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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Numerical Investigation of Susceptor-Catalyst Design for Ethylene Generation in Radio Frequency Based Reactors

Ethylene is the most widely produced petrochemical component in the world. Whether reactors are heated directly or indirectly via steam, manufacturers use economies of scale to overcome inherent thermodynamic inefficiencies when burning fossil fuels. While allowing large-scale operations to use alternative sources of energy and raw materials, new methods of supplying energy to chemical reactor systems can reduce the energy waste produced by conventional processes. One viable method for effectively supplying energy to reactor systems is electromagnetic (EM) induction heating. Using the properties of radio frequency (RF) waves, heterogeneous catalysts can be precisely targeted for heating inside reactors. Site-selective heating can greatly lower the energy requirements of the process by supplying heat to reaction sites while reducing needless heat transfer elsewhere. In this study, a microscale model was used to help create guidelines for susceptors and catalysts to improve ethylene production. The oxidative dehydrogenation of ethane is investigated by utilizing several catalysts and potential catalyst/susceptor combinations, with heat provided by an EM susceptor. Having the susceptors and catalyst function separately results in higher gradients in both heat and mass transfer, which drives transport through the catalyst region, while still providing adequate heating for endothermic reactions. However, using a susceptive core with a catalyst covering produces the maximum ethylene concentration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Flavin-dependent halogenases catalyze enantioselective olefin halocyclization

Abstract Halocyclization of alkenes is a powerful bond-forming tool in synthetic organic chemistry and a key step in natural product biosynthesis, but catalyzing halocyclization with high enantioselectivity remains a challenging task. Identifying suitable enzymes that catalyze enantioselective halocyclization of simple olefins would therefore have significant synthetic value. Flavin-dependent halogenases (FDHs) catalyze halogenation of arene and enol(ate) substrates. Herein, we reveal that FDHs engineered to catalyze site-selective aromatic halogenation also catalyze non-native bromolactonization of olefins with high enantioselectivity and near-native catalytic proficiency. Highly selective halocyclization is achieved by characterizing and mitigating the release of HOBr from the FDH active site using a combination of reaction optimization and protein engineering. The structural origins of improvements imparted by mutations responsible for the emergence of halocyclase activity are discussed. This expansion of FDH catalytic activity presages the development of a wide range of biocatalytic halogenation reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Front End Engineering Design Study on Gasification of Coal and Biomass to Generate Carbon- Free Electric Power and Hydrogen

A 2nd Phase Front End Engineering Design study of a gasification plant concept to co-produce electric power and hydrogen with net-negative CO2 emissions is being completed under the U.S. Department of Energy’s (DOE’s) 21st Century Power Plants initiative, whose goal is to advance innovative power plant concepts that are capable of flexible, net-zero carbon emission operations while producing cost-effective hydrogen to support economy-wide decarbonization goals. The proposed standalone plant would be constructed in Nebraska, USA. The specified design feedstock is a hybrid blend of Powder River Basin (PRB) subbituminous coal from Wyoming and local Nebraska biomass (corn stover), 50% each by weight (dry basis). Other potential feedstocks, including woody biomass (eastern red cedar) and waste plastic (auto shredder residue) were evaluated as alternates. The process block comprises a high-pressure, oxygen-blown fluidized bed gasifier coupled with water-gas shift, Selexol process for acid gas (H2S and CO2) removal, and pressure-swing adsorption (PSA) to yield 8,500 kg/h of high-purity hydrogen. Off-gas from the PSA unit is used in a gas turbine combined cycle plant (the power block) to supply 50 MWe net electric power to the grid. Overall thermal efficiency of the plant is 50% (HHV) with net atmospheric CO2 removal at a rate of 32 t/h. Design activities necessary to provide input to the current front-end engineering design (FEED) study, including, site selection, gasifier technology selection, investment case preparation, and the development of the Environmental Information Volume (EIV) for the host site, have been completed. These, as well as the current FEED activities, are described in this presentation.

gasification, biomass, coal, hydrogen, power gener↗
NASA NTRS1965

TYCHO study group Final report

Recommendations for earth space laboratory and lunar surface experiments, landing site selection, and comments on present knowledge of lunar surface

LUNAR LANDING SITE↗
DOE OSTI2020

Tunable assembly of hybrid colloids induced by regioselective depletion

Assembling colloidal particles using site-selective directional interactions into predetermined colloidal superlattices with desired properties is broadly sought-after, but challenging to achieve. Here in this paper, we exploit regioselective depletion interactions to engineer the directional bonding and assembly of non-spherical colloidal hybrid microparticles. We report that the crystallization of a binary colloidal mixture can be regulated by tuning the depletion conditions. Subsequently, we fabricate triblock biphasic colloids with controlled aspect ratios to achieve regioselective bonding. Without any surface treatment, these biphasic colloids assemble into various colloidal superstructures and superlattices featuring optimized pole-to-pole or center-to-center interactions. Additionally, we observe polymorphic crystallization, quantify the abundancy of each form using algorithms we developed, and investigate the crystallization process in real time. We demonstrate selective control of attractive interactions between specific regions on an anisotropic colloid with no need of site-specific surface functionalization, leading to a general method for achieving colloidal structures with yet unforeseen arrangements and properties.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Carbon Storage Site Mapping Inquiry Tool (MapIT)

To date, 48 projects, consisting of 139 wells, are currently under review with the Environmental Protection Agency’s (EPA) Underground Injection Control (UIC) Program for Class VI – wells used for geologic sequestration of carbon dioxide. The number of applications submitted is expected to increase in coming years with the increase of the 45Q tax credit available to projects that initiate construction prior to 2033. The amount of data collected to submit a Class VI permit is vast, and often disparate, coming from state, federal, and commercial entities, as well as field-specific data collected within an area of interest. When preparing for site selection and permitting, the initial aggregation of relevant public data can be time intensive. The Carbon Storage Site Mapping Inquiry tool (MapIT) was created to support and accelerate the discovery and accessibility of open-source data and information available across the USA. Data was aggregated and organized based on data types described within the EPA UIC Class VI permit documentation. The online tool enables users to explore hundreds of geospatial data layers and connect to additional external resources, leveraging API and REST services where possible to ensure updates to data in real time. MapIT enables users to explore state and federal data related to geologic, geophysical, structural, hydrologic, and contextual information. In addition to displaying spatial data and linking to external resources, MapIT leverages custom widgets to ensure that internal data and external data are discoverable and accessible. The widgets connect users to resources such as the USGS publications and the USGS Earthquake Catalog based on a user-defined location. This talk will describe data aggregation workflows, data types, data preparation, and tool development for MapIT. The Carbon Storage Site Mapping Inquiry Tool and underlying database are valuable, intuitive resources that empower government, academic, commercial and industry stakeholders to explore, analyze, and acquire carbon storage related data.

Morkner, Paige↗
NASA NTRSDate not supplied

Long-Term Corrosivity at NASA Kennedy Space Center as a Function of Distance and Time from the Atlantic Ocean

Long-term data to record both seasonal and notional bounding values for corrosivity at multiple sites at NASA Kennedy Space Center was needed to make better materials choices for NASA-based ground and spaceflight programs. The data was valuable for two key reasons, 1) to measure corrosion rate and chloride concentration as a function of time and distance from the Atlantic Ocean, and 2) compare the corrosivity at launchpad and site-specific areas to the more accelerated conditions at the KSC Beachside Atmospheric Corrosion Test Site for coating and materials performance prediction. Sites were chosen from 45 meter (150 feet) to 8 kilometers (5 miles) from the Atlantic Ocean and corrosion variables at each site were measured throughout each year from June 2017 to April 2023, except the Beachside site, which includes data from November 2010. The summary includes corrosivity data and coating performance comparisons at select sites, which will be used as the updated NASA corrosivity standard for corrosion control requirements.

NASA↗
DOE OSTI2020

Will Solar Panels Help When the Power Goes Out? Planning for PV Resilience

PV systems, like all energy systems, must chart a difficult course in order to improve resilience. They need to simultaneously withstand extreme conditions that cause grid power disruptions, be configured in a way that allows electricity to be delivered to meet the PV user's needs, and overcome disruptions arising from solar resource intermittency. Certain considerations reveal themselves as key to a PV system's resilience benefits. Choice of hardware is critical, as is site selection for the PV array. Voluminous evidence in a hurricane context demonstrates that durable hardware, properly maintained and sited, leads to PV systems surviving extreme weather with their functionality intact. Structurally weak or poorly maintained PV equipment, on the other hand, has demonstrated failures during extreme weather events. PV system stakeholders should ensure that best practices are followed for hardware procurement and siting. It is also important to understand that PV systems are not one-size-fits-all. While incorporating islanding capabilities and energy storage into the system's electrical topology will typically enhance resilience, the user's needs will determine the optimally resilient conformation of any given system. These factors - appropriate hardware, siting, maintenance, and system design - are the primary drivers of PV resilience. PV systems possess high potential for resilient energy generation due to their distributed, abundant, and free fuel supply, but the technology itself does not inherently lead to resilient outcomes. Realizing PV's potential for resilience requires consideration of these determinative factors.

14 SOLAR ENERGY↗
DOE OSTI2025

Cleaned 5-Minute Resolution Air Quality and Meteorological Data from Nine TCEQ CAMS Sites in Houston, Texas (Nov 2021 – Oct 2022)

These data encompass 5-minute air monitoring and meteorological observations collected in the greater Houston, Texas metropolitan region, at nine (9) Continuous Ambient Monitoring Stations (CAMS) operated by the Texas Commission on Environmental Quality (TCEQ) between November 1, 2021 and October 31, 2022. The CAMS sites (CAMS 1, 8, 35, 45, 148, 403, 405, 410, and 1052) were chosen because their instrumentation includes measurements of PM2.5. These sites also provide continuous multi-parameter air-quality and meteorological measurements. Particulate matter (PM2.5, PM10) was sampled along with several trace gases, including ozone (O3), nitrogen oxides (NO, NO2, NOx), sulfur dioxide (SO2), and carbon monoxide (CO). The data set also contains standard surface meteorological parameters (temperature, humidity, pressure, wind speed, and wind direction). Several sites also include AutoGC-based measurements of volatile organic compounds (VOCs). Air monitoring instruments deployed at the selected sites comprise the following systems: BAM-1020 or TEOM (PM2.5), Thermo Scientific TEI 49i (O3), TEI 42i (NOx), and AutoGCs (VOCs). This data set is similar to the data included within the houairq5mX1.00 datastream, except for a few additional quality control steps. A systematic data cleaning and verification process was performed on the data set to ensure its quality and preparation for analysis. Removal of non-numeric status flags (e.g., [LIM], [QAS], [SPZ], [CAL], [PMA], [AQI], [SPN], [MAL]) was accomplished by employing rule-based string parsing to extract valid numerical values. Missing entries were set to -9999; however, invalid or anomalous values (e.g., 99999) were retained as originally reported by the TCEQ to preserve data provenance. The time sequence was verified for completeness, removal of duplicates, and uniformity at 5-minute intervals. Column labeling was standardized, and corresponding values were assessed for physical plausibility. All timestamps in the data set were reported in Coordinated Universal Time (UTC) as provided by the TCEQ. Further, the latitude and longitude coordinates were added for each CAMS site. A subset of the data (June 1–September 30, 2022) has been used in the following publication: Subba et al. 2025. “Implications of sea breeze circulations on boundary layer aerosols in the southern coastal Texas region.” EGUsphere 2025: 1–49, https://doi.org/10.5194/egusphere-2025-2659.

latitude↗
NASA NTRS1982

Computer-aided Siting of Coal Conversion Facilities

The value of using geographic information systems in site selection for coal conversion plants is discussed. Environmental and cultural factors and capital/operating costs were considered to determine site suitability.

Moreno, D. D.↗
NASA NTRS1999

Landing Site Engineering Constraints

Based upon the lander design, constraints are placed upon the landing site selection process in order to mitigate landing risk and optimize mission performance. Constraints are placed on the landing site latitude, elevation, measured rock abundance and terrain slopes within the landing footprint. Estimated mission lifetime and power availability as a function of landing site latitude will be presented. The dimensions of the landing footprint will be given. Plans for obtaining high resolution MOC images of candidate landing sites will be discussed.

Spencer, D.↗
NASA NTRS1977

The Feasibility of Establishing Operational Water Hyacinth-Based Systems at the Treatment Facilities of Existing Cities

The wastewater treatment facilities of three communities in southern Florida and two in southern Texas areas having populations of 20,000 or fewer persons were surveyed to determine: (1) their performance characteristics and the nature of their customers; (2) facility upgrading requirements needed to meet current and future EPA and State standards; (3) their adaptability to water hyacinth utilization and harvested plant disposal; and (4) the level of community support. Guidelines for site selection were established and applied to five cities in Texas and four in Florida. An evaluation of the prospective sites reveals that the Florida locations are generally unsuitable for implementation of water hyacinth based systems because of regulatory philosophy. All five Texas sites have excellent potential.

Source record↗
NASA NTRS1995

A Strategy for Mars Exopaleontology

There is compelling geological evidence that the climate of early Mars was much more Earth-like, with a denser atmosphere and abundant surface water. Given that life developed on the Earth very quickly (between 4.2 and 3.5 Ga), it is quite plausible that life may have also developed on Mars during this early clement period. If Martian life developed, it is likely to have left behind a fossil record. Thus, an important focus for upcoming Mars missions is to explore for an ancient biosphere. This presents a set of goals and problems that are quite distinct from Exobiology. I call this new activity "Exopaleontology", whose core principles derive from studies of the Precambrian fossil record on Earth, biosedimentology and microbial fossilization. Such studies reveal that the most important factor favoring the long-term preservation of microbial fossils is rapid entombment of microorganisms by fine-grained, stable mineral phases such as silica, phosphate, carbonate and metal sulfides. Terrestrial environments where such aqueous mineral phases frequently entomb and preserve microorganisms include subaerial and subaqueous springs and shallow hydrothermal systems, evaporitic alkaline lakes, "hardpan" soils (e.g. calcretes, silcretes, ferracretes), and frozen soils or ground ice. With the exception of ice, which has a short crustal residence time, such deposits am known to retain a record of terrestrial life for billions of years. Current activities seek to refine and apply this strategy to the Mars Global Surveyor missions and beyond. Ongoing studies of microbial fossilization in each of the target environments identified above are aimed at improving our understanding of how biological information is incorporated into aqueous mineral deposits and preserved. Viking data is being used to target sites for high resolution orbital imaging and spectroscopy during upcoming Mars missions. Such data will provide a basis for selecting sites for future landed missions and eventually, sample return.

Farmer, Jack D.↗
NASA NTRS2012

Feasibility and Definition of a Lunar Polar Volatiles Prospecting Mission

The recent Lunar Crater Observing and Sensing Satellite (LCROSS) mission has provided evidence for significant amounts of cold trapped volatiles in Cabeus crater near the Moon's south pole. Moreover, LRO/Diviner measurements of extremely cold lunar polar surface temperatures imply that volatiles can be stable outside or areas of strict permanent shadows. These discoveries suggest that orbital neutron spectrometer data point to extensive deposits at both lunar poles. The physical state, composition and distribution of these volatiles are key scientific issues that relate to source and emplacement mechanisms. These issues are also important for enabling lunar in situ resource utilization (ISRU). An assessment of the feasibility of cold-trapped volatile ISRU requires a priori information regarding the location, form, quantity, and potential for extraction of available resources. A robotic mission to a mostly shadowed but briefly .unlit location with suitable environmental conditions (e.g. short periods of oblique sunlight and subsurface cryogenic temperatures which permit volatile trapping) can help answer these scientific and exploration questions. Key parameters must be defined in order to identify suitable landing sites, plan surface operations, and achieve mission success. To address this need, we have conducted an initial study for a lunar polar volatile prospecting mission, assuming the use of a solar-powered robotic lander and rover. Here we present the mission concept, goals and objectives, and landing site selection analysis for a short-duration, landed, solar-powered mission to a potential hydrogen volatile-rich site.

Heldmann, Jennifer↗
NASA NTRS2000

A Remote Sensing/Geographic Information Systems Approach in the Selection of Mars Sites of Biological Interest

The search for extinct or extant life on Mars is the search for past or present liquid water, respectively. There are numerous signs of past liquid water on Mars in the form of dry river valleys, paleolakes, and their associated flow and sediment patterns. While some of these features are recent (Amazonian, 1.8 billion years ago to present), there is no evidence that any are currently flowing. Liquid water on the surface would only be possible at those sites with sufficiently high temperatures and pressure. The key to the selection of sites on Mars to search for evidence of life is the search for the presence of water. An approach to this problem is the use of remotely sensed data incorporated in a geographic information system (GIS). A GIS is a computer-based system capable of assembling, storing, manipulating, and displaying geographically referenced information, i.e., data identified according to their locations. In planetary studies these data are acquired from remote sensing (RS) platforms (orbiters). These data are co-registered layers and, through the use of GIS analysis functions, areas on these layers can be selected as a function of the information desired. Our work used existing data layers from the Viking and Mars Global Surveyor missions to determine where water could be possible in liquid form on the Martian surface, based on the phase diagram for water.

Lobitz, B. M.↗
NASA NTRS1998

Potential Mars Surveyor 2001 Landing Sites: Low-Elevation Cratered "Highlands" in Central and Eastern Sinus Meridiani and Near Amenthes Fossae

The main scientific goal for the Mars Surveyor Program 2001 (MSP 01) landed mission is to collect and characterize 91 rock and 13 soil core samples using an integrated instrument suite onboard the Athena Rover. If possible, these samples will be retrieved and returned to Earth via a MSP 05 or MSP 07 mission. Preliminary engineering constraints for the MSP 01 landing site call for a location that lies between 15 S and 30 N, and below about 2 km elevation (based on Viking-era topography). Desirable landing sites for MSP 01 are to be located "in the ancient highlands where the environmental conditions may have been favorable to the preservation of evidence of possible prebiotic or biotic processes including the emergence (and, potentially, the persistence) of life". We interpret this to mean that the desirable sites include those that have evidence of aqueous sediments that might have been deposited during the Noachian and/or Hesperian Epochs of Mars' history. In addition to the search for subaqueous sedimentary deposits, we took into consideration the fact that the rover, Athena, will need to be able to access these materials. Thus, a site where aeolian deflation has occurred might be desirable because it might expose, in situ, layered sedimentary deposits. Deflated areas, of course, might include potential landing hazards in the form of meterscale buttes and mesas (e.g., Christmas Lake Valley, OR), thus careful study of such sites with high resolution images will be required before a decision is made to land. We have been examining three regions that have potential to be considered for MSP 01 landing sites. This work is based on Viking (VIS, IRTM) and Phobos 2 (Termoskan) observations and should be regarded as preliminary because we believe that the final site selection should also be based upon analysis of Mars Global Surveyor observations that help constrain mineralogy (TES) and local geomorphology (MOC, MOLA). (1) Eastern Sinus Meridiani Region (proposed by K. S. Edgett) Sinus Meridiani is a persistent low-albedo (< 0. 16) region on the martian equator that has been recognized for about 400 years. All of Sinus Meridiani is below the 2 km elevation constraint for MSP 01. The region includes cratered highlands, valley networks, aeolian dunes, and possible aqueous sedimentary deposits. The landing site study region is located in the eastern portion of Sinus Meridiani. It is bounded by latitudes 10 S to 2 N, longitudes 355 W to 345 W, and the elevations are mostly 1-2 km. The center of this area contains a medium-albedo (0.19-0.21), relatively smooth-surfaced deposit that was suggested by Rice to be a lacustrine deposit. Several potential landing areas can be suggested within this region. Based on Viking and Phobos 2 data, the favored sites so far are centered at 7.6 S, 346.9 W and 0.8 S, 349 W. Thermal inertias are 3.2-7.0 x 10(exp -3) cal /sq cm s(exp -0.5)/K; and rock abundances are around 2-6%. The site at 7.6 S, 346.9 W is at the southern end of the smooth, medium-albedo unit that might have a lacustrine origin. At this location, numerous channels appear to have drained toward the smooth unit. Viking images from orbit 747A show this area at about 15 m/pixel ground resolution. The images reveal that aeolian deflation has occurred along the deposit's margins. Bright (i.e., albedo >= 0.21) aeolian dunes are present on the channel floors and in some of the depressions on the smooth unit. The bright, apparently active dunes might consist of material (perhaps lakedeposited sands) that has been eroded from the smooth unit. The site at approximately 0.8 S, 349 W is selected because it offers an opportunity to solve a long-standing puzzle about Mars remote sensing. There are three main "color" units on Mars: "dark red, dark gray, and bright red". This landing site would allow the Athena rover an opportunity to investigate all three materials within close proximity (the best place on Mars to do so). There are no high resolution (better than 100 m/pixel) Viking or Mariner images of this site. (2) Central Sinus Meridiani Region (proposed by K. S. Edgett and T. J. Parker) Central Sinus Meridiani is characterized by two types of surfaces [4]. One is like typical martian cratered highlands elsewhere- there are old valley networks and old impact craters. The other is relatively smooth and flat. These two units are in contact around 3.1 S between 5 W and 4 E longitudes. Valley networks- including one at 6'S, 358 W that rivals the Grand Canyon of Arizona- once drained toward the smooth unit. Edgett and Parker [4] proposed that the smooth unit might consist of sediments laid down in a large Noachian-aged sea/ocean that would have covered much of the northern hemisphere. Schultz and Lutz [I I I suggested that it is a paleopolar layered deposit. Regardless, the smooth unit where it contacts the cratered terrain would make an excellent site for Athena rover to investigate. The site is best seen in Viking high resolution images from orbits 408B (about 30 m/pixel) and 746A (about 12 m/pixel). These images suggest that aeolian deflation has occurred along the margin of the smooth unit, and this deflation has exposed horizontal larrs of material. The elevation is about 0.5 km; thermal inertias are 6.5-8.0 x 10(exp -3) cal /sq cm s(exp -0.5) / K; rock abundances are 2-4%; and the surface is probably sandy with dark drifts and ripples but almost no actual dunes. We suggest a landing around 3.2 S, 3.0 W would test the aqueous sediment hypothesis and provide a potentially smooth surface on which to land. (3) Amenthes Fossae Region (proposed by S. N. Huntwork and K. S. Edgett) The Amenthes Fossae are a series of graben/fissures that are circumferential to the southeast side of Isidis Planitia. These fissures cross a variety of ancient, heavily cratered Noachian terrain and younger, Hesperian and Amazonian terrain. We focused our search on a region 0-15 N, 250 - 270 W. Elevations are -0.5 to 2 km. Depending upon whether Isidis Planitia was ever a water-rich environment, this region might have been influenced by aqueous sedimentation. Valley networks are common, and they drained toward the north and northwest. We focused our work on a set of Viking orbiter high-resolution images, 719A 1-48. These have resolutions 16-24 rri/pixel. We examined images 20-23, centered at 2 N, 258 W. This site, on the plains just southwest of a 42 km-diameter crater, includes a valley network channel, a relatively young crater ejecta deposit, a few buttes composed of presumably ancient, Noachian bedrock, and a "plains" unit. The plains might make an ideal landing surface, except for the presence of some fine-scale ridges (oriented approximately N-S). The ridges are probably yardangs, thus this site offers a place where aeolian deflation has probably exposed some of the layered rock units that comprise the "plains". Thermal inertias are 7.9-8.3 x 10(exp -3) cal/sq cm s(exp -0.5) /K and rock abundances are 10-15%. A rover traverse might include the opportunity to go down to the floor (and sample along the walls) of the valley network channel at 2 N 258.1 W.

Edgett, K. S.↗
DOE OSTI2025

Fracture Network Quantification for Enhanced Reservoir Characterization in CO2 Storage Sites

Presentation slides on “Fracture Network Quantification for Enhanced Reservoir Characterization in CO2 Storage Sites” for the CCUS 2025 conference held in Houston, Texas March 3-5, 2025. Accurate reservoir characterization is fundamental for the safe and efficient operation of carbon capture, utilization, and storage (CCUS) projects. This process is not only critical during initial site selection but also plays a key role in continuously updating reservoir geomodels throughout injection operations to effectively manage subsurface storage sites. Our primary objective is to develop a comprehensive understanding of fracture networks within CO2 injection reservoirs, which are critical for predicting the behavior of injected fluids, ensuring storage integrity post-injection, and mitigating risks such as leakage or induced seismicity.

artifical intelligence / machine learning (AI/ML)↗