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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Periodic orbit analysis of a system with continuous symmetry—A tutorial

Dynamical systems with translational or rotational symmetry arise frequently in studies of spatially extended physical systems, such as Navier-Stokes flows on periodic domains. In these cases, it is natural to express the state of the fluid in terms of a Fourier series truncated to a finite number of modes. Here, we study a 4-dimensional model with chaotic dynamics and SO(2) symmetry similar to those that appear in fluid dynamics problems. A crucial step in the analysis of such a system is symmetry reduction. We use the model to illustrate different symmetry-reduction techniques. The system's relative equilibria are conveniently determined by rewriting the dynamics in terms of a symmetry-invariant polynomial basis. However, for the analysis of its chaotic dynamics, the “method of slices,” which is applicable to very high-dimensional problems, is preferable. We show that a Poincaré section taken on the 'slice' can be used to further reduce this flow to what is for all practical purposes a unimodal map. This enables us to systematically determine all relative periodic orbits and their symbolic dynamics up to any desired period. We then present cycle averaging formulas adequate for systems with continuous symmetry and use them to compute dynamical averages using relative periodic orbits. The convergence of such computations is discussed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

The effect of shear flow on the rotational diffusion of a single axisymmetric particle

Understanding the orientation dynamics of anisotropic colloidal particles is important for suspension rheology and particle self-assembly. However, even for the simplest case of dilute suspensions in shear flow, the orientation dynamics of non-spherical Brownian particles are poorly understood. Here we analytically calculate the time-dependent orientation distributions for non-spherical axisymmetric particles confined to rotate in the flow–gradient plane, in the limit of small but non-zero Brownian diffusivity. For continuous shear, despite the complicated dynamics arising from the particle rotations, we find a coordinate change that maps the orientation dynamics to a diffusion equation with a remarkably simple ratio of the enhanced rotary diffusivity to the zero shear diffusion: $D_{eff}^{r}/D_{0}^{r}=(3/8)(p-1/p)^{2}+1$ , where $p$ is the particle aspect ratio. For oscillatory shear, the enhanced diffusion becomes orientation dependent and drastically alters the long-time orientation distributions. We describe a general method for solving the time-dependent oscillatory shear distributions and finding the effective diffusion constant. As an illustration, we use this method to solve for the diffusion and distributions in the case of triangle-wave oscillatory shear and find that they depend strongly on the strain amplitude and particle aspect ratio. These results provide new insight into the time-dependent rheology of suspensions of anisotropic particles. For continuous shear, we find two distinct diffusive time scales in the rheology that scale separately with aspect ratio $p$, as $1/D_{0}^{r}p^{4}$ and as $1/D_{0}^{r}p^{2}$ for $p\gg$ 1. For oscillatory shear flows, the intrinsic viscosity oscillates with the strain amplitude. Finally, we show the relevance of our results to real suspensions in which particles can rotate freely. Collectively, the interplay between shear-induced rotations and diffusion has rich structure and strong effects: for a particle with aspect ratio 10, the oscillatory shear intrinsic viscosity varies by a factor of ${\approx}2$ and the rotational diffusion by a factor of ${\approx}40$.

42 ENGINEERING↗
NASA NTRS1992

Stabilization of gaze during circular locomotion in darkness. II. Contribution of velocity storage to compensatory eye and head nystagmus in the running monkey

1. Yaw eye in head (Eh) and head on body velocities (Hb) were measured in two monkeys that ran around the perimeter of a circular platform in darkness. The platform was stationary or could be counterrotated to reduce body velocity in space (Bs) while increasing gait velocity on the platform (Bp). The animals were also rotated while seated in a primate chair at eccentric locations to provide linear and angular accelerations similar to those experienced while running. 2. Both animals had head and eye nystagmus while running in darkness during which slow phase gaze velocity on the body (Gb) partially compensated for body velocity in space (Bs). The eyes, driven by the vestibuloocular reflex (VOR), supplied high-frequency characteristics, bringing Gb up to compensatory levels at the beginning and end of the slow phases. The head provided substantial gaze compensation during the slow phases, probably through the vestibulocollic reflex (VCR). Synchronous eye and head quick phases moved gaze in the direction of running. Head movements occurred consistently only when animals were running. This indicates that active body and limb motion may be essential for inducing the head-eye gaze synergy. 3. Gaze compensation was good when running in both directions in one animal and in one direction in the other animal. The animals had long VOR time constants in these directions. The VOR time constant was short to one side in one animal, and it had poor gaze compensation in this direction. Postlocomotory nystagmus was weaker after running in directions with a long VOR time constant than when the animals were passively rotated in darkness. We infer that velocity storage in the vestibular system had been activated to produce continuous Eh and Hb during running and to counteract postrotatory afterresponses. 4. Continuous compensatory gaze nystagmus was not produced by passive eccentric rotation with the head stabilized or free. This indicates that an aspect of active locomotion, most likely somatosensory feedback, was responsible for activating velocity storage. 5. Nystagmus was compared when an animal ran in darkness and in light. the beat frequency of eye and head nystagmus was lower, and the quick phases were larger in darkness. The duration of head and eye quick phases covaried. Eye quick phases were larger when animals ran in darkness than when they were passively rotated. The maximum velocity and duration of eye quick phases were the same in both conditions. 6. The platform was counterrotated under one monkey in darkness while it ran in the direction of its long vestibular time constant.(ABSTRACT TRUNCATED AT 400 WORDS).

NASA Discipline Neuroscience↗
NASA NTRS1979

Accretion by rotating magnetic neutron stars. III - Accretion torques and period changes in pulsating X-ray sources

The solutions of the two-dimensional hydromagnetic equations are used to calculate the torque on a magnetic neutron star accreting from a Keplerian disk. It is found that the magnetic coupling between the star and the plasma in the outer transition zone is appreciable; that as a result, the spin-up torque on fast rotators is substantially less than that on slow rotators, and that for sufficiently high stellar angular velocities or sufficiently low mass accretion rates, the rotation of the star can be braked while accretion continues. These results are applied to pulsating X-ray sources, revealing that at high luminosities a star of given spin period rotating in the same direction as the disk can experience either spin-up or spin-down, depending on its luminosity. Also considered are the general problem of interpreting period changes in pulsating X-ray sources, and the dipole magnetic moments of nine pulsating X-ray sources are estimated by fitting the theoretical spin-up equation to estimates of the average luminosity and spin-up rate of each source.

Ghosh, P.↗
NASA NTRS1995

Modeling the vestibulo-ocular reflex of the squirrel monkey during eccentric rotation and roll tilt

Model simulations of the squirrel monkey vestibulo-ocular reflex (VOR) are presented for two motion paradigms: constant velocity eccentric rotation and roll tilt about a naso-occipital axis. The model represents the implementation of three hypotheses: the "internal model" hypothesis, the "gravito-inertial force (GIF) resolution" hypothesis, and the "compensatory VOR" hypothesis. The internal model hypothesis is based on the idea that the nervous system knows the dynamics of the sensory systems and implements this knowledge as an internal dynamic model. The GIF resolution hypothesis is based on the idea that the nervous system knows that gravity minus linear acceleration equals GIF and implements this knowledge by resolving the otolith measurement of GIF into central estimates of gravity and linear acceleration, such that the central estimate of gravity minus the central estimate of acceleration equals the otolith measurement of GIF. The compensatory VOR hypothesis is based on the idea that the VOR compensates for the central estimates of angular velocity and linear velocity, which sum in a near-linear manner. During constant velocity eccentric rotation, the model correctly predicts that: (1) the peak horizontal response is greater while "facing-motion" than with "back-to-motion"; (2) the axis of eye rotation shifts toward alignment with GIF; and (3) a continuous vertical response, slow phase downward, exists prior to deceleration. The model also correctly predicts that a torsional response during the roll rotation is the only velocity response observed during roll rotations about a naso-occipital axis. The success of this model in predicting the observed experimental responses suggests that the model captures the essence of the complex sensory interactions engendered by eccentric rotation and roll tilt.

NASA Discipline Neuroscience↗
DOE OSTI2021

Electrostatic Design and Characterization of a 200 keV Photogun and Wien Spin Rotator

High-energy nuclear physics experiments at the Jefferson Lab Continuous Electron Beam Accelerator Facility (CEBAF) require high spin-polarization electron beams produced from strained super-lattice GaAs photocathodes activated to negative electron affinity in a high voltage photogun operating at 130 kV dc. A pair of Wien filter spin rotators in the injector provides precise control of the electron beam polarization at the end station target. An upgrade of the CEBAF injector to better support the upcoming Moller experiment requires increasing the electron beam energy to 200 keV, resulting in better transmission through injector apertures and improved photocathode lifetime. In addition, the energy increase is expected to reduce unwanted helicity correlated intensity and position systematics. These requirements led to the design of a shielding electrode described in this work, which minimizes the electric field at the triple-point junction and linearizes the potential along the insulator, thus reducing the risk of field emission induced insulator arcing. The Wien spin rotator design was modified for increasing the electric field from 1.6 to 2.7 MV/m and the magnetic field from 9.1 to 13 mT. The upgrades required detailed modeling in Solidworks, electrostatic simulations using CST, beam dynamics using GPT, device implementation, and in situ high voltage characterization of the world?s first 200 keV polarized photoelectron gun and compatible Wien filter spin rotator.

Palacios-Serrano, Gabriel↗
DOE OSTI2013

Principles and biophysical applications of single particle super-localization and rotational tracking

While conventional Single Particle Tracking (SPT) techniques acquire 2D or 3D trajectories of particle probes, we have developed Single Particle Orientation and Rotational Tracking (SPORT) techniques to extract orientation and rotational information. Combined with DIC microscopy, the SPORT technique has been applied in biophysical studies, including membrane diffusion and intracellular transport. The rotational dynamics of nanoparticle vectors on live cell membranes was recorded and its influence on the fate of these nanoparticle vectors was elucidated. The rotational motions of gold nanorods with various surface modifiers were tracked continuously at a temporal resolution of 5 ms under a DIC microscope. We found that the rotational behaviors of gold nanorod vectors are strongly related to their surface charge, specific surface functional groups, and the availability of receptors on cell membranes. The study of rotational Brownian motion of nanoparticles on cell membranes will lead to a better understanding of the mechanisms of drug delivery and provide guidance in designing surface modification strategies for drug delivery vectors under various circumstances. To characterize the rotation mode of surface functionalized gold nanorods on cell membranes, the SPORT technique is combined with the correlation analysis of the bright and dark DIC intensities. The unique capabilities of visualizing and understanding rotational motions of functionalized nanoparticles on live cell membranes allow us to correlate rotational and translational dynamics in unprecedented detail and provide new insights for complex membrane processes, including electrostatic interactions, ligand-receptor binding, and lateral (confined and hopping) diffusion of membrane receptors. Surface-functionalized nanoparticles interact with the membrane in fundamentally different ways and exhibit distinct rotational modes. The early events of particle-membrane approach and attachment are directly visualized for the first time. The rotational dynamics of cargos in both active directional transport and pausing stages of axonal transport was also visualized using high-speed SPORT with a temporal resolution of 2 ms. Both long and short pauses are imaged, and the correlations between the pause duration, the rotational behaviour of the cargo at the pause, and the moving direction after the pause are established. Furthermore, the rotational dynamics leading to switching tracks are visualized in detail. These first-time observations of cargo's rotational dynamics provide new insights on how kinesin and dynein motors take the cargo through the alternating stages of active directional transport and pause. To improve the localization precision of the SPT technique with DIC microscopy, a precise three-dimensional (3D) localization method of spherical gold nanoparticle probes using model-based correlation coefficient mapping was introduced. To accomplish this, a stack of sample images at different z-positions are acquired, and a 3D intensity profile of the probe serving as the model is used to map out the positions of nanoparticles in the sample. By using this model-based correlation imaging method, precise localization can be achieved in imaging techniques with complicated point spread functions (PSF) such as differential interference contrast (DIC) microscopy. The 3D superlocalization method was applied to tracking gold nanospheres during live endocytosis events. Finally, a novel dual-modality imaging technique has been developed to super-localize a single gold nanorod while providing its orientation and rotational information. The super-localization of the gold nanorod can be accomplished by curve fitting the modified bright-field images generated by one of the two beams laterally shifted by the first Nomarski prism in a DIC microscope. The orientation and rotational information is derived from the DIC images of gold nanorods. The new imaging setup has been applied to study the steric hindrance induced by relatively large cargos in the microtubule gliding assay and to track nanocargos in the crowded cellular environment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2012

Three dimensional fabric evolution of sheared sand

Granular particles undergo translation and rolling when they are sheared. This paper presents a three-dimensional (3D) experimental assessment of fabric evolution of sheared sand at the particle level. F-75 Ottawa sand specimen was tested under an axisymmetric triaxial loading condition. It measured 9.5 mm in diameter and 20 mm in height. The quantitative evaluation was conducted by analyzing 3D high-resolution x-ray synchrotron micro-tomography images of the specimen at eight axial strain levels. The analyses included visualization of particle translation and rotation, and quantification of fabric orientation as shearing continued. Representative individual particles were successfully tracked and visualized to assess the mode of interaction between them. This paper discusses fabric evolution and compares the evolution of particles within and outside the shear band as shearing continues. Changes in particle orientation distributions are presented using fabric histograms and fabric tensor.

36 MATERIALS SCIENCE↗
NASA NTRS1993

Testing For Parasitic Lasing With Controlled Retroreflection

Controlled-retroreflection technique provides new capability to test safely for parasitic oscillations in laser. Continuously variable reflector adjusted continuously over dynamic range of about 3 decades by rotation of quarter-wave plate about optical axis. Neutral-density filter establishes maximum reflectivity. By selection of neutral-density filters and continuous adjustment, reflector made to have any reflectivity from about 1 down to 10 to the negative 8th power.

Storm, Mark E.↗
NASA NTRS1986

Shear deformation plate continua of large double layered space structures

A simple method is presented to model large rigid-jointed lattice structures as continuous elastic media with couple stresses using energy equivalence. In the analysis, the transition from the discrete system to the continuous media is achieved by expanding the displacements and the rotations of the nodal points in a Taylor series about a suitable chosen origin. The strain energy of the continuous media with couple stresses is then specialized to obtain shear deformation plate continua. Equivalent continua for single layered grids, double layered grids, and three-dimensional lattices are then obtained.

Hefzy, Mohamed Samir↗
DOE OSTI2012

MULTIPLICITY AMONG F-TYPE STARS

As part of a homogeneous all-sky volume-complete sample of half a thousand solar-type stars within 25 pc we present a census for the subset of the 150-mostly F-type stars-in the mass range 1.1 M{sub Sun} {<=} M {<=} 1.7 M{sub Sun} in terms of their observed multiplicities. The major obstacle, as expected, arises from the onset of stellar rotation in this mass range for it continues to support many hidden companions. Yet, a solid increase of the fraction of binary and higher level systems as a function of the primary mass is manifest. There is even the prospect that on account of many companion candidates the single-star fraction may already converge to zero at the transition to the A-type stars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

Modeling and Optimization of a Rotating Packed Bed Contactor with a Tetraamine-Appended Metal−Organic Framework for CO 2 Capture

A potential contactor technology for sorbent-based CO 2 capture is the rotating packed bed that contains separate sections for continuous adsorption and desorption. A heat exchanger can be embedded to remove heat in the adsorption section and add heat in the desorption section. In this work, we develop a two-dimensional (2D) model of a rotating packed bed for use in CO 2 capture applications. Mass and energy balances for the model are developed based on a Ljungström-type air preheater, which accounts for the counter-current axial flow of gas phases in separate sections of the bed and the rotation of a solid sorbent, which cycles between adsorption and desorption sections. The sorbent used for this analysis is the tetraamine-appended metal−organic framework Mg 2 (dobpdc)(3−4− 3), chosen for its stability and affinity for CO 2 at low partial pressures, such as those from a natural gas power plant source. An optimization problem is solved that considers the trade-off between maximizing the productivity of the bed and minimizing energy consumption. Maximum productivity and minimum energy are found to be 8.53 kg/h/m 3 and 3.84 MJ/kg, respectively, when these objectives are optimized independently. It is observed that the flue gas pressure and bed rotational speed are the desired operating variables to vary for model-based design of experiments to reduce uncertainty in parameter estimation, as these two variables yielded the most information content based on the Fisher information matrix.

20 FOSSIL-FUELED POWER PLANTS↗
NASA NTRS1979

Numerical analysis of turbulent wakes of axial flow turbomachinery rotor blades

The wakes of rotor blades are turbulent, three-dimensional, and are subjected to curvature and rotation effects. The objective of this study is to predict the development of such wakes and compare the predictions with the existing data. A finite difference procedure is employed in the numerical analysis of the wake utilizing the continuity, momentum, and turbulence closure equations in the rotating curvilinear and non-orthogonal coordinate system. The turbulence closure is affected by the two equations model and the simplified Reynolds stress model. The predictions from both the models agree well with the mean velocity and the turbulence data.

Hah, C.↗
NASA NTRS1999

Novel Approaches to Cellular Transplantation from the US Space Program

Research in the treatment of type I diabetes is entering a new era that takes advantage of our knowledge in an ever increasing variety of scientific disciplines. Some may originate from very diverse sources, one of which is the Space Program at National Aeronautics and Space Administration (NASA). The Space Program contributes to diabetes-related research in several treatment modalities. As an ongoing effort for medical monitoring of personnel involved in space exploration activities NASA and the extramural scientific community investigate strategies for noninvasive estimation of blood glucose levels. Part of the effort in the space protein crystal growth program is high-resolution structural analysis insulin as a means to better understand the interaction with its receptor and with host immune components and as a basis for rational design of a "better" insulin molecule. The Space Program is also developing laser technology for potential early cataract detection as well as a noninvasive analyses for addressing preclinical diabetic retinopathy. Finally, NASA developed an exciting cell culture system that affords some unique advantages in the propagation and maintenance of mammalian cells in vitro. The cell culture system was originally designed to maintain cell suspensions with a minimum of hydrodynamic and mechanical sheer while awaiting launch into microgravity. Currently the commercially available NASA bioreactor (Synthecon, Inc., Houston, TX) is used as a research tool in basic and applied cell biology. In recent years there is continued strong interest in cellular transplantation as treatment for type I diabetes. The advantages are the potential for successful long-term amelioration and a minimum risk for morbidity in the event of rejection of the transplanted cells. The pathway to successful application of this strategy is accompanied by several substantial hurdles: (1) isolation and propagation of a suitable uniform donor cell population; (2) management of host immune rejection; (3) protection from the autoimmune component of the disease; and (4) anatomic placement of the engrafted cells that permits timely response to blood sugar levels as well as effective release and deployment of insulin. Bioreactor technology may provide some critical advances for surmounting some of these scientific hurdles. The NASA bioreactor is a horizontally rotating cylinder that is completely filled with culture medium. Gaseous exchange is maintained by a concentric cylinder of permeable silicon. In slow rotation (15-25 rpm) particles of small mass such as cells and tissue aggregates remain suspended in the rotating body of fluid. This novel approach suspends cells without stirring thus, allowing objects of different size mass to colocate and interact in a very low shear environment. In fact, analysis of the forces acting on individual cells in the rotating bioreactor reveals that the cells are continuously falling through the fluid medium. The conditions in the bioreactor permit assembly of cells into aggregates. three-dimensional tissue growth, synthesis of intercellular matrix,10 differentiation, and some sinusoid formations that may serve as a surrogate vasculature for larger tissue segments.

Pellis, Neal R.↗
DOE OSTI2018

The Mochi LabJet Experiment for Measurements of Canonical Helicity Injection in a Laboratory Astrophysical Jet

The Mochi device is a new pulsed power plasma experiment designed to produce long, collimated, stable, magnetized plasma jets when set up in the LabJet configuration. The LabJet configuration aims to simulate an astrophysical jet in the laboratory by mimicking an accretion disk threaded by a poloidal magnetic field with concentric planar electrodes in front of a solenoidal coil. The unique setup consists of three electrodes, each with azimuthally symmetric gas slits. Two of the electrodes are biased independently with respect to the third electrode to control the radial electric field profile across the poloidal bias magnetic field. This design approximates a shear azimuthal rotation profile in an accretion disk. The azimuthally symmetric gas slits provide a continuously symmetric mass source at the footpoint of the plasma jet, so any azimuthal rotation of the plasma jet is not hindered by a discrete number of gas holes. The initial set of diagnostics consists of current Rogowski coils, voltage probes, magnetic field probe arrays, an interferometer and ion Doppler spectroscopy, supplemented by a fast ion gauge and a retarding grid energy analyzer. The measured parameters of the first plasmas are ~10 22 m -3 , ~0.4 T, and 5–25 eV, with velocities of ~20–80 km s -1 . Finally, the combination of a controllable electric field profile, a flared poloidal magnetic field, and azimuthally symmetric mass sources in the experiment successfully produces short-lived (~10 μs, ≳5 Alfvén times) collimated magnetic jets with a ~10:1 aspect ratio and long-lived (~100 μs, ≳40 Alfvén times) flow-stabilized, collimated, magnetic jets with a ~30:1 aspect ratio.

42 ENGINEERING↗
DOE OSTI2015

THE ROTATION PERIOD AND MAGNETIC FIELD OF THE T DWARF 2MASSI J1047539+212423 MEASURED FROM PERIODIC RADIO BURSTS

Periodic radio bursts from very low mass stars and brown dwarfs simultaneously probe their magnetic and rotational properties. The brown dwarf 2MASSI J1047539+212423 (2M 1047+21) is currently the only T dwarf (T6.5) detected at radio wavelengths. Previous observations of this source with the Arecibo observatory revealed intermittent, 100%-polarized radio pulses similar to those detected from other brown dwarfs, but were unable to constrain a pulse periodicity; previous Very Large Array (VLA) observations detected quiescent emission a factor of ∼100 times fainter than the Arecibo pulses but no additional events. Here we present 14 hr of VLA observations of this object that reveal a series of pulses at ∼6 GHz with highly variable profiles, showing that the pulsing behavior evolves on time scales that are both long and short compared to the rotation period. We measure a periodicity of ∼1.77 hr and identify it with the rotation period. This is just the sixth rotation period measurement in a late T dwarf, and the first obtained in the radio. We detect a pulse at 10 GHz as well, suggesting that the magnetic field strength of 2 M 1047+21 reaches at least 3.6 kG. Although this object is the coolest and most rapidly rotating radio-detected brown dwarf to date, its properties appear continuous with those of other such objects, suggesting that the generation of strong magnetic fields and radio emission may continue to even cooler objects. Further studies of this kind will help to clarify the relationships between mass, age, rotation, and magnetic activity at and beyond the end of the main sequence, where both theories and observational data are currently scarce.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Effect of initial orientation on dynamic recrystallization of a zirconium alloy during hot deformation

Highlights: • The dynamic recrystallization process is enhanced by the operation of slip. • Continuous dynamic recrystallization is promoted by the rotation of grains. • Texture induced hardening hides the softening induced by dynamic recrystallization. - Abstract: The present study investigated the influence of the initial orientation on the dynamic recrystallization (DRX) behavior of a Zr-1Sn-0.3Nb alloy. A hot-rolled and annealed Zr sheet was compressed along two directions: along the normal direction so that the grains' -axis was nearly parallel to the loading direction (0° sample) and along the transverse direction so that the grains' -axis was nearly perpendicular to the loading direction (90° sample). The samples were compressed at 700 °C at a strain rate of 1 s{sup −1}. The microstructures at different strains were characterized by the electron backscatter diffraction (EBSD) technique, and conventional dislocation analysis using transmission electron microscope (TEM) was performed. A threshold value of grain orientation spread (GOS) equaled to 5° was used to distinguish the dynamically recrystallized grains from the deformed matrix. The results revealed that the DRX behavior strongly depended on the initial orientation. The Schmid factor analysis and TEM observation confirmed that pyramidal slip operated from the first stage of deformation in the 0° sample but not in the 90° sample. For the 0° sample, in the early and medium stages of deformation, due to the high stored energy caused by the operation of pyramidal slip, DDRX was mainly contributed to the formation of new fine grains. However, in the later stage of deformation, the DRX mechanism changed from DDRX to CDRX. In the 90° sample, although DDRX featured by grain boundary bulging occurred, the main DRX mechanism was CDRX in the whole deformation processing. Moreover, texture induced hardening in the early stage of deformation hides the softening induced by DDRX.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Kinetics of Dechlorination of Molten Chloride Salt Using Protonated Ultrastable Y Zeolite

Investigation of the kinetics of the ion exchange between protonated ultrastable Y-type (USHY) and surrogate electrorefiner (ER) waste salt was performed to optimize the dechlorination process. The kinetics of the ion exchange reaction was investigated by measuring the amount of unreacted Cl. In theory, the kinetics of the ion exchange reaction in porous media will be limited by diffusion- or reaction-controlled mechanisms. Therefore, second order kinetics and diffusion-limited rate models have been derived and compared to experimental data to elucidate the rate-limiting step and develop a predictive model for the apparent rate of reaction. Ion exchange experiments were performed with varying zeolite particle sizes (up to 600 μm) at 625 °C. The experiments were performed with both unfluidized and continuously fluidized zeolite particles in static and rotating tube furnaces. Finally, it was concluded that the process is limited by reaction kinetics inside the zeolite crystals, and a second order kinetic model best fits the experimental data. Given that the zeolite is not stable at higher temperatures, further increase in the extent of dechlorination for a given batch reaction time requires an increase of the zeolite-to-salt ratio, which has the undesirable effect of increasing the volume of generated waste per amount of salt.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗