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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Significant reduction in arc frequency biased solar cells: Observations, diagnostics, and mitigation technique(s)

A variety of experiments were performed which identify key factors contributing to the arcing of negatively biased high voltage solar cells. These efforts have led to reduction of greater than a factor of 100 in the arc frequency of a single cell following proper remediation procedures. Experiments naturally lead to and focussed on the adhesive/encapsulant that is used to bond the protective cover slip to the solar cell. An image-intensified charge coupled device (CCD) camera system recorded UV emission from arc events which occurred exclusively along the interfacial edge between the cover slip and the solar cell. Microscopic inspection of this interfacial region showed a bead of encapsulant along this entire edge. Elimination of this encapsulant bead reduced the arc frequency by two orders of magnitude. Water contamination was also identified as a key contributor which enhances arcing of the encapsulant bead along the solar cell edge. Spectrally resolved measurements of the observable UV light shows a feature assignable to OH(A-X) electronic emission, which is common for water contaminated discharges. Experiments in which the solar cell temperature was raised to 85 C showed a reduced arcing frequency, suggesting desorption of H2O. Exposing the solar cell to water vapor was shown to increase the arcing frequency. Clean dry gases such as O2, N2, and Ar show no enhancement of the arcing rate. Elimination of the exposed encapsulant eliminates any measurable sensitivity to H2O vapor.

Upschulte, B. L.↗
NASA NTRS1992

Progress in p(+)n InP solar cells fabricated by thermal diffusion

In SPRAT XI, we proposed that p(sup +)n diffused junction InP solar cells should exhibit a higher conversion efficiency than their n(sup +)p counterparts. This was mainly due to the fact that our p(sup +)n (Cd,S) cell structures consistently showed higher V (sub OC) values than our n(sup +)p (S,Cd) structures. The highest V(sub OC) obtained with the p(sup +)n (Cd,S) cell configuration was 860 mV, as compared to the highest V(sub OC) 840 mV obtained with the n(sup +)p (S,Cd) configuration (AMO, 25 C). In this work, we present the performance results of our most recent thermally diffused cells using the p(sup +)n (Cd,S) structure. We have been able to fabricate cells with V(sub OC) values approaching 880 mV. Our best cell with an unoptimized front contact grid design (GS greater than or equal to 10%) showed a conversion efficiency of 13.4% (AMO, 25 C) without an AR coating layer. The emitter surface was passivated by a -50A P rich oxide. Achievement of such high V(sub OC) values was primarily due to the fabrication of emitter surfaces, having EPD densities as low as 2E2 cm(sup -2) and N(sub a)N(sub d) of about 3E18 cm (sup -3). In addition, our preliminary investigation of p(sup +)n structures seem to suggest that Cd-doped emitter cells are more radiation resistant than Zn-doped emitter cells against both high energy electron and proton irradiation.

Faur, Mircea↗
NASA NTRS2004

Automated Rendezvous and Capture System Development and Simulation for NASA

The United States does not have an Automated Rendezvous and Capture/Docking (AR and C) capability and is reliant on manned control for rendezvous and docking of orbiting spacecraft. This reliance on the labor intensive manned interface for control of rendezvous and docking vehicles has a significant impact on the cost of the operation of the International Space Station (ISS) and precludes the use of any U.S. expendable launch capabilities for Space Station resupply. The Soviets have the capability to autonomously dock in space, but their system produces a hard docking with excessive force and contact velocity. Automated Rendezvous and Capture/Docking has been identified as a key enabling technology for the Space Launch Initiative (SLI) Program, DARPA Orbital Express and other DOD Programs. The development and implementation of an AR&C capability can significantly enhance system flexibility, improve safety, and lower the cost of maintaining, supplying, and operating the International Space Station. The Marshall Space Flight Center (MSFC) has conducted pioneering research in the development of an automated rendezvous and capture (or docking) (AR and C) system for U.S. space vehicles. This AR&C system was tested extensively using hardware-in-the-loop simulations in the Flight Robotics Laboratory, and a rendezvous sensor, the Video Guidance Sensor was developed and successfully flown on the Space Shuttle on flights STS-87 and STS-95, proving the concept of a video- based sensor. Further developments in sensor technology and vehicle and target configuration have lead to continued improvements and changes in AR&C system development and simulation. A new Advanced Video Guidance Sensor (AVGS) with target will be utilized on the Demonstration of Autonomous Rendezvous Technologies (DART) flight experiment in 2004.

Roe, Fred D.↗
NASA NTRS2010

Formation Ages of the Apollo 16 Regolith Breccias: Implications for Accessing the Bombardment History of the Moon

Regolith breccias are lithified samples of the regolith that have been fused together by impact shock and thermal metamorphism. In lunar regolith samples, the ratio of trapped 40Ar/36Ar is a useful indicator of antiquity and can be used to model the closure age/lifithication event of the regolith (i.e. the apparent time when Ar became trapped [1]), thus providing an important insight into specific times when that regolith was interacting with the the dynamic inner solar system space environment [2-4].

Joy, K. H.↗
DOE OSTI2022

Acceleration of Biexciton Radiative Recombination at Low Temperature in CdSe Nanoplatelets

Colloidal semiconductor nanocrystals offer bandgap tunability, high photoluminescence quantum yield, and colloidal processing of benefit to optoelectronics, however rapid nonradiative Auger recombination (AR) deleteriously affects device efficiencies at elevated excitation intensities. AR is understood to transition from temperature-dependent behavior in bulk semiconductors to temperature-independent behavior in zero-dimensional quantum dots (QDs) as a result of discretized band structure that facilitates satisfaction of linear momentum conservation. For nanoplatelets (NPLs), two-dimensional morphology renders prediction of photophysical behaviors challenging. Here, in this study, we investigate and compare the temperature dependence of excited-stated lifetime and fluence-dependent emission of CdSe NPLs and QDs. For NPLs, upon temperature reduction, biexciton lifetime surprisingly decreases (even becoming shorter lived than trion emission) and emission intensity increases nearly linearly with fluence rather than saturating, consistent with dominance of radiative recombination rather than AR. CdSe NPLs thus differ fundamentally from core-only QDs and foster increased utility of photogenerated excitons and multiexcitons at low temperatures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

UNESE Argon-39 Measurement Techniques: Developing an above-ground Argon-39 Measurement Capability

The Underground Nuclear Explosion Signatures Experiment (UNESE) sought to use 37 Ar as a tracer for measuring noble-gas migration in the soil surrounding historic Underground Nuclear Explosions (UNE). One unexpected observation was the presence of the much longer-lived isotope 39 Ar from historic UNEs. Quantifying the activity of 39 Ar proved difficult due to the lack of capability to measure significantly-above-background levels of 39 Ar and a general discomfort to repeatedly expose Ultra-Low-Background Proportional Counters (ULBPCs) to significant radioactivity. Because the whole-air samples collected for the 37 Ar tracer measurement were already being measured on the above-ground argon capability, it was decided to expand that capability to include 39 Ar. This document describes the efforts required to achieve quantitative reporting of the 39 Ar backgrounds measured during experiments at the sites of the historic Barnwell and Disko Elm UNEs.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS2002

Temperature Dependence of the Rate Constant for the CH3 Recombination Reaction: A Loss Process in Outer Planet Atmospheres

The methyl free radical (CH3) has been observed in the atmospheres of Saturn and Neptune by the ISO satellite. There are discrepancies between the column densities for the CH3 radical derived from the ISO observations and the column densities derived from atmospheric photochemical models. For Neptune the model column density is 1.5 times that derived from ISO. For Saturn the model is 6 times that from ISO. The recombination of methyl radicals is the major loss process for methyl in these atmospheres. The serious disagreement between observed and calculated levels of CH3 has led to suggestions that the atmospheric models greatly underestimated the loss of CH3 due to poor knowledge of the rate of the reaction (1) CH3 + CH3 + M goes to C2H6 + M at the low temperatures and pressures of these atmospheric systems. Although the reaction CH3 + CH3 + M goes to C2H6 + M has been extensively studied both theoretically and experimentally, the laboratory conditions have been, with only a few exceptions, higher temperatures (T greater than 298K), higher pressures (P greater than or equal to 10 Torr - 13.3 mbar) or M=Ar rather than H2 or He as the bath gas.

Cody, R. J.↗
DOE OSTI2024

Towards rational control of seed oil composition: dissecting cellular organization and flux control of lipid metabolism

Plant lipids represent a fascinating field of scientific study, in part due to a stark dichotomy in the limited fatty acid (FA) composition of cellular membrane lipids vs the huge diversity of FAs that can accumulate in triacylglycerols (TAGs), the main component of seed storage oils. With few exceptions, the strict chemical, structural, and biophysical roles imposed on membrane lipids since the dawn of life have constrained their FA composition to predominantly lengths of 16–18 carbons and containing 0–3 methylene-interrupted carbon-carbon double bonds in cis-configuration. However, over 450 “unusual” FA structures can be found in seed oils of different plants, and we are just beginning to understand the metabolic mechanisms required to produce and maintain this dichotomy. Here we review the current state of plant lipid research, specifically addressing the knowledge gaps in membrane and storage lipid synthesis from 3 angles: pathway fluxes including newly discovered TAG remodeling, key acyltransferase substrate selectivities, and the possible roles of “metabolons.”

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Complete replacement of Arabidopsis oil-producing enzymes with heterologous diacylglycerol acyltransferases

Acyl-CoA:diacylglycerol acyltransferase 1 (DGAT1) and phospholipid:diacylglycerol acyltransferase 1 (PDAT1) share responsibility for triacylglycerol (TAG) biosynthesis, and their selectivities control TAG fatty acid (FA) compositions. For rational metabolic engineering of seed oils, replacing endogenous TAG biosynthesis with exogenous enzymes containing different substrate FA selectivities is desirable; however, the dgat1-1/pdat1-2 double mutant is pollen lethal. Here, we evaluated the ability of 3 DGAT1s, from phylogenetically diverse plants with distinct TAG assembly processes, to completely replace endogenous TAG biosynthesis in Arabidopsis ( Arabidopsis thaliana ). We transformed dgat1-1 mutant plants with expression constructs for DGAT1 s from Camelina sativa , Physaria fendleri , and castor ( Ricinus communis ). Transgene expression was properly “contextualized” by using a previously determined minimum necessary expression unit containing the promoter/5′ UTR and first intron of native AtDGAT1 ; both of these DNA elements are essential for pollen expression. Next, we crossed homozygous lines with a DGAT1/DGAT1/PDAT1/pdat1-2 parent. C. sativa and P. fendleri DGAT1s restored the FA compositions and transcriptional differences of dgat1-1 to near wild-type and rescued the dgat1-1/pdat1-2 pollen lethality. R. communis DGAT1 was active in dgat1-1 seeds but produced unique oil profiles and alterations in the expression of lipid metabolic genes; it also failed to rescue dgat1-1/pdat1-2 lethality. This study confirms that the promoter and first intron of AtDGAT1 can modulate the expression of foreign DGAT1 genes to fit the correct spatiotemporal profile necessary for completely replacing endogenous TAG biosynthesis. Furthermore, it demonstrates an additional layer of unexpected enzyme incompatibility between oilseed lineages, which may complicate bioengineering approaches that seek to replace essential genes with orthologs.

McGuire, Sean T. [Washington State Univ., Pullman,↗
DOE OSTI2022

Impact of CH 4 addition on the electron properties and electric field dynamics in a Ar nanosecond-pulsed dielectric barrier discharge

Non-equilibrium plasmas derive their low temperature reactivity from producing and driving energetic electrons and active species under large electric fields. Therefore, the impact of reactants on the plasma properties including electron number density, electric field, and electron temperature is critical for applications such as plasma CH 4 reforming. Due to experimental complexity, electron properties and the electric field are rarely measured together in the same discharge. Here, we combine time-resolved Thomson scattering and electric field induced second harmonic generation (EFISH) to probe electron temperature, electron density, and electric field strength in a 60 Torr CH 4 /Ar nanosecond-pulsed dielectric barrier discharge (ns-DBD) while varying the CH 4 mole fraction from 0 to 8%. These measurements are compared to a 1-D numerical model to benchmark its predictions and identify areas of uncertainty. Nonlinear coupling between CH 4 addition, electron temperature, electron density, and the electric field was directly observed. Contrary to previous measurements in He, the electron temperature increased with CH 4 mole fraction. This rise in electron temperature is identified as electron heating by residual electric fields that increased with larger CH 4 mole fraction. Moreover, the electron number density has been found to decrease rapidly with the increase of methane mole fraction. Comparison of these measurements with the model yielded better agreement at higher CH 4 mole fractions and with the usage of ab initio calculated Ar electron-impact cross-sections from the B-spline R-matrix (BSR) database. Furthermore, the calculated plasma properties are shown to be sensitive to the residual surface charge implanted on the quartz dielectric surfaces. Without considering surface charge in the simulations, the calculated electric field profiles agreed well with the measurements, but the electron properties were underpredicted by more than a factor of three. Therefore, measurements of either the electric field or electron properties measurements alone are insufficient to fully validate modelling predictions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

Experimental Characterization and Modeling of High Hole Mobility GeSn Quantum Wells: The Role of Alloy Disorder Scattering

Understanding mechanisms influencing electrical transport in material systems not only provides a scientific explanation for observed behavior but also offers insight into ways to enhance transport in devices. This study reports experimental hole mobility of 8 x 10 4 cm 2 V -1 s -1 in a Ge 0.92 Sn 0.08 , the highest recorded mobility for the GeSn system. A study of the material's quality is presented using structural and electrical characterization techniques, with transport data being supported by simulations using an extensive modeling framework. Quantum Hall measurements further indicate the material's high quality and potential spintronic applications, with extracted values of 0.0689$m$ 0 and 13.6 for the effective mass and effective g‐factor, respectively. It is observed that transport is limited by alloy disorder scattering at cryogenic temperatures. A comparative study between the presented structure and similar quantum well heterostructures revealed that the difference in hole mobilities is captured by a disparity in the reduced nominal alloy disorder scattering potential (Δ U alloy = 0.8 eV), that is lower than the value of a fully random alloy (Δ U alloy = 1.4–1.7 eV) potential. The difference in Δ U alloy suggests that heterostructures with similar geometries and alloy compositions can have different alloy disorder scattering, implying that an underlying mechanism, such as short‐range order, may be responsible and warrants further investigation.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
NASA NTRS1973

Study of neutral composition of lower thermosphere at Fort Churchill.

On Feb. 4 and 6, 1969, and May 11, 1970, Aerobee rockets carrying neutral mass spectrometers were flown at Fort Churchill, Canada during conditions of low geomagnetic activity. As in earlier flights at White Sands, New Mexico, each rocket carried both 'open' and 'closed' ion source instruments. Vertical profiles of N2, O2, O, Ar, and He were measured. Results obtained were essentially the same as those observed at White Sands except that for the winter flights helium appeared to be in diffusive equilibrium.

Nier, A. O.↗
NASA NTRS1973

Vibrational deactivation of O3/101/ molecules in gas mixtures

The laser excited fluorescence method has been employed to determine rate constants for vibrational relaxation of O3(101) molecules by O3, O2, CO2, H2, D2, CH4, N2, He, and Ar collision partners at 298 K. Excitation of the O3(001) level by absorption of laser transitions on the CO2 9.5-micron band have permitted the first measurements of vibrational relaxation on O3.

Rosen, D. I.↗
NASA NTRS1978

Shock tube and shock wave research; Proceedings of the Eleventh International Symposium, University of Washington, Seattle, Wash., July 11-14, 1977

Papers are presented on the applications of shock-wave technology to the study of hydrodynamics, the use of the pressure-wave machine for charging diesel engines, and measurements of the heat-transfer rate in gas-turbine components. Consideration is given to shock propagation along 90-degree bends, the explosive dissemination of liquids, and rotational and vibrational relaxation behind weak shock waves in water vapor. Shock phenomena associated with expansion flows are described and stratospheric-related research using the shock tube is outlined. Attention is given to shock-wave ignition of magnesium powders, Mach reflection and boundary layers, and transition in the shock-induced unsteady boundary layer on a flat plate. Shock-tube measurements of induction and post-induction rates for low-Btu gas mixtures are presented and shock-initiated ignition in COS-N2O-Ar mixtures is described. Cluster growth rates in supersaturated lead vapor are presented and a study of laser-induced plasma motion in a solenoidal magnetic field is reviewed.

Ahlborn, B.↗
NASA NTRS1985

Chronology and petrogenesis of a 1.8 g lunar granitic clast:14321,1062

Geochronological, isotopic, and trace element data for a pristine granite clast from Apollo 14 breccia 14321 obtained using Rb-Sr, Sm-Nd, and (Ar-39)-(Ar-40) methods are presented. Trace element data for a possibly related evolved rock, the quartz-monodiorite clast from breccia 15404 are also presented, and the relationship between these two rock types is discussed. The concordancy of the Rb-Sr and Sm-Nd internal isochron ages and especially the Rb-Sr model age strongly suggest that the granite clast formed 4.1 AE ago. It probably crystallized slowly in the crust and was later excavated and brecciated about 3.88 AE ago, as indicated by the Ar-Ar age. A two-stage model involving crystal fractionation followed by silicate liquid immiscibility is proposed for the lunar granite genesis.

Shih, C.-Y.↗
NASA NTRS1991

Signal processing considerations for low signal to noise ratio laser Doppler and phase Doppler signals

The relative performance of current methods used for estimating the phase and the frequency in LDV and phase Doppler applications in low signal to noise ratio conditions is analyzed. These methods include the Fourier analysis and the correlation techniques. Three methods that use the correlation function for frequency and phase estimations are evaluated in terms of accuracy and speed of processing. These methods include: (1) the frequency estimation using zero crossings counting of the auto-correlation function, (2) the Blackman-Tukey method, and (3) the AutoRegressive method (AR). The relative performance of these methods is evaluated and compared with the Fourier analysis method which provides the optimum performance in terms of the Maximum Likelihood (ML) criteria.

Ibrahim, K. M.↗
NASA NTRS2001

Early Thermal History of Eucrites by Ar-39-Ar-40

Ar-39-Ar-40 ages for Piplia Kalan (3.58 +/- 0.02 Ga) and two other eucrites indicate later impact resetting. Older Ar-39-Ar-40 ages exist for the Moama cumulate eucrite (4.42 +/- 0.01 Ga) and the PCA82502 (4.506 +/- 0.009 Ga) and PCA91007 non-brecciated eucrites. Additional information is contained in the original extended abstract.

Bogard, D. D.↗
NASA NTRS2005

Lightning Mapping and the Nowcasting of Severe Storms

This paper describes a successful research and operational collaboration between NASA scientists and NWS forecasters to improve severe stor m warnings using real-time data from a regional VHF total lightning mapping array (LMA). Key objectives of our research using LMA data ar e: a) Identification of intensifying and weakening storms using the time rate-of-change of total flash rate; b) Improved severe storm poten tial situational awareness; c) Evaluation of the potential of total f lash rate trend to improve severe storm probability of detection (POD ) and lead time; and d) Validation of mesoscale model forecasts of th understorm initiation. The LMA data are distributed for ingest and di splay in the WFO AWIPS decision support system, and archived at each WFO for case studies, event playbacks, and assessments using the NWS Warning Event Simulator. The Huntsville WFO has upgraded severe thund erstorm warnings to verified tornado warnings and avoided a false ala rm on a severe storm through the added information on storm growth, intensification, and decay that can be deduced from the magnitude and temporal trend of total flash rates. We present detailed case studies of the observed relationships between lightning activity and tornadi c storm development as determined by radar reflectivity and velocity fields, and thunderstorms forecast by the Weather Research and Foreca st (WRF) model. From these collaborative studies, forecasters can eva luate the added value of total lightning data within the forecast and warning decision-making process (http://weather.msfc.nasa.gov/sport) .

Goodman, S.↗