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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Climatic consequences of very high CO2 levels in Earth's early atmosphere

Earth has approximately 60 bars of carbon dioxide tied up in carbonate rocks, or roughly 2/3 the amount of CO2 of the atmosphere of Venus. Two different lines of evidence, one based on thermodynamics and the other on geochemical cycles, indicate that a substantial fraction of thes CO2 may have resided in the atmosphere during the first few hundred million years of the Earth's history. A natural question which arises is whether this much CO2 would have resulted in a runaway greenhouse effect. One dimensional radiative/convective model calculations presented showed that the surface temperature of a hypothetical primitive atmosphere containing 20 bars of CO2 was less than 100 C; thus no runaway greenhouse effect would have occurred. The climatic stability of the early atmosphere is a consequence of three factors: reduced solar luminosity at that time, an increase in planetary albedo caused by Rayleigh scattering by CO2, and the stabilizing effects of a moist convection. The latter two factors are sufficient to prevent a CO2 induced runaway greenhouse effect on the present Earth as well, for CO2 levels up to 100 bars. Further studies are being undertaken to determine whether a runaway greenhouse effect could have occurred during the latter stages of the accretion process and, if so, whether it would have collapsed one the influx of material slowed down.

Katsing, J. F.↗
NASA NTRS1988

Documentation of the Benson Diesel Engine Simulation Program

This report documents the Benson Diesel Engine Simulation Program and explains how it can be used to predict the performance of diesel engines. The program was obtained from the Garrett Turbine Engine Company but has been extensively modified since. The program is a thermodynamic simulation of the diesel engine cycle which uses a single zone combustion model. It can be used to predict the effect of changes in engine design and operating parameters such as valve timing, speed and boost pressure. The most significan change made to this program is the addition of a more detailed heat transfer model to predict metal part temperatures. This report contains a description of the sub-models used in the Benson program, a description of the input parameters and sample program runs.

Vangerpen, Jon↗
NASA NTRS2014

Bimodal Nuclear Thermal Rocket Analysis Developments

Nuclear thermal propulsion has long been considered an enabling technology for human missions to Mars and beyond. One concept of operations for these missions utilizes the nuclear reactor to generate electrical power during coast phases, known as bimodal operation. This presentation focuses on the systems modeling and analysis efforts for a NERVA derived concept. The NERVA bimodal operation derives the thermal energy from the core tie tube elements. Recent analysis has shown potential temperature distributions in the tie tube elements that may limit the thermodynamic efficiency of the closed Brayton cycle used to generate electricity with the current design. The results of this analysis are discussed as well as the potential implications to a bimodal NERVA type reactor.

Nuclear rocket engines↗
NASA NTRS2005

Development of a Stirling System Dynamic Model With Enhanced Thermodynamics

The Stirling Convertor System Dynamic Model developed at NASA Glenn Research Center is a software model developed from first principles that includes the mechanical and mounting dynamics, the thermodynamics, the linear alternator, and the controller of a free-piston Stirling power convertor, along with the end user load. As such it represents the first detailed modeling tool for fully integrated Stirling convertor-based power systems. The thermodynamics of the model were originally a form of the isothermal Stirling cycle. In some situations it may be desirable to improve the accuracy of the Stirling cycle portion of the model. An option under consideration is to enhance the SDM thermodynamics by coupling the model with Gedeon Associates Sage simulation code. The result will be a model that gives a more accurate prediction of the performance and dynamics of the free-piston Stirling convertor. A method of integrating the Sage simulation code with the System Dynamic Model is described. Results of SDM and Sage simulation are compared to test data. Model parameter estimation and model validation are discussed.

Regan, Timothy F.↗
DOE OSTI2023

Revisiting the pseudo-supercritical path method: An improved formulation for the alchemical calculation of solid–liquid coexistence

Alchemical free energy calculations via molecular dynamics have been applied to obtain thermodynamic properties related to solid–liquid equilibrium conditions, such as melting points. In recent years, the pseudo-supercritical path (PSCP) method has proved to be an important approach to melting point prediction due to its flexibility and applicability. In the present work, we propose improvements to the PSCP alchemical cycle to make it more compact and efficient through a concerted evaluation of different potential energies. The multistate Bennett acceptance ratio (MBAR) estimator was applied at all stages of the new cycle to provide greater accuracy and uniformity, which is essential concerning uncertainty calculations. In particular, for the multistate expansion stage from solid to liquid, we employed the MBAR estimator with a reduced energy function that allows affine transformations of coordinates. Free energy and mean derivative profiles were calculated at different cycle stages for argon, triazole, propenal, and the ionic liquid 1-ethyl-3-methyl-imidazolium hexafluorophosphate. Comparisons showed a better performance of the proposed method than the original PSCP cycle for systems with higher complexity, especially the ionic liquid. Furthermore, a detailed study of the expansion stage revealed that remapping the centers of mass of the molecules or ions is preferable to remapping the coordinates of each atom, yielding better overlap between adjacent states and improving the accuracy of the methodology.

25 ENERGY STORAGE↗
DOE OSTI2024

Factors that Impact the Redox Kinetics Associated with Sr1-xAxFeO3 (A = Ca, Ba) in Air Separations Technologies

Perovskite oxides, including SrFeO3-δ, have garnered significant interest for their impressive oxygen storage thermodynamics and kinetics. While traditional oxygen production is performed through cryogenic separation methods at the industrial scale, oxygen carrier-based separations have offered an attractive alternative at the modular scale. Perovskites are considered ideal oxygen carriers, with their structural flexibility minimizing both the thermodynamic barrier and the structural strain related to the oxygen uptake/release cycle. Our latest work has identified a few major factors that directly impact the oxygen release thermodynamics and kinetics for Sr1-xAxFeO3-δ (A = Ca, Ba) materials including elemental composition, crystallographic symmetry, surface area, and pretreatment conditions. This presentation will discuss these factors using Sr1¬-xCaxFeO3 and Ba1-xSrxFeO3 to illustrate their individual and collective impacts on the design of high-performance oxygen carriers when operating at 300-700 °C. Additionally, we will discuss how each of these factors can be leveraged for the numerous catalytic applications also dependent on the redox properties of mixed metal oxides.

Popczun, Eric↗
DOE OSTI2020

Design screening and analysis of gas-fired ammonia-based chemisorption heat pumps for space heating in cold climate

Thermally-driven ammonia-based chemisorption heat pumps (CSHP) have the potential to provide high-efficiency space heating in cold climates. Using the reversible chemical bond between sorbent salt and ammonia, CSHP thermochemically pumps heat from the cold ambient to the end-uses of space heating at 50 °C. The heating coefficient of performance (COP) of a CSHP largely depends on the selection of the sorbent salts, cycle configuration, and the system operation. This study uses a thermodynamic model to investigate the performance of six CSHP system configurations, including four single-effect and two double-effect cycles. The feasibility and performance of 121 available NH 3 /salt reactions are studied for each configuration. The thermal COP of the cycles and the primary energy COP of the gas-fired CSHP systems are evaluated assuming 50 °C supply temperature for building space heating and the optimal system designs are identified. The highest thermal COP for single-effect and double-effect cycles under -25 °C ambient temperatures are predicted to be 1.22 and 1.57, respectively. The corresponding primary energy COPs are above 1.0 and 1.15, which are 30% higher than condensing furnaces and is sustained into the same cold temperatures.

42 ENGINEERING↗
DOE OSTI2020

Electronic and Vibrational Contributions to the Bulk Stabilities of Trivalent 3d Transition Metal Oxyhydroxides from Electronic Structure Calculations

Any understanding of the thermodynamic driving forces active in the global cycles of earth abundant metals requires attendant knowledge of the bulk mineral free energies. This can be particularly challenging for metal (oxyhydr)oxide phases which at low temperature aqueous conditions can be produced at a variety of hydration states and particle sizes. Here we present high quality density functional theory calculations of the relative bulk stabilities of a geologically important family of polymorphic trivalent metal oxyhydroxide crystal structures MOOH (M=Cr, Al, Fe). To improve understanding of their relative stabilities we permute the metal cations into the various possible canonical structure types including goethite (isostructural to diaspore and bracewillite), lepidocrocite (isosctructural to boehmite), guyaniite, and grimaldiite. Electronic, vibrational, and magnetic contributions are considered on a consistent theoretical footing using hybrid functionals and converged plane-wave bases. We find the considered bulk structures to be thermodynamically degenerate within the precision of the available theory, despite the fact that the vibrational and magnetic contributions vary substantially among the cations. A significant conclusion is that Cr3+ supports strong hydrogen bonds, low O-H stretching frequencies and facile H movement relative to the other cations.

Prange, Micah P.↗
DOE OSTI2025

Design Assessment of Brayton Cycles for Combined Heat and Power from Nuclear Power Plants

Brayton cycles (BCs) are gaining renewed interest for use in high-temperature nuclear reactors for power production. This study explores the potential of nuclear Brayton systems in industrial combined heat and power (CHP) production. After a review of the historical deployment and technical development of BC systems for nuclear and cogeneration applications several BCs in CHP configurations are assessed when applied to representative high-temperature reactor types. The analysis emphasizes process heat delivery options, electrical efficiency, and component performance for the case of a direct cycle—Helium BC in a high temperature gas reactor, and an open-air Brayton cycle with a high temperature gas reactor. The results highlight thermodynamic trade-offs in cogeneration operation, particularly in recuperated configurations, and compare BC-based CHP with conventional Rankine cycle (RC) performance. Key findings suggest Helium BCs offer viable CHP performance primarily at lower process heat temperatures, with open air cycles being less efficient. The work also demonstrates trade-off between CHP performance and power production performance with a detailed comparison to where steam RC has better performance. The work is designed to be used as a reference work when cogeneration is proposed from high temperature reactors alongside the use of BCs.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

Thermoeconomic Evaluation and Optimization of Using Different Environmentally Friendly Refrigerant Pairs for a Dual-Evaporator Cascade Refrigeration System

Applications of dual-evaporator refrigeration systems have recently gained much attention both in academia and industry due to their multiple benefits. In this study, a comprehensive thermodynamic and economic analysis is conducted to evaluate the potential of using several environmentally friendly refrigerant couples and identifies the most suitable one yielding the best economic results. To achieve this goal, a detailed parametric study is conducted, and an optimization process is performed using a particle swarm optimization (PSO) approach to minimize the unit production cost of cooling (UPCC) of the cascade refrigeration system. The results showed that among all selected 18 refrigerant pairs and for all ranges of examined operating parameters, the R170-R161 pair and R1150-R1234yf pair are identified as the best and worst pairs, respectively, from both thermodynamic and economic viewpoints. The results also confirm that R170-R161 pair has an improvement over R717-R744, used as a typical refrigerant pair of cascade refrigeration cycles. For a base case analysis, the COP of R170-R161 and R1150-R1234yf pairs is determined as 1.727 and 1.552, respectively, while their UPCC is found to be $0.395/ton-hr and $0.419/ton-hr, respectively, showing the influence of proper selection of refrigerant pairs on the cascade cycle’s performance. Overall, this study offers a useful thermodynamic and economic insight regarding the selection of proper refrigerant pairs for a dual-evaporator cascade vapor compression refrigeration system.

42 ENGINEERING↗
DOE OSTI2024

Probing the state of hydrogen in δ − AlOOH at mantle conditions with machine learning potential

Hydrous and nominally anhydrous minerals are a fundamental class of solids of enormous significance to geophysics. They are the water carriers in the deep geological water cycle and impact structural, elastic, plastic, and thermodynamic properties and phase relations in Earth's forming aggregates (rocks). They play a critical role in the geochemical and geophysical processes that shape the planet. Their complexity has prevented predictive calculations of their properties, but progress in materials simulations ushered by machine-learning potentials is transforming this state of affairs. Here, we adopt a hybrid approach that combines deep learning potentials (DPs) with the strongly constrained and appropriately normed meta-generalized gradient approximation functional to simulate a prototypical hydrous system. We illustrate the success of this approach to simulate δ − AlOOH ( δ ) , a phase capable of transporting water down to near the core-mantle boundary of the Earth ( ∼ 2900 km depth and ∼ 135 GPa ) in subducting slabs. A high-throughput sampling of phase space using molecular dynamics simulations with DPs sheds light on the hydrogen-bond behavior and proton diffusion at geophysical conditions. These simulations provide a pathway for a deeper understanding of these crucial components that shape Earth's internal state. Published by the American Physical Society 2024

Luo, Chenxing (ORCID:0000000341166851)↗
NASA NTRS1984

Energy Efficient Engine high pressure turbine component test performance report

The high pressure turbine for the General Electric Energy Efficient Engine is a two stage design of moderate loading. Results of detailed system studies led to selection of this configuration as the most appropriate in meeting the efficiency goals of the component development program. To verify the design features of the high pressure turbine, a full scale warm air turbine test rig with cooling flows simulated was run. Prior to this testing, an annular cascade test was run to select vane unguided turn for the first stage nozzle. Results of this test showed that the base configuration exceeded the lower unguided turning configuration by 0.48 percent in vane kinetic energy efficiency. The air turbine test program, consisting of extensive mapping and cooling flow variation as well as design point evaluation, demonstrated a design point efficiency level of 90.0 percent based on the thermodynamic definition. In terms of General Electric cycle definition, this efficiency was 92.5 percent. Based on this test, it is concluded that efficiency goals for the Flight Propulsion System were met.

Timko, L. P.↗
NASA NTRS2017

The Modern Near-Surface Martian Climate: A Review of In-Situ Meteorological Data from Viking to Curiosity

We analyze the complete set of in-situ meteorological data obtained from the Viking landers in the 1970s to todays Curiosity rover to review our understanding of the modern near-surface climate of Mars, with focus on the dust, CO2 and H2O cycles and their impact on the radiative and thermodynamic conditions near the surface. In particular, we provide values of the highest confidence possible for atmospheric opacity, atmospheric pressure, near-surface air temperature, ground temperature, near-surface wind speed and direction, and near-surface air relative humidity and water vapor content. Then, we study the diurnal, seasonal and interannual variability of these quantities over a span of more than twenty Martian years. Finally, we propose measurements to improve our understanding of the Martian dust and H2O cycles, and discuss the potential for liquid water formation under Mars present day conditions and its implications for future Mars missions.

Martinez, G. M.↗
NASA NTRS1991

Production and uses of liquefied atmosphere (CO2) on Mars

Carbon dioxide is universally accessible on Mars, and can be liquefied and separated from residual atmospheric gases by various compress-refrigeration cycles. Liquid CO2, stored under elevated pressures, can be used as a source of high pressure gas for nighttime power generation at a Martian base powered by solar energy during the daytime. Carbon dioxide can also be used for vehicular power. The extractable energy per unit mass of CO2 can exceed that of commercial lead-acid batteries for operating cycles without heat addition. Improved performance is possible using heat input from the ambient atmosphere or thermochemical agents. A unique vehicular application uses pressurized CO2 as a non-combustion low performance propellant for intermediate distance surface transportation. The thermodynamic properties of CO2 are presented with typical operating cycles for the application classes described above.

Waldron, R. D.↗
NASA NTRS2018

Extratropical Cyclone Precipitation Life Cycles: A Satellite-Based Analysis

Although extratropical cyclones are the most common midlatitude storms, the relationship between their precipitation life cycle and dynamical strength life cycle has not been thoroughly analyzed. Given that thermodynamic heat exchanges associated with precipitation impact cyclone circulation, there is a need to understand the precipitation/dynamics relationship. Based on Integrated MultisatellitE Retrievals for Global Precipitation MeasurementGPM precipitation and Lagrangian cyclone tracks, the precipitation maximum occurs prior to the dynamical strength maximum 70% of the time. The lag in timing is consistent with the difference in cyclone precipitable water vapor at the two peaks. Conditional subsetting of the cyclone composites shows that if the precipitable water vapor distribution is constrained to be equal throughout the composite life cycle, the precipitation peak occurs very near the time of the peak in cyclone dynamical strength. Thus, the boost in dynamical strength caused by latent heat associated with precipitation manifest itself with little to no time lag.

Extratropical cyclone↗
DOE OSTI2021

Projecting Permafrost Thaw of Sub-Arctic Tundra With a Thermodynamic Model Calibrated to Site Measurements

Northern circumpolar permafrost thaw affects global carbon cycling, as large amounts of stored soil carbon becomes accessible to microbial breakdown under a warming climate. The magnitude of carbon release is linked to the extent of permafrost thaw, which is locally variable and controlled by soil thermodynamics. Soil thermodynamic properties, such as thermal diffusivity, govern the reactivity of the soil-atmosphere thermal gradient, and are controlled by soil composition and drainage. In order to project permafrost thaw for an Alaskan tundra experimental site, we used seven years of site data to calibrate a soil thermodynamic model using a data assimilation technique. The model reproduced seasonal and interannual temperature dynamics for shallow (5–40 cm) and deep soil layers (2–4 m), and simulations of seasonal thaw depth closely matched observed data. The model was then used to project permafrost thaw at the site to the year 2100 using climate forcing data for three future climate scenarios (RCP 4.5, 6.0, and 8.5). Minimal permafrost thawing occurred until mean annual air temperatures rose above the freezing point, after which we measured over a 1 m increase in thaw depth for every 1 °C rise in mean annual air temperature. Under no projected warming scenario was permafrost remaining in the upper 3 m of soil by 2100. We demonstrated an effective data assimilation method that optimizes parameterization of a soil thermodynamic model. The sensitivity of local permafrost to climate warming illustrates the vulnerability of sub-Arctic tundra ecosystems to significant and rapid soil thawing.

54 ENVIRONMENTAL SCIENCES↗