells show degradations that are typical of the 0.1 ohm-cm material from which they are fabricated. Furthermore, exposure to ionizing radiation causes oxide degradation and decreased cell performance in cells that depend on a charged oxide to achieve significant cell properties. Hence, the combination of a charged oxide and a relatively deep n-type emitter is not recommended for incorporation into a cell designed for use in the particulate radiation environment of space.

Weinberg, I.↗

Validation of Ocean Color Remote Sensing Data using a Moored Databuoy

NASA's Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) aims to measure global ocean color from space to within 5% to provide insights into fundamental ocean processes. SeaWiFS must be backed by comprehensive calibration and validation programs if the mission is to achieve this. In situ measurements of normalized water-leaving radiance (L(sub wn)) made simultaneously with satellite measurements can complement on-orbit methods of tracking changes in the calibration of the satellite radiometer and allow end-to-end vicarious validation of the remotely-sensed data. A moored optical databuoy was developed at Plymouth Marine Laboratory, UK to measure L(sub wn) in the western English Channel. Tests indicate that the buoy is capable of measuring spectral incident irradiance with less than 10% error and water-leaving radiance with less than 20% error; these errors are reduced by averaging and show no bias. There were 24 match-ups with good quality SeaWiFS data at the buoy site during the ten months of deployment within the period May 1997 and September 1998. The differences between the buoy and SeaWiFS measurements of L(sub wn) were found to be variable and often large. The root-mean-square (RMS) differences varied from 102% at 412 nm to 50% at 555 nm. The RMS differences in measurements of L(sub wn) could be reduced to less than 18% by a combination of increasing the calibration coefficients of SeaWiFS by between 0.2 and 4.3% in the visible bands and by tuning the extrapolation of aerosol radiances from the near infrared to the visible wavelengths. These results imply that the monitoring of the absolute calibration of the SeaWiFS bands is imperfect and errors remain in the extrapolation of aerosol radiances for atmospheric correction.

Lavender, Samantha↗

Evidence of Nebula Processes from Primitive Meteorites

Astronomical observations of T Tauri stars provide information about the masses, sizes, temperatures, and lifetimes of the solar-nebula-like disks surrounding these stars. Theoretical interpretations of these observations can be used to construct models of the evolution of the solar nebula, and to derive implications for the properties of meteoritic material. The consequences of nebular thermal history might have been retained in patterns of elemental fractionation, presolar grains abundances, and oxygen isotopes, among other meteorite properties. Thus, such data may be used in conjunction with models to constrain the parameters that describe the overall evolution of the solar nebula. On the other hand, major meteoritic components such as chondrules and CAIs apparently reflect localized processes that are not readily related to global thermal evolution. In several cases, the theoretical tools required for the evaluation of proposals for their mode of formation exist, but have yet to be applied. Proposals that meteoritic material was thermally and radiatively processed very close to the young Sun, based on the emerging picture of the interactions between young stars and their disks, have radical consequences for the distribution of solid material in the solar system and the formation of chondritic meteorites. Tests of these models may be provided by their predictions for irradiated material and the physical characteristics of primitive meteorites.

Cassen, Patrick↗

In Situ Testing Methods for Mixed-Mode Harsh Environments

A review of the radiation effects investigation capabilities of the JPL Dynamitron Accelerator Facility are discussed. A process for its use in performing total ionizing dose (TID) studies are outlined. The results of radiation effects in complicated test systems where device effects may occur due to local system irradiation are also presented.

Wong, A. T.↗

Dose rate and bias dependency of total dose sensitivity of low dropout voltage regulators

Total dose tests of six different low dropout voltage regulators show sensitivity to both dose rate and bias during exposure. All devices tested exhibited Enhanced Low Dose Rate Sensitivity (ELDRS) and performed worse for the unbiased irradiation condition. Behavior of critical parameters in different dose rate and bias conditions is compared and the impact to hardness assurance methodology is discussed.

Voltage↗

Increased Tensile Strength of Carbon Nanotube Yarns and Sheets through Chemical Modification and Electron Beam Irradiation

The inherent strength of individual carbon nanotubes offers considerable opportunity for the development of advanced, lightweight composite structures. Recent work in the fabrication and application of carbon nanotube (CNT) forms such as yarns and sheets has addressed early nanocomposite limitations with respect to nanotube dispersion and loading; and has pushed the technology toward structural composite applications. However, the high tensile strength of an individual CNT has not directly translated to macro-scale CNT forms where bulk material strength is limited by inter-tube electrostatic attraction and slippage. The focus of this work was to assess post processing of CNT sheet and yarn to improve the macro-scale strength of these material forms. Both small molecule functionalization and e-beam irradiation was evaluated as a means to enhance tensile strength and Youngs modulus of the bulk CNT material. Mechanical testing results revealed a tensile strength increase in CNT sheets by 57 when functionalized, while an additional 48 increase in tensile strength was observed when functionalized sheets were irradiated; compared to unfunctionalized sheets. Similarly, small molecule functionalization increased yarn tensile strength up to 25, whereas irradiation of the functionalized yarns pushed the tensile strength to 88 beyond that of the baseline yarn.

composites↗

Search for effect of longitudinally polarized protons on optically active amino acids

The influence of irradiation by longitudinally polarized protons on the differential decomposition of amino acid is investigated in a test of the Vester Ulbricht hypothesis that L-amino acids were produced in preference to the D isomers on the primitive earth due to the effects of parity violation in beta decay. Samples of DL-leucine were irradiated with protons of both positive and negative longitudinal polarization, then analyzed by gas chromatography. Despite advantages of higher polarization, lower velocity and higher ionization density of protons with respect to electrons, proton irradation is found to lead to no detectable asymmetries in DL-leucine degradation, even at 50% gross degradation.

Lemmon, R. M.↗

Motor and cognitive testing of bone marrow transplant patients after chemoradiotherapy

Assessment of cognitive and motor performance of bone marrow transplant patients prior to, during, and following intensive toxic chemoradiotherapy may provide an important adjunct to measures of physiological and medical status. The present study is an attempt to assess whether, as side-effects, these aggressive treatments result in cognitive performance deficits, and if so, whether such changes recover posttreatment. Measurement of cognitive ability in this situation presents special problems not encountered with one-time tests intended for healthy adults. Such tests must be sensitive to changes within a single individual, which emphasizes the crucial importance of high reliability, stability across repeated-measures, and resistance to confounding factors such as motivation and fatigue. The present research makes use of a microbased portable test battery developed to have reliable and sensitive tests which were adapted to study the special requirements of transplant patients who may suffer cognitive deficits as a result of treatment. The results showed slight but significant changes in neuropsychological capacity when compared to baseline levels and controls, particularly near the beginning of treatment. The sensitivity of the battery in detecting such subtle temporary changes is discussed in terms of past research showing effects of other stressors, such as stimulated high altitude and ingestion of alcohol, on these measures.

Non-NASA Center↗

Survival of spacecraft-associated microorganisms under simulated Martian UV irradiation

Spore-forming microbes recovered from spacecraft surfaces and assembly facilities were exposed to simulated Martian UV irradiation. The effects of UVA (315 to 400 nm), UVA_B (280 to 400 nm), and the full UV spectrum (200 to 400 nm) on the survival of microorganisms were studied at UV intensities expected to strike the surfaces of Mars. Microbial species isolated from the surfaces of several spacecraft, including Mars Odyssey, X-2000 (avionics), and the International Space Station, and their assembly facilities were identified using 16S rRNA gene sequencing. Forty-three Bacillus spore lines were screened, and 19 isolates showed resistance to UVC irradiation (200 to 280 nm) after exposure to 1,000 J m_2 of UVC irradiation at 254 nm using a low-pressure mercury lamp. Spores of Bacillus species isolated from spacecraft-associated surfaces were more resistant than a standard dosimetric strain, Bacillus subtilis 168. In addition, the exposure time required for UVA_B irradiation to reduce the viable spore numbers by 90% was 35-fold longer than the exposure time required for the full UV spectrum to do this, confirming that UVC is the primary biocidal bandwidth. Among the Bacillus species tested, spores of a Bacillus pumilus strain showed the greatest resistance to all three UV bandwidths, as well as the total spectrum. The resistance to simulated Mars UV irradiation was strain specific; B. pumilus SAFR-032 exhibited greater resistance than all other strains tested. The isolation of organisms like B. pumilus SAFR-032 and the greater survival of this organism (sixfold) than of the standard dosimetric strains should be considered when the anitation capabilities of UV irradiation are determined.

Venkateswaran, Kasthuri↗

Total Ionizing Dose Test Report BFR92A NPN 5 GHz Wide Band Transistor from NXP

The purpose of this test was to characterize the Philips/NXP BFR92A NPN 5 gigahertz wide band silicon transistor for total dose response. This test shall serves as the radiation lot acceptance test (RLAT) for the lot date code (LDC) 1027. The BFR92A is packaged in a 3-pin plastic SOT23 package. Low dose rate (LDR/ELDRS) irradiations was performed.

Total Ionizing Dose (TID)↗