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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Polaron Delocalization and Transport in Doped Graphene Nanoribbon Thin Films

Graphene nanoribbons (GNRs) are quantum-confined π-conjugated monolayer semiconductors with attractive properties for optoelectronic applications. However, the ground- and excited-state properties of charge carriers in GNRs are still poorly understood, particularly with regards to the coupling between charges and the GNR lattice and the degree to which this coupling impacts local and macroscopic charge transport. To address this issue, we systematically correlate carrier density-dependent charge transport with spectroscopic modulations in chemically doped thin films of armchair graphene nanoribbons (9-aGNRs). This study combines Fourier transform infrared (FTIR) and ultraviolet−visible−near-infrared (UV−vis−NIR) spectroscopy with both local and macroscopic conductivity measurements to arrive at a full and self-consistent picture of transport in doped GNR thin films. Using three different molecular p-type dopants (i.e., oxidants), we demonstrate that hole polarons are the dominant quasi-particle determining charge transport in GNRs and that the degree of polaron delocalization depends sensitively on the dopant and the hole density. For all three dopants, the local conductivity probed by microwave spectroscopy substantially exceeds the long-range conductivity obtained by four-point probe measurements. Interestingly, the dopant size substantially influences charge transport at high hole densities. We ascribe this effect to different propensities for forming bipolarons with lower mobilities than polarons. Comparison of GNR transport and spectral properties to other prototypical π-conjugated semiconductors (e.g., semiconducting polymers or carbon nanotubes) benchmark the charge transport properties of GNR thin films for optoelectronic devices and applications.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2026

Characterization of Electronic Stress-Induced Changes in Multilayer MoS 2

Transition metal dichalcogenides like molybdenum disulfide (MoS 2 ) are compelling for next-generation electronic devices. In this work, we investigate the impact of electronic stress on MoS 2 to illustrate that observational and phenomenological information on multiple devices can be useful to describe changes in the device, and caution against the rationalization of paltry results as representative or correlative to device behavior. Here, we stress MoS 2 by applying a sustained 20 V DC bias to study the material’s response. Post-stress electronic characterization revealed nonuniform shifts in current–voltage (I–V) behavior alongside microscale changes. Complementary mechanical, spectroscopic, and scanning microwave impedance measurements showed that stress-induced features locally modulate stiffness, surface potential, Raman intensity, and charge carrier density. We correlated I–V behavior with morphological features (wrinkles, tears, folds, height) and device-level geometry (MoS 2 overlap with electrodes, channel area, contact length) on 50 test structures across five chips to move beyond anecdotal conclusions. We found no universal correlations before DC stress. However, device-level geometry was correlated with I–V behavior after DC stress, suggesting that electrode contacts play a more dominant role than morphology in determining performance. Delamination and thinning induced by DC stress led to localized reductions in charge carrier density within the affected regions. Further, delamination and thinning appear to map to I–V device performance in a few samples, but the correlation is lost when a larger sample size is considered. This suggests significant sample-to-sample variability in surface electronic states of the test structures. We also discuss how environmental factors introduced during fabrication may contribute to the observed heterogeneous device response. Progress will require high-resolution, multimodal analysis across many samples constructed under controlled, clean conditions. By building data sets that capture variability, we can better identify the true drivers of performance.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Nanoarchitectonic Semiconductor–Bio Hybrid Systems with Enhanced Charge Transfer for Hydrogen Peroxide Production

Nanoarchitectonics offers a systematic approach to creating an artificial framework by integrating different multiscale components such as semiconductor lattices and biological substances. However, most nanoarchitectonic abiotic-biotic hybrid systems have intrinsic limitations in imparting nonequilibrium biological features into semiconductor lattices at the nanoscale. Here, in this study, we report a new nanoarchitectonic system integrating bismuth oxychloride (BiOCl) nanosheets with purple membrane (PM) patches. PM is an archaeal subcellular fraction capable of unidirectionally transferring photogenerated charge carriers to its surroundings at the nanoscale independent of archaeal metabolism and retaining this dynamic functionality after isolation from living archaea. Microscopy, spectroscopy, electrochemical, and synchrotron X-ray scattering analyses verify that the nanoarchitectonic hybridization between BiOCl and PM generates a vertical heterostructure, thereby enhancing photogenerated charge-carrier dynamics and enabling the associated photocatalytic capacity. The resulting PM-BiOCl hybrid nanosheets efficiently convert dioxygen into hydrogen peroxide through a two-electron and two-proton transfer process under ambient conditions while simultaneously converting ethylene glycol into value-added chemicals. This study presents a nanoarchitectonic approach that leverages the photogenerated charge-carrier dynamics of the archaeal subcellular fractions to modulate the optoelectronic and catalytic capacity limitations of semiconductors.

catalysis↗
NASA NTRS1977

A linear phase demodulator

Circuit operates on feedback principle to reduce modulation index of received signal, and thus reinserts carrier component in suppressed carrier signal. Device can demodulate phase-shift-keyed signals which do not have carrier component, and it has linear region of + or - 150 deg.

Rippy, R. R.↗
NASA NTRS1993

A three channel telemetry system

A three channel telemetry system intended for biomedical applications is described. The transmitter is implemented in a single chip using a 2 micron BiCMOS processes. The operation of the system and the test results from the latest chip are discussed. One channel is always dedicated to temperature measurement while the other two channels are generic. The generic channels carry information from transducers that are interfaced to the system through on-chip general purpose operational amplifiers. The generic channels have different bandwidths: one from dc to 250 Hz and the other from dc to 1300 Hz. Each generic channel modulates a current controlled oscillator to produce a frequency modulated signal. The two frequency modulated signals are summed and used to amplitude modulate the temperature signal which acts as a carrier. A near-field inductive link telemeters the combined signals over a short distance. The chip operates on a supply voltage anywhere from 2.5 to 3.6 Volts and draws less than 1 mA when transmitting a signal. The chip can be incorporated into ingestible, implantable and other configurations. The device can free the patient from tethered data collection systems and reduces the possibility of infection from subcutaneous leads. Data telemetry can increase patient comfort leading to a greater acceptance of monitoring.

Lesho, Jeffery C.↗
NASA NTRS1993

Telemetering and telecommunications research

The New Mexico State University (NMSU) Center for Space Telemetering and Telecommunications systems is engaged in advanced communications systems research. Four areas of study that are being sponsored concern investigations into the use of trellis-coded modulation (TCM). In particular, two areas concentrate on carrier synchronization research in TCM M-ary phase shift key (MPSK) systems. A third research topic is the study of interference effects on TCM, while the fourth research area is in the field of concatenated TCM systems.

Osborne, William↗
NASA NTRS2000

New Schemes for Improved Opto-Electronic Oscillator

The opto-Electronic Oscillator (OEO) has already demonstrated superior spectral purity as a for microwave and millimeter wave reference signals. Experimental results have produced a performance characterized by noise as low as -50 dBc/Hz at 10 Hz and -140 dBc/Hz for a 10 GHz oscillator. This performance is significant because it was produced by an oscillator that was free running. Since the noise in an OEO is independent of the oscillation frequency, the same performance may also be obtained at higher frequency. The recent work in our laboratory has been focused in three areas: 1) realization of a compact OEO based on semiconductor lasers and modulators, 2) reduction of the close-to-carrier noise of the OEO originating from the 1/f noise of the amplifier, and 3) miniaturization of the OEO. In this paper we report on progress made in these areas, and describe future plans to increase the performance and the efficiency of the OEO.

Maleki, Lute↗
NASA NTRS2004

Characteristics of Electromagnetic Pulse Propagation in Metal

It is well known that the solution of the diffusion equation for an electromagnetic field with a time harmonic term, e(sup iwt), is in the form of a traveling wave whose amplitude attenuates over distance into a conducting medium. As the attenuation is an increasing function of frequency, the high frequency components attenuate more rapidly than those of low ones upon entering a well conducting object. At the same time, the phase velocity of an individual component is also an increasing function of frequency causing a broadening of the pulse traveling inside a conductor. In the results of our previous study of numerical simulations, the problem of using a gaussian input pulse was immediately clear. First, having the dominant frequency components distributed around zero, the movement of the peak was not well defined. Second, with the amplitude of fourier components varying slowly over a wide range, the dispersion-induced blurring of the peak position was seen to be severe. For the present study, we have used a gaussian modulated single frequency sinusoidal wave, i. e., the carrier, as an input pulse in an effort to improve the issues related to the unclear movement of peak and dispersion as described above. This was based on the following two anticipated advantages: First, the packet moves in a conductor at the group velocity calculated at the carrier frequency, which means it is well controllable. Second, the amplitude of frequency components other than that of the carrier can be almost negligible, such that the effect of dispersion can be significantly reduced. A series of experiments of transmitting electromagnetic pulses through aluminum plates of various thickness was performed to test the validity of the above points. The results of numerical simulation based on wave propagation are discussed with respect to the experimental results. Finally, a simple simulation was performed based on diffusion of a continuous sine wave input and the results are compared with those of a single frequency sinusoidal wave observed over time at difference locations inside a conductor.

Namkung, M.↗
NASA NTRS2004

High Electron Mobility Transistor Structures on Sapphire Substrates Using CMOS Compatible Processing Techniques

System-on-a-chip (SOC) processes are under intense development for high-speed, high frequency transceiver circuitry. As frequencies, data rates, and circuit complexity increases, the need for substrates that enable high-speed analog operation, low-power digital circuitry, and excellent isolation between devices becomes increasingly critical. SiGe/Si modulation doped field effect transistors (MODFETs) with high carrier mobilities are currently under development to meet the active RF device needs. However, as the substrate normally used is Si, the low-to-modest substrate resistivity causes large losses in the passive elements required for a complete high frequency circuit. These losses are projected to become increasingly troublesome as device frequencies progress to the Ku-band (12 - 18 GHz) and beyond. Sapphire is an excellent substrate for high frequency SOC designs because it supports excellent both active and passive RF device performance, as well as low-power digital operations. We are developing high electron mobility SiGe/Si transistor structures on r-plane sapphire, using either in-situ grown n-MODFET structures or ion-implanted high electron mobility transistor (HEMT) structures. Advantages of the MODFET structures include high electron mobilities at all temperatures (relative to ion-implanted HEMT structures), with mobility continuously improving to cryogenic temperatures. We have measured electron mobilities over 1,200 and 13,000 sq cm/V-sec at room temperature and 0.25 K, respectively in MODFET structures. The electron carrier densities were 1.6 and 1.33 x 10(exp 12)/sq cm at room and liquid helium temperature, respectively, denoting excellent carrier confinement. Using this technique, we have observed electron mobilities as high as 900 sq cm/V-sec at room temperature at a carrier density of 1.3 x 10(exp 12)/sq cm. The temperature dependence of mobility for both the MODFET and HEMT structures provides insights into the mechanisms that allow for enhanced electron mobility as well as the processes that limit mobility, and will be presented.

Mueller, Carl↗
NASA NTRS1989

Unsymmetrical QPSK demodulator

The present invention is a demodulator for demodulating an unsymmetrical QPSK signal (1), i.e., one in which the amplitudes of the I and Q channels are different, and the I and Q channels have been modulated by signals having differnt bit rates. Analog versions of the I and Q modulating baseband signals are first extracted from the carrier. Each baseband signal is then subjected to a bit-rate-matched low pass filter (23, 13). The channel having the higher bit rate is subjected to a delay (32) to time-align the two baseband signals. The time-aligned filtered signals are then amplified by amplifiers (22, 12) having unequal gains that are preselected to substantially equalize the amplifier (22, 12) outputs. The amplified time-aligned filtered signals are then subjected to a phase error (E) generating means (15, 25, 16, 26, 34). The phase error (E) is passed through a loop integrator (38) and a VCO (30) and back to the baseband signal extracting means to complete a phase lock loop. Frequency searching means (40), frequency lock detect means (42, 44), and AGC control ( 46, 8) are optionally present.

Guyer, Edward↗
NASA NTRS2024

Investigation into the Origin of the RF Phase Noise for the LISA Laser Transmitter

The Laser Interferometer Space Antenna (LISA) mission is a collaborative consortium led by the European Space Agency (ESA)in cooperation with the National Aeronautics and Space Administration (NASA). LISA’s goal is to capture gravitational wave events, such as spacetime distortions caused by massive orbiting bodies. Multiple low noise, single frequency master oscillator power amplifier (MOPA) lasers with a polarization-maintaining Yb-fiber amplifier will serve as the light sources for the LISA observatory. The NASA Goddard Space Flight Center (GSFC)is currently developing the laser transmitters for this project. The LISA lasers will carry radio frequency (RF)sidebands for exchanging reference RF clock information between spacecrafts. Excess phase noise, especially carrier-sideband differential phase noise added to the modulation side band by the phase modulator and the fiber amplifier, becomes a concern. In the gravitational wave frequency ranges, leading sources of this RF “differential” phase noise can be both intrinsic and extrinsic. Examples of intrinsic sources include thermal load on the active fiber, thermo-mechanical induced birefringence, and nonlinearities in the various passive and active fibers. Extrinsic sources can include external temperature fluctuations and infrasonic mechanical strain or vibrations. These noise spectra usually include both white and pink (1/f) thermal noise contributions. This work investigates the physical origins and impact of these sources of RF phase noise, and their characteristic spectra and management will be discussed.

Laser Interferometer Space Antenna↗
NASA NTRS1986

Observations of the Earth's magnetic field from the shuttle: Using the Spartan carrier as a magnetic survey tool

The shuttle-deployed and recovered Spartan shows promise as an inexpensive and simple support module for potential field measurements. The results of a preliminary engineering study on the applications of the Spartan carrier to magnetic measurements shows: (1) Extension of the mission duration to as long as 7 days is feasible but requires more reconfiguration of the internal systems; (2) On-board recording of Global Positioning System signals will provide position determination with an accuracy consistent with the most severe requirements; and (3) Making Spartan a magnetically clean spacecraft is straight forward but requires labor-intensive modifications to both the data and power systems. As a magnetic survey tool, Spartan would allow surveys at regularly spaced intervals and could make quick-reaction surveys at times of instability in the secular variation.

Webster, W. J., Jr.↗
NASA NTRS2005

Phase Modulator with Terahertz Optical Bandwidth Formed by Multi-Layered Dielectric Stack

An optical phase modulator includes a bandpass multilayer stack, formed by a plurality of dielectric layers, preferably of GaAs and AlAs, and having a transmission function related to the refractive index of the layers of the stack, for receiving an optical input signal to be phase modulated. A phase modulator device produces a nonmechanical change in the refractive index of each layer of the stack by, e.g., the injection of free carrier, to provide shifting of the transmission function so as to produce phase modulation of the optical input signal and to thereby produce a phase modulated output signal.

Andrew S Keys↗
NASA NTRS1998

Application of a Modified Gas Chromatograph to Analyze Space Experiment Combustion Gases on Space Shuttle Mission STS-94

A space experiment designed to study the behavior of combustion without the gravitational effects of buoyancy was launched aboard the Space Shuttle Columbia on July 1, 1997. The space experiment, designated as Combustion Module-1 (CM-1), was one of several manifested on the Microgravity Sciences Laboratory - 1 (MSL-1) mission. The launch, designated STS-94, had the Spacelab Module as the payload, in which the MSL-1 experiments were conducted by the Shuttle crewmembers. CM-1 was designed to accommodate two different combustion experiments during MSL-1. One experiment, the Structure of Flame Balls at Low Lewis-number experiment (SOFBALL), required gas chromatography analysis to verify the composition of the known, premixed gases prior to combustion, and to determine the remaining reactant and the products resulting from the combustion process in microgravity. A commercial, off-the-shelf, dual-channel micro gas chromatograph was procured and modified to interface with the CM-1 Fluids Supply Package and the CM-1 Combustion Chamber, to accommodate two different carrier gases, each flowing through its own independent column module, to withstand the launch environment of the Space Shuttle, to accept Spacelab electrical power, and to meet the Spacelab flight requirements for electromagnetic interference (EMI) and offgassing. The GC data was down linked to the Marshall Space Flight Center for near-real time analysis, and stored on-orbit for post-flight analysis. The gas chromatograph operated successfully during the entire SOFBALL experiment and collected 309 runs. Because of the constraints imposed upon the gas chromatograph by the CM-1 hardware, system and operations, it was unable to measure the gases to the required accuracy. Future improvements to the system for a re-flight of the SOFBALL experiment are expected to enable the gas chromatograph to meet all the requirements.

Coho, William K.↗
NASA NTRS2004

Improved Measurement of Dispersion in an Optical Fiber

An improved method of measuring chromatic dispersion in an optical fiber or other device affords a lower (relative to prior such methods) limit of measurable dispersion. This method is a modified version of the amplitude-modulation (AM) method, which is one of the prior methods. In comparison with the other prior methods, the AM method is less complex. However, the AM method is limited to dispersion levels . 160 ps/nm and cannot be used to measure the symbol of the dispersion. In contrast, the present modified version of the AM method can be used to measure the symbol of the symbol of the dispersion and affords a measurement range from about 2 ps/nm to several thousand ps/nm with a resolution of 0.27 ps/nm or finer. The figure schematically depicts the measurement apparatus. The source of light for the measurement is a laser, the wavelength of which is monitored by an optical spectrum analyzer. A light-component analyzer amplitude-modulates the light with a scanning radio-frequency signal. The modulated light is passed through a buffer (described below) and through the device under test (e.g., an optical fiber, the dispersion of which one seeks to measure), then back to the light-component analyzer for spectrum analysis. Dispersion in the device under test gives rise to phase shifts among the carrier and the upper and lower sideband components of the modulated signal. These phase shifts affect the modulation-frequency component of the output of a photodetector exposed to the signal that emerges from the device under test. One of the effects is that this component goes to zero periodically as the modulation frequency is varied.

Huang, Shouhua↗
NASA NTRS1993

A method of obtaining signal components of residual carrier signal with their power content and computer simulation

A novel algorithm to obtain all signal components of a residual carrier signal with any number of channels is presented. The phase modulation type may be NRZ-L or split phase (Manchester). The algorithm also provides a simple way to obtain the power contents of the signal components. Steps to recognize the signal components that influence the carrier tracking loop and the data tracking loop at the receiver are given. A computer program for numerical computation is also provided.

Kantak, Anil V.↗
NASA NTRS1972

RAM - A concept for reducing space payload costs.

The post-Apollo era in manned space flight will be dominated in the short term by development of the space shuttle as an economical transportation system for payloads to low earth orbit. Research and Applications Modules (RAM) are a related group of shuttle-launched carriers for such payloads which can be used many times over, thus effecting great savings over currently conventional methods of implementing a program of this type. In order to maximize the potential savings, development and unit costs of the RAM vehicles must be minimized. All of the mission and operating modes can be covered in an economical fashion by the use of only three basic RAM elements - a pressurized module, an unpressurized pallet, and a pressurizable free-flying unit utilized in several combinations. These have been developed as a least cost approach through the consideration of such cost/weight related drivers as available crew size, separability of costly subsystems for multiple use, easy accessibility for maintenance/refurbishment for reuse, and a maximum commonality of hardware with existing and projected space projects.

Powell, D. J.↗