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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Tracking Optical Phonon Dynamics in InP Nanocrystals via Transient Absorption and Femtosecond Stimulated Raman Spectroscopy

Semiconductor nanocrystals (NCs) offer actualized and prospective utility in optoelectronic technologies, yet key aspects of their thermal and vibrational behaviors remain unresolved. Compared with bulk crystals, heat dissipation involving NCs can differ substantially owing to pervasiveness of interfacial scattering, phonon confinement, and relaxed phonon momentum selection rules, as well as influences of ligands. Here, in addition to transient absorption, we use femtosecond stimulated Raman spectroscopy to track nonequilibrium optical-phonon dynamics in InP NCs capped with myristic acid ligands and compare the same particles coated with a ZnS shell. We identify distinct phonon decay pathways in ligand-capped versus ZnS-shelled NCs. Increasing the excitation density and introducing the ZnS shell measurably modify optical-phonon lifetimes, whereas phonon formation times remain largely unchanged. In addition, we observe phonon mode softening in ligand-capped nanocrystals, consistent with lattice expansion. Together, these results demonstrate that core–shell structures can strongly govern nanocrystal thermal dissipation pathways and should be considered a key design parameter for optoelectronic operation.

dissipation↗
DOE OSTI2026

Mimicking Extradiol Dioxygenase Reactivity on Iridium

Extradiol dioxygenases catalyze the cleavage of benzenediol (catechol) or vicinal aminophenols via oxygen atom insertion into the 2,3- C–C bond. These reactions are most often proposed to proceed through the migratory rearrangement of a d6 alkylperoxide, generating the corresponding d 6 ring expanded product. However, regiospecific insertion remains a rare outcome among synthetic model complexes. Here, a dioxygenated Ir complex (2) converts to (a) the paramagnetic metallatrioxolane (3) and (b) oxygen atom inserted products (4) and (5); all three complexes are third-row metal analogues of enzymatic intermediates. The conversion of 2 to 3 was triggered by an H• abstraction, generating a third-row metallatrioxolane that is one electron reduced from the canonical d 6 alkylperoxide. Alternatively, photolysis of 2 (467 nm) results in ring-expanded product 4, from which an H• can be abstracted to generate 5. This latter complex is also one electron reduced relative to the canonical ring expansion product. Because extradiol mechanisms were largely defined using Fe(II) metallocofactors, 3 and 5 may be especially relevant to the known Co(II) accepting variants. We propose these states became synthetically accessible via the incorporation of a catechol-like substrate into the larger, multidentate ligand L1. This perturbation enhances the affinity of L1 (and related intermediates) to the metal. The same perturbation may have also been key in characterizing the first κ 2 -bound, dianionic ortho ester ligand – the observed binding mode in the x-ray structure of 5. Broadly, we propose through this case study that connecting abiological dioxygen complexes to non-heme oxygenase-like intermediates might be a “roadmap” towards regiospecific aerobic oxygenations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Effect of Density Irregularities on Radio Frequency Wave Propagation in Ionospheric Plasmas

Density irregularities play a vital role in determining how radio frequency (RF) waves travel through plasmas. In the Earth’s ionosphere, these density irregularities also impact radio communication. In this study, we conduct a detailed numerical analysis of RF wave propagation in small-scale ionospheric density irregularities using the advanced Petra-M code. We focus specifically on high-frequency (HF) waves, ranging from 3 to 30 MHz, which are essential for military, amateur radio operators, and emergency communications. By introducing density structures, such as equatorial plasma bubbles derived from fluid simulations, we demonstrate that HF waves can scatter in multiple directions when they encounter these irregularities. Additionally, we observe significant mode conversion, where incoming electromagnetic waves transform into electrostatic modes within the density gradient layer. This shows that smaller density irregularities can greatly weaken signals or cause complete signal loss for receivers, emphasizing the need for increased awareness and innovative solutions in radio communication transmission.

Kim, Eun-Hwa [Princeton Plasma Physics Laboratory ↗
NASA NTRS1973

Plasmaspheric hiss.

A relatively steady band of ELF hiss has been detected by the OGO 5 search coil magnetometer on almost every passage through the plasmasphere; except for an anomalous region of the dayside at high geomagnetic latitudes, the emissions terminate abruptly at the plasmapause and are therefore referred to as 'plasmaspheric hiss.' A preliminary statistical study of the properties of the observed whistler mode turbulence has yielded the following characteristics: the waves are band limited with a sharp lower-frequency cutoff and a more diffuse upper-frequency cutoff; power spectra show a well-defined maximum near a few hundred hertz, the peak intensities generally ranging between 10 to the minus 7th power and 0.00001 gamma squared/Hz; the wave energy is spread over a bandwidth of a few hundred hertz, and corresponding wideband amplitudes are 5 to 50 milligamma; the waves are highly turbulent in nature and show little tendency toward definite polarization.

Thorne, R. M.↗
NASA NTRS1974

A balloon-borne 1 meter telescope for far-infrared astronomy

The flight of a balloon-borne one-meter telescope for infrared astronomy in the wavelength interval of 40 to 240 microns is discussed. The gyro-stabilized telescope mapped the intensity of the far infrared radiation from NGC 7538, Mars, the Orion Nebula, and W3 with a resolution of one minute and from selected regions of these sources with a resolution of 30 seconds. The infrared detection is described and its capabilities are analyzed. The instrumentation, orientation system, and modes of observation of the telescope are defined.

Fazio, G. G.↗
NASA NTRS1975

Progress in the development of the hollow fiber sodium-sulfur secondary cell

This report describes the development and status of the sodium-sulfur secondary cell which uses fine hollow glass fibers as the electrolyte. Laboratory size cells containing up to 7000 fibers and having capacities up to 5 ampere-hours have been built and operated. These cells have been run at various cycle depths up to 95% of capacity. Lifetime does not depend on depth of discharge up to at least 50% depth and possibly deeper. Rates of charge and discharge of the nominally one hour cells have been varied from three times the design rate to 0.05 times the design rate. Smaller cells operate with essentially no internal resistance increase during their lifetimes of over four months on continuous charge/discharge at the one hour rate. Larger cells assembled with somewhat different mechanical assembly techniques have shorter lives. Two types of failure modes are observed: progressive weakening and breaking of the fibers inside the cell assembly, and fiber breakage at the fiber/tube sheet interface.

Levine, C. A.↗
NASA NTRS1975

Fatigue of notched fiber composite laminates. Part 1: Analytical model

A description is given of a semi-empirical, deterministic analysis for prediction and correlation of fatigue crack growth, residual strength, and fatigue lifetime for fiber composite laminates containing notches (holes). The failure model used for the analysis is based upon composite heterogeneous behavior and experimentally observed failure modes under both static and fatigue loading. The analysis is consistent with the wearout philosophy. Axial cracking and transverse cracking failure modes are treated together in the analysis. Cracking off-axis is handled by making a modification to the axial cracking analysis. The analysis predicts notched laminate failure from unidirectional material fatique properties using constant strain laminate analysis techniques. For multidirectional laminates, it is necessary to know lamina fatique behavior under axial normal stress, transverse normal stress and axial shear stress. Examples of the analysis method are given.

Mclaughlin, P. V., Jr.↗
NASA NTRS1977

Dual-polarized ring lasers

Simultaneous laser oscillation of four nondegenerate polarization and propagation direction eigenstates of a single TEM-00 mode was observed in a ring laser cavity. The observed polarization and frequency properties of the ring laser were analyzed in terms of the Jones matrix calculus.

Sanders, V. E.↗
NASA NTRS1979

Diffuse Jovian aurora influenced by plasma injection from Io

The paper demonstrates that the broad band of whistler-mode waves observed within the high density torus surrounding Io is consistent with electron cyclotron generation. Cyclotron resonant instability of Jovian energetic electrons is enhanced due to the lower resonant electron energy within the equatorial high density plasma torus surrounding the orbit of Io. The higher energy resonant electron scattering and the corresponding energetic electron lifetimes indicate that an efficient local acceleration process is required to replenish the precipitating relativistic electrons. Calculated energy deposition into the Jovian atmosphere should provide a dominant source of middle atmospheric ionization and excite a continuous band of diffuse auroral emission. It is suggested that the diffuse Jovian aurora should be influenced by the variable volcanic activity on Io which is thought to be an important source of plasma, since the cyclotron scattering process is strongly influenced by the ambient equatorial thermal plasma density.

Thorne, R. M.↗
NASA NTRS1980

Correlated whistler and electron plasma oscillation bursts detected on ISEE-3

The ISEE-3 plasma wave instrument detects associated bursts of electron plasma oscillations and whistler mode waves at an average rate of event one every two days. The plasma wave measurements give the electron number density, and simultaneously measured E and B amplitudes are used to deduce an index of refraction consistent with whistler mode propagation for the measured number density and magnetic field. Burst durations are a few minutes, with some trains of bursts lasting up to an hour. Individual spectral scans (two per second) reveal that the whistler and plasma wave amplitude-time profiles differ within a burst. Peak plasma wave amplitudes are near one mV/m, and the peak whistler mode energy density exceeds that of the plasma oscillations by about a factor 100. The frequency of the whistler mode wave observed in one well diagnosed event agrees with the predictions of the heat flux whistler instability theory. The associated plasma wave instability probably requires a bump-on-tail feature in the heat flux electron component, possibly due to impulsive heating elsewhere on the field-line connecting to ISEE-3.

Kennel, C. F.↗
NASA NTRS1980

Notched graphite polymimide composites at room and notched graphite polymide composites at room and elevated temperatures

The fracture behavior in graphite/polyimide (Gr/PI) Celion 6000/PMR-15 composites was characterized. Emphasis was placed on the correlation between the observed failure modes and the deformation characteristics of center-notched Gr/Pl laminates. Crack tip damage growth, fracture strength and notch sensitivity, and the associated characterization methods were also examined. Special attention was given to nondestructive evaluation of internal damage and damage growth, techniques such as acoustic emission, X-ray radiography, and ultrasonic C-scan. Microstructural studies using scanning electron microscopy, photomicrography, and the pulsed nuclear magnetic resonance technique were employed as well. All experimental procedures and techniques are described and a summary of representative results for Gr/Pl laminates is given.

Awerbuch, J.↗
NASA NTRS1981

The Mg 2 h and k lines in a sample of dMe and dM stars

Both Mg II h and k line fluxes are presented for a sample of 4 dMe and 3 dM stars obtained with the IUE satellite in the long wavelength, low dispersion mode. The observed fluxes are converted to stellar surface flux units and the importance of chromospheric non radiative heating in this sample of M dwarf stars is intercompared. In addition, the net chromospheric radiative losses due to the Ca II H and K lines in those stars in the sample for which calibrated Ca II H and K line data exist are compared. Active region filling factors which likely give rise to the observed optical and ultraviolet chromospheric emission are estimated. The implications of the results for homogeneous, single component stellar model chromospheres analyses are discussed.

Giampapa, M. S.↗
NASA NTRS1981

Effects of temperature fluctuations of IUE data quality

Analysis of IUE calibration lamp images shows that variation in the temperature of the scientific instrument causes shifts in the location of the spectral format with respect to the reseau grid on the detector and in the location of the reseaux themselves. In high dispersion, a camera head amplifier temperature difference of 6C corresponds to a shift of 4 pixels in the spectral format for LWR and 2 pixels for SWP along the dispersion direction. Shifts perpendicular to the disperson (for the same temperature difference) are less than one pixel for both cameras. In low dispersion spectra, the shifts are similar but orthogonal to those described above with the larger motion lying in the direction perpendicular to the dispersion. In both dispersion modes, the observed shifts are apparently independent of wavelength. In high dispersion, the constant pixel shift mimics a constant velocity error.

Thompson, R. W.↗
NASA NTRS1981

Mechanism of instabilities in turbulent combustion leading to flashback

High-speed schlieren cinematography, combined with synchronized pressure transducer records, was used to investigate the mechanism of combustion instabilities leading to flashback. The combustion chamber had an oblong rectangular cross-section to model the essential features of planar flow, and was provided with a rearward facing step acting as a flameholder. As the rich limit was approached, three instability modes were observed: (1) humming - a significant increase in the amplitude of the vortex pattern; (2) buzzing - a large-scale oscillation of the flame; and (3) chucking - a cyclic reformation of the flame, which results in flashback. The mechanism of these phenomena is ascribed to the action of vortices in the recirculation zone and their interactions with the trailing vortex pattern of the turbulent mixing layer behind the step.

Keller, J. O.↗
NASA NTRS1981

Surface waves on Saturn's magnetopause

Voyager 1 magnetometer data have shown that small-amplitude surface waves occurred on Saturn's dayside magnetopause, causing multiple inbound crossings of this boundary. These waves were travelling approximately parallel to Saturn's equatorial plane along the magnetopause ('tailward'), suggesting that they were driven by the rotation of Saturn's magnetosphere. Hydromagnetic waves (possibly slow mode) were observed in the adjacent magnetosheath.

Lepping, R. P.↗
NASA NTRS1983

Vibration studies of a lightweight three-sided membrane suitable for space application

Vibration studies carried out in a vacuum chamber are reported for a three-sided membrane with inwardly curved edges. Uniform tension was transmitted by thin steel cables encased in the edges. Variation of ambient air pressure from atmospheric to near vacuum resulted in increased response frequencies and amplitudes. The first few vibration modes measured in a near vacuum are shown to be predictable by a finite element structural analysis over a range of applied tension loads. The complicated vibration mode behavior observed during tests at various air pressures is studied analytically with a nonstructural effective air-mass approximation. The membrane structure is a candidate for reflective surfaces in space antennas.

Sewell, J. L.↗