Results for “surface complexation” — Page 18

NASA NTRSDate not supplied

Simulation of Oxidative Etch Pit Formation and Growth on FiberForm

Erosion of carbon surfaces due to oxidation does not occur uniformly but through the formation of localized etch pits because of active surface sites. These active sites are formed due to the presence of atomic defects on the carbon surface and have much higher reactivity compared to average non-defective sites. Thus, these active sites are the first to react during ablation, resulting in their removal. This causes all the neighboring atoms to be defective, and increasing their reactivity, thus leading to localized carbon removal around these “active” sites. In this manner, these highly reactive defects serve as nucleation sites for the formation and growth of etch pits, with detrimental effects on the structural integrity. In order to understand the influence of these etch pits on the material properties of carbon fiber microstructures, we have developed a new capability within direct simulation Monte Carlo (DSMC) to capture the etch pit formation process. This capability is developed within the DSMC code SPARTA (Stochastic PArallel Rarefied-gas Time-accurate Analyzer) and can model the material removal in the presence of active sites leading to the formation of etch pits. The focus of the current work will be to study the effect of etch pits on the material properties of FiberForm, the precursor substrate of the PICA Thermal Protection System (TPS) material. The microstructure of virgin FiberForm obtained directly from X-ray microtomography scans is used within SPARTA to obtain the ablated geometries with etch pits. These pitted microstructures are then imported into the Porous Microstructure Analysis (PuMA) software and various material properties such as thermal conductivity, elasticity, and permeability are computed. The variation of these properties because of the complex evolution of the surface topology due to the formation of etch pits is studied and analyzed. Furthermore, the effect of pitting is compared to the case of uniform radial shrinking of fibers, which has been the standard for modelling ablation of carbon structures, and significant differences are observed. Thus, a physically realistic model of material removal through the formation of etch pits will be helpful in predicting the degradation of carbon-based TPS more accurately during oxidation; as well as other mechanisms such as spallation, which involves the removal of chunks of material into the flow due to the growth of etch pits. This will ultimately improve our understanding of the failure modes in these materials due to ablation.

DSMC↗

NASA NTRSDate not supplied

Computational Study of Oxidative Etch Pitting in FiberForm and the Effect on Its Material Properties

Erosion of carbon due to oxidation does not occur uniformly but through the formation of localized etch pits because of active surface sites. These active sites are formed due to the presence of atomic defects on the carbon surface, and have much higher reactivity compared to average non-defective sites. Thus, these active sites are first to react during ablation, resulting in their removal. This causes all the neighboring atoms to be defective and increase their reactivity, thus leading to the localized carbon removal around these “active” sites. In this manner, these highly reactive defective sites serve as nucleation sites for the formation and growth of etch pits with potentially detrimental effects on the structural integrity. In order to understand the influence of these etch pits on the material properties of carbon fiber microstructures, we have developed a new capability within direct simulation Monte Carlo (DSMC) to capture the etch pit formation process. This capability is developed within the DSMC code SPARTA (Stochastic PArallel Rarefied-gas Time-accurate Analyzer) and can model the material removal in presence of active sites leading to the formation of etch pits. The focus of the current work will be to study the effect of etch pits on the material properties of FiberForm, a commonly used base material within many thermal protection system materials (TPS). The microstructure of virgin FiberForm obtained directly from X-ray microtomography experiments is used within SPARTA to obtain the ablated geometries with etch pits. These pitted microstructures are then imported within the Porous Microstructure Analysis (PuMA) software and various material properties such as elasticity, thermal conductivity, and permeability are computed. The variation of these properties as a result of the complex evolution of the surface topology due to etch pit formation is studied and analyzed. Furthermore, the effect of pitting is compared to the case of shrinking fibers, which has been the standard for modelling ablation of carbon structures; and significant differences are observed. Thus, such a physically realistic modeling of material removal through the formation of etch pits will be helpful in predicting the degradation of carbon-based TPS more accurately during oxidation; as well as other mechanisms such as spallation, which involves the removal of chunks of material into the flow due to etch pit growth. This will ultimately improve our understanding of the failure modes in these materials due to ablation.

Carbon Ablators↗

NASA NTRSDate not supplied

Computational Study of Oxidative Etch Pitting in FiberForm and the Effect on Its Material Properties

Erosion of carbon due to oxidation does not occur uniformly but through the formation of localized etch pits because of active surface sites. These active sites are formed due to the presence of atomic defects on the carbon surface, and have much higher reactivity compared to average non-defective sites. Thus, these active sites are first to react during ablation, resulting in their removal. This causes all the neighboring atoms to be defective and increase their reactivity, thus leading to the localized carbon removal around these “active” sites. In this manner, these highly reactive defective sites serve as nucleation sites for the formation and growth of etch pits with potentially detrimental effects on the structural integrity. In order to understand the influence of these etch pits on the material properties of carbon fiber microstructures, we have developed a new capability within direct simulation Monte Carlo (DSMC) to capture the etch pit formation process. This capability is developed within the DSMC code SPARTA (Stochastic PArallel Rarefied-gas Time-accurate Analyzer) and can model the material removal in presence of active sites leading to the formation of etch pits. The focus of the current work will be to study the effect of etch pits on the material properties of FiberForm, a commonly used base material within many thermal protection system materials (TPS). The microstructure of virgin FiberForm obtained directly from X-ray microtomography experiments is used within SPARTA to obtain the ablated geometries with etch pits. These pitted microstructures are then imported within the Porous Microstructure Analysis (PuMA) software and various material properties such as elasticity, thermal conductivity, and permeability are computed. The variation of these properties as a result of the complex evolution of the surface topology due to etch pit formation is studied and analyzed. Furthermore, the effect of pitting is compared to the case of shrinking fibers, which has been the standard for modelling ablation of carbon structures; and significant differences are observed. Thus, such a physically realistic modeling of material removal through the formation of etch pits will be helpful in predicting the degradation of carbon-based TPS more accurately during oxidation; as well as other mechanisms such as spallation, which involves the removal of chunks of material into the flow due to etch pit growth. This will ultimately improve our understanding of the failure modes in these materials due to ablation.

Carbon Ablators↗

NASA NTRS2007

Titan's Surface from Cassini RADAR SAR and High Resolution Radiometry Data of the First Five Flybys

The first five Titan flybys with Cassini's Synthetic Aperture RADAR (SAR) and radiometer are examined with emphasis on the calibration and interpretation of the high-resolution radiometry data acquired during the SAR mode (SAR-radiometry). Maps of the 2-cm wavelength brightness temperature are obtained coincident with the SAR swath imaging, with spatial resolution approaching 6 km. A preliminary calibration shows that brightness temperature in these maps varies from 64 to 89 K. Surface features and physical properties derived from the SAR-radiometry maps and SAR imaging are strongly correlated; in general, we find that surface features with high radar reflectivity are associated with radiometrically cold regions, while surface features with low radar reflectivity correlate with radiometrically warm regions. We examined scatterplots of the normalized radar cross-section sigma(exp o) versus brightness temperature, finding differing signatures that characterize various terrains and surface features. Implications for the physical and compositional properties of these features are discussed. The results indicate that volume scattering is important in many areas of Titan's surface, particularly Xanadu, while other areas exhibit complex brightness temperature variations consistent with variable slopes or surface material and compositional properties.

Titan↗

NASA NTRS1977

Comment on the relation between the nonadiabatic coupling and the complex intersection of potential energy curves

Simple relations are discussed that provide a correspondence between the complex intersection of two potential surfaces and the nonadiabatic coupling matrix element between those surfaces. These are key quantities in semiclassical and quantum mechanical theories of collision induced electronic transitions. Within the two state approximation, the complex intersection is shown to be directly related to the location and magnitude of the peak in the nonadiabatic coupling. Two cases are considered: the avoided crossing between two potential surfaces; and the spin orbit interaction due to a P-2 halogen atom. Comparisons are made between the results of the two-state model and the results of ab initio quantum chemical calculations.

Jaffe, R. L.↗

NASA NTRS1998

Comparison of Continuous-Wave CO2 Lidar Calibration by use of Earth-Surface Targets in Laboratory and Airborne Measurements

Backscatter of several Earth surfaces was characterized in the laboratory as a function of incidence angle with a focused continuous-wave 9.1 micro meter CO2 Doppler lidar for use as possible calibration targets. Some targets showed negligible angular dependence, while others showed a slight increase with decreasing angle. The Earth-surface signal measured over the complex Californian terrain during a 1995 NASA airborne mission compared well with laboratory data. Distributions of the Earth's surface signal shows that the lidar efficiency can be estimated with a fair degree of accuracy, preferably with uniform Earth-surface targets during flight for airborne or space-based lidar.

Jarzembski, Maurice A.↗

NASA NTRS2021

Supraglacial River Forcing of Subglacial Water Storage and Diurnal Ice Sheet Motion

Surface melting impacts ice sheet sliding by supplying water to the bed, but subglacial processes driving ice accelerations are complex. We examine linkages between surface runoff, transient subglacial water storage, and short-term ice motion from 168 consecutive hourly measurements of meltwater discharge (moulin input) and GPS-derived ice surface motion for Rio Behar, a ∼60 sq. km moulin-terminating supraglacial river catchment on the southwest Greenland Ice Sheet. Short-term accelerations in ice speed correlate strongly with lag-corrected measures of supraglacial river discharge (r = 0.9, τ = 0.7, p < 0.01). Though our 7 days record cannot address seasonal-scale forcing, diurnal ice accelerations align with normalized differenced supraglacial and proglacial discharge, a proxy for subglacial storage change, better than GPS-derived ice surface uplift. These observations counter theoretical steady state basal sliding laws and suggest that moulin and proglacially induced fluctuations in subglacial water storage, rather than absolute subglacial water storage, drive short-term ice accelerations.

Glacial↗

NASA NTRS1972

Flight loads and control

The prediction of flight loads and their potential reduction, using various control logics for the space shuttle vehicles, is very complex. Some factors, not found on previous launch vehicles, that increase the complexity are large lifting surfaces, unsymmetrical structure, unsymmetrical aerodynamics, trajectory control system coupling, and large aeroelastic effects. Discussed are these load producing factors and load reducing techniques. Identification of potential technology areas is included.

Mowery, D. K.↗

NASA NTRS1972

Fundamental concepts of structural loading and load relief techniques for the space shuttle

The prediction of flight loads and their potential reduction, using various control system logics for the space shuttle vehicles, is discussed. Some factors not found on previous launch vehicles that increase the complexity are large lifting surfaces, unsymmetrical structure, unsymmetrical aerodynamics, trajectory control system coupling, and large aeroelastic effects. These load-producing factors and load-reducing techniques are analyzed.

Ryan, R. S.↗

NASA NTRS1974

The micrometeoroid complex and evolution of the lunar regolith

The interaction of the micrometeoroid complex with the lunar surface is evidenced by numerous glass-lined microcraters on virtually every lunar surface exposed to space. Such craters range in size from less than .1 micron to approximately 2 sq cm diameter. Using small scale laboratory cratering experiments for calibration, the observed crater-sized frequency distributions may be converted into micrometeoroid mass distributions. These lunar mass distributions are in essential agreement with satellite data. Some physical properties of micrometeoroids may be deduced by comparing lunar crater geometries with those obtained in laboratory experiments. The proponderance of circular outlines of lunar microcraters necessitates equidimensional, if not spherical, micrometeoroids.

Hoerz, F.↗

NASA NTRS1976

Status of the Viking missions

A chronology of Viking 1 lander activities is presented for the first 43 sols (Martian days) of surface sampling and analysis. The orbital insertion of the second Viking spacecraft is reviewed along with the search for the second landing site. A general assessment of the planet is made on the basis of the data thus far obtained. Some of the findings reported are that: (1) there is extensive evidence of volcanism, fluvial and aeolian erosion, and deposition over the entire surface; (2) the floor of Vallis Marineris is significantly younger than the planet's surface; (3) the morphology of Martian crater ejecta is indicative of surface flow rather than ballistic deposition; (4) the rocks in the immediate vicinity of the lander are all covered by a layer of fine red dust; (5) the atmosphere is optically thick and well mixed, with suspended particles giving the sky a pink color; (6) the N and Ar isotopic ratios are different from those on earth; (7) atmospheric water vapor varies with both time of day and location; (8) the summer northern polar regions have a high water concentration in the atmosphere; (9) a large fraction of magnetic material resides in the surface; and (10) no complex organic compounds have been detected in the two samples analyzed.

Soffen, G. A.↗

NASA NTRS1976

Stratigraphy and structural geology

The immediate goal of stratigraphy and structural geology is to reduce the enormous complexity of a planetary surface to comprehensible proportions by dividing the near-surface rocks into units and mapping their distribution and attitude.

Carr, M. H.↗

NASA NTRS1978

Inlet boundary-layer shapes on four aircraft forebodies at Mach 6

Boundary-layer shape measurements at the engine inlet on four different hypersonic aircraft forebody designs (with no engine on the forebody) are reported. The measurements provide a qualitative assessment of the effectiveness of various forebody geometries as engine inlet precompression surfaces. The designs, tested in a hypersonic tunnel at Mach 6 and a nominal freestream Reynolds number of 30,500,000, included a semiconical forebody, a configuration similar to a slab delta wing, a conical nose blended into a flat surface, and a conical, complex forebody shape. Boundary layer height as a function of forebody compression is shown for each design.

Lawing, P. L.↗

NASA NTRS1979

Lunar magnetic anomalies detected by the Apollo subsatellite magnetometers

Properties of lunar crustal magnetization thus far deduced from Apollo subsatellite magnetometer data are reviewed using two of the most accurate available magnetic anomaly maps, one covering a portion of the lunar near side and the other a part of the far side. The largest single anomaly found within the region of coverage on the near-side map correlates exactly with a conspicuous light-colored marking in western Oceanus Procellarum called Reiner Gamma. This feature is interpreted as an unusual deposit of ejecta from secondary craters of the large nearby primary impact crater Cavalerius. The mean altitude of the far-side anomaly gap is much higher than that of the near side map and the surface geology is more complex; individual anomaly sources have therefore not yet been identified. The mechanism of magnetization and the origin of the magnetizing field remain unresolved, but the uniformity with which the Reiner Gamma deposit is apparently magnetized, and the north-south depletion of magnetization intensity across a substantial portion of the far side, seem to require the existence of an ambient field, perhaps of global or larger extent.

Hood, L. L.↗

NASA NTRS1980

Comparison of NASCAP modelling results with lumped circuit analysis

Engineering design tools that can be used to predict the development of absolute and differential potentials by realistic spacecraft under geomagnetic substorm conditions are described. Two types of analyses are in use: (1) the NASCAP code, which computes quasistatic charging of geometrically complex objects with multiple surface materials in three dimensions; (2) lumped element equivalent circuit models that are used for analyses of particular spacecraft. The equivalent circuit models require very little computation time, however, they cannot account for effects, such as the formation of potential barriers, that are inherently multidimensional. Steady state potentials of structure and insulation are compared with those resulting from the equivalent circuit model.

Stang, D. B.↗

NASA NTRS1985

Morphological and physical characteristics of the Virgo Cluster - First results from the Las Campanas photographic survey

Preliminary results are presented of a photographic survey of the Virgo cluster to the faintest convenient limit of the Las Campanas du Pont 2.5 m reflector, performed in order to study the complexity of both the surface and velocity distributions within the central 6 degree radius region. The survey is described and the resulting Catalog is discussed, and the frequency of galaxy types found and listed in the Catalog is described. The physical properties of the dwarfs are summarized, and luminosity functions are given separately for each morphological type. The progressive change of (MBT) faintward along the morphological sequence from Sc I through Sm and Im types is shown, leading to a calibration of the de Vaucouleurs Lambda luminosity index and a determination of its intrinsic dispersion. The preliminary results on the distribution of galaxies of all types in the two principal subclustering regions found are summarized, and the velocity distributions over the face of the 6 degree core are discussed for the various galaxy types.

Sandage, A.↗

NASA NTRS1988

A jet in a crossflow

In the transition from hover to wingborn flight, V/STOL aircraft rely on the direct thrust of lift jets to supplement wing generated lift. The lifting jets interact with the flow over the aerodynamic surface to produce a complex flow around the aircraft. The simplest configuration which retains the essential characteristics of the jet/aerodynamic-surface interaction problem is a subsonic round jet exhausting perpendicularly through a large flat plate into a uniform crossflow. This configuration was studied extensively, both by experiment and by analysis. As a result, a fairly complete experiment data base exists for comparison with the numerical calculations. Research publications and presentations in this area are included. Each citation is followed by an abstract of the work.

Fearn, Richard L.↗

NASA NTRS1987

Chemical and spectroscopic characterization of a suite of Mars soil analogs

The National Aeronautics and Space Administration has begun preparations for the flight of the Mars Observer Mission in the early 1990s. An advanced ground-based study is being conducted on a usefully limited suite of Mars Soil Analog Materials (MarSAM) intended to simulate the aeolian material covering the surface of Mars. A series of variably proportioned iron/calcium smectite clays were prepared from a typical montmorillonite clay using the Banin method. The effect of increasing iron on a diverse set of chemical and spectroscopic properties of the suite of clays is discussed. In order to chemically characterize the MarSAM and compare them with the Martian soil studied by Viking, the clays were analyzed for their major and minor elemental compositions by X-ray fluorescence and ion-coupled plasma techniques. It was concluded that the surface iron has a complex and hitherto uninvestigated impact on the catalytic and spectroscopic properties of clays and on the ability of these material to store energy.

Coyne, L. M.↗