Space technology applicable to hybrid vehicle batteries
Investigation of techniques to improve performance and service life of nickel-zinc electric batteries for application to low pollutant propulsion systems
Schwartz, H. J.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Thermal Properties of Microstrain Gauges Used for Protection of Lithium-Ion Cells of Different Designs
The purpose of this innovation is to use microstrain gauges to monitor minute changes in temperature along with material properties of the metal cans and pouches used in the construction of lithium-ion cells. The sensitivity of the microstrain gauges to extremely small changes in temperatures internal to the cells makes them a valuable asset in controlling the hazards in lithium-ion cells. The test program on lithium-ion cells included various cell configurations, including the pouch type configurations. The thermal properties of microstrain gauges have been found to contribute significantly as safety monitors in lithium-ion cells that are designed even with hard metal cases. Although the metal cans do not undergo changes in material property, even under worst-case unsafe conditions, the small changes in thermal properties observed during charge and discharge of the cell provide an observable change in resistance of the strain gauge. Under abusive or unsafe conditions, the change in the resistance is large. This large change is observed as a significant change in slope, and this can be used to prevent cells from going into a thermal runaway condition. For flexible metal cans or pouch-type lithium-ion cells, combinations of changes in material properties along with thermal changes can be used as an indication for the initiation of an unsafe condition. Lithium-ion cells have a very high energy density, no memory effect, and almost 100-percent efficiency of charge and discharge. However, due to the presence of a flammable electrolyte, along with the very high energy density and the capability of releasing oxygen from the cathode, these cells can go into a hazardous condition of venting, fire, and thermal runaway. Commercial lithium-ion cells have current and voltage monitoring devices that are used to control the charge and discharge of the batteries. Some lithium-ion cells have internal protective devices, but when used in multi-cell configurations, these protective devices either do not protect or are themselves a hazard to the cell due to their limitations. These devices do not help in cases where the cells develop high impedance that suddenly causes them to go into a thermal runaway condition. Temperature monitoring typically helps with tracking the performance of a battery. But normal thermistors or thermal sensors do not provide the accuracy needed for this and cannot track a change in internal cell temperatures until it is too late to stop a thermal runaway.
Jeevarajan, Judith↗
Use of silver oxide batteries on Explorers XVII and XXXII
Service performance and tests of zinc silver oxide batteries on Explorers 17 and 32
Hennigan, T. J.↗
Lithium Ion Batteries for Mars Exploration Missions
The desired performance characteristics and physical requirements of spacecraft batteries for planetary exploration are reviewed, particularly with respect to surface landers and rovers intended for near-future Mars missions.
rechargeable↗
Lightweight bipolar storage battery
An apparatus [10] is disclosed for a lightweight bipolar battery of the end-plate cell stack design. Current flow through a bipolar cell stack [12] is collected by a pair of copper end-plates [16a,16b] and transferred edgewise out of the battery by a pair of lightweight, low resistance copper terminals [28a,28b]. The copper terminals parallel the surface of a corresponding copper end-plate [16a,16b] to maximize battery throughput. The bipolar cell stack [12], copper end-plates [16a,16b] and copper terminals [28a,28b] are rigidly sandwiched between a pair of nonconductive rigid end-plates [20] having a lightweight fiber honeycomb core which eliminates distortion of individual plates within the bipolar cell stack due to internal pressures. Insulating foam [30] is injected into the fiber honeycomb core to reduce heat transfer into and out of the bipolar cell stack and to maintain uniform cell performance. A sealed battery enclosure [ 22] exposes a pair of terminal ends [26a,26b] for connection with an external circuit.
Rowlette, John J.↗
An Update of the Ground Testing of the Li-ion Batteries in Support of JPL's 2003 Mars Exploration Rover Mission
In early 2004, JPL successfully landed two Rovers, named Spirit and Opportunity, on the surface of Mars after traveling > 300 million miles over a 6-7 month period. In order to operate for extended duration (>9 months), both Rovers are equipped with rechargeable Lithium-ion batteries, which have enabled operation for over 854 and 834 Sols of operation, respectively, to date. Given that the batteries were required to support the mission for 90 Sols of operation by design, it is significant that the batteries have demonstrated over a nine fold increase in life over mission objectives. In addition to supporting the surface operations in conjunction with a triple-junction deployable solar arrays, the batteries were designed to aid in the launch and the EDL pyros, and allow for anomalies during cruise. In summary, the requirements of the Lithium-ion battery include the ability to provide power at least 90 sols on the surface of Mars, operate over a wide temperature range (-20 C to +30 C), withstand long storage periods (e.g., cruise period), operate in an inverted orientation, and support high current pulses (e.g., firing pyro events). In order to determine the viability of meeting these requirements, ground testing was performed on a Rover Battery Assembly Unit (RBAU), consisting of two 8-cell 10 Ah lithium-ion batteries connected in parallel. The RBAU upon which the performance testing was performed is nearly identical to the batteries incorporated into the two Rovers currently on Mars. The testing includes, (a) performing initial characterization tests (discharge capacity at different temperatures), (b) simulating the launch conditions, (c) simulating the cruise phase conditions (including trajectory correction maneuvers), (d) simulating the entry, decent, and landing (EDL) pulse load profile (required to support the pyros) (e) simulating the Mars surface operation mission simulation conditions, as well as, (f) assessing capacity loss and impedance characteristics as a function of temperature and life. This paper provides further detail to previously reported results1 of the RBAU testing program, especially with regard to the life characteristics. To date, the lithium-ion batteries (fabricated by Lithion/Yardney, Inc.) have been demonstrated to far exceed the requirements defined by the mission, both on Mars and on the ground, and are projected to support an extended mission (> 4 years).
Mars Exploration Rovers (MER) Mission↗
Development and testing of a high cycle life 30 A-h sealed AgO-Zn battery
A two-phase program was initiated to investigate design parameters and technology to develop an improved AgO-Zn battery. The basic performance goal was 100 charge/discharge cycles (22 h/2 h) at 50 percent depth of discharge following a six-month period of charged stand at room temperature. Phase 1, cell evaluation, involved testing 70 cells in five-cell groups. The major design variables were active material ratios, electrolyte concentrations, separator systems, and negative plate shape. Phase 1 testing showed that cycle life could be improved 10 percent to 20 percent by using greater ratios of zinc to silver oxide and higher electrolyte concentrations. Wedge-shaped negatives increased cycle life by nearly 100 percent. Phase 2 battery evaluation, which was initiated before the Phase 1 results were known completely, involved evaluation of six designs as 19-cell batteries. Only one battery exceeded 100 cycles following nine months charged stand.
Bogner, R. S.↗
Safe, High Power/Voltage Battery Module Design Challenges
NASA seeks to demonstrate a path for achieving safe, high power, and high performing Li-ion battery designs for the purpose of establishing design guidelines for our aeronautic and spacecraft applications. Safe means passively resistant to thermal runaway propagation of any single cell catastrophic thermal runaway. High power means capable of 3C continuous discharge without overheating. High performing means achieving > 160 Wh/kg, 200 Wh/L. The biggest challenge has been balancing a high flux light weight path for cell heat dissipation during the high rate discharge that minimizes thermal gradients between cells and also protects adjacent cells from the heat load of thermal runaway cell. Our solution includes an oscillating heat pipe spine that contacts every 18650 cell in the pack and careful cell design selection to maximize the range of initial temperatures conditions where the battery can safely complete the 3C discharge.
Thermal runaway↗
Parametric Study of State-of-Charge for an Electric Aircraft in Urban Air Mobility
The envisioned concept of urban air mobility is anticipated to support passenger transportation, cargo delivery, and emergency services in major metropolitan areas with increasing autonomy levels in the future. Distributed electric propulsion powered electric vertical takeoff and landing aircraft are expected to enable urban air mobility. However, the low specific energy of onboard lithium-ion polymer batteries and wind conditions impose constraints on flight endurance. Therefore, to enable autonomous urban air mobility operations using electric aircraft, one of the critical steps from a safety and efficiency perspective is to understand how various operational and environmental conditions impact the state-of-charge of the onboard lithium-ion polymer batteries. This research performs a parametric study of the state-of-charge for a NASA-proposed conceptual multirotor aircraft flight in the urban environment. The parameters considered for the parametric analysis are cruise airspeed, cruise altitude, climb and descent profiles, wind conditions (wind magnitude, wind direction relative to the route, and wind magnitude uncertainty), and required time of arrival.
Urban Air Mobility↗
Parametric Study of State of Charge for an Electric Aircraft in Urban Air Mobility
The envisioned concept of urban air mobility is anticipated to support passenger transportation, cargo delivery, and emergency services in major metropolitan areas with increasing autonomy levels in the future. Distributed electric propulsion powered electric vertical takeoff and landing aircraft are expected to enable urban air mobility. However, the low specific energy of onboard lithium-ion polymer batteries and wind conditions impose constraints on flight endurance. Therefore, to enable autonomous urban air mobility operations using electric aircraft, one of the critical steps from a safety and efficiency perspective is to understand how various operational and environmental conditions impact the state-of-charge of the onboard lithium-ion polymer batteries. This research performs a parametric study of the state-of-charge for a NASA-proposed conceptual multirotor aircraft flight in the urban environment. The parameters considered for the parametric analysis are cruise airspeed, cruise altitude, climb and descent profiles, wind conditions (wind magnitude, wind direction relative to the route, and wind magnitude uncertainty), and required time of arrival.
Urban Air Mobility↗
An averaging battery model for a lead-acid battery operating in an electric car
A battery model is developed based on time averaging the current or power, and is shown to be an effective means of predicting the performance of a lead acid battery. The effectiveness of this battery model was tested on battery discharge profiles expected during the operation of an electric vehicle following the various SAE J227a driving schedules. The averaging model predicts the performance of a battery that is periodically charged (regenerated) if the regeneration energy is assumed to be converted to retrievable electrochemical energy on a one-to-one basis.
Bozek, J. M.↗
Evaluation of the use of on-board spacecraft energy storage for electric propulsion missions
On-board spacecraft energy storage represents an under utilized resource for some types of missions that also benefit from using relatively high specific impulse capability of electric propulsion. This resource can provide an appreciable fraction of the power required for operating the electric propulsion subsystem in some missions. The most probable mission requirement for utilization of this energy is that of geostationary satellites which have secondary batteries for operating at high power levels during eclipse. The study summarized in this report selected four examples of missions that could benefit from use of electric propulsion and on-board energy storage. Engineering analyses were performed to evaluate the mass saved and economic benefit expected when electric propulsion and on-board batteries perform some propulsion maneuvers that would conventionally be provided by chemical propulsion. For a given payload mass in geosynchronous orbit, use of electric propulsion in this manner typically provides a 10% reduction in spacecraft mass.
Poeschel, R. L.↗
Development of high energy density primary batteries Topical report
Development of high energy density primary batteries - construction and performance tests of experimental copper fluoride-lithium cells using methyl formate electrolyte system
Abens, S. G.↗
An ataxia test battery not requiring rails.
Quantitative postural equilibrium ataxia test battery without rails performed on normal and labyrinthine defective subjects
Fregly, A. R.↗
A battery simulator
Simulator verifies proper operation of a battery cell voltage-monitoring device. It also contains variable ac voltage to ascertain that a battery scanner will perform its function at all possible ac voltages.
Ferrell, S., Jr.↗
General Electric 20-ampere hour nickel-cadmium battery
The interaction, effect, and controllability of the performance parameters of the General Electric 20-ampere-hour, 24-cell nickel cadmium battery are investigated. The battery was cycled under simulated orbit conditions. The acquired data was analyzed and evaluated in terms of battery parameters and performance characteristics. Conclusions and tests results are presented along with recommendations for further study.
Kirsch, W. W.↗
LST power system long life design techniques
The LST mission of up to 15 years plus about two years allotment for ground return maintenance could stretch the LST operation to the end of the century. This extended mission life, combined with the large power requirements of the telescope and the scientific instruments, imposes stringent requirements on the electrical power subsystem. The use of an onboard microprocessor for individual battery cell control and monitoring offers a technique that could improve the battery cycle life dramatically. The battery configuration includes spare battery cells which can be switched by the microprocessor to replace failed cells. The microprocessor can also be used for inflight reconditioning of the batteries to increase performance and verify ampere-hour capacity. The Flexible Roll-Up Solar Array (FRUSA) system offers a solar array at an acceptable cost that can stay within weight and volume constraints.
Smith, O. B.↗
Evaluation program for secondary spacecraft cells: Cycle life test
The service life and storage stability for several storage batteries were determined. The batteries included silver-zinc batteries, nickel-cadmium batteries, and silver-cadmium batteries. The cell performance characteristics and limitations are to be used by spacecraft power systems planners and designers. A statistical analysis of the life cycle prediction and cause of failure versus test conditions is presented.
Harkness, J. D.↗