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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Combining TOPEX and SeaWinds Data to Refine Models for Ocean Surface Emissivity: Wind Vector Signatures at 18, 21 and 37 GHz

TOPEX Microwave Radiometer (TMR) brightness temperature observations at 18, 21, and 37 GHz have been collocated with near-simultaneous SeaWinds wind vector data as well as with a monthly SST climatological product. The combined data set allows us to study the dependence of ocean surface emissivity (at each frequency) upon both wind speed. Results show clear two-branch wind speed dependence; weak and linear below 6 m/s with an abrupt increase in sensitivity above that point. The analysis also shows that the zenith-directed ocean surface emissivity is polarization dependent above wind speeds of 5-6 m/s with an azimuthal variation related to the wind direction. This last result accords with recent polarimetric radiometer observations collected from aircraft. Implications of these observations to water vapor retrieval algorithms, nadir-viewing polarimetry, and ocean emission modeling will be discussed.

Vandemark, D.↗
NASA NTRS1994

Velocity surface measurements for ZnO films over /001/-cut GaAs

A potential application for a piezoelectic film deposited on a GaAs substrate is the monolithic integration of surface acoustic wave (SAW) devices with GaAs electronics. Knowledge of the SAW properties of the filmed structure is critical for the optimum design of such devices. In this article, the measurements of the velocity surface, which directly affects the SAW diffraction, on the bare and metallized ZnO/SiO2 or Si3N4/GaAs /001/-cut samples are reported using two different techniques: (1) knife-edge laser probe, (2) line-focus-beam scanning acoustic microscope. Comparisons, such as measurement accuracy and tradeoffs, between the former (dry) and the latter (wet) method are given. It is found that near the group of zone axes (110) propagation direction the autocollimating SAW property of the bare GaAs changes into a noncollimating one for the layered structure, but a reversed phenomenon exists near the group of zone axes (100) direction. The passivation layer of SiO2 or Si3N4 (less than 0.2 micrometer thick) and the metallization layer change the relative velocity but do not significantly affect the velocity surface. On the other hand, the passivation layer reduces the propagation loss by 0.5-1.3 dB/microseconds at 240 MHz depending upon the ZnO film thickness. Our SAW propagation measurements agree well with theorectical calculations. We have also obtained the anisotropy factors for samples with ZnO films of 1.6, 2.8, and 4.0 micrometer thickness. Comparisons concerning the piezoelectric coupling and acoustic loss between dc triode and rf magnetron sputtered ZnO films are provided.

Kim, Yoonkee↗
NASA NTRS2000

A Comparison of GPS and Scatterometer Sensing of Ocean Wind Speed and Direction

Initial estimates of ocean surface wind speed and direction based on observations of reflected Global Positioning System (GPS) signals are presented and compared to QuikSCAT wind fields. The two wind speed estimates are generally in agreement to within 2-3 m/s, and under favorable conditions of well developed seas and stable winds, direction estimates agree to within 10 deg. An overview of the GPS technique is presented as well as a presentation and discussion of these first results.

Armatys, Michael↗
NASA NTRSDate not supplied

Parallelized Carbon Oxidation and Surface Recession Model in Direct-Simulation Monte Carlo Code, SPARTA

Ablative thermal protection system (TPS) materials for spacecraft are composites that often consist of a carbon-based reinforcement and a polymeric matrix. During Earth re-entry, they endure high-temperature oxidation and surface recession. Oxidation is an important mechanism for ablation, sometimes leading to the weakening, spallation, or failure of the oxidized fibers at the surface and in the char layer. However, more details are required including accurate material properties of the fiber microstructure, whether the fibers recede homogenously or localized at pits, and the role of pyrolysis outgassing in order to evaluate the role oxidation plays in the degradation and failure mechanisms of these materials. In this work, we demonstrate a parallelizable oxidation-driven ablation model developed for detailed, large-scale simulations in the DSMC code SPARTA. We also develop robust algorithms which handle the conservation of the surface state after an ablation step. Finally, we verify our model for both simple and more complex chemistry as well as microstructures with reaction statistics, oxidation depth calculations, and detailed visualization of oxidation-induced material recession at the microscale.

V Arias↗
NASA NTRS1991

High-resolution observations of the solar granulation

Digitally-enhanced high-resolution images from space and ground observatories have yielded data on the solar granulation which show it to be a more complex combination of phenomena than previously suspected. These new data have been used to detect large-scale horizontal flows over the solar surface through direct measurements of granule proper motions. The results thus obtained may have important implications for the heating of the solar chromosphere and corona. The observed intensity pattern on the surface of the sun is noted to be due not only to granulation, but the superposition of different types of waves as well. All such phenomena are modified in the presence of magnetic fields, becoming smaller and of reduced contrast.

Topka, K. P.↗
NASA NTRS1999

Ultraviolet Radiation on the Surface of Mars

An evaluation of the ultraviolet (UV) flux incident on the Martian surface is important for a number of issues. UV-induced photolysis of water changes the chemistry of the soil and atmosphere, inducing its oxidizing nature. Alternatively, UV may directly affect surface chemistry by generating silicate defects. UV also rapidly degrades organic material delivered by meteoritic infall. Consequently, UV affects the overall chemistry of the Martian surface and atmosphere. The extent of UV breakdown of organic molecules is also relevant to concerns regarding contaminants on lander or rover surfaces that could interfere with life-detection experiments causing "false positives". The radiation flux at a point on the surface of Mars depends on factors such as cloud cover, atmospheric dust loading, season, local time, and latitude. Previously, the UV spectrum incident on the surface of Mars has been calculated from a simple radiative transfer model. Limitations of this earlier model include no accounting for the effect of dust, which may be a perennial constituent of the atmosphere, and also the use of gas absorption data measured at room temperature that overestimate absorption for lower Martian temperatures. We present an updated model for UV radiation (200-400 nm) that incorporates dust and more recent data for the solar spectrum, gas absorption, and UV surface albedo. Additional information is contained in the original extended abstract.

Catling, D. C.↗
NASA NTRSDate not supplied

Assessment of the Sentinel-6Michael Frielich extension to the TOPEX/Jason Sea Surface Height Climate Data Record referenced to ITRF2020

The recent launch of Sentinel-6 Michael Freilichoffers the possibility of continuing global mean sea level (GMSL) monitoring well into the currentdecade. In this presentation we report Sentinel-6/Jason-3inter-mission bias estimates based on direct sea surface height (SSH) collinear differences of near coincident measurements during the verification phase, and with comparisons to a global network of tide gauges. In an effort to provide a more consistent SSH time series and seamlesstransition to Sentinel-6, we have generated orbits for the entire time span based on the revised ITRF2020terrestrial reference frame.We reportthe efficacy ofcorrection algorithm revisions leading to the development of the NASA MEaSURE’s V6.0 sea surface height Climate Data Record(MEaSUREs -Integrated Multi-Mission Ocean Altimeter Data for Climate Research (MEaSUREs-SSH) | PO.DAAC / JPL / NASA).We provide an assessment of recent improvements to the accuracy of the 30+ year sea surface height time series, describe continuing calibration/validation activities, and evaluate the subsequent impact on current global mean sea level estimates, and the accounting of the ocean mass budget.

B D Beckley↗
DOE OSTI2021

Low-temperature (< 200 °C) degradation of electronic nicotine delivery system liquids generates toxic aldehydes

Electronic cigarette usage has spiked in popularity over recent years. The enhanced prevalence has consequently resulted in new health concerns associated with the use of these devices. Degradation of the liquids used in vaping have been identified as a concern due to the presence of toxic compounds such as aldehydes in the aerosols. Typically, such thermochemical conversions are reported to occur between 300 and 400 °C. Herein, the low-temperature thermal degradation of propylene glycol and glycerol constituents of e-cigarette vapors are explored for the first time by natural abundance 13 C NMR and 1 H NMR, enabling in situ detection of intact molecules from decomposition. The results demonstrate that the degradation of electronic nicotine delivery system (ENDS) liquids is strongly reliant upon the oxygen availability, both in the presence and absence of a material surface. When oxygen is available, propylene glycol and glycerol readily decompose at temperatures between 133 and 175 °C over an extended time period. Among the generated chemical species, formic and acrylic acids are observed which can negatively affect the kidneys and lungs of those who inhale the toxin during ENDS vapor inhalation. Further, the formation of hemi- and formal acetals is noted from both glycerol and propylene glycol, signifying the generation of both formaldehyde and acetaldehyde, highly toxic compounds, which, as a biocide, can lead to numerous health ailments. The results also reveal a retardation in decomposition rate when material surfaces are prevalent with no directly observed unique surface spectator or intermediate species as well as potentially slower conversions in mixtures of the two components. The generation of toxic species in ENDS liquids at low temperatures highlights the dangers of low-temperature ENDS use.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1981

High resolution X-ray scattering measurements for Advanced X-ray Astrophysics Facility /AXAF/

The Advanced X-ray Astrophysics Facility (AXAF) is to be an orbiting X-ray observatory with high resolution imaging capabilities. Specific goals of 0.5 arcsecond resolution, and an encircled energy of 60% within a 1.0 arcsecond diameter circle at 2.5 keV have been established for AXAF. Imaging X-ray optics are primarily limited by scattering of the X-rays from the mirror surfaces. To ensure that the AXAF goals can be met, comprehensive X-ray scattering measurements are being conducted on a large number of flat samples. Sub-arcsecond resolution is achieved in these measurements through use of the MSFC 1000 ft X-ray calibration facility and a high spatial resolution X-ray detector. Flats of various materials, various coatings, and a range of rms surface roughness are being evaluated. Direct evaluation of surface microroughness is also provided by a variety of optical and non-optical means. This paper describes the scattering measurement program, the instrumentation used to obtain the measurements and preliminary results of measurements on several of the sample flats.

Zombeck, M. V.↗
NASA NTRS2008

Effect of Surface Traffic Count on Taxi Time at Dallas-Fort Worth (DFW) International Airport

As the amount of air traffic increases over the years, most airports simply do not have the means of expanding to handle the intensified traffic on the surface that will ensue. Precise surveillance equipment and automation concepts, as well as advanced surface traffic algorithms are being developed to improve airport efficiency. These surface algorithms require inputs unique to each airport to ensure maximum efficiency, and minimal taxi delay. This study analyzes surface traffic at Dallas-Fort Worth International Airport (DFW) to determine the effect of the number of aircraft on the surface and the amount of stop and go situations they experience to the amount of additional taxi time encountered. If the surface capacity of an airport is known, minimal delay can be accomplished by limiting the number of taxiing aircraft to that capacity. This concept is related to highways, where traffic flow drastically decreases as more cars occupy the road. An attempt to minimize this effect on highways is seen with the use of metering lights at freeway on-ramps. Since the surface traffic at airports is highly regulated, and aircraft are less mobile on the ground, limiting the surface count to a certain number can greatly reduce the amount of additional taxi time encountered, as well as reduce hazardous emissions. This study will also find the regions of an airport that encounter the most additional taxi time when the number of aircraft in that area is increased. This could help surface traffic algorithms avoid congesting that area, or re-route aircraft to different runways when that area reaches its capacity. The relationship between the amount of stop and go situations an aircraft encounters and their effect on the taxi time of that aircraft will also be investigated. This will help to determine the effect of holding an aircraft on the taxiway as opposed to re-routing it. The lesser of the two should be used when developing surface traffic algorithms to further minimize the delay encountered. The fields investigated in this study include taxi time, the number of aircraft on the surface, the number of stop and go situations, and the time stopped for each aircraft. Taxi time is defined as spot to runway for departures, and runway to spot for arrivals. It does not include ramp area taxi time because the ramp area is controlled differently, and surface traffic schedulers do not currently incorporate them. Taxi time is found by finding the difference between take-off time (OFF) and spot crossing time for departures, and spot crossing time and landing time (ON) for arrivals. All surface data was either found directly using the Surface Operations Data Analysis and Adaptation (SODAA), a tool to analyze the Surface Management System (SMS) generated log files, or indirectly from SODAA using Matlab to derive values from SODAA data. The number of aircraft on the surface is found by looping through the ON times, OFF times, and spot times for each aircraft during a particular day. For each departure aircraft, surface counts are taken at its spot crossing and OFF time. The average of these two is used as the surface count for that aircraft. For arrivals, surface counts are taken at its ON time and its spot crossing time. The average of these two is used.

Kistler, Matthew Stephen↗
DOE OSTI2024

Actively cooled optical substrates for high average power reflective or diffractive optic

Integrated active cooling of high-power reflective or diffractive optics uses substrates manufactured from low-expansion ceramics to flow coolant between the back surface of the substrate and chambers behind but adjacent a reflective front surface, in a direction transverse to the front surface, to thereby achieve much greater average power handling than known cooling techniques.

Power, Erik P.↗
NASA NTRSDate not supplied

Formaldehyde Column Density as an Indicator for Elevated Surface Ozone

Efforts to observe near-surface ozone directly from space are hindered by the limited sensitivity of ozone satellite retrievals to the lower troposphere. Formaldehyde (HCHO) column observations from the NASA DISCOVER-AQ campaign showed a strong relationship with surface ozone, particularly when biogenic volatile organic compounds (VOCs) were the dominant ozone precursor due to their strong temperature-driven variability. Both tropospheric ozone and HCHO are secondarily produced through the oxidation of VOCs and in regions where the main fate of RO2 is reaction with NO, thus formaldehyde and ozone are generally co-produced. This work explores the relationship between column formaldehyde and surface ozone using data from two air quality research campaigns, the Long Island Sound Tropospheric Ozone Study (LISTOS) in 2018 and the Korea U.S. - Air Quality (KORUS-AQ) campaign in 2016. These campaigns included HCHO column information from airborne in-situ profiling and remote sensing and ground-based Pandora spectrometers in combination with surface ozone monitors in each region. These data are used to further explore the HCHO-ozone relationship and its potential for identifying areas of elevated ozone using remote sensing or satellite observations of column HCHO alone. These two regions offer a valuable comparison given their different VOC mixtures and the higher NOx levels in Seoul that result in ozone titration effects. This work will also address the potential for this application with future geostationary satellite observations.

Laura Margaret Judd↗
NASA NTRS1986

Surface roughness studies for wind tunnel models used in high Reynolds number testing

This paper focuses on stylus and optical techniques for the measurement of surface roughness in wind tunnel models. The stylus instruments provide detailed information, such as surface profiles and area maps, that may then be used either to calculate statistical properties (i.e., the rms surface roughness) or to study individual surface peaks or other features. By contrast, certain optical techniques yield area-averaged statistical properties of the surface roughness directly. Two instruments that use the technique of optical angular scattering are compared. One is a research instrument that has been developed to study the basic scattering phenomena by testing the optical theories and surface models used in inverse calculations of statistical roughness parameters. The second instrument is more compact and is under development as a hand held, on-line device to be used during manufacture of wind tunnel models for the National Transonic Facility at NASA Langley Research Center. The scattering geometries for the two instruments are compared and results from these instruments and the stylus technique are shown for roughness specimens that are typical of the surface finish of wind tunnel models.

Vorburger, T. V.↗
NASA NTRS1993

Particle kinetic simulation of high altitude hypervelocity flight

In this grant period, the focus has been on enhancement and application of the direct simulation Monte Carlo (DSMC) particle method for computing hypersonic flows of re-entry vehicles. Enhancement efforts dealt with modeling gas-gas interactions for thermal non-equilibrium relaxation processes and gas-surface interactions for prediction of vehicle surface temperatures. Both are important for application to problems of engineering interest. The code was employed in a parametric study to improve future applications, and in simulations of aeropass maneuvers in support of the Magellan mission. Detailed comparisons between continuum models for internal energy relaxation and DSMC models reveals that several discrepancies exist. These include definitions of relaxation parameters and the methodologies for implementing them in DSMC codes. These issues were clarified and all differences were rectified in a paper (Appendix A) submitted to Physics of Fluids A, featuring several key figures in the DSMC community as co-authors and B. Haas as first author. This material will be presented at the Fluid Dynamics meeting of the American Physical Society on November 21, 1993. The aerodynamics of space vehicles in highly rarefied flows are very sensitive to the vehicle surface temperatures. Rather than require prescribed temperature estimates for spacecraft as is typically done in DSMC methods, a new technique was developed which couples the dynamic surface heat transfer characteristics into the DSMC flow simulation code to compute surface temperatures directly. This model, when applied to thin planar bodies such as solar panels, was described in AIAA Paper No. 93-2765 (Appendix B) and was presented at the Thermophysics Conference in July 1993. The paper has been submitted to the Journal of Thermophysics and Heat Transfer. Application of the DSMC method to problems of practical interest requires a trade off between solution accuracy and computational expense and limitations. A parametric study was performed and reported in AIAA Paper No. 93-2806 (Appendix C) which assessed the accuracy penalties associated with simulations of varying grid resolution and flow domain size. The paper was also presented at the Thermophysics Conference and will be submitted to the journal shortly. Finally, the DSMC code was employed to assess the pitch, yaw, and roll aerodynamics of the Magellan spacecraft during entry into the Venus atmosphere at off-design attitudes. This work was in support of the Magellan aerobraking maneuver of May 25-Aug. 3, 1993. Furthermore, analysis of the roll characteristics of the configuration with canted solar panels was performed in support of the proposed 'Windmill' experiment. Results were reported in AIAA Paper No. 93-3676 (Appendix D) presented at the Atmospheric Flight Mechanics Conference in August 1993, and were submitted to Journal of Spacecraft and Rockets.

Haas, Brian L.↗
DOE OSTI2025

Single-molecule reaction mapping uncovers diverse behaviours of electrocatalytic surface Pd–H intermediates

Many vital electrocatalytic transformations hinge on reactive surface metal–hydrogen intermediates (M–H*), yet the low concentration and transient nature of such intermediates present formidable challenges to in-depth investigation. Here we use single-molecule super-resolution reaction imaging to directly probe surface palladium–hydrogen (Pd–H*) intermediates on individual palladium nanocubes during electrocatalytic hydrogen evolution. Our approach visualizes hydrogen spillover from palladium to the surrounding substrate surface over hundreds of nanometres away and dissects substantial inter- and intraparticle heterogeneity. Through Gaussian-broadening kinetic analysis, we reveal that ensemble-averaged measurements systematically overestimate the stability of Pd–H*. Moreover, we resolve three subpopulations of palladium nanocubes with distinct reactivity features, uncovering critical correlations between intermediate stability, hydrogenation reactivity and transition-state properties. Finally, our findings highlight the necessity of single-particle resolution for capturing the intrinsic complexity of electrocatalysts; our approach is also broadly applicable to interrogate surface-reactive intermediates across a wide array of electrocatalytic pathways.

electrocatalysis↗
NASA NTRS1982

Effects of varying soil moisture contents and vegetation canopies on microwave emissions

Results of NASA airborne passive microwave scans of bare and vegetated fields for comparison with ground truth tests are discussed and a model for atmospheric scattering of radiation by vegetation is detailed. On-board radiometers obtained data at 21, 2.8, and 1.67 cm during three passes over each of 46 fields, 28 of which were bare and the others having wheat or alfalfa. Ground-based sampling included moisture in five layers down to 15 cm in addition to soil temperature. The relationships among the brightness temperature and soil moisture, as well as the surface roughness and the vegetation canopy were examined. A model was developed for the dielectric coefficient and volume scattering for a vegetation medium. L- to C-band data were found useful for retrieving soil information directly. A surface moisture content of 5-35% yielded an emissivity of 0.9-0.7. The data agreed well with a combined multilayer radiative transfer model with simple roughness correction.

Burke, H.-H. K.↗
NASA NTRS1992

Dynamics of the Venus atmosphere

The superrotation of the Venus atmosphere is a major unanswered problem in planetary science. At cloud-top levels (65-70 km altitude) the atmosphere rotates with a five-day period, corresponding to an equatorial wind speed of 90 m/s. Angular velocity is roughly constant on spherical shells, and decreases linearly with altitude to zero at the surface. The direction of rotation is the same as that of the solid planet, which is retrograde--opposite to the direction of orbital motion, but the 5-day period is short compared to the 243-day spin period of the solid planet or to the mean solar day, which is 117 Earth-days at the surface. The problem with the superrotation is that shearing stresses tend to transfer angular momentum downward, and would slow the atmosphere until it is spinning with the solid planet. Some organized circulation pattern is counteracting the tendency, but the pattern has not been identified. A simple Hadley-type circulation cannot do it because such a circulation is zonally symmetric and Hide's Theorem states that in an axisymmetric circulation an extremum in angular momentum per unit mass M can exist only at the surface. Venus violates the last condition, having a maximum of retrograde M on the equator at 70-80 km altitude. This leaves waves and eddies to maintain the superrotation but the length scales and forcing mechanisms for these motions need to be specified. Possible forcing mechanisms associated with waves, eddies and tides are discussed.

Ingersoll, A. P.↗
NASA NTRS1991

Atomic oxygen erosion of polymer matrix composites

Results are presented on atomic oxygen erosion of circular tubes and flat plates fabricated from different epoxy matrix composites containing, boron and Kevlar fiber reinforcements. The UTIAS experiment was located at station D-12, at 90 deg to the LDEF leading edge which was yawed about approximately 8 to 10 deg relative to the velocity vector. This resulted in enhanced atomic oxygen exposure at D-12, providing a total fluence of about 4 x 10(exp 20) atoms/sq cm. Thickness loss measurements were obtained for both flat plates and cylindrical tubes. The effect of reflected atomic oxygen on erosion yield and surface morphology on back surfaces (not directly exposed to AO) are graphically demonstrated. Erosion yields are also compared with other space flight data for similar materials, and ground-based tests in the UTIAS AO simulator. The effect of angle of incidence on surface morphology, erosion profiles and thickness losses are presented and the results correlated with simulator tests as well.

Tennyson, R. C.↗