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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18

Review—Micro-Fuel Cell Principal Biosensors for Monitoring Transdermal Volatile Organic Compounds in Humans

Knowledge of transduction mechanisms in biosensing applications paves the way for ultrasensitive and dynamic detection in living systems. Real-world biosensing applications where ultra-sensitivity and dynamic detection are paramount include monitoring the anesthetic agent concentration during surgery; the slightest variation in concentration can potentially result in a life-threatening overdose or, on the other end of the spectrum, the patient’s awareness during the procedure. We review the benefits and functions of the transcutaneous biosensor device compared with other current technology and discuss the sensor’s capability to accurately measure volatile anesthetic gas concentration in blood using fuel cell technology. We review fundamental concepts of fuel-cell technology for wearable bio-sensing applications. The fuel cell sensor can also continuously monitor other volatile organic compounds making it versatile with numerous potential applications.

42 ENGINEERING↗

An Analysis of Published DAS Studies for Application to SPE Phase III

Distributed Acoustic Sensing (DAS) is an emerging technology capable of recording the acoustic wavefield at unprecedented spatial resolution. However, this new tool requires significant refinements before it becomes operational for explosion monitoring objectives. Recent studies have shown significant development of array processing with DAS data. In this report we explore three such array processing methods including DAS strain-rate data versus geophone measured ground motion, beamforming for event parameters, and machine learning based denoising. Prior to applying these algorithms to the Source Physics Experiment Phase II and Phase III data, we validate these methods through replication analysis.

47 OTHER INSTRUMENTATION↗

Ultrathin Boron Growth onto Nanodiamond Surfaces via Electrophilic Boron Precursors

Diamond as a templating substrate is largely unexplored, and the unique properties of diamond, including its large bandgap, thermal conductance, and lack of cytotoxicity, makes it versatile in emergent technologies in medicine and quantum sensing. Surface termination of an inert diamond substrate and its chemical reactivity are key in generating new bonds for nucleation and growth of an overlayer material. Oxidized high-pressure high temperature (HPHT) nanodiamonds (NDs) are largely terminated by alcohols that act as nucleophiles to initiate covalent bond formation when an electrophilic reactant is available. In this work, we demonstrate a templated synthesis of ultrathin boron on ND surfaces using trigonal boron compounds. Boron trichloride (BCl 3 ), boron tribromide (BBr 3 ), and borane (BH 3 ) were found to react with ND substrates at room temperature in inert conditions. BBr 3 and BCl 3 were highly reactive with the diamond surface, and sheet-like structures were produced and verified with electron microscopy. Surface-sensitive spectroscopies were used to probe the molecular and atomic structure of the ND constructs’ surface, and quantification showed the boron shell was less than 1 nm thick after 1–24 h reactions. Observation of the reaction supports a self-terminating mechanism, similar to atomic layer deposition growth, and is likely due to the quenching of alcohols on the diamond surface. X-ray absorption spectroscopy revealed that boron-termination generated midgap electronic states that were originally predicted by density functional theory (DFT) several years ago. DFT also predicted a negative electron surface, which has yet to be confirmed experimentally here. The boron-diamond nanostructures were found to aggregate in dichloromethane and were dispersed in various solvents and characterized with dynamic light scattering for future cell imaging or cancer therapy applications using boron neutron capture therapy (BNCT). The unique templating mechanism based on nucleophilic alcohols and electrophilic trigonal precursors allows for covalent bond formation and will be of interest to researchers using diamond for quantum sensing, additive manufacturing, BNCT, and potentially as an electron emitter.

36 MATERIALS SCIENCE↗

Magnetic Field Sensing via Multi-Material Acoustic Sensing Optical Fibers with Magnetostrictive Cladding Inclusions

In this conducted research, optical fiber sensors are used to measure low strength alternating magnetic fields. Various fiber sensor configurations are tested and investigated to demonstrate sensing capabilities at different field magnitudes and frequencies. Distributed acoustic sensing fibers (DAS) have been largely studied and documented across a variety of applications and sensing systems. This research uses the DAS technology in tandem with magnetostrictive materials to create a distributed multi-material optical fiber magnetic sensor. Magnetic sensing has high demand across different fields and often runs into challenges of extreme environments including high temperature, corrosion, and areas with poor accessibility. The robust and distributed nature of optical fiber sensors which can be cheaply produced for long lengths is an attractive option over other single point magnetic sensors. In down hole applications specifically, having a distributed sensor able to be deployed easily and over long distances for magnetic sensing would be a large improvement to bulkier traditional magnetometers. In the conducted study, different magnetostrictive materials are implemented in distributed optical fiber sensors to analyze and compare the effective sensitivity and potential commercial viability. Nickel, galfenol alloy, and MetGlas alloy inclusions are drawn into fused silica optical fibers with Bragg gratings inscribed later on for DAS capability. Each was investigated for its response to varying AC magnetic fields to determine relative sensitivity and resolution for distributed magnetic field sensing.

Dejneka, Zach↗

Development of self-sensing materials for extreme environments based on metamaterial concept and additive manufacturing

Structural health monitoring of an engineered component in a harsh environment is critical for multiple DOE missions including nuclear fuel cycle, subsurface energy production/storage, and energy conversion. Supported by a seeding Laboratory Directed Research & Development (LDRD) project, we have explored a new concept for structural health monitoring by introducing a self-sensing capability into structural components. The concept is based on two recent technological advances: metamaterials and additive manufacturing. A self-sensing capability can be engineered by embedding a metastructure, for example, a sheet of electromagnetic resonators, either metallic or dielectric, into a material component. This embedment can now be realized using 3-D printing. The precise geometry of the embedded metastructure determines how the material interacts with an incident electromagnetic wave. Any change in the structure of the material (e.g., straining, degradation, etc.) would inevitably perturbate the embedded metastructures or metasurface array and therefore alter the electromagnetic response of the material, thus resulting in a frequency shift of a reflection spectrum that can be detected passively and remotely. This new sensing approach eliminates complicated environmental shielding, in-situ power supply, and wire routing that are generally required by the existing active-circuit-based sensors. The work documented in this report has preliminarily demonstrated the feasibility of the proposed concept. The work has established the needed simulation tools and experimental capabilities for future studies.

36 MATERIALS SCIENCE↗

Multiaxis sensing system for detection of airborne molecules and radionuclides

Various technologies presented herein relate to a method and equipment for detecting both airborne radioisotope and molecular effluent gases. Multi-Axis Sensing can be conducted by utilizing a pressurized MOF sorbent, such as a scintillating Metal-Organic Frameworks (S-MOFs). These MOFs are crystalline nanoporous materials that have synthetic versatility that allow adjustment of pore size, chemical environment, and luminescence properties. A method for detecting an analyte in a fluid sample is provided that comprises: loading a sorbent with a sample fluid, wherein the sorbent comprises a MOF material; pressurizing the sample fluid to increase the fluid in the sorbent thereby making a pressurized sorbent; and detecting ionizing radiation or a chemical property of the analyte in the pressurized sorbent.

Allendorf, Mark D.↗

Multiparameter optical fiber sensing for energy infrastructure through nanoscale light–matter interactions: From hardware to software, science to commercial opportunities

Monitoring of energy infrastructure through robust yet economical sensing platforms is becoming an area of increased importance, with ubiquitous applications including the electrical grid, natural gas and oil transportation pipelines, H2 infrastructure (storage and transportation), carbon storage, power generation, and subsurface environments. Plasmonic and functional nanomaterial enabled fiber optic sensors show excellent promise for a wide range of sensing applications due to their versatility to be engineered for specific analytes of interest while retaining inherent advantages of the optical fiber sensor platform. Through the design of novel sensing layers, the optical transduction mechanism and wavelength dependence can also be tailored for ease of integration with low-cost interrogation systems enabling an inexpensive yet highly functional optical fiber sensing platform. In addition, recent advances in artificial intelligence and machine learning theoretical methods have been leveraged to simultaneously extract multiple parameters through multi-wavelength interrogation such that unique wavelengths can also serve as unique sensing elements, analogous to electronic nose sensor technologies. The concept of an optical fiber based “photonic nose” via multiple interrogation wavelengths and/or sensor nodes offers a compelling platform technology to realize multiparameter speciation of chemical analytes within complex gas mixtures. In this Perspective, we further generalize the notion of multiparameter sensing through the novel “photonic nervous system” concept based upon low-cost, functionalized optical fiber sensor probes monitoring a variety of distinct analyte classes (physical, chemical, electromagnetic, etc.) simultaneously to provide broad situational awareness via integrated sensors.

Su, Yang-Duan (ORCID:0000000214820902)↗

HyperKube: A Kubernetes Based System for the Automation of Processing and Analysis of Hyperspectral Data Obtained from Multiple Hyperspectral Imaging Systems

Hyperspectral imagery is an emerging field of technology that has enormous potential for remote and proximal sensing in numerous areas of research. The plant phenotyping community is applying this technology to advance the throughput and accuracy of plant phenotypes based on airborne and lab-based hyperspectral imaging technology. Here we report an automated processing and analysis pipeline for four different hyperspectral imaging platforms, discuss the data issues involved, and present a strategy for computing and data architecture to handle hyperspectral data.

47 OTHER INSTRUMENTATION↗

Pilot-Scale Validation of Distributed Optical Fiber Sensors for Underground Pipeline Monitoring

Distributed fiber optic sensing is a cutting-edge technology that has found extensive applications in the monitoring of Ensuring the safety, integrity, and operational efficiency of underground product pipelines is vital for maintaining the nation’s critical infrastructure. Monitoring parameters such as hoop strain, pressure, and acoustic vibrations is key to detecting potential leaks, intrusions, or structural issues. Distributed optical fiber sensor (DOFS) systems provide a compelling solution for continuous, real-time monitoring over long distances. This paper details the development and pilot-scale implementation of DOFS systems for underground pipeline monitoring, evolving from a proof-of-concept stage. Multiple custom-designed DOFS interrogator units—such as optical frequency-domain reflectometry (OFDR), Brillouin optical time-domain analysis (BOTDA), and multimodal interferometer-based fiber acoustic sensors—were employed to measure key parameters like hoop strain, pressure, and acoustic vibrations. The underground product pipeline's outer diameter is 30 inches, the wall thickness is 1.28 inches, and the 3-foot depth. The fiber deployment strategies, and sensing data acquisition methods for these systems are discussed. The results demonstrate the effectiveness of DOFS in detecting hoop strain, temperature changes, and acoustic vibrations, showcasing their potential for real-time monitoring and enhancing pipeline safety.

distributed fiber sensing↗

Shielding the Quantum Realm: Technical Considerations for Maintaining a Stable and Secure Radio Frequency Environment for Quantum Research

Advancements in quantum technology, which include quantum computing, quantum sensing, quantum communications, and associated research, continue to revolutionize various fields of study by solving challenging problems deemed too difficult or more efficient than those used for classical computers. However, as these systems become ever so complex, it is critical to secure their electromagnetic operational environments and the associated impact on quantum systems and infrastructure. The goal of this synopsis is to bring attention to the susceptibility of quantum technology facilities to potential issues related to the radio frequency (RF) environment within the broader electromagnetic context. A framework is proposed for identifying, mitigating, monitoring, and auditing these often complex operational environments. By establishing best practices in the consideration and evaluation of these criteria, one can enhance the operational integrity, resilience, and security of quantum technology systems and facilities, thereby supporting their continued development and application in research and industry.

42 ENGINEERING↗

Adaptive Circuit Learning for Quantum Metrology

Quantum sensing is an important application of emerging quantum technologies. We explore whether a hybrid system of quantum sensors and quantum circuits can surpass the classical limit of sensing. In particular, we use optimization techniques to search for encoder and decoder circuits that scalably improve sensitivity under given application and noise characteristics. Furthermore, our approach uses a variational algorithm that can learn a quantum sensing circuit based on platform-specific control capacity, noise, and signal distribution. The quantum circuit is composed of an encoder which prepares the optimal sensing state and a decoder which gives an output distribution containing information of the signal. We optimize the full circuit to maximize the Signal-to-Noise Ratio (SNR). Furthermore, this learning algorithm can be run on real hardware scalably by using the "parameter-shift" rule which enables gradient evaluation on noisy quantum circuits, avoiding the exponential cost of quantum system simulation. We demonstrate up to 13.12x SNR improvement over existing fixed protocol (GHZ), and 3.19x Classical Fisher Information (CFI) improvement over the classical limit on 15 qubits using IBM quantum computer. More notably, our algorithm overcomes the decreasing performance of existing entanglement-based protocols with increased system sizes.

42 ENGINEERING↗

Far-field speckle correlations as a function of object position for microscopically distinguishing objects hidden in a randomly scattering medium

Super-resolution optical sensing is of critical importance in science and technology and has required prior information about an imaging system or obtrusive near-field probing. Additionally, coherent imaging and sensing in heavily scattering media such as biological tissue has been challenging, and practical approaches have either been restricted to measuring the field transmission of a single point source, or to where the medium is thin. We present the concept of far-subwavelength spatial sensing with relative object motion in speckle as a means to coherently sense through heavy scatter. Experimental results demonstrate the ability to distinguish nominally identical objects with nanometer-scale translation while hidden in randomly scattering media, without the need for precise or known location and with imprecise replacement. The theory and supportive illustrations presented provide the basis for super-resolution sensing and the possibility of virtually unlimited spatial resolution, including through thick, heavily scattering media with relative motion of an object in a structured field. This work provides enabling opportunities for material inspection, security, and biological sensing.

Hastings, Ryan L. (ORCID:0009000095977807)↗

Distributed Acoustic Sensing for Whale Vocalization Monitoring: A Vertical Deployment Field Test

Abstract There is growing interest in floating offshore wind turbine (FOWT) technology, where turbines are installed on floating structures anchored to the seabed, allowing wind energy development in areas unsuitable for traditional fixed-platform turbines. Responsible development requires monitoring the impact of FOWTs on marine wildlife, such as whales, throughout the operational lifecycle of the turbines. Distributed acoustic sensing (DAS)—a technology that transforms fiber-optic cables into vibration sensor arrays—has been demonstrated for acoustic monitoring of whales using seafloor telecommunications cables. However, no studies have yet evaluated DAS performance in dynamic, engineered environments, such as floating platforms or moving vessels with complex, dynamic strain loads, despite their relevance to FOWT settings. This study addresses that gap by deploying DAS aboard a boat in Monterey Bay, California, where a fiber-optic cable was lowered using a weighted and suspended mooring line, enabling vertical deployment. Humpback whale vocalizations were captured and identified in the DAS data, noise sources were identified, and DAS data were compared to audio captured by a standalone hydrophone attached to the mooring line and a nearby hydrophone on a cabled observatory. This study is unique in: (1) deploying DAS in a vertical deployment mode, where noise from turbulence, cable vibrations, and other sources posed additional challenges compared to seafloor DAS applications; (2) demonstrating DAS in a dynamic, nonstationary setup, which is uncommon for DAS interrogators typically used in more stable environments; and (3) leveraging looped sections of the cable to reduce the noise floor and mitigate the effects of excessive cable vibrations and strain. This research demonstrates DAS’s ability to capture whale vocalizations in challenging environments, highlighting its potential to enhance underwater acoustic monitoring, particularly in the context of renewable energy development in offshore environments.

Saw, Jaewon↗

LiDAR-Aided Interior Orientation Parameters Refinement Strategy for Consumer-Grade Cameras Onboard UAV Remote Sensing Systems

Unmanned aerial vehicles (UAVs) are quickly emerging as a popular platform for 3D reconstruction/modeling in various applications such as precision agriculture, coastal monitoring, and emergency management. For such applications, LiDAR and frame cameras are the two most commonly used sensors for 3D mapping of the object space. For example, point clouds for the area of interest can be directly derived from LiDAR sensors onboard UAVs equipped with integrated global navigation satellite systems and inertial navigation systems (GNSS/INS). Imagery-based mapping, on the other hand, is considered to be a cost-effective and practical option and is often conducted by generating point clouds and orthophotos using structure from motion (SfM) techniques. Mapping with photogrammetric approaches requires accurate camera interior orientation parameters (IOPs), especially when direct georeferencing is utilized. Most state-of-the-art approaches for determining/refining camera IOPs depend on ground control points (GCPs). However, establishing GCPs is expensive and labor-intensive, and more importantly, the distribution and number of GCPs are usually less than optimal to provide adequate control for determining and/or refining camera IOPs. Moreover, consumer-grade cameras with unstable IOPs have been widely used for mapping applications. Therefore, in such scenarios, where frequent camera calibration or IOP refinement is required, GCP-based approaches are impractical. To eliminate the need for GCPs, this study uses LiDAR data as a reference surface to perform in situ refinement of camera IOPs. The proposed refinement strategy is conducted in three main steps. An image-based sparse point cloud is first generated via a GNSS/INS-assisted SfM strategy. Then, LiDAR points corresponding to the resultant image-based sparse point cloud are identified through an iterative plane fitting approach and are referred to as LiDAR control points (LCPs). Finally, IOPs of the utilized camera are refined through a GNSS/INS-assisted bundle adjustment procedure using LCPs. Seven datasets over two study sites with a variety of geomorphic features are used to evaluate the performance of the developed strategy. The results illustrate the ability of the proposed approach to achieve an object space absolute accuracy of 3–5 cm (i.e., 5–10 times the ground sampling distance) at a 41 m flying height.

47 OTHER INSTRUMENTATION↗

pystorms: A simulation sandbox for the development and evaluation of stormwater control algorithms

Advances in cyber–physical technologies have enabled real-time sensing and adaptive control of stormwater infrastructure. These smart stormwater systems allow for inexpensive, minimally-invasive stormwater control interventions in lieu of new construction. Importantly, however promising the area of smart stormwater control, there still remain barriers – for experts and novices alike – to access shared tools and methods for investigating, developing, and contributing to it. In an effort to make smart stormwater control research more methodical and accessible, we present pystorms, an open-source Python-based simulation sandbox that facilitates the quantitative evaluation and comparison of control strategies. pystorms consists of a collection of real world-inspired smart stormwater control scenarios on which any number of control strategies can be applied and tested via an accompanying Python programming interface and coupled stormwater simulator. pystorms provides a framework for the rigorous and efficient evaluation of smart stormwater control methodologies across diverse watersheds with only a few lines of code.

54 ENVIRONMENTAL SCIENCES↗

Towards robust laser beam propagation in atmospheric turbulence

High-fidelity optical propagation through the atmosphere is essential for free-space optical technologies, including laser-based remote sensing and optical communication. However, atmospheric turbulence severely distorts beams and compromises system performance. In this work, we employ hypergeometric-Gaussian (HyGG) vortex beams as probes to characterize and mitigate atmospheric turbulence. Using over 250,000 experimental and simulated frames, we show that refining the power spectrum density (PSD) can reduce numerical prediction errors by up to 79.8%. Concurrently, experimental observations supported by numerical simulations demonstrate that HyGG beams exhibit superior turbulence resilience across multiple metrics compared to conventional Gaussian beams, particularly in their ability to withstand over 5 times stronger turbulence while maintaining similar intensity fluctuations. These dual investigations, on both turbulence mitigation and robust beam solutions, converge to form a unified strategy for enhancing free-space optical system performance. Collectively, our findings provide new insights into light–turbulence interactions and highlight the practical utility of vortex beams under atmospheric conditions.

Zhang, Boyu↗

Distributed Acoustic Sensing (DAS) Seismic Monitoring of CO 2 Injected for Enhanced Oil Recovery in Northern Michigan

As part of the Midwest Regional Carbon Sequestration Partnership (MRCSP) Phase III project, a monitoring study was conducted to assess the effectiveness of DAS (Distributed Acoustic Sensing) -based VSP (Vertical Seismic Profiling) technology for delineating CO 2 injected into the Silurian-age pinnacle reefs in northern Michigan, the host rocks for the MRCSP Phase III demonstration project. The DAS VSP study was conducted in the Chester 16 reef, one of several reefs in Otsego County Michigan that is operated by Core Energy, LLC, of Traverse City, Michigan.

47 OTHER INSTRUMENTATION↗

Evaluation of Potential DAS Array Geometries for the Source Physics Experiment, Phase III

Distributed Acoustic Sensing (DAS) is a rapidly developing technology that can record acoustic wavefields at high sampling rates and with dense spatial spacing difficult to achieve with seismometers. However, the geophysical community has not fully explored DAS survey parameters to characterize the ideal array design. A better quantitative understanding of DAS array behavior prior to SPE Phase III acquisition can help improve the quality of the data recorded by guiding the DAS array design. Here we use array response functions as well as beamforming and backprojection results from forward modelling calculations to assess the performance of varying DAS array geometries to record regional and local sources. A seven-sided polygon DAS array demonstrated improved capabilities for recording regional sources over segmented linear arrays, with potential improvements in recording and locating local sources. These results help reveal DAS array performance as a function of geometry.

58 GEOSCIENCES↗