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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Atmospheric Excitation of Planetary Normal Modes

The objectives of this study were to: (1) understand the phenomenon of continuous free oscillations of the Earth and (2) examine the idea of using this phenomenon for planetary seismology. We first describe the results on (1) and present our evaluations of the idea (2) in the final section. In 1997, after almost forty years since the initial attempt by Benioff et al, continuous free oscillations of the Earth were discovered. Spheroidal fundamental modes between 2 and 7 millihertz are excited continuously with acceleration amplitudes of about 0.3-0.5 nanogals. The signal is now commonly found in virtually all data recorded by STS-1 type broadband seismometers at quiet sites. Seasonal variation in amplitude and the existence of two coupled modes between the atmosphere and the solid Earth support that these oscillations are excited by the atmosphere. Stochastic excitation due to atmospheric turbulence is a favored mechanism, providing a good match between theory and data. The atmosphere has ample energy to support this theory because excitation of these modes require only 500-10000 W whereas the atmosphere contains about 117 W of kinetic energy. An application of this phenomenon includes planetary seismology, because other planets may be oscillating due to atmospheric excitation. The interior structure of planets could be learned by determining the eigenfrequencies in the continuous free oscillations. It is especially attractive to pursue this idea for tectonically quiet planets, since quakes may be too infrequent to be recorded by seismic instruments.

Tanimoto, Toshiro↗

Test of Hydrogen-Oxygen PEM Fuel Cell Stack at NASA Glenn Research Center

This paper describes performance characterization tests of a 64 cell hydrogen oxygen PEM fuel cell stack at NASA Glenn Research Center in February 2003. The tests were part of NASA's ongoing effort to develop a regenerative fuel cell for aerospace energy storage applications. The purpose of the tests was to verify capability of this stack to operate within a regenerative fuel cell, and to compare performance with earlier test results recorded by the stack developer. Test results obtained include polarization performance of the stack at 50 and 100 psig system pressure, and a steady state endurance run at 100 psig. A maximum power output of 4.8 kWe was observed during polarization runs, and the stack sustained a steady power output of 4.0 kWe during the endurance run. The performance data obtained from these tests compare reasonably close to the stack developer's results although some additional spread between best to worst performing cell voltages was observed. Throughout the tests, the stack demonstrated the consistent performance and repeatable behavior required for regenerative fuel cell operation.

Bents, David J.↗

Monolithic Interconnected Modules (MIMs) for Thermophotovoltaic Energy Conversion

Monolithic Interconnected Modules (MIM) are under development for thermophotovoltaic (TPV) energy conversion applications. MIM devices are typified by series-interconnected photovoltaic cells on a common, semi-insulating substrate and generally include rear-surface infrared (IR) reflectors. The MIM architecture is being implemented in InGaAsSb materials without semi-insulating substrates through the development of alternative isolation methodologies. Motivations for developing the MIM structure include: reduced resistive losses, higher output power density than for systems utilizing front surface spectral control, improved thermal coupling and ultimately higher system efficiency. Numerous design and material changes have been investigated since the introduction of the MIM concept in 1994. These developments as well as the current design strategies are addressed.

Wilt, David↗

Isothermal Calorimetric Observations of the Effect of Welding on Compatibility of Stainless Steels with High-Test Hydrogen Peroxide Propellant

High-Test Hydrogen Peroxide (HTP) is receiving renewed interest as a monopropellant and as the oxidizer for bipropellant systems. HTP is hydrogen peroxide having concentrations ranging from 70 to 98%. In these applications the energy and oxygen released during decomposition of HTP is used for propulsion. In propulsion systems components must be fabricated and connected using available joining processes. Welding is a common joining method for metallic components. The goal of this study was to compare the HTP compatibility of welded vs. unwelded stainless steel.

Gostowski, Rudy↗

Solar Schematic

The home shown at right is specially designed to accommodate solar heating units; it has roof planes in four directions, allowing placement of solar collectors for best exposure to the sun. Plans (bottom) and complete working blueprints for the solar-heated house are being marketed by Home Building Plan Service, Portland, Oregon. The company also offers an inexpensive schematic (center) showing how a homeowner only moderately skilled in the use of tools can build his own solar energy system, applicable to new or existing structures. The schematic is based upon the design of a low-cost solar home heating system built and tested by NASA's Langley Research Center; used to supplement a warm-air heating system, it can save the homeowner about 40 percent of his annual heating bill for a modest investment in materials and components. Home Building Plan Service saved considerable research time by obtaining a NASA technical report which details the Langley work. The resulting schematic includes construction plans and simplified explanations of solar heat collection, collectors and other components, passive heat factors, domestic hot water supply and how to work with local heating engineers.

Source record↗

Alignment System for Full-Shell Replicated X-Ray Mirrors

We are developing grazing-incidence x-ray optics for high-energy astrophysical applications using the electroformnickel replication process. For space-based applications these optics must be light-weight yet stable, which dictates the use of very-thin-walled full-shell mirrors. Such shells have been fabricated with resolution as good as 11 arcsec for hard x-rays, and technology enhancements under development at MSFC are aimed at producing mirrors with resolution better than 10 arcsec. The challenge, however, is to preserve this resolution during mounting and assembly. We present here a status report on a mounting and alignment system currently under development at Marshall Space Flight Center designed to meet this challenge.

Gubarev, Mikhail↗

Hard X-ray Optics Technology Development for Astronomy at the Marshall Space Flight Center

Grazing-incidence telescopes based on Wolter 1 geometry have delivered impressive advances in astrophysics at soft-x-ray wavelengths, while the hard xray region remains relatively unexplored at fine angular resolution and high sensitivities. The ability to perform ground-breaking science in the hard-x-ray energy range had been the motivation for technology developments aimed at fabricating low-cost, light-weight, high-quality x-ray mirrors. Grazing-incidence x-ray optics for high-energy astrophysical applications is being developed at MSFC using the electroform-nickel replication process.

Gubarev, Mikhail↗

Correcting Thermal Deformations in an Active Composite Reflector

Large, high-precision composite reflectors for future space missions are costly to manufacture, and heavy. An active composite reflector capable of adjusting shape in situ to maintain required tolerances can be lighter and cheaper to manufacture. An active composite reflector testbed was developed that uses an array of piezoelectric composite actuators embedded in the back face sheet of a 0.8-m reflector panel. Each individually addressable actuator can be commanded from 500 to +1,500 V, and the flatness of the panel can be controlled to tolerances of 100 nm. Measuring the surface flatness at this resolution required the use of a speckle holography interferometer system in the Precision Environmental Test Enclosure (PETE) at JPL. The existing testbed combines the PETE for test environment stability, the speckle holography system for measuring out-of-plane deformations, the active panel including an array of individually addressable actuators, a FLIR thermal camera to measure thermal profiles across the reflector, and a heat source. Use of an array of flat piezoelectric actuators to correct thermal deformations is a promising new application for these actuators, as is the use of this actuator technology for surface flatness and wavefront control. An isogrid of these actuators is moving one step closer to a fully active face sheet, with the significant advantage of ease in manufacturing. No extensive rib structure or other actuation backing structure is required, as these actuators can be applied directly to an easy-to-manufacture flat surface. Any mission with a surface flatness requirement for a panel or reflector structure could adopt this actuator array concept to create lighter structures and enable improved performance on orbit. The thermal environment on orbit tends to include variations in temperature during shadowing or changes in angle. Because of this, a purely passive system is not an effective way to maintain flatness at the scale of microns over several meters. This technology is specifically referring to correcting thermal deformations of a large, flat structure to a specified tolerance. However, the underlying concept (an array of actuators on the back face of a panel for correcting the flatness of the front face) could be extended to many applications, including energy harvesting, changing the wavefront of an optical system, and correcting the flatness of an array of segmented deployable panels.

Bradford, Samuel C.↗

NASA Tech Briefs, November 2012

The topics include: Visual System for Browsing, Analysis, and Retrieval of Data (ViSBARD); Time-Domain Terahertz Computed Axial Tomography NDE System; Adaptive Sampling of Time Series During Remote Exploration; A Tracking Sun Photometer Without Moving Parts; Surface Temperature Data Analysis; Modular, Autonomous Command and Data Handling Software with Built-In Simulation and Test; In-Situ Wire Damage Detection System; Amplifier Module for 260-GHz Band Using Quartz Waveguide Transitions; Wideband Agile Digital Microwave Radiometer; Buckyball Nucleation of HiPco Tubes; FACT, Mega-ROSA, SOLAROSA; An Integrated, Layered-Spinel Composite Cathode for Energy Storage Applications; Engineered Multifunctional Surfaces for Fluid Handling; Polyolefin-Based Aerogels; Adjusting Permittivity by Blending Varying Ratios of SWNTs; Gravity-Assist Mechanical Simulator for Outreach; Concept for Hydrogen-Impregnated Nanofiber/Photovoltaic Cargo Stowage System; DROP: Durable Reconnaissance and Observation Platform; Developing Physiologic Models for Emergency Medical Procedures Under Microgravity; Spectroscopic Chemical Analysis Methods and Apparatus; Low Average Sidelobe Slot Array Antennas for Radiometer Applications; Motion-Corrected 3D Sonic Anemometer for Tethersondes and Other Moving Platforms; Water Treatment Systems for Long Spaceflights; Microchip Non-Aqueous Capillary Electrophoresis (MicronNACE) Method to Analyze Long-Chain Primary Amines; Low-Cost Phased Array Antenna for Sounding Rockets, Missiles, and Expendable Launch Vehicles; Mars Science Laboratory Engineering Cameras; Seismic Imager Space Telescope; Estimating Sea Surface Salinity and Wind Using Combined Passive and Active L-Band Microwave Observations; A Posteriori Study of a DNS Database Describing Super critical Binary-Species Mixing; Scalable SCPPM Decoder; QuakeSim 2.0; HURON (HUman and Robotic Optimization Network) Multi-Agent Temporal Activity Planner/Scheduler; MPST Software: MoonKommand

Source record↗

Low Temperature Double-layer Capacitors with Improved Energy Density: An Overview of Recent Development Efforts

Electrochemical double-layer capacitors are finding increased use in a wide range of energy storage applications, particularly where high pulse power capabilities are required. Double-layer capacitors store charge at a liquid/solid interface, making them ideal for low temperature power applications, due to the facile kinetic processes associated with the rearrangement of the electrochemical double-layer at these temperatures. Potential low temperature applications include hybrid and electric vehicles, operations in polar regions, high altitude aircraft and aerospace avionics, and distributed environmental and structural health monitoring. State-of-the-art capacitors can typically operate to -40 C, with a subsequent degradation in power performance below room temperature. However, recent efforts focused on advanced electrolyte and electrode systems can enable operation to temperatures as low as -70 C, with capacities similar to room temperature values accompanied by reasonably low equivalent series resistances. This presentation will provide an overview of recent development efforts to extend and improve the wide temperature performance of these devices.

Supercapacitors↗

RadWorks Project. ISS REM - to - BIRD - to - HERA: The Evolution of a Technology

The advancement of particle detectors based on technologies developed for use in high-energy physics applications has enabled the development of a completely new generation of compact low-power active dosimeters and area monitors for use in space radiation environments. One such device, the TimePix, is being developed at CERN, and is providing the technology basis for the most recent line of radiation detection devices being developed by the NASA AES RadWorks project. The most fundamental of these devices, an ISS-Radiation Environment Monitor (REM), is installed as a USB device on ISS where it is monitoring the radiation environment on a perpetual basis. The second generation of this TimePix technology, the BIRD (Battery-operated Independent Radiation Detector), was flown on the NASA EFT-1 flight in December 2014. Data collected by BIRD was the first data made available from the Trapped Belt region of the Earth's atmosphere in over 40 years. The 3rdgeneration of this technology, the HERA (Hybrid Electronic Radiation Assessor), is planned to be integrated into the Orion EM-1, and EM-2 vehicles where it will monitor the radiation environment. For the EM-2 flight, HERA will provide Caution and Warning notification for SPEs as well as real time dose measurements for crew members. The development of this line of radiation detectors provide much greater information and characterization of charged particles in the space radiation environment than has been collected in the past, and in the process provide greater information to inform crew members of radiation related risks, while being very power and mass efficient.

McLeod, Catherine D.↗

Synthesis and Modification of Holey Graphene for Energy Storage

Porous graphene materials have recently drawn significant interest for energy storage applications due to the effective use of the graphitic surface area provided by the pores. Holey graphene is a type of porous graphene with pores in the form of physical through thickness holes. This type of porous graphene provides a unique morphology that allows for effective transport of molecular species through the graphene plane. Therefore, as we recently demonstrated, holey graphene could be advantageous in the preparation of electrodes in supercapacitors with high volumetric performance.1 We have developed methodologies to scalably prepare holey graphene materials with or without the use of catalysts (Figure 1).1,2 In this presentation, we will discuss the choice of synthetic strategies and experimental conditions on the morphology and physical properties of holey graphene (Figure 2) and the effect on their electrochemical properties. We will also present the results on the further modification of holey graphene to study their physical and chemical properties, especially with regard to the stability and chemical reactivity of carbons located around the edges of the holes.

Lin, Yi↗

TPSAS-NF1676L-34417-DND

A boron nitride nanotube (BNNT), an electrically-insulating counterpart of a carbon nanotube (CNT), is a great nanofiller candidate for ferroelectric polymeric nanocomposites due to BNNT?s exceptional properties in piezoelectricity, thermal stability, mechanical strength, and radiation shielding capability. Fast and high-yield polar crystallization of polyvinylidene fluoride (PVDF) was accomplished by incorporating BNNTs as a nucleating agent. As-fabricated BNNT-PVDF nanocomposites were characterized by Fourier-transform infrared spectroscopy (FTIR), wide-angle X-ray diffraction (XRD), and differential scanning calorimetry (DSC) to identify and quantify chain conformations. Besides, piezoelectric constants, d33 of BNNT-PVDF nanocomposites were measured and compared with that of a mechanically drawn beta phase polar PVDF. The polar transformation due to BNNT incorporation has a great advantage over conventional beta or gamma transformation methods that require (1) mechanical drawing often resulting in defects or (2) high-temperature annealing for an extended time. In addition to the fast polar crystallization, BNNTs had a role of reinforcement of the polymer matrix. The improved Young?s modulus and electromechanical coupling coefficient of BNNT-PVDF nanocomposites indicated potential applications in energy harvesting under harsh environments such as large deformation, wide temperature cycles, and high radiation.

Dongwon Lee↗

Designing Molten Salt Eutectics: A Combined Thermodynamic Modeling and Machine Learning Approach

Designing stable electrolytes with target properties is an important challenge in realizing next generation energy storage devices. Molten salt eutectics-based electrolytes are known for their stability with minimal parasitic reactions when compared to traditional organic electrolytes and are an attractive option for different battery chemistries. The operating temperature of the molten salt batteries depends on the melting temperature of the eutectic and hence there is a necessity to discover novel low melting temperature molten salt eutectic mixtures for energy storage applications. In this work we develop a high throughput computational screening approach for molten salt mixtures using thermodynamic modeling and machine learning (ML). COSMO-SAC model and ML approaches were independently developed based on the existing experimental data and these models were further used to predict the eutectic melting temperature and composition of several new binary, ternary, and quaternary mixtures. We show that combining ML and thermodynamic modeling strategies is effective in exploring the vast design space of molten salt mixtures.

Thermodynamics↗

Designing Molten Salt Eutectics

Designing stable electrolytes with target properties is an important challenge in realizing next generation energy storage devices. Molten salt eutectics-based electrolytes are known for their stability with minimal parasitic reactions when compared to traditional organic electrolytes and are an attractive option for different battery chemistries. The operating temperature of the molten salt batteries depends on the melting temperature of the eutectic and hence there is a necessity to discover novel low melting temperature molten salt eutectic mixtures for energy storage applications. In this work we develop a high throughput computational screening approach for molten salt mixtures using thermodynamic modeling and machine learning (ML). COSMO-SAC model and ML approaches were independently developed based on the existing experimental data and these models were further used to predict the eutectic melting temperature and composition of several new binary, ternary, and quaternary mixtures. We show that combining ML and thermodynamic modeling strategies is effective in exploring the vast design space of molten salt mixtures.

Ashwin Ravichandran↗

Advances in Detector-Integrated Filter Coatings for the Far Ultraviolet

We report on the continued development of multilayer optical coatings on back-illuminated silicon imaging sensors in order to enhance the functionality of such systems at ultraviolet wavelengths. This includes the development metal-dielectric filter structures to enable solar-blind operation, and graded thickness coatings to tune the spatial response of a detector system to the dispersion of a spectrometer. Such systems can maintain the high internal quantum efficiency afforded by the delta-doping process utilized at NASA JPL, while also providing long-wavelength rejection or a spatially optimized efficiency (or both). We present the characterization of CCD and CMOS image sensors incorporating these processes, and describe the atomic layer deposition coating processes. Such detectors are currently being developed for ground-based high energy physics applications as well as NASA orbital astrophysics instruments operating at wavelengths shorter than 200 nm.

Nikzad, Shouleh↗

Special Grain Boundaries in NiTi Shape Memory Alloys as Sites for Preferential Martensite Nucleation

Shape memory alloys (SMAs) exhibit unique thermomechanical properties due to a reversible martensitic transformation which can be controlled via chemical composition and microstructural features. Among the latter, grain boundaries (GBs) are key in determining how the transformation nucleates and propagates. We performed molecular dynamics simulations to examine the roles of a few special GBs in the austenite phase of NiTi. The GBs can act as preferential host sites for martensite nuclei which can substantially lower the nucleation barrier for transformation and thereby result in reduced thermal hysteresis, an important SMA property for cyclic actuation applications. Free energy calculations show that a characteristic of these GBs is a negative entropy which drops sharply close to the transformation temperature, an anomalous behavior for GBs with fixed composition which is a direct result of the martensitic transformation. We discuss implications of these results with respect to SMA processing techniques for achieving improved properties.

Gabriel Plummer↗

Wire-break Ignition Testing of Materials for Spacesuit Fire Hazard Control

The input design constraints applied to the extravehicular activity (EVA) spacesuit pose a significant challenge for mitigation of fire hazards. To minimize fatigue and increase comfort of the crewmember operating the suit, the suit pressure is lowered below sea level conditions with typical EVA suit designs operating with 4.3 psia (29.7 kPa). With the lowered operating pressures and the use of closed-loop life support, the suit requires elevated concentrations of oxygen, typically >95%. At these oxygen concentrations, nearly the entirety of the suit internal materials are flammable. This leaves one remaining possible control leg of the fire triangle: ignition sources. Since the Gemini and Apollo programs, this has been a risk that has undergone constant reassessment, with a focus on improved mitigation. After the Apollo I fire, an arc ignition method was developed and used to quantify ignition thresholds for in-suit materials resulting in a current limit for powered in-suit devices applied to all subsequent suit designs. After the discovery of a frayed spacesuit biomed cable on STS-113 during the Shuttle Program, the previous arcing method was repeated with additional methods developed to extend the testing further. One of those methods was wire-break ignition testing, in which the current in a single strand of wire was progressively increased, preheating the material in proximity with a resultant break and the application of a reasonably repeatable arc to ignite the material, all while exposed in the selected environment. This method was used to test a suite of spacesuit materials providing relative performance with respect to ignition with this configuration for application of energy. This paper discusses extension of the current data set to address recent material additions, lowering of energy test levels for quantification of materials too low to measure in previous testing, as well as future plans to improve this method.

Colin Campbell↗