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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Review of alternative fuels data bases

Based on an analysis of the interaction of fuel physical and chemical properties with combustion characteristics and indicators, a ranking of the importance of various fuel properties with respect to the combustion process was established. This ranking was used to define a suite of specific experiments whose objective is the development of an alternative fuels design data base. Combustion characteristics and indicators examined include droplet and spray formation, droplet vaporization and burning, ignition and flame stabilization, flame temperature, laminar flame speed, combustion completion, soot emissions, NOx and SOx emissions, and the fuels' thermal and oxidative stability and fouling and corrosion characteristics. Key fuel property data is found to include composition, thermochemical data, chemical kinetic rate information, and certain physical properties.

Harsha, P. T.↗

Formulations for Stronger Solid Oxide Fuel-Cell Electrolytes

Tests have shown that modification of chemical compositions can increase the strengths and fracture toughnesses of solid oxide fuel-cell (SOFC) electrolytes. Heretofore, these solid electrolytes have been made of yttria-stabilized zirconia, which is highly conductive for oxygen ions at high temperatures, as needed for operation of fuel cells. Unfortunately yttria-stabilized zirconia has a high coefficient of thermal expansion, low resistance to thermal shock, low fracture toughness, and low mechanical strength. The lack of strength and toughness are especially problematic for fabrication of thin SOFC electrolyte membranes needed for contemplated aeronautical, automotive, and stationary power-generation applications. The modifications of chemical composition that lead to increased strength and fracture toughness consist in addition of alumina to the basic yttria-stabilized zirconia formulations. Techniques for processing of yttria-stabilized zirconia/alumina composites containing as much as 30 mole percent of alumina have been developed. The composite panels fabricated by these techniques have been found to be dense and free of cracks. The only material phases detected in these composites has been cubic zirconia and a alumina: this finding signifies that no undesired chemical reactions between the constituents occurred during processing at elevated temperatures. The flexural strengths and fracture toughnesses of the various zirconia-alumina composites were measured in air at room temperature as well as at a temperature of 1,000 C (a typical SOFC operating temperature). The measurements showed that both flexural strength and fracture toughness increased with increasing alumina content at both temperatures. In addition, the modulus of elasticity and the thermal conductivity were found to increase and the density to decrease with increasing alumina content. The oxygen-ion conductivity at 1,000 C was found to be unchanged by the addition of alumina.

Bansal, Narottam P.↗

Flame characteristics of a NASA contra swirler module

Results are presented for an investigation of the structure of unconfined propane flames stabilized on a NASA contra-swirl can. General flame characterization, flame visualization by sodium chloride, temperature measurements, combustion products analysis, nitric oxide concentrations, and laser anemometer studies are considered. The results are discussed relative to sodium chloride visualization, temperature distributions, chemical composition of flames, nitric oxide distributions, and velocity distributions. It is shown that unconfined propane-air flames can be stabilized downstream of a NASA contra-swirl can under a wide range of airflow rates and fuel-air ratios. However, on increasing fuel input from the lowest at which flames can be stabilized, a compact recirculation zone-stabilized flame is formed. The effect of confinement on changes in flame shape and structure is determined.

Thompson, D.↗

Cutting Edge Technologies Presentation: An Overview of Developing Sensor Technology Directions and Possible Barriers to New Technology Implementation

The aerospace industry requires the development of a range of chemical sensor technologies for such applications as leak detection, emission monitoring, fuel leak detection, environmental monitoring, and fire detection. A range of chemical sensors are being developed based on micromachining and microfabrication technology to fabricate microsensors with minimal size, weight, and power consumption; and the use of nanomaterials and structures to develop sensors with improved stability combined with higher sensitivity, However, individual sensors are limited in the amount of information that they can provide in environments that contain multiple chemical species. Thus, sensor arrays are being developed to address detection needs in such multi-species environments. These technologies and technical approaches have direct relevance to breath monitoring for clinical applications. This presentation gives an overview of developing cutting-edge sensor technology and possible barriers to new technology implementation. This includes lessons learned from previous microsensor development, recent work in development of a breath monitoring system, and future directions in the implementation of cutting edge sensor technology.

Hunter, Gary W.↗

Current Concepts and Future Directions of CELSS

Bioregenerative life support systems for use in space were studied. Concepts of such systems include the use of higher plants and/or microalgae as sources of food, potable water and oxygen, and as sinks for carbon dioxide and metabolic wastes. Recycling of materials within the system will require processing of food organism and crew wastes using microbiological and/or physical chemical techniques. The dynamics of material flow within the system will require monitoring, control, stabilization and maintenance imposed by computers. Studies included higher plant and algal physiology, environmental responses, and control; flight experiments for testing responses of organisms to weightlessness and increased radiation levels; and development of ground based facilities for the study of recycling within a bioregenerative life support system.

Macelroy, R. D.↗

High temperature resistant polyimide from tetra ester, diamine, diester and N-arylnadimide

The invention described relates to improved polyimide resins which are noted for their high thermal and oxidative stability, high strength at elevated temperatures and which exhibit many other outstanding physical and chemical properties, especially useful in high temperature applications. The polyimides are prepared by the reaction, with application of heat of a mixture of monomers comprising: (1) a dialkyl or tetraalkyl ester of an aromatic tetracarboxylic acid, (2) and aromatic diamine, (3) a monoalkyl or dialky ester of a dicarboxylic acid, and (4) a N-arylnadimide such as N-phenylnadimide. Polyimides of monomers (1), (2) and (3) are known.

Pater, R. H.↗

Mass comparisons of electric propulsion systems for NSSK of geosynchronous spacecraft

A model was developed and exercised to allow wet mass comparisons of three axis stabilized communication satellites delivered to geosynchronous transfer orbit. The mass benefits of using advanced chemical propulsion for apogee injection and north-south stationkeeping (NSSK) functions or electric propulsion (hydrazine arcjets and xenon ion thrusters) for NSSK functions are documented. A large derated ion thrusters is proposed which minimizes thruster lifetime concerns and qualification test times when compared to those of smaller ion thrusters planned for NSSK applications. The mass benefits, which depend on the spacecraft mass and mission duration, increase dramatically with arcjet specific impulse in the 500 to 600 s range, but are nearly constant for the derated ion thruster operated in the 2300 to 3000 s range. For a given mission, the mass benefits with an ion system are typically double those of the arcjet system; however, the total thrusting time with arcjets is less than 1/3 that with ion thrusters for the same thruster power. The mass benefits may permit increases in revenue producing payload or reduce launch costs by allowing a move to a smaller launch vehicle.

Rawlin, Vincent K.↗

Mass comparisons of electric propulsion systems for NSSK of geosynchronous spacecraft

A model was developed and exercised to allow wet mass comparisons of three-axis stabilized communications satellites delivered to geosynchronous transfer orbit. The mass benefits of using advanced chemical propulsion for apogee injection and north-south stationkeeping (NSSK) functions or electric propulsion (hydrazine arcjets and xenon ion thrusters) for NSSK functions are documented. A large derated ion thruster is proposed which minimizes thruster lifetime concerns and qualification test times when compared to those of smaller ion thrusters planned for NSSK applications. The mass benefits, which depend on the spacecraft mass and mission duration, increase dramatically with arcjet specific impulse in the 500-600 s range, but are nearly constant for the derated ion thruster operated in the 2300-3000 s range. For a given mission, the mass benefits with an ion system are typically double those of the arcjet system; however, the total thrusting time with arcjets is less than one-third that with ion thrusters for the same thruster power.

Rawlin, V. K.↗

Detailed Multidimensional Simulations of the Structure and Dynamics of Flames

Numerical simulations in which the various physical and chemical processes can be independently controlled can significantly advance our understanding of the structure, stability, dynamics and extinction of flames. Therefore, our approach has been to use detailed time-dependent, multidimensional, multispecies numerical models to perform carefully designed computational experiments of flames on Earth and in microgravity environments. Some of these computational experiments are complementary to physical experiments performed under the Microgravity Program while others provide a fundamental understanding that cannot be obtained from physical experiments alone. In this report, we provide a brief summary of our recent research highlighting the contributions since the previous microgravity combustion workshop. There are a number of mechanisms that can cause flame instabilities and result in the formation of dynamic multidimensional structures. In the past, we have used numerical simulations to show that it is the thermo-diffusive instability rather than an instability due to preferential diffusion that is the dominant mechanism for the formation of cellular flames in lean hydrogen-air mixtures. Other studies have explored the role of gravity on flame dynamics and extinguishment, multi-step kinetics and radiative losses on flame instabilities in rich hydrogen-air flames, and heat losses on burner-stabilized flames in microgravity. The recent emphasis of our work has been on exploring flame-vortex interactions and further investigating the structure and dynamics of lean hydrogen-air flames in microgravity. These topics are briefly discussed after a brief discussion of our computational approach for solving these problems.

Patnaik, G.↗

Analyses Made to Order: Using Transformation to Rapidly Configure a Multidisciplinary Environment

Aerospace problems are highly multidisciplinary. Four or more major disciplines are involved in analyzing any particular vehicle. Moreover, the choice of implementation technology of various subsystems can lead to a change of leading domain or reformation of the driving equations. An excellent example is the change of expertise required to consider aircraft built from composite or metallic structures, or those propelled by chemical or electrical thrusters. Another example is in the major reconfiguration of handling and stability equations with different control surface configuration (e.g., canards, t-tail v four-post tail). Combinatorial problems are also commonplace anytime that a major system is to be designed. If there are only 5 attributes of a design to consider with 4 different options, this is already 1024 options. Adding just 5 more dimensions to the study explodes the space to over one million. Even generous assumptions like the idea that only 10% of the combinations are physically feasible can only contain the problem for so long. To make matters worse, the simple number of combinations is only the beginning. Combining the issue of trade space size with the need to reformulate the design problem for many of the possibilities makes life exponentially more difficult. Advances in software modeling approaches have led to the development of model-driven architecture. This approach uses the transformation of models into inferred models (e.g. inferred execution traces from state machines) or the skeletons for code generation. When the emphasis on transformation is applied to aerospace, it becomes possible to exploit redundancy in the information specified in multiple domain models into a unified system model. F1urther, it becomes possible to overcome the combinatorial nature of specifying integrated system behavior by manually combining the equations governing a given component technology. Transformations from a system specification combined with a system-analysis mapping specification enable one-click combination of domain analyses. This is a flexibility that has been missing from many engineering codes, which often entangle design specification and physical examination much more than is required to conduct the analysis. This capability has been investigated and cultivated within the DARPA F6 program by a team of JPL and Phoenix Integration engineers building the Adapatable Systems Design and Analysis (ASDA) framework. By embracing system modeling with SysML and the Query-View-Transformation (QVT) language, the ASDA team has been able to build a flexible, easily reconfigurable framework for building up and solving large tradespaces. Examples of application and lessons learned in building the framework will be described in this paper. In addition, the motivation will be laid for various tool vendors to develop open model description standards while being able to maintain competitive advantage through proprietary algorithms and approaches. These standards will also be compared to the underpinnings of model-driven architecture and the OMG standards of the Meta-Object Facility (MOF), SysML, and QVT.

Cole, Bjorn↗

Oxygen Buffering in High Pressure Solid Media Assemblies: New Approach Enabling Study of fO2 from IW-4 to IW+4.5

Oxygen fugacity is an intensive parameter that controls some fundamental chemical and physical properties in planetary materials. In terrestrial magmas high fO2 promotes magnetite stability and low fO2 causes Fe-enrichment due to magnetite suppression. In lunar and asteroidal basalts, low fO2 can allow metal to be stable. Experimental studies will therefore be most useful if they are done at a specific and relevant fO2 for the samples under consideration. Control of fO2 in the solid media apparatus (piston cylinder multi-anvil) has relied on either sliding sensors or graphite capsule buffering, which are of limited application to the wide range of fO2 recorded in planetary or astromaterials. Here we describe a new approach that allows fO2 to be specified across a wide range of values relevant to natural samples.

Righter, K.↗

Long Term Biological Treatment of Space Habitation Waste Waters in a One Stage MABR: Comparison of Operation for N and C Oxidation With and Without Simultaneous Denitrification

Aerobic biological stabilization has been previously demonstrated for full size MABR?s (CoMANDR 1.0, CoMANDR 2.0, and R-CoMANDR) over operating periods of ~1 year. These systems have successfully treated a variety of possible habitation waste streams including an ISS (urine + flush and humidity condensate) and Early Planetary Base (EPB) wastewater (urine, flush water, hygiene wastewater, and laundry). Biological stabilization has a number of advantages including: 1) elimination of hazardous pre-treat chemicals; 2) production of NOx species (that can be easily rejected by evaporative or membrane systems); 3) elimination of volatile organic constituents; 4) a low pH effluent that facilitates membrane and distillation processes; and 5) a effluent that produces a better quality and less hazardous brine for water recovery. Previous work has primarily evaluated aerobic operation in which organic carbon and nitrogen is converted to CO2 and NOx-, respectively. An alternative to aerobic operation would be to include anoxic operation to promote denitrification and production of N2 gas. This allows for production of make-up gas as well as reduces the O2 demand and can increase ammonia oxidation efficiency. We evaluated the operation of a full scale (2 crew/day) MABR operated to perform oxidation of organic carbon and nitrogen with and without simultaneous reduction of oxidized N to N2 gas, simultaneous nitrification denitrification (SNDN). The system was challenged with a variety of space habitation wastewaters ranging from an ISS composition to a possible EPB waste stream under both continuous and on-production feeding modes. The system has been operated for over 2.5 years. We report on an overall comparison of aerobic oxidation and SNDN operational regimes to evaluate the system with the best overall attributes to support recycling of space habitation waste streams.

Biological water processing↗

Microstructural and strength stability of CVD SiC fibers in argon environment

The room temperature tensile strength and microstructure of three types of commercially available chemically vapor deposited silicon carbide fibers were measured after 1, 10, and 100 hour heat treatments under argon pressures of 0.1 to 310 MPa at temperatures to 2100 C. Two types of fiber had carbon-rich surface coatings and the other contained no coating. All three fiber types showed strength degradation beyond 1400 C. Time and temperature of exposure had greater influence on strength degradation than argon pressure. Recrystallization and growth of near stoichiometric SiC grains appears to be the dominant mechanism for the strength degradation.

Bhatt, Ramakrishna T.↗

Microstructural and strength stability of CVD SiC fibers in argon environments

The room temperature tensile strength and microstructure of three types of commercially available chemically vapor deposited silicon carbide fibers were measured after 1, 10, and 100 hour heat treatments under argon pressures of 0.1 to 310 MPa at temperatures to 2100 C. Two types of fiber had carbon-rich surface coatings and the other contained no coating. All three fiber types showed strength degradation beyond 1400 C. Time and temperature of exposure had greater influence on strength degradation than argon pressure. Recrystallization and growth of near stoichiometric SiC grains appears to be the dominant mechanism for the strength degradation.

Bhatt, Ramakrishna T.↗

Model Validation for Propulsion - On the TFNS and LES Subgrid Models for a Bluff Body Stabilized Flame

With advances in computational power and availability of distributed computers, the use of even the most complex of turbulent chemical interaction models in combustors and coupled analysis of combustors and turbines is now possible and more and more affordable for realistic geometries. Recent more stringent emission standards have enticed the development of more fuel-efficient and low-emission combustion system for aircraft gas turbine applications. It is known that the NOx emissions tend to increase dramatically with increasing flame temperature. It is well known that the major difficulty, when modeling the turbulence-chemistry interaction, lies in the high non-linearity of the reaction rate expressed in terms of the temperature and species mass fractions. The transport filtered density function (FDF) model and the linear eddy model (LEM), which both use local instantaneous values of the temperature and mass fractions, have been shown to often provide more accurate results of turbulent combustion. In the present, the time-filtered Navier-Stokes (TFNS) approach capable of capturing unsteady flow structures important for turbulent mixing in the combustion chamber and two different subgrid models, LEM-like and EUPDF-like, capable of emulating the major processes occurring in the turbulence-chemistry interaction will be used to perform reacting flow simulations of a selected test case. The selected test case from the Volvo Validation Rig was documented by Sjunnesson.

bluff body↗

Humidity resistant solar cell contacts

Gold-platinum solar cell contact is developed which does not exhibit chemical reactivity of titanium or porosity of silver. This contact offers excellent ohmic characteristics and stability in humid air.

Bishop, C. J.↗

Synthetic oils

Synthetic lubricants are discussed by chemical class and their general strengths and weaknesses in terms of lubrication properties are analyzed. Comparative ratings are given for 14 chemical classes and are used as a guide for lubricant selection. The effects of chemical structure on the properties of the lubricant are described with special emphasis on thermal stability. The diversity of synthetic lubricants which is provided by the wide range of properties permits many applications, some of which are reported.

Hatton, R. E.↗

A comprehensive model to determine the effects of temperature and species fluctuations on reaction rates in turbulent reacting flows

Reaction rates in turbulent, reacting flows are reviewed. Assumed probability density functions (pdf) modeling of reaction rates is being investigated in relation to a three variable pdf employing a 'most likely pdf' model. Chemical kinetic mechanisms treating hydrogen air combustion is studied. Perfectly stirred reactor modeling of flame stabilizing recirculation regions was used to investigate the stable flame regions for silane, hydrogen, methane, and propane, and for certain mixtures thereof. It is concluded that in general, silane can be counted upon to stabilize flames only when the overall fuel air ratio is close to or greater than unity. For lean flames, silane may tend to destabilize the flame. Other factors favoring stable flames are high initial reactant temperatures and system pressure.

Goldstein, D.↗