A study of a sorption process.
Sorption process for determining sticking probability of molecules on surface of sorbents, diffusion coefficient of molecules through sorbents and adsorption isotherms
DIFFUSION COEFFICIENT↗
SEARCH · Search NASA
Results for “surface diffusion”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
The chemical arc - A spectrometric study.
IR spectrometric analysis of flames of composite rocket propellants, maintaining diffusion flames between surfaces of decomposing ammonium perchlorate and fuel source
Aimen, W. R.↗
Monte Carlo calculation of free molecule flow over concave spherical surfaces.
Monte Carlo calculation of free molecular flow over concave spherical surface, considering partial diffuse reflection and imperfect energy accommodation
Fan, C.↗
Vibration detection using lasers
Interference displacement patterns produced when light from a laser illuminates diffusely reflecting, vibrating surface are observed and photographed. Standing wave modes on model surface can be interpreted in order to yield amplitude and frequency of vibrations. Flat, white surfaces yield best interference patterns, even over considerable surface curvature.
Massey, G. A.↗
Mechanism of the oxidation of titanium disilicide.
Study of the oxidation of TiSi2 at temperatures of 300 to 1300 C. Wafers prepared using the techniques of powder metallurgy had densities of 95 to 98% of the theoretical value. On oxidation at temperatures up to 600 C, the polished wafers formed a protective, titania-silica glass. The rate data indicate a complex surface and diffusion-limited mechanism. Above 600 deg C, the oxide consisted of an amorphous SiO2 film with crystalline islands of TiO2 (rutile). From 1000 to 1300 C, parabolic kinetics with an activation energy of 21.3 kcal/mole were observed. These data are consistent with a model in which the rate-determining step is the diffusion of oxygen through the silica film with the simultaneous diffusion of titanium from the substrate to the islands of rutile growing on top of the amorphous silica.
Schwettmann, F. N.↗
Diurnal behaviour of water on Mars
A numerical model of the diurnal transport of water across the Martian surface is developed. The atmospheric boundary layer is modeled in terms of local radiative-convective processes, and radiative effects of ice fogs near the surface are included. Diffusion of water in the ground is treated for the cases of adsorption and condensation. The model is applied to the diurnal variation of water vapor in the atmosphere as observed by Barker (1974). The morning rise in the amount of water vapor can be explained in terms of the evaporation of ground fogs. The evening decrease is compatible with the model if adsorption dominates in the soil. The average level of vapor concentration requires that the atmosphere above the boundary layer be relatively dry. The ground fogs persist until midmorning and should be observable. Some consequences of these conclusions are discussed.
Flasar, F. M.↗
Effects of grain boundaries in polycrystalline solar cells
In polycrystalline solar cells, the short-circuit current is reduced (compared to single-crystal cells) due to recombination of minority carriers at the grain boundaries. The magnitude of this reduction is calculated for the case of a monochromatic beam of light, assuming that both the light beam and the grain boundaries are perpendicular to a p-n junction. The photoresponse of the junction is calculated in terms of the absorption coefficient of the light, the minority-carrier diffusion length, the surface recombination velocity at the grain boundary and the distance of the light beam from the grain boundary. The analysis gives an expression for an effective grain boundary width which depends on wavelength. This width determines the reduction in short-circuit current of solar cells made from material with columnar-type grains.
Zook, J. D.↗
High performance silicon solar arrays employing advanced structures
Specific design features to reduce cell mass, lower panel operating temperatures, and improve power to mass ratios for silicon solar cell arrays in space applications are presented. Because mass constraints limit payload capacity for launch into GEO, graphite/epoxy structures combined with high performance Si cells are needed to deliver a power/mass ratio of 265 W/kg, notably for Solar Electric Propulsion systems, compared with existing level of 65 W/kg. Shallow diffusion and back surface field cell technology have raised cell efficiencies to 15%, with a back emissivity of 1.64. Structural design requirements comprise Shuttle interface compatibility, full ground test capability, low mass, and high stiffness. Three array alternatives are discussed, and the STACBEAM configuration, which consists of a triangular truss and a piston deployer with folding accomplished on simple hinges, provides 0.2 Hz stiffness and achieves the design power/mass goals.
Rockey, D. E.↗
Radiation-dominated Snowmelt on Mars
A set of microclimatic conditions conducive to the generation of liquid water is being sought to see whether their requirements are any less stringent than those suggested by the global-climatic models. In particular, the melting of snow and ice in the equatorial zone (where the valley networks are preferentially situated) is investigated with a model that includes detailed infrared radiation transfer between the atmosphere and the snow, penetration of sunlight into the snow, sensible heat transfer to the atmosphere, and water vapor diffusion within the surface boundary layer. IR fluxes are calculated by using pressure and temperature dependent forms for the band absorptances of CO2 and H2O in the spectral range 50 to 2000/cm.
Clow, G. D.↗
Silicon production in an aerosol reactor
An aerosol reactor system was developed in which large particles of silicon can be grown by silane pyrolysis. To grow particles to sizes larger than one micron, vapor deposition must be used to grow a relatively small number of seed particles. Suppression of nucleation is achieved by limiting the rate of gas phase chemical reactions such that the condensible products of the gas phase chemical reactions diffuse to the surface of the seed particles as rapidly as they are produced. This prevents high degrees of supersaturation and runaway nucleation during the growth process. Particles on the order of 10 microns were grown repeatedly with the present aersol reactor. The nucleation controlled aerosol reactor is, therefore, a suitable system for the production of powders that can readily be separated from the gas by aerodynamic means.
Wu, J. J.↗
Hollow cathodes for arcjet thrusters
In an attempt to prevent exterior spot emission, hollow cathode bodies and orifice plates were constructed from boron nitride which is an electrical insulator, but the orifice plates melted and/or eroded at high interelectrode pressures. The most suitable hollow cathodes tested included a refractory metal orifice plate in a boron nitride body, with the insert insulated electrically from the orifice plate. In addition, the hollow cathode interior was evacuated to assure a low pressure at the insert surface, thus promoting diffuse electron emission. At high interelectrode pressures, the electrons tended to flow through the orifice plate rather than through the orifice, which could result in overheating of the orifice plate. Using a carefully aligned centerline anode, electron flow through the orifice could be sustained at interelectrode pressures up to 500 torr - but the current flow path still occasionally jumped from the orifice to the orifice plate. Based on these tests, it appears that a hollow cathode would operate most effectively at pressures in the arcjet regime with a refractory, chemically stable, and electrically insulating cathode body and orifice plate.
Luebben, Craig R.↗
Rugged low-resistance contacts to YBa2Cu3O(x)
Rugged low-resistance contacts to a high-T(c) superconductor YBa2Cu3O(x) were made by melting gold onto the sample surface, where it diffused into the sample pores making a strong mechanical contact in the form of a bead. Contact resistances lower than 50 microohm were obtained, allowing passage, without heating, of a direct current of about 5 A while the sample remained in the superconducting state at 20 K. Results of SEM and of contact-resistance, critical-current, and shear-strength measurements on these contacts are included.
Caton, R.↗
Observed variability of the solar luminosity
Data on solar luminosity variations are compiled in graphs and analyzed, with a focus on the SMM satellite bolometric measurements and other observations made since 1983. Consideration is given to total irradiance measurements in integrated light; emission-line variability in the visible, UV, and IR; mechanisms contributing to the solar variability (sunspots, faculae, rotation, oscillations, granulation, and active networks); the role of the solar magnetic cycle; and other observable parameters indicating variability. Also discussed are the effects of solar variations on the earth climate and the implications of the observations for theoretical models of convective-envelope processes (thermal diffusion near the surface and magnetic pressure in the interior).
Hudson, H. S.↗
A simplified treatment of SiB's land surface albedo parameterization
The earlier presented surface albedo parameterization is simplified by assuming that the reflectance of direct solar radiation is a simple function of solar zenith angle. The function chosen contains three parameters that vary with vegetation type, greenness, and leaf area index. Tables of parameter values are presented. Using these tables, SiB's (Simple Biosphere model) absorbances of direct solar radiation can be reproduced with an average relative error of less than 0.5 percent. Finally, the direct reflectance function is integrated over zenith angle to produce an equation for the surface reflectance of diffuse radiation.
Koster, Randal D.↗
Distillation of H2O from hard-frozen Martian permafrost
The authors present a method for distillation of hard-frozen Martian permafrost. A cable-tool is drilled into hard frozem permafrost to a depth of 10 to 20 m. They calculate that a 10 m hole could be drilled in a few days. A 10 m shaft with a diameter equal to the bore is inserted into the hole, and a air tight tent-like structure is erected over the borehole. Photovoltaic cells mounted on the tent supply electrical energy that is dissipated in the shaft. Drilling power can be supplied by other sources. With 1000 watts, the shaft can be heated to near 350 K, producing relatively high temperatures in the vicinity of the borehole. Surrounding H2O is vaporized and diffuses up through the regolith. The authors calculate that a tent of a radius of no more than a few meters would intercept most of the H2O as it diffused to the surface. Calculations suggest that it would require perhaps 30 days to extract H2O from most of the volume drained by this technique. Assuming that the hard frozen regolith is no more than 10 percent ice, the author's calculate that that about 2890 kg of H2O could be extracted in 30 days. Since the nominal requirement for each crew member is about 5 kg/day, one such borehole might be expected to supply enough H2O to maintain a crew of 5 for perhaps 100 days. Additional engineering studies will be done to attempt to improve the capacity or efficiency of this method.
Zent, A. P.↗
On the origin of the diffuse x ray background
The first measurement is reported of the intensity and spectrum of the diffuse x ray background in the 0.16 to 3.5 keV band which is free from contamination by sources with fluxes greater than approx. 6 x 10(exp -14) erg/sq cm/s. This result was made possible by the development of a number of techniques for reducing cosmic ray contamination and instrumental artifacts in the data collected by the Einstein Observatory imaging proportional counter. The analysis of the background data reveals a mean absolute intensity for the emission I sub x(0.16 to 3.5 keV) approx. = 5.6 x 10(exp -8) erg/sq cm/s/sr. The intensity is dependent on galactic longitude even when only high galactic data are used, allowing the setting of a lower limit of 20 pct. on the galactic contribution to the mean emission band. The spectrum of the total background is consistent with a power law of slope similar to 0.7 between 0.16 and 3.5 keV with evidence for a steep rise toward lower energies. Preliminary evidence is also reported for the association of faint radio sources with peaks in the arcminute scale fluctuations of the diffuse x ray surface brightness distribution and then some implications are considered of these results.
Helfand, David J.↗
Property changes induced by the space environment in composite materials on LDEF: Solar array materials passive LDEF experiment A0171 (SAMPLE)
Surface modifications to composite materials induced by long term exposure in low earth orbit (LEO) were dominated by atomic oxygen erosion and micrometeoroid and space debris impacts. As expected, calculated erosion rates were peculiar to material type and within the predicted order of magnitude. Generally, about one ply of the carbon fiber composites was eroded during the 70 month LDEF experiment. Matrix erosion was greater than fiber erosion and was more evident for a polysulfone matrix than for epoxy matrices. Micrometeoroid and space debris impacts resulted in small (less than 1mm) craters and splattered contaminants on all samples. Surfaces became more diffuse and darker with small increases in emissivity and absorption. Tensile strength decreased roughly with thickness loss, and epoxy matrices apparently became slightly embrittled, probably as a result of continued curing under UV and/or electron bombardment. However, changes in the ultimate yield stress of the carbon reinforced epoxy composites correlate neither with weave direction nor fiber type. Unexpected developments were the discovery of new synergistic effects of the space environment in the interaction of atomic oxygen and copious amounts of contamination and in the induced luminescence of many materials.
Source record↗
Method and Apparatus for Polaradiometric Pyrometer
A radiation pyrometer for measuring the true temperature of a body is provided by detecting and measuring thermal radiation from the body based on the principle that the effects of angular emission I(sub 1) and reflection I(sub 2) on the polarization states p and s of radiation are complementary such that upon detecting the combined partial polarization state components I(sub p) = I(sub 1p) + I(sub 2p) and I(sub s) = I(sub 1s) + I(sub 2s) and adjusting the intensity of the variable radiation source of the reflected radiation I(sub 2) until the combined partial radiation components I(sub p) and I(sub s) are equal, the effects of emissivity as well as diffusivity of the surface of the body are eliminated, thus obviating the need for any post processing of brightness temperature data.
Abtahi, Ali A.↗