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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

High-power test results for a cylindrical-shell silicon carbide higher-order-mode damper

The next high-current Electron-Ion Collider (EIC) is a new accelerator to be built at Brookhaven National Laboratory in collaboration with Thomas Jefferson National Accelerator Facility. In the EIC Electron Storage Ring (ESR), there will be beam currents of up to 2.5 A, which will excite massive higher-order-mode (HOM) power in the 17 single-cell 591 MHz superconducting radio-frequency (SRF) cavities. Damping the HOM power in the ESR SRF cavities is a challenge. A room temperature cylindrical shell shape silicon carbide (SiC) beamline HOM absorber (BLA) was chosen as the baseline design, due to its broadband and high-power capability, and previous demonstrations at other accelerator facilities, albeit at much lower power. Because the EIC BLA HOM power dissipation is significantly greater than the previous applications, it is imperative to carry out high-power testing to determine the maximum device performance levels achievable for thermal transport, rf breakdown, and mechanical stress, prior to finalizing the design. A SiC HOM absorber with a state-of-the-art geometry size was prototyped to verify the shrink-fit technique, test outgassing rate, and high-power handling capability. This paper presents the HOM damper’s prototyping and test results. Published by the American Physical Society 2024

43 PARTICLE ACCELERATORS↗
NASA NTRS1998

Electron Beam Welder Used to Braze Sapphire to Platinum

A new use for electron beam brazing was recently developed by NASA Lewis Research Center's Manufacturing Engineering Division. This work was done to fabricate a fiberoptic probe (developed by Sentec Corporation) that could measure high temperatures less than 600 deg C of vibrating machinery, such as in jet engine combustion research. Under normal circumstances, a sapphire fiber would be attached to platinum by a ceramic epoxy. However, no epoxies can adhere ceramic fibers to platinum under such high temperatures and vibration. Also, since sapphire and platinum have different thermal properties, the epoxy bond is subjected to creep over time. Therefore, a new method had to be developed that would permanently and reliably attach a sapphire fiber to platinum. Brazing a sapphire fiber to a platinum shell. The fiber-optic probe assembly consists of a 0.015-in.-diameter sapphire fiber attached to a 0.25-in.-long, 0.059-in.-diameter platinum shell. Because of the small size of this assembly, electron beam brazing was chosen instead of conventional vacuum brazing. The advantage of the electron beam is that it can generate a localized heat source in a vacuum. Gold reactive braze was used to join the sapphire fiber and the platinum. Consequently, the sapphire fiber was not affected by the total heat needed to braze the components together.

Forsgren, Roger C.↗
DOE OSTI2020

Measurements of inner-shell excited levels of Na-, Mg-, and Al-like europium on the LLNL EBIT

We report on a measurement of several n = 3 → n = 2 inner-shell transitions in sodiumlike, magnesiumlike, and aluminumlike europium, performed at the EBIT-I electron beam ion trap facility at the Lawrence Livermore National Laboratory using an x-ray calorimeter. Although the inner-shell x-ray lines of such M-shell ions are typically dominated by electric dipole allowed transitions, we have also identified a weak feature that appears to be the result of electric quadrupole decay in sodiumlike Eu 52+ . Here, we compare the measured transitions energies to the calculated values obtained using the flexible atomic code. We find agreement in most cases within 2 eV or better.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1975

The 10 sheath-accelerated electrons and ions

A model is presented that suggests that plasma sheaths form between the ionospheric plasma moving with Io and the ambient plasma corotating with Jupiter. Potentials across these sheaths could be as high as 580 kV which is the motional emf across Io's ionosphere. Electrons and ions can be accelerated across these sheaths. The sheaths may exist at the top of the Io ionosphere with characteristic thicknesses of 1/4 kilometers. The model is consistent with the Pioneer observations of 0.15 MeV electrons at the inner edge of Io's L-shell and the enhanced number density of low-energy protons at the outer edge. Ion sputtering of the Io surface is discussed and may explain the presence of atomic hydrogen and sodium in the vicinity of Io. Also these accelerated particles may be important to the formation of the Io ionosphere. High electron flux which may lead to decametric radio emissions, Jovian atmospheric heating and optical and X-ray emissions is also discussed.

Shawhan, S. D.↗
DOE OSTI2022

Manifestation of postcollision interaction in Krypton LMN Auger spectra following K-shell photoionization

In this work, we report on an experimental and theoretical study of post-collision interaction (PCI) effects on L 2 -M 4,5 N 2,3 Auger electrons measured above the Kr K-edge in which L 2 vacancies are primarily generated by KL 2 x-ray emission. Such cascade processes, in which a deep inner-shell vacancy decays first by x-ray emission followed by Auger electron emission, is a strong decay mode in heavy atoms. The L 2 -M 4,5 N 2,3 Auger electron peak is observed to become increasingly asymmetric with a shifting peak maximum as the absorbed x-ray energy approaches the K-shell ionization threshold. This is attributed to PCI energy exchanges of the Auger electron with the 1s photoelectron. To model the PCI effects, we have applied a semiclassical approach modified to account for the combined lifetimes of the K and L 2 hole states. In addition, our analysis treats several closely spaced Auger transitions with final ionic states having different terms and angular momenta.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1985

Lightning-induced electron precipitation from the magnetosphere

Precipitation of radiation belt particles induced by whistlers that are generated by atmospheric lightning discharges and propagate over L shells of 2-4.5 is considered. Using a test particle model of the whistler-particle interaction, the energy spectra and temporal profile of whistler-induced fluxes as a function of L shell are quantitatively determined for a representative plasmaspheric cold plasma distribution. Results indicate that for higher energy electron precipitation (E greater than 40 keV) there exists an inner magnetospheric region (L between 2 and 3) where the level of whistler-induced precipitation can be expected to be comparatively high. Implications of this finding in terms of observational results are discussed.

Chang, H. C.↗
DOE OSTI2025

Kβ X-ray Emission Spectra Analysis Using Bayesian Optimization

The Kβ X-ray emission spectrum of 3 d transition metals is rich with electronic and structural information due to strong exchange interactions with the valence shell of the metal, and has become crucial for understanding their spin and oxidation states. The spectrum is commonly treated using crystal-field multiplet theory, a semi-empirical theory that uses tunable parameters to control the strength of the effects present in X-ray emission spectroscopy (XES). However, determining the experimental values of these parameters remains a challenge. We present a methodology that applies Bayesian optimization to crystal-field multiplet theory to determine parameter values. The algorithm is tested on the X-ray emission spectra of a collection of Mn, Co, and Ni oxides. We are able to find optimal values for the four most impactful parameters: Slater−Condon reduction factors F dd , F pd , and G pd , and crystal field splitting 10 Dq . The algorithm produces significantly improved accuracy compared to current analysis methods, and probes interparameter dependencies by modeling the error landscape. This advancement enhances XES analysis by offering an approach of obtaining quantitative electronic structural information on 3 d transition metal valence shells, facilitating applications across various scientific fields.

Bayesian optimization↗
NASA NTRS1980

Motion of trapped electrons and protons in Saturn's inner magnetosphere

A summary is given of basic formulas for the guiding center motion of energetic charged particles trapped in a dipolar magnetic field. These formulas for longitudinal drift rates, latitudinal bounce periods, equatorial gyroradii, and equatorial gyroperiods are then stated in convenient numerical form for electrons and protons as functions of kinetic energy E, magnetic shell parameter L, and equatorial pitch angle alpha 0 for a slightly simplified model of the observed magnetic field of Saturn. To aid in the study of the interaction of charged particles with the rings and inner satellites of Saturn, additional formulas are given for the time interval between successive encounters of charged particles with a satellite in a circular prograde orbit and for the energy of electrons whose longitudinal angular velocity is resonant, or synchronous, with the Keplerian angular velocity of such a satellite.

Thomsen, M. F.↗
NASA NTRS2020

Radial Response of Outer Radiation Belt Relativistic Electrons During Enhancement Events at Geostationary Orbit

Forecasting relativistic electron fluxes at geostationary Earth orbit (GEO) has been a long‐term goal of the scientific community, and significant advances have been made in the past, but the relation to the interior of the radiation belts, that is, to lower L‐shells, is still not clear. In this work we have identified 60 relativistic electron enhancement events at GEO to study the radial response of outer belt fluxes and the correlation between the fluxes at GEO and those at lower L‐shells. The enhancement events occurred between 1 October 2012 and 31 December 2017 and were identified using Geostationary Operational Environmental Satellite (GOES) 15 >2 MeV fluxes at GEO, which we have used to characterize the radial response of the radiation belt, by comparing to fluxes measured by the Van Allen probes Energetic Particle, Composition and Thermal Plasma Suite Relativistic Electron‐Proton Telescope (ECT‐REPT) between 2.5 5.0 and generally similar for L>4.5. Post‐enhancement maximum fluxes show a remarkable correlation for all L>4.0 although the magnitude of the pre‐existing fluxes on the outer belt plays a significant role and makes the ratio of pre‐enhancement to post‐enhancement fluxes less predictable in the region 4.0<L<4.5. For L<4 the fluxes are poorly correlated with geostationary orbit, but they also tend to be less variable. We have also examined SYM‐H, Kp, and AE indices and found that depending on their magnitude, the response of different parts of the outer belt can be better quantified.

Victor A. Pinto↗
NASA NTRS1978

Infrared excesses in early-type stars - Gamma Cassiopeiae

Spectrophotometry of the classical Be star Gamma Cas (1-4 microns, with about 2% spectral resolution) is presented. These data, together with existing broad-band observations, are accurately described by simple isothermal LTE models for the IR excess which differ from most previously published work in three ways: (1) hydrogenic bound-free emission is included; (2) the attenuation of the star by the shell is included; and (3) no assumption is made that the shell contribution is negligible in some bandpass. It is demonstrated that the bulk of the IR excess consists of hydrogenic bound-free and free-free emission from a shell of hot ionized hydrogen gas, although a small thermal component cannot be ruled out. The bound-free emission is strong, and the Balmer, Paschen, and Brackett discontinuities are correctly represented by the shell model with physical parameters as follows: a shell temperature of approximately 18,000 K, an optical depth (at 1 micron) of about 0.5, an electron density of approximately 1 trillion per cu cm, and a size of about 2 trillion cm. Phantom shells (i.e., ones which do not alter the observed spectrum of the underlying star) are discussed.

Scargle, J. D.↗
DOE OSTI2024

Engineering Ultrathin Alloy Shell in Au@AuPd Core-Shell Nanoparticles for Efficient Plasmon-Driven Photocatalysis

Bimetallic core-shell nanoparticles (NPs) possessing a synergetic coupling of plasmonic and catalytic metals have emerged as promising prototypes for efficient plasmon-driven photocatalysis. Here, Au@AuPd core-shell NPs composed of Au core NP and ultrathin AuPd shell are introduced to acquire improved light utilization efficiency in photocatalytic selective oxidation. With systematical control of the composition of the ultrathin alloy shell, it reveals that the Au@AuPd core-shell NPs with 10 at% Pd (in the single-atom alloy regime) is an effective nanostructure capable of maximizing the quantum yield of plasmon-induced light absorption and optimizing the surface electronic structure for catalytic reactions. This controlled system provides new insights into shell engineering for enhancing photocatalytic performance via the regulation of energy funneling processes in core-shell nanocatalysts.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Strain-Enhanced Metallic Intermixing in Shape-Controlled Multilayered Core–Shell Nanostructures: Toward Shaped Intermetallics

Controlling the surface composition of shaped bimetallic nanoparticles could offer precise tunability of geometric and electronic surface structure for new nanocatalysts. To achieve this goal, a platform for studying the intermixing process in a shaped nanoparticle was designed, using multilayered Pd-Ni-Pt core–shell nanocubes as precursors. Under mild conditions, the intermixing between Ni and Pt could be tuned by changing layer thickness and number, triggering intermixing while preserving nanoparticle shape. Intermixing of the two metals is monitored using transmission electron microscopy. The surface structure evolution is characterized using electrochemical methanol oxidation. DFT calculations suggest that the low-temperature mixing is enhanced by shorter diffusion lengths and strain introduced by the layered structure. The platform and insights presented are an advance toward the realization of shape-controlled multimetallic nanoparticles tailored to each potential application.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2009

Method of synthesizing small-diameter carbon nanotubes with electron field emission properties

Carbon nanotube material having an outer diameter less than 10 nm and a number of walls less than ten are disclosed. Also disclosed are an electron field emission device including a substrate, an optionally layer of adhesion-promoting layer, and a layer of electron field emission material. The electron field emission material includes a carbon nanotube having a number of concentric graphene shells per tube of from two to ten, an outer diameter from 2 to 8 nm, and a nanotube length greater than 0.1 microns. One method to fabricate carbon nanotubes includes the steps of (a) producing a catalyst containing Fe and Mo supported on MgO powder, (b) using a mixture of hydrogen and carbon containing gas as precursors, and (c) heating the catalyst to a temperature above 950.degree. C. to produce a carbon nanotube. Another method of fabricating an electron field emission cathode includes the steps of (a) synthesizing electron field emission materials containing carbon nanotubes with a number of concentric graphene shells per tube from two to ten, an outer diameter of from 2 to 8 nm, and a length greater than 0.1 microns, (b) dispersing the electron field emission material in a suitable solvent, (c) depositing the electron field emission materials onto a substrate, and (d) annealing the substrate.

Liu, Jie↗
DOE OSTI2022

Inferences of hot electron preheat and its spatial distribution in OMEGA direct drive implosions

Hot electrons generated from laser plasma instabilities degrade performance of direct drive implosions by preheating the deuterium and tritium (DT) fuel resulting in early decompression and lower areal densities at stagnation. A technique to quantify the hot electron preheat of the dense DT fuel and connect it to the degradation in areal density is described in detail. Hot electrons are measured primarily from the hard x-rays they emit as they slow down in the target. The DT preheat is inferred from a comparison of the hard x-ray signals between a DT-layered implosion and its mass equivalent ablator only implosion. The preheat energy spatial distribution within the imploding shell is inferred from experiments using high Z payloads of varying thicknesses. It is found that the electrons deposit their energy uniformly throughout the shell material. For typical direct-drive OMEGA implosions driven with an overlapped intensity of ∼9·1014 W/cm2, approximately ∼0.02%–0.03% of the laser energy is converted into preheat of the stagnated fuel which corresponds to areal density degradations of 10%–20%. The degradations in areal density explain some of the observed discrepancies between the simulated and measured areal densities.

Christopherson, A. R. (ORCID:000000033578635X)↗
NASA NTRS2018

Ultralow Frequency Waves as an Intermediary for Solar Wind Energy Input Into the Radiation Belts

Enhancements of electron fluxes in the outer radiation belt have been closely linked to increases in solar wind speed and density as well as to prolonged intervals of southward interplanetary magnetic field. Periodic oscillations in the Earth's magnetic field with frequencies in the range of a few millihertz (ultralow frequency or ultralow frequency waves) may be an intermediary through which these solar wind drivers influence radiation belt dynamics due to their potential for resonant interactions with energetic electrons causing the radial migration of resonant electrons. Using data from more than 180 ground magnetometers contributing to the worldwide SuperMAG collaboration, we explore possible relationships between relativistic electron flux variations and the spatial and temporal profiles of ultralow frequency wave power contained in the Pc5 frequency band (2–7 mHz). During 19 geomagnetic storms marked by relativistic (1.5 MeV < E < 6 MeV) electron flux enhancements and 19 storms that led to prolonged electron flux depletions, Pc5 wave power is found penetrating to L shells as low as 2–3. The enhancement of Pc5 wave power starts almost simultaneously with the storm onset. The depth of wave activity penetration was found associated with the strength of geomagnetic activity (Spearman's ρ = 0.54), which is also related to the location of electron flux maximum observed in the recovery phase. Pc5 wave activity persists longer (for up to ≈62 hr) for those storms that produced relativistic electrons. We also investigate the combination of interplanetary conditions necessary to differentiate the response of relativistic electron fluxes to geomagnetic storms. A coupling function that captures the increased reconnection rate at the dayside magnetopause affecting magnetospheric processes which may produce Pc5 wave power offers an additional key to further understanding the outer belt dynamics.

Georgiou, M.↗
DOE OSTI2025

The Effect of Core-Hole Shape on Attosecond Valence Electron Dynamics

Rapid X-ray ionization of a core electron is known to induce the attosecond motion of valence electrons; however, the effect of core-hole shape on the triggered dynamics remains relatively unknown. In this work, the sub-four fs response of prototypical functionalized/heterocyclic/polycyclic molecules was simulated using real-time time-dependent density functional theory (RT-TDDFT), a sudden approximation core-hole, and phenomenologically Auger–Meitner (AM) decay. These molecules included fluorobenzene, chlorobenzene, bromobenzene, phenol, thiophenol, pyridine, phosphorus, and azulene. It is observed that the valence electron dynamics are essentially independent of the core-hole created, provided that it is ionized from an inner-shell orbital and not an inner-valence orbital. This has broad implications for free-electron laser studies of X-ray pumped attosecond processes since the flexibility in edge allows for a wide range of experimental modalities, core-holes with longer AM lifetimes, and molecular targets.

aromatic compounds↗
NASA NTRS1977

Charged-particle absorption by Io

The electrostatic field associated with the rotation of Jupiter, relative to the rest frame of Io, would be distorted if the satellite were an electrical conductor. An idealized two-dimensional model of the distorted electric-field configuration, in the limit of a perfectly conducting satellite or satellite ionosphere, has been constructed and used to trace the adiabatic guiding-center trajectories of energetic protons and electrons across Jupiter's magnetic field lines, which are taken as rectilinear. The adiabatic trajectories of very low-energy particles (cold plasma) are found to avoid the satellite and escape absorption. In the limit of very high particle energies, the adiabatic trajectories are undistorted, and absorption proceeds as if Io were an insulator. The interpolation between these limits is monotonic for protons, such that Io sweeps out a drift shell half as wide as the satellite for first invariants of the order of 1 GeV per gauss. The situation for electrons is more complicated, and no absorption from adiabatic trajectories is found at first invariants not exceeding 46 GeV per gauss. Electrons having first invariants of at least 50 GeV per gauss are typically swept out of drift shells wider than the satellite itself. However, electrons can impact only a portion of Io's exposed hemisphere for first invariants of 50-200 GeV per gauss. Thus, the particle-absorbing characteristics of an electrically conducting Jovian satellite are found to depend on both the species and the energy of the incident particle, and the satellite's particle-absorbing cross section differs systematically from its geometric cross section.

Schulz, M.↗
DOE OSTI2025

Probing Electronic Coherence between Core-Level Vacancies at Different Atomic Sites

The detailed understanding of electronic coherence in quantum systems requires measurements on the attosecond timescale. Attosecond x-ray pulses enable the study of electronic coherence in core-excited molecular systems. Here we report on the coherent motion of electrons in the 1,1-difluoroethylene ion following ionization of the K shell of the two nonequivalent carbon sites with a subfemtosecond x-ray pulse. Using the angular streaking technique to track the Auger-Meitner decay, we observe temporal modulations of the emission, indicating the electronic coherence of the core-excited ionic states, and extract a 6.5 ± 0.8 fs average lifetime of the core-level vacancies. A quantum-mechanical model is employed to interpret the measurement, and we find the observed temporal modulations are independent of charge density oscillations. This work opens a new regime of coherent electronic motion, beyond charge migration, where electronic coherence manifests in the nonlocal quantum correlation between atomic sites while charge density oscillation is absent. Our results broaden the landscape of electronic coherence in molecular systems. Published by the American Physical Society 2025

Wang, Jun (ORCID:000000031962895X)↗